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1

Jiang, He, Jibiao Jin, Zijie Wang, et al. "Constructing Donor-Resonance-Donor Molecules for Acceptor-Free Bipolar Organic Semiconductors." Research 2021 (February 9, 2021): 1–10. http://dx.doi.org/10.34133/2021/9525802.

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Organic semiconductors with bipolar transporting character are highly attractive as they offer the possibility to achieve high optoelectronic performance in simple device structures. However, the continual efforts in preparing bipolar materials are focusing on donor-acceptor (D-A) architectures by introducing both electron-donating and electron-withdrawing units into one molecule in static molecular design principles. Here, we report a dynamic approach to construct bipolar materials using only electron-donating carbazoles connected by N-P=X resonance linkages in a donor-resonance-donor (D-r-D)
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2

Marszalek, Tomasz, Maciej Gazicki-Lipman, and Jacek Ulanski. "Parylene C as a versatile dielectric material for organic field-effect transistors." Beilstein Journal of Nanotechnology 8 (July 28, 2017): 1532–45. http://dx.doi.org/10.3762/bjnano.8.155.

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An emerging new technology, organic electronics, is approaching the stage of large-scale industrial application. This is due to a remarkable progress in synthesis of a variety of organic semiconductors, allowing one to design and to fabricate, so far on a laboratory scale, different organic electronic devices of satisfactory performance. However, a complete technology requires upgrading of fabrication procedures of all elements of electronic devices and circuits, which not only comprise active layers, but also electrodes, dielectrics, insulators, substrates and protecting/encapsulating coating
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3

Feng, Cheng, Xihong Mi, Dingwen Zhong, et al. "Chemically Bonded N-PDI-P/WO3 Organic-Inorganic Heterojunction with Improved Photoelectrochemical Performance." Catalysts 10, no. 1 (2020): 122. http://dx.doi.org/10.3390/catal10010122.

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The chemical bonding of bandgap adjustable organic semiconductors with inorganic semiconducting materials is effective in constructing a high-performance heterogeneous photoanode. In this study, a new asymmetric perylene diimide derivative molecule (N-PDI-P) was synthesized by connecting tert-butoxycarbonyl on an N-site at one end of a PDI molecule through methylene and connecting naphthalene directly onto the other end. This molecule was bonded onto the WO3 film surface, thereby forming the photoanode of organic-inorganic heterojunction. Under light illumination, the photocurrent density of c
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4

Wu, Jieyun, Qing Li, Wen Wang, and Kaixin Chen. "Optoelectronic Properties and Structural Modification of Conjugated Polymers Based on Benzodithiophene Groups." Mini-Reviews in Organic Chemistry 16, no. 3 (2019): 253–60. http://dx.doi.org/10.2174/1570193x15666180406144851.

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Organic conjugated materials have shown attractive applications due to their good optoelectronic properties, which enable them solution processing techniques in organic optoelectronic devices. Many conjugated materials have been investigated in polymer solar cells and organic field-effect transistors. Among those conjugated materials, Benzo[1,2-b:4,5-b′]dithiophene (BDT) is one of the most employed fused-ring building groups for the synthesis of conjugated materials. The symmetric and planar conjugated structure, tight and regular stacking of BDT can be expected to exhibit the excellent carrie
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5

INOKUCHI, Hiroo. "The construction of novel organic semiconductors." Nihon Kessho Gakkaishi 30, no. 1 (1988): 9–17. http://dx.doi.org/10.5940/jcrsj.30.9.

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6

Heimel, Georg, Ingo Salzmann, Steffen Duhm, and Norbert Koch. "Design of Organic Semiconductors from Molecular Electrostatics†." Chemistry of Materials 23, no. 3 (2011): 359–77. http://dx.doi.org/10.1021/cm1021257.

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7

Baumeier, Björn, Falk May, Christian Lennartz, and Denis Andrienko. "Challenges for in silico design of organic semiconductors." Journal of Materials Chemistry 22, no. 22 (2012): 10971. http://dx.doi.org/10.1039/c2jm30182b.

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8

Henson, Zachary B., Klaus Müllen, and Guillermo C. Bazan. "Design strategies for organic semiconductors beyond the molecular formula." Nature Chemistry 4, no. 9 (2012): 699–704. http://dx.doi.org/10.1038/nchem.1422.

