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Journal articles on the topic 'Organoboran compounds'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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1

Brown, Charles, R. Harry Cragg, Tim J. Miller, and David O'N Smith. "Organoboron compounds." Journal of Organometallic Chemistry 342, no. 2 (March 1988): 153–57. http://dx.doi.org/10.1016/s0022-328x(00)99452-x.

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2

Cragg, R. Harry, and Manije Nazery. "Organoboron compounds." Journal of Organometallic Chemistry 303, no. 3 (April 1986): 329–35. http://dx.doi.org/10.1016/0022-328x(86)82034-4.

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3

Bubnov, Yu N., A. I. Grandberg, M. Sh Grigorian, V. G. Kiselev, M. I. Struchkova, and B. M. Mikhailov. "Organoboron compounds." Journal of Organometallic Chemistry 292, no. 1-2 (September 1985): 93–104. http://dx.doi.org/10.1016/0022-328x(85)87325-3.

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4

Cragg, R. Harry, and Tim J. Miller. "Organoboron compounds." Journal of Organometallic Chemistry 294, no. 1 (October 1985): 1–6. http://dx.doi.org/10.1016/0022-328x(85)88048-7.

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5

Cragg, R. Harry, Tim J. Miller, and David O'N Smith. "Organoboron compounds." Journal of Organometallic Chemistry 302, no. 1 (March 1986): 19–21. http://dx.doi.org/10.1016/0022-328x(86)80058-4.

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6

Cragg, R. Harry, Tim J. Miller, and David O'N Smith. "Organoboron compounds." Journal of Organometallic Chemistry 291, no. 3 (August 1985): 273–75. http://dx.doi.org/10.1016/0022-328x(85)80179-0.

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7

Boldyreva, O. G., V. A. Dorokhov, and B. M. Mikhailov. "Organoboron compounds." Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 34, no. 2 (February 1985): 390–92. http://dx.doi.org/10.1007/bf00951292.

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8

Dorokhov, V. A., O. G. Boldyreva, B. M. Mikhailov, Z. A. Starikova, and I. A. Teslya. "Organoboron compounds." Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 34, no. 2 (February 1985): 393–97. http://dx.doi.org/10.1007/bf00951293.

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9

Wang, Jianbo. "When diazo compounds meet with organoboron compounds." Pure and Applied Chemistry 90, no. 4 (March 28, 2018): 617–23. http://dx.doi.org/10.1515/pac-2017-0713.

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AbstractTransition-metal free reactions of diazo compounds with organoboron compounds provide some unique approaches for the formation of C–C, C–B and C–Si bonds. WithN-tosylhydrazones as the precursors for non-stabilized diazo compound, this type of reaction becomes practically useful in organic synthesis. Transition-metal-free synthetic methodologies for borylation,gem-diborylation,gem-silylborylation arylation, 2,2,2-trifluoroethylation andgem-difluorovinylation have been successfully developed.

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10

Valencia López, Luis Alexandro, Francisco Javier Enríquez-Medrano, Ricardo Mendoza Carrizales, Florentino Soriano Corral, Adali Castañeda Facio, and Ramón Enrique Díaz de León Gómez. "Influence of Organoboron Compounds on Ethylene Polymerization Using Cp2ZrCl2/MAO as Catalyst System." International Journal of Polymer Science 2014 (2014): 1–8. http://dx.doi.org/10.1155/2014/519203.

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Organoboron compounds of nonionic and ionic nature, tris(pentafluorophenyl)borane, and N,N-dimethylanilinium tetra(pentafluorophenyl)borate were evaluated to act in conjunction with MAO as activators on ethylene polymerization by using the catalyst Cp2ZrCl2. A decrease on the catalytic activity was observed in both cases in relation with a reference polyethylene which was synthesized in absence of any organoboron compound. An increase on the crystallinity degree and molecular weight, as well as an improvement in thermal and dynamic-mechanical properties, was observed in polyethylenes synthetized in presence of tris(pentafluorophenyl)borane. A low density polyethylene with improved thermal stability was obtained when N,N-dimethylanilinium tetra(pentafluorophenyl)borate was employed as activator.

