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Journal articles on the topic 'Organoantimony compounds'

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Published: 4 June 2021

Last updated: 4 March 2023

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1

Jha, N. K., and Pankaj Sharma. "Novel trinuclear organoantimony compounds." Journal of the Chemical Society, Chemical Communications, no. 19 (1992): 1447. http://dx.doi.org/10.1039/c39920001447.

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2

Huang, Yaozeng. "Synthetic applications of organoantimony compounds." Accounts of Chemical Research 25, no. 4 (1992): 182–87. http://dx.doi.org/10.1021/ar00016a002.

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3

Rala, Sarbjit. "Electrochemical Synthesis of Organoantimony Compounds and their Coordination Compounds." Asian Journal of Chemistry 31, no. 3 (2019): 642–46. http://dx.doi.org/10.14233/ajchem.2019.21730.

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Electrochemical reactions of bromoethane, 1-bromopropane, 1-chlorobutane and chlorobenzene have been carried out in acetonitrile at sacrificial antimony anode using tetrabutylammonium chloride as supporting electrolyte. The products isolated from the anode compartment have been characterized by elemental analysis and infrared spectral studies and are identified as organoantimony compounds. Coordination compounds of same have been synthesized with ligand (1,10-phenanthroline and 2,2'-bipyridyl). All these reactions proceed with high current efficiencies.

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4

Yadav, Ram Nath Prasad. "Antimony(V) as Acceptors." Academic Voices: A Multidisciplinary Journal 5 (September 30, 2016): 34–39. http://dx.doi.org/10.3126/av.v5i0.15850.

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Lewis acidity of antimony(V) pentahalides and their organo substituted derivatives is well known. SbX5 acts as a strong acceptor towards halide ion as compared to antimony trihalide due to presence of two more electronegative halogen atoms in antimony pentahalide makes it better acceptor. Hexacoordinated organoantimony(V) complexes including chelating ligands are also known and hexacoordination and heptacoordination environment have been suggested for such compounds. The substitution of hydrocarbon groups bound to antimony by trifluoromethyl or pentafluorophenyl groups enhances the Lewis acidi

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5

Breunig, H. J., and R. Rösler. "Organoantimony compounds with element—element bonds." Coordination Chemistry Reviews 163 (July 1997): 33–53. http://dx.doi.org/10.1016/s0010-8545(97)00008-8.

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6

JHA, N. K., and P. SHARMA. "ChemInform Abstract: Novel Trinuclear Organoantimony Compounds." ChemInform 24, no. 3 (2010): no. http://dx.doi.org/10.1002/chin.199303213.

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7

Gupta, R., and A. Mathur. "Synthesis, Spectroscopic Studies and Antispermatogenic Activity of Tri- and Pentavalent Organoantimony Derivatives of Schiff Bases." Asian Journal of Organic & Medicinal Chemistry 5, no. 2 (2020): 113–19. http://dx.doi.org/10.14233/ajomc.2020.ajomc-p257.

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Diphenyl antimony(III) and triphenylantimony(V) derivatives of Schiff bases having general formulae Ph2Sb[OC(R)CHC(R′)NC6H5] and Ph3Sb[OC(R)CHC(R′)NC6H5]2 (where R=R′=CH3,C6H5; R = CH3, R′=C6H5), respectively have been prepared. Trivalent organoantimony derivatives have been synthesized by the reaction of RC(O)CHC(R′)-NH(C6H5) with Ph3Sb in 1: 1 molar ratio whereas, pentavalent organoantimony derivatives have been synthesized by the reaction of Ph3SbBr2 with Na[OC(R)CHC(R′)N(C6H5)] in 1:2 molar ratio, respectively in benzene solution. The structures of these complexes have been assigned on the

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8

HUANG, Y. Z. "ChemInform Abstract: Synthetic Applications of Organoantimony Compounds." ChemInform 23, no. 31 (2010): no. http://dx.doi.org/10.1002/chin.199231300.

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9

Gawargious, Youssef A., Abdel-Fattah B. Farag, Hassan N. A. Hassan, and Mohamed E. M. Hassouna. "Microdetermination of carbon and hydrogen in organoantimony compounds." Analyst 111, no. 7 (1986): 845. http://dx.doi.org/10.1039/an9861100845.