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9

Nishida, Jun-ichi, and Yoshiro Yamashita. "Molecular Design of Organic Semiconductors for High Performance Organic Field-effect Transistors." Journal of Synthetic Organic Chemistry, Japan 66, no. 5 (2008): 515–24. http://dx.doi.org/10.5059/yukigoseikyokaishi.66.515.

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10

Okamoto, Toshihiro, Shohei Kumagai, Eiji Fukuzaki, et al. "Robust, high-performance n-type organic semiconductors." Science Advances 6, no. 18 (2020): eaaz0632. http://dx.doi.org/10.1126/sciadv.aaz0632.

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Organic semiconductors (OSCs) are important active materials for the fabrication of next-generation organic-based electronics. However, the development of n-type OSCs lags behind that of p-type OSCs in terms of charge-carrier mobility and environmental stability. This is due to the absence of molecular designs that satisfy the requirements. The present study describes the design and synthesis of n-type OSCs based on challenging molecular features involving a π-electron core containing electronegative N atoms and substituents. The unique π-electron system simultaneously reinforces both electron
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11

Mei, Jianguo, Ying Diao, Anthony L. Appleton, Lei Fang, and Zhenan Bao. "Integrated Materials Design of Organic Semiconductors for Field-Effect Transistors." Journal of the American Chemical Society 135, no. 18 (2013): 6724–46. http://dx.doi.org/10.1021/ja400881n.

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12

Hathwar, Venkatesha, Mads Jørgensen, Mattia Sist, et al. "Material Design Inputs from Charge Density Analysis in Organic Semiconductors." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C1552. http://dx.doi.org/10.1107/s2053273314084472.

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In recent years, semiconducting organic materials have attracted a considerable amount of interest to develop all-organic or hybrid organic-inorganic electronic devices such as organic light-emitting diodes (OLEDs), organic field-effect transistors (OFETs), or photovoltaic cells. Rubrene (5,6,11,12-tetraphenyltetracene, RUB) is one of the most explored compound in this area as it has nearly 100% fluorescence quantum efficiency in solution. Additionally, the OFET fabricated by vacuum-deposited using orthorhombic rubrene single crystals show p-type characteristics with high mobility up to 20cm2/
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13

Newman, Christopher R., C. Daniel Frisbie, Demetrio A. da Silva Filho, Jean-Luc Brédas, Paul C. Ewbank, and Kent R. Mann. "Introduction to Organic Thin Film Transistors and Design of n-Channel Organic Semiconductors." Chemistry of Materials 16, no. 23 (2004): 4436–51. http://dx.doi.org/10.1021/cm049391x.

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14

Klimovich, I. V., L. I. Leshanskaya, S. I. Troyanov, et al. "Design of indigo derivatives as environment-friendly organic semiconductors for sustainable organic electronics." J. Mater. Chem. C 2, no. 36 (2014): 7621–31. http://dx.doi.org/10.1039/c4tc00550c.

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15

Zhao, Wenrui, Jiamin Ding, Ye Zou, Chong-an Di, and Daoben Zhu. "Chemical doping of organic semiconductors for thermoelectric applications." Chemical Society Reviews 49, no. 20 (2020): 7210–28. http://dx.doi.org/10.1039/d0cs00204f.

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16

Chen, Mengyun, Lijia Yan, Yang Zhao, Imran Murtaza, Hong Meng, and Wei Huang. "Anthracene-based semiconductors for organic field-effect transistors." Journal of Materials Chemistry C 6, no. 28 (2018): 7416–44. http://dx.doi.org/10.1039/c8tc01865k.

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17

Ortiz, Rocío Ponce, Helena Herrera, Carlos Seoane, José L. Segura, Antonio Facchetti, and Tobin J. Marks. "Rational Design of Ambipolar Organic Semiconductors: Is Core Planarity Central to Ambipolarity in Thiophene-Naphthalene Semiconductors?" Chemistry - A European Journal 18, no. 2 (2011): 532–43. http://dx.doi.org/10.1002/chem.201101715.