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11

Kliś, Tomasz, and Marcin Kublicki. "Organoboron Compounds in Visible Light-driven Photoredox Catalysis." Current Organic Chemistry 25, no. 9 (May 25, 2021): 994–1027. http://dx.doi.org/10.2174/1385272825666210225103418.

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The increasing importance of visible light photoredox catalysis as a powerful strategy for the activation of small molecules require the development of new effective radical sources and photocatalysts. The unique properties of organoboron compounds have contributed significantly to the rapid progress of photocatalysis. Since the first work on the topic in 2005, many researchers have appreciated the role of boron-containing compounds in photocatalysis, and this is reflected in several publications. In this review, we highlight the utility of organoboron compounds in various photocatalytic reactions enabling the construction of carbon- carbon and carbon-heteroatom bonds. The dual role of organoboron compounds in photocatalysis is highlighted by their applications as reactants and as well as organic photocatalysts.

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12

Pattison, Graham. "Fluorination of organoboron compounds." Organic & Biomolecular Chemistry 17, no. 23 (2019): 5651–60. http://dx.doi.org/10.1039/c9ob00832b.

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13

Coghi, Paolo Saul, Yinghuai Zhu, Hongming Xie, Narayan S. Hosmane, and Yingjun Zhang. "Organoboron Compounds: Effective Antibacterial and Antiparasitic Agents." Molecules 26, no. 11 (May 31, 2021): 3309. http://dx.doi.org/10.3390/molecules26113309.

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The unique electron deficiency and coordination property of boron led to a wide range of applications in chemistry, energy research, materials science and the life sciences. The use of boron-containing compounds as pharmaceutical agents has a long history, and recent developments have produced encouraging strides. Boron agents have been used for both radiotherapy and chemotherapy. In radiotherapy, boron neutron capture therapy (BNCT) has been investigated to treat various types of tumors, such as glioblastoma multiforme (GBM) of brain, head and neck tumors, etc. Boron agents playing essential roles in such treatments and other well-established areas have been discussed elsewhere. Organoboron compounds used to treat various diseases besides tumor treatments through BNCT technology have also marked an important milestone. Following the clinical introduction of bortezomib as an anti-cancer agent, benzoxaborole drugs, tavaborole and crisaborole, have been approved for clinical use in the treatments of onychomycosis and atopic dermatitis. Some heterocyclic organoboron compounds represent potentially promising candidates for anti-infective drugs. This review highlights the clinical applications and perspectives of organoboron compounds with the natural boron atoms in disease treatments without neutron irradiation. The main topic focuses on the therapeutic applications of organoboron compounds in the diseases of tuberculosis and antifungal activity, malaria, neglected tropical diseases and cryptosporidiosis and toxoplasmosis.

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14

Yang, Tianbao, Niu Tang, Qizhong Wan, Shuang-Feng Yin, and Renhua Qiu. "Recent Progress on Synthesis of N,N′-Chelate Organoboron Derivatives." Molecules 26, no. 5 (March 5, 2021): 1401. http://dx.doi.org/10.3390/molecules26051401.

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N,N′-chelate organoboron compounds have been successfully applied in bioimaging, organic light-emitting diodes (OLEDs), functional polymer, photocatalyst, electroluminescent (EL) devices, and other science and technology areas. However, the concise and efficient synthetic methods become more and more significant for material science, biomedical research, or other practical science. Here, we summarized the organoboron-N,N′-chelate derivatives and showed the different routes of their syntheses. Traditional methods to synthesize N,N′-chelate organoboron compounds were mainly using bidentate ligand containing nitrogen reacting with trivalent boron reagents. In this review, we described a series of bidentate ligands, such as bipyridine, 2-(pyridin-2-yl)-1H-indole, 2-(5-methyl-1H-pyrrol-2-yl)quinoline, N-(quinolin-8-yl)acetamide, 1,10-phenanthroline, and diketopyrrolopyrrole (DPP).

