Academic literature on the topic 'Organic silane'

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Journal articles on the topic "Organic silane"

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Gross, Thoralf, Helmut Reinke, and Hartmut Oehme. "Geminal bis(hypersilyl) compounds — the synthesis and structure of bis[tris(trimethylsilyl)silyl]silanes." Canadian Journal of Chemistry 78, no. 11 (2000): 1399–404. http://dx.doi.org/10.1139/v00-136.

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Protodesilylation of diphenylsilane with trifluoromethanesulfonic acid and subsequent reaction of the obtained bis(trifluoromethanesulfonyloxy)silane with tris(trimethylsilyl)silyllithium (1) (molar ratio 1:2) afforded bis[tris(trimethylsilyl)silyl]silane (8). Methyl-bis[tris(trimethylsilyl)silyl]silane (3) and phenyl-bis[tris(trimethylsilyl)silyl]silane (10) were obtained by coupling reactions of 1 with MeHSiCl2 or PhHSiCl2, respectively, (2:1). By treatment with HCBr3, the H-silanes 3, 8, and10 were converted into the bromosilanes [(Me3Si)3Si]2SiR1R2 (9: R1 = R2 = Br; 11: R1 = Me, R2 = Br; 1
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Koerwitz, Frederick L., Gerald B. Hammond, and David F. Wiemer. "Synthesis of vinyl silanes from vinyl silane phosphates." Journal of Organic Chemistry 54, no. 4 (1989): 743–47. http://dx.doi.org/10.1021/jo00265a005.

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Ran, Xiao Li, and Tian Yi Li. "Research Progress in Protective Organic Silane Films." Advanced Materials Research 306-307 (August 2011): 1537–40. http://dx.doi.org/10.4028/www.scientific.net/amr.306-307.1537.

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The silane treatment is a new kind of metal surface treatment technique. Compared with the traditional chromate and phosphate treatment, organic silane treatment is friendly to environment. In this paper, the structure, classification and corrosion protection mechanism of silane films were introduced. The application and research progress of protective organic silane films were reviewed.The prospect of organic silane treatment technique was put forward.
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Neves, Rodrigo S., Daiane P. B. Silva, and Artur J. Motheo. "Corrosion Protection of AA7075 Aluminium Alloy by Trimethoxy-Silanes Self-Assembled Monolayers." ISRN Electrochemistry 2013 (April 2, 2013): 1–9. http://dx.doi.org/10.1155/2013/142493.

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This study presents electrochemical data concerning the aluminium alloy AA7075 surface modified by self-assembled monolayers (SAMs) of octadecyl-trimethoxy-silane and propyl-trimethoxy-silane. Polarisation curves have shown SAMs blocking effect, as they partially block the oxygen reduction reaction and displace the corrosion potential to positive values. Electrochemical impedance spectroscopy experiments have suggested that the protective effect comes from the oxide layer stabilization by the organic monolayers, which block the corroding species diffusion to the surface. These results show the
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Linnemannstöns, Marvin, Beate Neumann, Hans-Georg Stammler, and Norbert W. Mitzel. "Synthesis and Structural Diversity of Triaryl(phenylethyl)silanes." Synthesis 52, no. 07 (2020): 1025–34. http://dx.doi.org/10.1055/s-0039-1690785.

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Starting from trichloro(phenylethyl)silane, six differently fluorinated triaryl(phenylethyl)silanes were synthesized by salt elimination reactions and their structures were determined by X-ray diffraction analysis. Tris(pentafluorophenyl)(phenylethyl)silane reveals a folded structure due to intramolecular π-stacking interactions, while those with a lower degree of fluorination show either intermolecular π-stacking or no interplay between the aryl groups. A similar folded structure was observed for (4-methylphenethyl)tris(pentafluorophenyl)silane and [2-(naphth-2-yl)ethyl]tris(pentafluorophenyl
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Wang, Hongxia, Jie Ding, Yuhua Xue, Xungai Wang, and Tong Lin. "Superhydrophobic fabrics from hybrid silica sol-gel coatings: Structural effect of precursors on wettability and washing durability." Journal of Materials Research 25, no. 7 (2010): 1336–43. http://dx.doi.org/10.1557/jmr.2010.0169.