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18

Jung, Byung Jun, Noah J. Tremblay, Ming-Ling Yeh, and Howard E. Katz. "Molecular Design and Synthetic Approaches to Electron-Transporting Organic Transistor Semiconductors†." Chemistry of Materials 23, no. 3 (2011): 568–82. http://dx.doi.org/10.1021/cm102296d.

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19

Bronstein, Hugo, Christian B. Nielsen, Bob C. Schroeder, and Iain McCulloch. "The role of chemical design in the performance of organic semiconductors." Nature Reviews Chemistry 4, no. 2 (2020): 66–77. http://dx.doi.org/10.1038/s41570-019-0152-9.

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20

Friederich, Pascal, Artem Fediai, Simon Kaiser, Manuel Konrad, Nicole Jung, and Wolfgang Wenzel. "Organic Semiconductors: Toward Design of Novel Materials for Organic Electronics (Adv. Mater. 26/2019)." Advanced Materials 31, no. 26 (2019): 1970188. http://dx.doi.org/10.1002/adma.201970188.

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21

Ward, Jeremy W., Ruipeng Li, Abdulmalik Obaid, et al. "Organic Semiconductors: Rational Design of Organic Semiconductors for Texture Control and Self-Patterning on Halogenated Surfaces (Adv. Funct. Mater. 32/2014)." Advanced Functional Materials 24, no. 32 (2014): 5168. http://dx.doi.org/10.1002/adfm.201470216.

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22

Casalini, Stefano, Carlo Augusto Bortolotti, Francesca Leonardi, and Fabio Biscarini. "Self-assembled monolayers in organic electronics." Chemical Society Reviews 46, no. 1 (2017): 40–71. http://dx.doi.org/10.1039/c6cs00509h.

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23

Ling-Hai, XIE, CHANG Yong-Zheng, GU Ju-Fen та ін. "Design of Organic/Polymeric π-Semiconductors: the Four-Element Principle". Acta Physico-Chimica Sinica 26, № 07 (2010): 1784–94. http://dx.doi.org/10.3866/pku.whxb20100713.

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24

Takimiya, Kazuo, Masahiro Nakano, Hiroyoshi Sugino, and Itaru Osaka. "Design and elaboration of organic molecules for high field-effect-mobility semiconductors." Synthetic Metals 217 (July 2016): 68–78. http://dx.doi.org/10.1016/j.synthmet.2016.02.018.

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25

Guo, Xiaojie, Qiaogan Liao, Eric F. Manley, et al. "Materials Design via Optimized Intramolecular Noncovalent Interactions for High-Performance Organic Semiconductors." Chemistry of Materials 28, no. 7 (2016): 2449–60. http://dx.doi.org/10.1021/acs.chemmater.6b00850.

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26

Kanibolotsky, Alexander L., Nicolas Laurand, Martin D. Dawson, Graham A. Turnbull, Ifor D. W. Samuel, and Peter J. Skabara. "Design of Linear and Star-Shaped Macromolecular Organic Semiconductors for Photonic Applications." Accounts of Chemical Research 52, no. 6 (2019): 1665–74. http://dx.doi.org/10.1021/acs.accounts.9b00129.

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27

Jin, Ruifa, Fengxin Wang, Ruijie Guan, Xiaomin Zheng, and Tao Zhang. "Design of perylene-diimides-based small-molecules semiconductors for organic solar cells." Molecular Physics 115, no. 14 (2017): 1591–97. http://dx.doi.org/10.1080/00268976.2017.1308028.

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28

Xie, Wenjun, Weicong Huang, Lingzhi Tu, Hu Shi, and Hongguang Liu. "Design of one-dimensional organic semiconductors with high intrinsic electron mobilities: lessons from computation." Journal of Materials Chemistry C 9, no. 10 (2021): 3620–25. http://dx.doi.org/10.1039/d0tc05817c.

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29

Thorley, Karl J., and Chad Risko. "Mapping the configuration dependence of electronic coupling in organic semiconductors." Journal of Materials Chemistry C 4, no. 17 (2016): 3825–32. http://dx.doi.org/10.1039/c5tc03765d.

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30

Dhar, Joydeep, Ulrike Salzner, and Satish Patil. "Trends in molecular design strategies for ambient stable n-channel organic field effect transistors." Journal of Materials Chemistry C 5, no. 30 (2017): 7404–30. http://dx.doi.org/10.1039/c6tc05467f.