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10

YASUIKE, Shuji. "Synthesis and Properties of Optically Active Organoantimony Compounds." YAKUGAKU ZASSHI 123, no. 7 (2003): 577–85. http://dx.doi.org/10.1248/yakushi.123.577.

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11

Matsukawa, Shiro, Hideaki Yamamichi, Yohsuke Yamamoto, and Kaori Ando. "Pentacoordinate Organoantimony Compounds That Isomerize by Turnstile Rotation." Journal of the American Chemical Society 131, no. 10 (2009): 3418–19. http://dx.doi.org/10.1021/ja808113q.

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12

AKIBA, K. Y., and Y. YAMAMOTO. "ChemInform Abstract: Syntheses of Organoantimony and Organobismuth Compounds." ChemInform 26, no. 1 (2010): no. http://dx.doi.org/10.1002/chin.199501302.

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13

Andrewes, Paul, William R. Cullen, J�rg Feldmann, Iris Koch, Elena Polishchuk, and Kenneth J. Reimer. "The production of methylated organoantimony compounds byScopulariopsis brevicaulis." Applied Organometallic Chemistry 12, no. 12 (1998): 827–42. http://dx.doi.org/10.1002/(sici)1099-0739(199812)12:12<827::aid-aoc797>3.0.co;2-o.

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14

BREUNIG, H. J., and R. ROESLER. "ChemInform Abstract: Organoantimony Compounds with Element-Element Bonds." ChemInform 29, no. 5 (2010): no. http://dx.doi.org/10.1002/chin.199805265.

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15

Kant, Ravi, Amresh K. Chandrashekar, and Anil K. S. Kumar. "Synthesis and Biological Activity on Some Organoantimony (III) Compounds." Phosphorus, Sulfur, and Silicon and the Related Elements 183, no. 6 (2008): 1410–19. http://dx.doi.org/10.1080/10426500701655932.

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16

Raţ, Ciprian I., Cristian Silvestru, and Hans Joachim Breunig. "Hypervalent organoantimony and -bismuth compounds with pendant arm ligands." Coordination Chemistry Reviews 257, no. 5-6 (2013): 818–79. http://dx.doi.org/10.1016/j.ccr.2012.07.026.

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17

Gerasimchuk, Nikolay, Kevin Pinks, Tarosha Salpadoru, et al. "Non-Antibiotic Antimony-Based Antimicrobials." Molecules 27, no. 21 (2022): 7171. http://dx.doi.org/10.3390/molecules27217171.

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A series of the eight novel organoantimony(V) cyanoximates of Sb(C6H5)4L composition was synthesized using the high-yield heterogeneous metathesis reaction between solid AgL (or TlL) and Sb(C6H5)4Br in CH3CN at room temperature. Cyanoximes L were specially selected from a large group of 48 known compounds of this subclass of oximes on the basis of their water solubility and history of prior biological activity. The synthesized compounds are well soluble in organic solvents and were studied using a variety of conventional spectroscopic and physical methods. The crystal structures of all reporte

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18

Fuchigami, Toshio, and Motoko Miyazaki. "Electrochemistry of hypervalent compounds—V. Anodic oxidation of trivalent organoantimony and organobismuth compounds." Electrochimica Acta 42, no. 13-14 (1997): 1979–84. http://dx.doi.org/10.1016/s0013-4686(97)85470-9.

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19

Zhang, Li-Jun, Xue-Sheng Mo, Ji-Ling Huang, and Yao-Zeng Huang. "Regioselective reactions of trimethylsilylpropargylic and trimethylsilylallylic organoantimony compounds with aldehydes." Tetrahedron Letters 34, no. 10 (1993): 1621–24. http://dx.doi.org/10.1016/0040-4039(93)85024-q.

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20

Akhtar, Muhammad Shoaib, Zulfiqar Khan, Muhammad Naveed Mushtaq, and Muhammad Salman Akhtar. "Comparative Evaluation of Analgesic, Anti-inflammatory and Antipyretic Effects of Synthetic Derivatives of Organoantimony (?) Ferocenyl Benzoate with Piroxicam." Bangladesh Pharmaceutical Journal 19, no. 1 (2016): 15–24. http://dx.doi.org/10.3329/bpj.v19i1.29230.