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Particle-containing silica sol was synthesized by co-hydrolysis and co-condensation of two silane precursors, tetraethylorthosilicate (TEOS) and an organic silane composed of a non-hydrolyzable functional group (e.g., alkyl, fluorinated alkyl, and phenyl), and used to produce superhydrophobic coatings on fabrics. It has been revealed that the non-hydrolyzable functional groups in the organic silanes have a considerable influence on the fabric surface wettability. When the functional group was long chain alkyl (C16), phenyl, or fluorinated alkyl (C8), the treated surfaces were highly superhydro
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Palmer, Bentley J., та Ross H. Hill. "The energetics of the oxidative addition of trisubstituted silanes to photochemically generated (η5-C5R5)Mn(CO)2". Canadian Journal of Chemistry 74, № 11 (1996): 1959–67. http://dx.doi.org/10.1139/v96-223.

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The rates for the oxidative addition reaction of trisubstituted silanes (Et3SiH, Et2MeSiH, EtMe2SiH, Et2SiH2) to photochemically generated (η5-C5R5)Mn(CO)2 (R5 = H5, Me5, H4Me) species have been measured for the temperature range 70–125 K. The reactions were carried out in either neat silane or a 50/50, by volume, mixture of methylcyclohexane and silane. The activation energies, determined using Arrhenius law, varied from 2 to 35 kj/mol. The kinetic data fit an isokinetic relationship with an isokinetic temperature of 102 ± 6 K. The results are interpreted in terms of a variation in the loss o
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Weng, Rui, Lian Meng Zhang, Chong Hui Wang, and Shui Ping Wang. "Synthesis of Fluorine-Containing Organic Silane Reagent." Materials Science Forum 620-622 (April 2009): 599–602. http://dx.doi.org/10.4028/www.scientific.net/msf.620-622.599.

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Organic silane perfluorinated octyl sulfonic acid amide is synthesized by compounding aminosilane (N-(β-aminoethyl)-γ-aminopropyl trimethoxy silane) and perfluorinated octyl sulfonic acid fluoride. The results show that the product yield of 88% is achieved when the ratio of perfluorinated octyl sulfonic acid fluoride and aminosilane is maintained at 1:1.1 at 50°C for 2 hours.
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Li, Li, Yun-Long Wei, and Li-Wen Xu. "Organosilicon-Mediated Organic Synthesis (SiMOS): A Personal Account." Synlett 31, no. 01 (2019): 21–34. http://dx.doi.org/10.1055/s-0039-1691496.

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The organosilicon-mediated organic synthesis (SiMOS) has attracted much attention over the recent decades. However, the use of organosilicon reagents with novel catalytic strategies remains to be explored. This Account summarizes our group’s progress mainly based on the application of a wide variety of organosilicon reagents, including allylic silanes, trifluoromethyl silane, acylsilanes, chlorosilanes, hydrosilanes, trimethylsilyldiazomethane, trimethylsiloxyfuran, silanols, α-trimethylsilylmethylacetate, and trimethylsilylcyanide, in catalysis and organic reactions. These transformations wer
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Fournier, Jean-Hugues, Xin Wang, and James D. Wuest. "Derivatives of tetraphenylmethane and tetraphenylsilane: Synthesis of new tetrahedral building blocks for molecular construction." Canadian Journal of Chemistry 81, no. 5 (2003): 376–80. http://dx.doi.org/10.1139/v03-056.

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Useful derivatives of tetraphenylmethane and tetraphenylsilane have been synthesized by efficient methods that give crystalline products without chromatographic purification. New compounds include tetrakis(4-hydroxyphenyl)methane (21), tetrakis(4-formylphenyl)methane (22), tetrakis[(4-hydroxymethyl)phenyl]methane (23), tetrakis(4-bromophenyl)silane (24), tetrakis(4-iodophenyl)silane (25), tetrakis(4-hydroxyphenyl)silane (26), tetrakis[(4-hydroxymethyl)phenyl]silane (27), and tetrakis[(4-chloromethyl)phenyl]silane (28). These compounds are valuable precursors for the construction of complex mol
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Dissertations / Theses on the topic "Organic silane"

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Bexell, Ulf. "Surface Characterisation Using ToF-SIMS, AES and XPS of Silane Films and Organic Coatings Deposited on Metal Substrates." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis : Univ.-bibl. [distributr], 2003. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-3438.

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Joo, Minjung. "Silane terminated macromonomers with nanoparticles and surface segregation of fluorinated moieties." University of Akron / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=akron1478876813425998.

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Kumar, Girdhari. "Development and characterization of novel organic coatings based on biopolymer chitosan." Columbus, Ohio : Ohio State University, 2006. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1164589725.

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Kumar, Girdhari. "Development and characterization of novel organic coatings based on biopolymer chitsan." The Ohio State University, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=osu1164589725.