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31

Zeng, Xingwei, Dongwei Zhang, Yanan Zhu, et al. "Insight into in-plane isotropic transport in anthracene-based organic semiconductors." Journal of Materials Chemistry C 7, no. 45 (2019): 14275–83. http://dx.doi.org/10.1039/c9tc03915e.

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32

Niazi, Muhammad Rizwan, Ehsan Hamzehpoor, Pegah Ghamari, Igor F. Perepichka, and Dmitrii F. Perepichka. "Nitroaromatics as n-type organic semiconductors for field effect transistors." Chemical Communications 56, no. 47 (2020): 6432–35. http://dx.doi.org/10.1039/d0cc01236j.

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The utility of the NO<sub>2</sub>-group in the design of organic semiconductors is demonstrated by fabricating OFETs with 5 nitrofluorenone derivatives and analyzing the effects of molecular and crystal structure on their charge transport characteristics.
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33

Yahiro, Masayuki, Tomo Sakanoue, Hiroyuki Uchiuzou, Takahito Oyamada, Akio Toshimitsu, and Chihaya Adachi. "Material Design of Organic Semiconductors for Light Emitting Organic Field-effect Transistors and Their Device Characteristics." Journal of Synthetic Organic Chemistry, Japan 66, no. 5 (2008): 493–503. http://dx.doi.org/10.5059/yukigoseikyokaishi.66.493.

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34

Gao, Xike, and Yunbin Hu. "Development of n-type organic semiconductors for thin film transistors: a viewpoint of molecular design." J. Mater. Chem. C 2, no. 17 (2014): 3099–117. http://dx.doi.org/10.1039/c3tc32046d.

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35

Kolaczkowski, Matthew A., Andrés Garzón-Ruiz, Akash Patel, et al. "Design and Synthesis of Annulated Benzothiadiazoles via Dithiolate Formation for Ambipolar Organic Semiconductors." ACS Applied Materials & Interfaces 12, no. 47 (2020): 53328–41. http://dx.doi.org/10.1021/acsami.0c16056.

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36

Liu, Chang, Ming-Hua Zeng, Yuexing Zhang, Paul M. Lahti, and Dimitrios Maroudas. "Theoretical design of new cyclopentadithiophene-based organic semiconductors with tunable nature and performance." Synthetic Metals 258 (December 2019): 116196. http://dx.doi.org/10.1016/j.synthmet.2019.116196.

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37

Shan, Bowen, and Qian Miao. "Molecular design of n-type organic semiconductors for high-performance thin film transistors." Tetrahedron Letters 58, no. 20 (2017): 1903–11. http://dx.doi.org/10.1016/j.tetlet.2017.04.023.

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38

Salzmann, Ingo, Georg Heimel, Martin Oehzelt, Stefanie Winkler, and Norbert Koch. "Molecular Electrical Doping of Organic Semiconductors: Fundamental Mechanisms and Emerging Dopant Design Rules." Accounts of Chemical Research 49, no. 3 (2016): 370–78. http://dx.doi.org/10.1021/acs.accounts.5b00438.

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39

Shen, Hong-Yi, Lei He, Ping-Ping Shi, and Qiong Ye. "Lead-free organic–inorganic hybrid semiconductors and NLO switches tuned by dimensional design." Journal of Materials Chemistry C 9, no. 12 (2021): 4338–43. http://dx.doi.org/10.1039/d1tc00278c.

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40

Zhang, Chuang, Yongli Yan, Yong Sheng Zhao, and Jiannian Yao. "From Molecular Design and Materials Construction to Organic Nanophotonic Devices." Accounts of Chemical Research 47, no. 12 (2014): 3448–58. http://dx.doi.org/10.1021/ar500192v.

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41

Kumari, Anu, Sandeep Kaushal, and Prit Pal Singh. "Bimetallic metal organic frameworks heterogeneous catalysts: Design, construction, and applications." Materials Today Energy 20 (June 2021): 100667. http://dx.doi.org/10.1016/j.mtener.2021.100667.