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The current study was planned to evaluate comparative anti-inflammatory, analgesic and anti-pyretic activities of two newly synthesized organo-antimony (v) ferrocenyl benzoate derivatives with piroxicam. Anti-microbial activity of these compounds was also screened against two microorganisms. Analgesic effect of test compounds was evaluated by formalin-induced paw licking test in mice. The test compounds at 50 and 100 mg/kg b.w. doses exhibited significant (p<0.001) reduction of paw licking in treated mice comparable with standard drug piroxicam. Anti-inflammatory activity was assessed again

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21

Socaciu, Carmen, Ioan Pasca, Cristian Silvestru, Adela Bara, and Ionel Haiduc. "Antitumor Organometallics. IV. The Mutagenic Potential of Some Diphenylantimony(III) Dithiophosphorus Derivatives." Metal-Based Drugs 1, no. 4 (1994): 291–97. http://dx.doi.org/10.1155/mbd.1994.291a.

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Two diphenylantimony(III) derivatives of dithiophosphorus ligands, i.e. Ph2SbS2PPh2 and Ph2SbS2P(OPr-i)2, which were previously found to exhibit antitumor properties, have been now investigated for potential mutagenic effects in healthy and Ehrlich ascites tumor-bearing mice. Two short-term tests, i.e. the micronucleus test and the cytogenetic analysis, were used as end-points for mutagenicity. The results are consistent with a mutagenic potential for both organoantimony(III) compounds tested, the effect being higher for the phosphorodithioato derivative.

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22

Sharma, P., D. Castillo, N. Rosas, et al. "Synthesis and structures of organoantimony compounds containing intramolecular Sb–N interactions." Journal of Organometallic Chemistry 689, no. 16 (2004): 2593–600. http://dx.doi.org/10.1016/j.jorganchem.2004.05.016.

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23

Yanaga, Makoto, Kazutoyo Endo, Toshio Shimizu, Hiromichi Nakahara, Masashi Takahashi, and Masuo Takeda. "121Sb Mössbauer spectroscopic study on electronic states of pentavalent organoantimony compounds." Hyperfine Interactions 90, no. 1 (1994): 499–503. http://dx.doi.org/10.1007/bf02069162.

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24

Yanaga, M., H. Nakahara, K. Endo, M. Takahashi, and M. Takeda. "121Sb Mössbauer spectroscopic study of a series of organoantimony(III) compounds." Hyperfine Interactions 68, no. 1-4 (1992): 197–200. http://dx.doi.org/10.1007/bf02396470.

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25

Chen, Yi, Kun Yu, Nian-Yuan Tan, et al. "Synthesis, characterization and anti-proliferative activity of heterocyclic hypervalent organoantimony compounds." European Journal of Medicinal Chemistry 79 (May 2014): 391–98. http://dx.doi.org/10.1016/j.ejmech.2014.04.026.

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26

SHARMA, P., A. CABRERA, N. K. JHA, et al. "ChemInform Abstract: Novel Organoantimony Compounds Containing Sb-Sb Bonds: A Review." ChemInform 29, no. 13 (2010): no. http://dx.doi.org/10.1002/chin.199813277.

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27

Sharma, R. K., M. P. Dobhal, Y. P. Singh, et al. "Effects of Organoantimony(III) Compounds of Sterically Hindered Bifunctional Tetradentate Ligands on the Reproductive System of Male Rats." Metal-Based Drugs 7, no. 5 (2000): 271–74. http://dx.doi.org/10.1155/mbd.2000.271.

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The antifertility activity of organoantimony(III) complexes PhSb[RC(NC6H4S)CH2(NC6H4S)CR′] {R' = CH3 (R1) and R = R' = CF3 (R2)} derived from corresponding sterically hinlered bifuinctional tetradentate ligands in the male rats was determined. The administration of compounds R1 and R2 at the dose level of 20 mg/kg. b. wt. siignificantly reduced the weights of testes and epididymides. Auxiliary glands showed a significant reduction after the treatment of compound R1 only. Treated animals showed a notable depression of spermatogenesis. The preleptotene spermatocytes were decreased by 76.19 and 4

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28

BREUNIG, Hans Joachim. "The role of the substituents in the chemistry of organoantimony(I) compounds." Revue Roumaine de Chimie 65, no. 7-8 (2020): 635–46. http://dx.doi.org/10.33224/rrch.2020.65.7-8.01.

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29

Breunig, Hans Joachim, and Lucia Balázs. "Low-Valent Organoantimony and -bismuth Compounds with Neopentyl and (Trimethylsilyl)methyl Substituents." Organometallics 23, no. 3 (2004): 304–10. http://dx.doi.org/10.1021/om030601+.