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ASHIRGADE, AKSHAY A. "ENVIRONMENTALLY-COMPLIANT NOVOLAC SUPERPRIMERS FOR CORROSION PROTECTION OF ALUMINUM ALLOYS." University of Cincinnati / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1153245386.

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Gregory, Alexander William. "Cyclisation cascades via reactive iminium intermediates." Thesis, University of Oxford, 2014. http://ora.ox.ac.uk/objects/uuid:8e633fee-3457-4c31-939c-4421fac2fb8f.

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The aim of this D.Phil was to develop a range of cyclisation cascades, which initially form a reactive iminium intermediates that can then be attacked by a pendant nucleophile resulting in novel polycyclic structures. This concept has been applied to the development of three methodologies and has resulted in the discovery of new reactivity as well as the synthesis of a wide range of interesting novel structures <b>Chapter 1: Enantioselective chiral-BINOL-phosphoric acid catalysed reaction cascade</b> A highly enantioselective hydroamination / N-sulfonyliminium cyclisation cascade using a combi
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Wray, Brenda Caroline. "Development of Novel Methods to Prepare Nitrogen and Oxygen Heterocycles." The Ohio State University, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=osu1306329847.

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Manoso, Amy Slover. "Hypercoordinate silicon compounds In organic synthesis improved methods for the synthesis of aryl(trialkoxy)silane derivatives ; and trimethylsilyl cyanide as a cyanide source for nucleophilic substitution /." College Park, Md. : University of Maryland, 2004. http://hdl.handle.net/1903/1664.

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Thesis (Ph. D.)--University of Maryland, College Park, 2004.<br>Thesis research directed by: Chemistry. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.
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Otoo, Barnabas. "Conjugate Additions and Transposition of the Allylic Alcohols of Enol Ethers of 1, 2-Cyclohexanedione." Digital Commons @ East Tennessee State University, 2010. https://dc.etsu.edu/etd/1748.

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A variety of protected enolic forms of 1, 2-cyclohexanedione was prepared as substrates for conjugate addition studies using organocopper reagents. The sequence involved the enol ether preparation via the enolate, alkylation with an organometalic reagent, and oxidative rearrangement with pyridinium chlorochromate followed by the conjugate addition reactions. Protection of 1, 2-cyclohexanedione was achieved by reacting with chloro tert-butyldimethyl silane and subjected to alkylation. Steric problems were encountered and so an alternative protective group the methoxymethyl acetal was prepared a
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PERMOGOROV, DMITRI. "Spectroscopie intracavite laser des transitions harmoniques du methane, silane, germane et de leurs derives deuteres dans les domaines visible et proche infrarouge." Université Joseph Fourier (Grenoble), 1996. http://www.theses.fr/1996GRE10074.

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Nos resultats experimentaux concernant la spectroscopie d'absorption intracavite laser (iclas) de petites molecules polyatomiques dans les domaines visible et proche infrarouge ont mis en evidence certaines caracteristiques propres d'etats vibrationnels tres excites de ces molecules. Les spectres iclas des transitions harmoniques v=6, 7, 8 de silane, des trois isotopomeres les plus abondants du germane naturel et de ses derives deuteres ont ete obtenus a haute resolution. L'hamiltonien du modele local decrit dans cette these ne dependant que de trois parametres effectifs independants de la var
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Books on the topic "Organic silane"

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Larson, G. L. Ionic and organometallic-catalyzed organosilane reductions. Wiley, 2010.

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Turley, Fred. Mighty music at the movies: The cinema organ in Sheffield and the surrounding area. Sheaf Pub., 1990.

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Turley, Fred. Mighty music at the movies. Sheaf, 1990.

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M, Hall Ben, ed. The best remaining seats: The golden age of the movie palace. Da Capo Press, 1988.

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Leslie, Young Colin, Fogg P. G. T, Clever H. Lawrence, and Hayduk Walter, eds. Ammonia, amines, phosphine, arsine, stibine, silane, germane and stannane in organic solvents. Pergamon, 1985.

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Ammonia, Amines, Phosphine, Arsine, Stibine, Silane, Germane and Stannane in Organic Solvents. Elsevier, 1985. http://dx.doi.org/10.1016/c2009-0-01218-5.

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Young, Colin L. Ammonia, Amines, Phosphine, Arsine, Stibine, Silane, Germane and Stannane in Organic Solvents (Solubility Data Series). Elsevier Science Publishing Company, 1985.

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Jessica Wüstholz, Salomé Carrasco, U. Berger, A. Sundrum, and G. Bellof. Silage from alfalfa (Medicago sativa) harvested at an early stage as home-grown protein feed for organic broilers. Verlag Eugen Ulmer, 2016. http://dx.doi.org/10.1399/eps.2016.150.