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42

Kirsch, Peer, Qiong Tong, and Harald Untenecker. "Crystal design using multipolar electrostatic interactions: A concept study for organic electronics." Beilstein Journal of Organic Chemistry 9 (November 5, 2013): 2367–73. http://dx.doi.org/10.3762/bjoc.9.272.

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Using a simple synthetic protocol, heterohexacene analogues with a quadrupolar distribution of partial charges are readily available. In contrast to most other acenes, these compounds crystallize with a slipped-stack, brickwork-like packing which is mainly controlled by electrostatic interactions. This type of packing offers an advantage for organic semiconductors, because it allows more isotropic charge transport compared to the “herring bone” stacking observed for other acenes.
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43

Mike, Jared F., Jeremy J. Inteman, Arkady Ellern, and Malika Jeffries-EL. "Facile Synthesis of 2,6-Disubstituted Benzobisthiazoles: Functional Monomers for the Design of Organic Semiconductors." Journal of Organic Chemistry 75, no. 2 (2010): 495–97. http://dx.doi.org/10.1021/jo9023864.

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44

Pathan, Abrarkhan M., Dhawal H. Agrawal, Pina M. Bhatt, Hitarthi H. Patel, and U. S. Joshi. "Design and Construction of Low Temperature Attachment for Commercial AFM." Solid State Phenomena 209 (November 2013): 137–42. http://dx.doi.org/10.4028/www.scientific.net/ssp.209.137.

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With the rapid advancements in the field of nanoscience and nanotechnology, scanning probe microscopy has become an integral part of a typical R&amp;D lab. Atomic force microscope (AFM) has become a familiar name in this category. The AFM measures the forces acting between a fine tip and a sample. The tip is attached to the free end of a cantilever and is brought very close to a surface. Attractive or repulsive forces resulting from interactions between the tip and the surface will cause a positive or negative bending of the cantilever. The bending is detected by means of a laser beam, which i
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45

LI, YUNING, and BENG S. ONG. "HIGH MOBILITY CONJUGATED POLYMER SEMICONDUCTORS FOR ORGANIC THIN FILM TRANSISTORS." COSMOS 05, no. 01 (2009): 59–77. http://dx.doi.org/10.1142/s0219607709000427.

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Organic thin film transistors (OTFTs) are promising candidates as alternatives to silicon TFTs for applications where light weight, large area and flexibility are required. OTFTs have shown potential for cost effective fabrication using solution deposition techniques under mild conditions. However, two major issues must be addressed prior to the commercialization of OTFT-based electronics: (i) low charge mobilities and (ii) insufficient air stability. This article reviews recent progress in the design and development of thiophene-based polymer semiconductors as channel materials for OTFTs. To
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46

Garnier, Francis, Abderrahim Yassar, Ryad Hajlaoui, et al. "Molecular engineering of organic semiconductors: design of self-assembly properties in conjugated thiophene oligomers." Journal of the American Chemical Society 115, no. 19 (1993): 8716–21. http://dx.doi.org/10.1021/ja00072a026.

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47

Takimiya, Kazuo, Tatsuya Yamamoto, Hideaki Ebata, and Takafumi Izawa. "Design strategy for air-stable organic semiconductors applicable to high-performance field-effect transistors." Science and Technology of Advanced Materials 8, no. 4 (2007): 273–76. http://dx.doi.org/10.1016/j.stam.2007.02.010.

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48

Nakano, Masahiro, Itaru Osaka, Daisuke Hashizume та Kazuo Takimiya. "α-Modified Naphthodithiophene Diimides—Molecular Design Strategy for Air-Stable n-Channel Organic Semiconductors". Chemistry of Materials 27, № 18 (2015): 6418–25. http://dx.doi.org/10.1021/acs.chemmater.5b02601.

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49

Li, Yuheng, and Kesong Yang. "High-throughput computational design of organic–inorganic hybrid halide semiconductors beyond perovskites for optoelectronics." Energy & Environmental Science 12, no. 7 (2019): 2233–43. http://dx.doi.org/10.1039/c9ee01371g.

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50

Zhang, Weifeng, and Gui Yu. "Rational design of diarylethylene-based polymeric semiconductors for high-performance organic field-effect transistors." Journal of Polymer Science Part A: Polymer Chemistry 55, no. 4 (2016): 585–603. http://dx.doi.org/10.1002/pola.28391.

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