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30

Yasuike, Shuji, Yoshihito Kishi, Shin-ichiro Kawara, Kentaro Yamaguchi, and Jyoji Kurita. "Synthesis of enantiomerically pure Sb-chirogenic organoantimony compounds and their crystal structures." Journal of Organometallic Chemistry 691, no. 10 (2006): 2213–20. http://dx.doi.org/10.1016/j.jorganchem.2005.10.042.

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31

Lermontov, Sergei A., Sergei V. Shkavrov, Anatoly S. Lermontov, Vladimir O. Zavelsky, and Nikolai S. Zefirov. "Oxidative fluorination of some organoantimony and organotellurium compounds by 2-hydroperfluoropropyl azide." Journal of Fluorine Chemistry 94, no. 1 (1999): 43–45. http://dx.doi.org/10.1016/s0022-1139(98)00335-2.

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32

ZHANG, L. J., X. S. MO, J. L. HUANG, and Y. Z. HUANG. "ChemInform Abstract: Regioselective Reactions of Trimethylsilylpropargylic and Trimethylsilylallylic Organoantimony Compounds with Aldehydes." ChemInform 24, no. 29 (2010): no. http://dx.doi.org/10.1002/chin.199329098.

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33

FUCHIGAMI, T., and M. MIYAZAKI. "ChemInform Abstract: Electrochemistry of Hypervalent Compounds. Part 5. Anodic Oxidation of Trivalent Organoantimony and Organobismuth Compounds." ChemInform 28, no. 37 (2010): no. http://dx.doi.org/10.1002/chin.199737035.

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34

Hara, Takato, Shihoko Nakano, Yuki Kitamura, Chika Yamamoto, Shuji Yasuike, and Toshiyuki Kaji. "Intracellular accumulation-independent cytotoxicity of pentavalent organoantimony compounds in cultured vascular endothelial cells." Journal of Toxicological Sciences 44, no. 12 (2019): 845–48. http://dx.doi.org/10.2131/jts.44.845.

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35

Urbanová, Iva, Roman Jambor, Aleš Růžička, Robert Jirásko, and Libor Dostál. "Synthesis and structure of N,C-chelated organoantimony(v) and organobismuth(v) compounds." Dalton Trans. 43, no. 2 (2014): 505–12. http://dx.doi.org/10.1039/c3dt51733k.

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36

Jha, N. K., A. C. Misra, and P. Bajaj. "Flame retardation of polypropylene: Effect of organoantimony compounds on the melt flow behavior." Polymer Engineering and Science 26, no. 4 (1986): 332–36. http://dx.doi.org/10.1002/pen.760260412.

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37

Dostál, Libor, Roman Jambor, Aleš Růžička, Antonín Lyčka, Jiří Brus, and Frank de Proft. "Synthesis and Structure of Organoantimony(III) Compounds Containing Antimony−Selenium and −Tellurium Terminal Bonds†." Organometallics 27, no. 23 (2008): 6059–62. http://dx.doi.org/10.1021/om800945g.

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38

Jha, N. K., P. Bajaj, A. C. Misra, and P. L. Maurya. "Flame retardation of polypropylene: Effect of organoantimony compounds on the flammability and thermal behavior." Journal of Applied Polymer Science 32, no. 4 (1986): 4393–403. http://dx.doi.org/10.1002/app.1986.070320409.

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39

Bajaj, P., N. K. Jha, P. L. Maurya, and A. C. Misra. "Flame retardation of polypropylene: Effect of organoantimony compounds on the structural and mechanical properties." Journal of Applied Polymer Science 34, no. 5 (1987): 1785–801. http://dx.doi.org/10.1002/app.1987.070340502.

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40

Eaborn, Colin. "Gmelin Handbook of Inorganic Chemistry. Sb. Organoantimony Compounds. Part 4. Compounds of Pentavalent Antimony with Three SbC Bonds." Journal of Organometallic Chemistry 326, no. 1 (1987): C52. http://dx.doi.org/10.1016/0022-328x(87)80146-8.

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41

Yanaga, Makoto, Taichi Miura, Kazutoyo Endo, Hiromichi Nakahara, and Masuo Takeda. "121Sb Mössbauer and1H and13C NMR Spectroscopic Studies of a Series of Organoantimony(V) Compounds, R3SbX2." Bulletin of the Chemical Society of Japan 59, no. 10 (1986): 3085–89. http://dx.doi.org/10.1246/bcsj.59.3085.