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Barton, Gregory A. The Global History of Organic Farming. Oxford University Press, 2018. http://dx.doi.org/10.1093/oso/9780199642533.001.0001.

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Organic farming is a major global movement that is changing land use and consumer habits around the world. This book tells the untold story of how the organic farming movement nearly faltered after an initial flurry of scientific interest and popular support. Drawing on newly unearthed archives, Barton argues that organic farming first gained popularity in an imperial milieu before shifting to the left of the political spectrum after decolonization and serving as a crucial middle stage of environmentalism. Modern organic protocols developed in British India under the guidance of Sir Albert How
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McLauchlin, J. Listeriosis. Oxford University Press, 2011. http://dx.doi.org/10.1093/med/9780198570028.003.0014.

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Listeriosis occurs in a variety of animals including humans, and most often affects the pregnant uterus, the central nervous system (CNS) or the bloodstream. During pregnancy, infection spreads to the foetus, which will either be born severely ill or die in-utero. In non-pregnant animals, listeriosis usually presents as meningitis, encephalitis. In humans, infection most often occurs in the immunocompromised and elderly, and to a lesser extent the pregnant woman, the unborn, or the newly delivered infant. Infection can be treated successfully with antibiotics, however 20–40% of human cases are
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Book chapters on the topic "Organic silane"

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Chatgilialoglu, C., and D. Griller. "Tris(Trimethylsilyl)Silane. A New Reducing Agent." In Organic Free Radicals. Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73963-7_13.

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Baruwa, A. D., Esther T. Akinlabi, O. P. Oladijo, and F. M. Mwema. "Surface Coating Processes: From Conventional to Silane Organic Compound Applications: Recent and Prospects." In Lecture Notes in Mechanical Engineering. Springer Singapore, 2020. http://dx.doi.org/10.1007/978-981-15-5753-8_45.

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Kang, Young Taec, Jin Kook Lee, and Dong Pil Kang. "Properties of Organic/Inorganic Hybrid Material Synthesized from Acrylic Resin and Silane-Terminated CS." In Materials Science Forum. Trans Tech Publications Ltd., 2007. http://dx.doi.org/10.4028/0-87849-431-6.809.

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Takebayashi, Kenji, Yoshinori Tsuji, Shuji Sasabe, Motoyuki Iijima, and Hidehiro Kamiya. "Dispersion Behavior of Carbon Black Nanoparticles with a Silane Coupling Agent in an Organic Solvent." In Ceramic Transactions Series. John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470917145.ch21.

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Gao, A., and Y. Huang. "Sol-gel hybrid layer encapsulated aluminum pigments using organic silane acrylate resin/TEOS as precursors." In Advances in Energy Science and Equipment Engineering II. CRC Press, 2017. http://dx.doi.org/10.1201/9781315116174-24.

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Chatgilialoglu, C. "Silanes as New Reducing Agents in Organic Synthesis." In Free Radicals in Synthesis and Biology. Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-0897-0_10.

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Mori, Miwako. "Synthesis and Reactivity of Zirconium–Silene Complex." In New Aspects of Zirconium Containing Organic Compounds. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/b98424.

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Davies, Alwyn G., and Anthony G. Neville. "An Electron Spin Resonance Study of some Silanone Radical Anions." In Organic Free Radicals. Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73963-7_72.

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Baev, Alexei K. "Specific Intermolecular Interactions of Silanes and Their Derivatives." In Specific Intermolecular Interactions of Element-Organic Compounds. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-08563-0_2.

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Graja, A. "Silent and Higher Order Vibrations in the Infrared Transmission of C60 Clathrates." In Photoactive Organic Materials. Springer Netherlands, 1996. http://dx.doi.org/10.1007/978-94-017-2622-1_31.

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Conference papers on the topic "Organic silane"

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Baruwa, Akinsanya Damilare, Esther Titilayo Akinlabi, O. P. Oladijo, and Frederick Mwema. "Structural and Mechanical Analysis of Silane Compounds Coatings on AISI 304." In ASME 2019 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2019. http://dx.doi.org/10.1115/imece2019-10721.