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42

Opris, Laura M., Ana Maria Preda, Richard A. Varga, Hans J. Breunig, and Cristian Silvestru. "Synthesis and Characterization of Hypervalent Organoantimony(III) Compounds Containing the [2-(Me2NCH2)C6H4]2Sb Fragment." European Journal of Inorganic Chemistry 2009, no. 9 (2009): 1187–93. http://dx.doi.org/10.1002/ejic.200801129.

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43

Shanker, D., A. K. Rai, Y. P. Singh, H. Rehwani, V. Khushalani, and R. S. Gupta. "Effect of Benzothiazoline Ligand and Corresponding Organoantimony(V) Derivative on the Reproductive System of Male Rats." Bioinorganic Chemistry and Applications 2006 (2006): 1–7. http://dx.doi.org/10.1155/bca/2006/20979.

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BenzothiazolineHNC6H4SC︹(C6H5)CH:C(OH)COOCH3 1prepared by the condensation reaction of aroyl pyruvate and 2-aminothiophenol has been treated withPh3Sb(OPri)2to yieldPh3Sb[SC6H4NC(C6H5)CH:CO︹COOCH3] 2. These compounds have been characterized by elemental analyses and molecular weight determinations. The probable structures of the ligand as well as antimony complex have been tentatively proposed on the basis of IR and NMR (H1andC13) spectral evidences. Both compounds have been tested for their antifertility activity in male albino rats. The oral administration of compounds1and2at the dose level

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44

Copolovici, Dana, Vilma R. Bojan, Ciprian I. Raţ, Anca Silvestru, Hans J. Breunig, and Cristian Silvestru. "New chiral organoantimony(iii) compounds containing intramolecular N → Sb interactions – solution behaviour and solid state structures." Dalton Transactions 39, no. 28 (2010): 6410. http://dx.doi.org/10.1039/c003318a.

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45

Šimon, Petr, Frank de Proft, Roman Jambor, Aleš Růžička, and Libor Dostál. "Monomeric Organoantimony(I) and Organobismuth(I) Compounds Stabilized by an NCN Chelating Ligand: Syntheses and Structures." Angewandte Chemie International Edition 49, no. 32 (2010): 5468–71. http://dx.doi.org/10.1002/anie.201002209.

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46

Šimon, Petr, Frank de Proft, Roman Jambor, Aleš Růžička, and Libor Dostál. "Monomeric Organoantimony(I) and Organobismuth(I) Compounds Stabilized by an NCN Chelating Ligand: Syntheses and Structures." Angewandte Chemie 122, no. 32 (2010): 5600–5603. http://dx.doi.org/10.1002/ange.201002209.

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47

Davies, A. G. "Gmelin handbook of inorganic chemistry, 8th edition. Sborganoantimony compounds, part 4, compounds of pentavalent antimony with three SbC bonds." Polyhedron 6, no. 3 (1987): 660. http://dx.doi.org/10.1016/s0277-5387(00)81045-1.

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48

Tan, Nianyuan, Yi Chen, Shuangfeng Yin, Renhua Qiu, Yongbo Zhou, and C. T. Au. "Synthesis, Structure and Applications of Hypervalent Organoantimony Compounds Having Intramolecular E→Sb (E = N, O, S) Coordinations." Current Organic Chemistry 16, no. 20 (2012): 2462–81. http://dx.doi.org/10.2174/138527212803520083.

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49

Urbanová, Iva, Milan Erben, Roman Jambor, Aleš Růžička, Robert Jirásko, and Libor Dostál. "Opening of the azastibol heterocycle with various acids: Isolation of novel N,C-chelated organoantimony(III) compounds." Journal of Organometallic Chemistry 743 (October 2013): 156–62. http://dx.doi.org/10.1016/j.jorganchem.2013.06.023.

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50

ZHANG, L. J., X. S. MO, and Y. Z. HUANG. "ChemInform Abstract: Pentaorganylstiborane. Part 3. Regio- and Diastereoselective Additions of Acetylenic and Allenic Organoantimony Compounds to Aldehydes." ChemInform 25, no. 37 (2010): no. http://dx.doi.org/10.1002/chin.199437069.

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