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Abstract The structures and mechanical strength existing in three different hydrophobic silane compounds, Henicosyl-1,1,2,2-tetrahydrododecyltrichlorosilane (FDDTS), Tridecafloro-1,1,2,2-tetrahydrooctyltrichlorosilane (FOTS) and [Tris(trimethylsiloxy)silyethyl]dimethylchlorosilane (Alkyl) under same deposition conditions were studied and presented in this paper. The effect of the chemical composition on the mechanical strength and the structural evolutions as related to chlorosilane was inquired. The structures were investigated by using field emission scanning electron microscope (FESEM), ato
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Wang, Lingling, Yuanyuan Lv, Ting Wang, and Minhong Xu. "Study on Organic Modification of Attapulgite with Silane Coupling Agents KH570." In International Conference on Chemical,Material and Food Engineering. Atlantis Press, 2015. http://dx.doi.org/10.2991/cmfe-15.2015.52.

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Wenxiu Que, C. Y. Jia, M. Sun, et al. "GeO2/organically modified silane sol-gel hybrid organic-inorganic films for photonic applications." In 2008 2nd IEEE International Nanoelectronics Conference. IEEE, 2008. http://dx.doi.org/10.1109/inec.2008.4585463.

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Nicolescu, F. Adriana, Victor V. Jerca, Ana M. Albu, D. Sorin Vasilescu, and D. Mircea Vuluga. "Synthesis and characterization of organic-inorganic polymers from new methacrylate monomers and silane derivatives." In SPIE Europe Security + Defence, edited by James G. Grote, François Kajzar, and Roberto Zamboni. SPIE, 2009. http://dx.doi.org/10.1117/12.832282.

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Sasaki, K., T. Miyajima, H. Hosoya, and S. Furukawa. "Si Grain-Free Highly Conductive Microcrystalline SiC Films Prepared by Using Organic Silane Gas." In 1993 International Conference on Solid State Devices and Materials. The Japan Society of Applied Physics, 1993. http://dx.doi.org/10.7567/ssdm.1993.d-1-2.

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van Ooij, W. J., B. C. Zhang, K. D. Conners, and S. E. Hörnström. "On the use, characterization and performance of silane coupling agents between organic coatings and metallic or ceramic substrates." In The proceedings of the 53rd international meeting of physical chemistry: Organic coatings. AIP, 1996. http://dx.doi.org/10.1063/1.49478.

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Metem, Prattakorn, Wisarn Patchoo, Waleed S. Mohammed, and Charusluk Viphavakit. "Numerical investigation of Au-silane functionalised optical fibre sensor for volatile organic compounds biomarker (VOCs) detection." In Optical Fibers and Sensors for Medical Diagnostics, Treatment and Environmental Applications XXI, edited by Israel Gannot and Katy Roodenko. SPIE, 2021. http://dx.doi.org/10.1117/12.2578258.

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Ito, Yutaka, Ajay Virkar, Jason Locklin, Stefan Mannsfeld, Michael Toney, and Zhenan Bao. "Preparation of crystalline dielectric modification silane layer by spin-coating and its improvements on organic transistor performance." In SPIE Photonic Devices + Applications, edited by Zhenan Bao and Iain McCulloch. SPIE, 2009. http://dx.doi.org/10.1117/12.827000.

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Baruwa, Akinsanya Damilare, Oluseyi Philip Oladijo, Nthabiseng Maledi, and Esther Titilayo Akinlabi. "Influence of Surface Pretreatment on the Hydrophobic Silane Coating on AISI 304 Steel." In ASME 2018 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2018. http://dx.doi.org/10.1115/imece2018-86256.

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The influence of surface pretreatment on the integrity of Tridecafloro-1,1,2,2-tetrahydrooctyltrichlorosilane (FOTS) coating on the substrate is presented. FOTS is a hydrophobic organic compound deposited on the SS 304 surface to enhance the corrosion protection of the metal. The surface was pretreated with silicon oxide, plasma oxide and both served as adhesions before the coating was deposited on the substrate by atomic layer deposition technique. The coatings were characterized by scanning electron microscope (morphology), atomic force microscope (surface roughness). The chemical compositio
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Liu, X., H. C. Chin, L. S. Tan, and Y. C. Yeo. "Metal-Gate/High-Permittivity Dielectric Stack on Gallium Nitride formed by Silane Surface Passivation and Metal-Organic Chemical Vapor Deposition." In 2009 International Conference on Solid State Devices and Materials. The Japan Society of Applied Physics, 2009. http://dx.doi.org/10.7567/ssdm.2009.g-8-3.

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Reports on the topic "Organic silane"

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Palilis, Leonidas C., Antti J. Maekinen, Hideyuki Murata, Manabu Uchida, and Zakya H. Kafafi. Efficient Molecular Organic Light-Emitting Diodes Based on Silole Derivatives. Defense Technical Information Center, 2003. http://dx.doi.org/10.21236/ada447724.

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