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15

Kabalka, George W., Min-Liang Yao, Murthy Akula, and Li Yong. "Isotope incorporation using organoboranes." Pure and Applied Chemistry 84, no. 11 (June 24, 2012): 2309–15. http://dx.doi.org/10.1351/pac-con-12-01-13.

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Isotopes have played an important role in chemistry, biology, and medicine. For the last three decades, we have focused on the use of organoboron compounds as precursors to isotopically labeled physiologically active reagents. During that period, we have successfully developed methods for incorporating short- and long-lived isotopes of carbon, nitrogen, oxygen, and the halogens using a variety of reactive organoboron precursors. In addition, labeling strategies employing polymer-supported organoboron derivatives were developed. In this report, we present a short overview focused on the evolution of radiolabeling techniques based on boron chemistry.

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16

Lu, Xiao-Yu, Chu-Ting Yang, Jing-Hui Liu, Zheng-Qi Zhang, Xi Lu, Xin Lou, Bin Xiao, and Yao Fu. "Cu-Catalyzed cross-coupling reactions of epoxides with organoboron compounds." Chemical Communications 51, no. 12 (2015): 2388–91. http://dx.doi.org/10.1039/c4cc09321f.

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17

Köster, Roland, and Günter Seidel. "Borverbindungen, LXXXI. Neue Organobor-Sulfide — Herstellung und Anwendung / Boron Compounds, LXXXI. New Organoboron Sulfides — Preparation and Uses." Zeitschrift für Naturforschung B 43, no. 6 (June 1, 1988): 687–93. http://dx.doi.org/10.1515/znb-1988-0609.

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Bis(9-borabicyclo[3.3.1]nonane) reacts with sulfur to give the bis(1,5-cyclooctanediylboryl)- monosulfide (1) in high yield. The (9-BBN)2 disulfide 2 is easily prepared from 1 with sulfur. 2, which can also be obtained from 9-Iodo-9-BBN with sulfur, reacts with (9-BBN)2 to form 1.1 is an excellent sulfidation reagent for preparing thio compounds by S/O-exchange.

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18

Wang, Jianbo, Huan Li, and Yan Zhang. "Reaction of Diazo Compounds with Organoboron Compounds." Synthesis 45, no. 22 (October 10, 2013): 3090–98. http://dx.doi.org/10.1055/s-0033-1340041.

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19

Petasis, Nicos A. "Expanding Roles for Organoboron Compounds – Versatile and Valuable Molecules for Synthetic, Biological and Medicinal Chemistry." Australian Journal of Chemistry 60, no. 11 (2007): 795. http://dx.doi.org/10.1071/ch07360.

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The present essay offers an overview of the latest developments in the chemistry of organoboron compounds. The unique structural characteristics and the versatile reactivity profile of organoboron compounds continue to expand their roles in several areas of chemistry. A growing number of boron-mediated reactions have become vital tools for synthetic chemistry, particularly in asymmetric synthesis, metal-catalyzed processes, acid catalysis, and multicomponent reactions. As a result, boronic acids and related molecules have now evolved as major players in synthetic and medicinal chemistry. Moreover, their remnant electrophilic reactivity, even under physiological conditions, has allowed their incorporation in a growing number of bioactive molecules, including bortezomib, a clinically approved anticancer agent. Finally, the sensitive and selective binding of boronic acids to diols and carbohydrates has led to the development of a growing number of novel chemosensors for the detection, quantification, and imaging of glucose and other carbohydrates. There is no doubt that the chemistry of organoboron compounds will continue to expand into new discoveries and new applications in several fields of science.

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20

Hosoi, Kohei, Yu Kuriyama, Shinsuke Inagi, and Toshio Fuchigami. "Electrochemical hydroxylation of organoboron compounds." Chemical Communications 46, no. 8 (2010): 1284. http://dx.doi.org/10.1039/b914093j.

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21

Dhital, Raghu Nath, and Hidehiro Sakurai. "Oxidative Coupling of Organoboron Compounds." Asian Journal of Organic Chemistry 3, no. 6 (March 12, 2014): 668–84. http://dx.doi.org/10.1002/ajoc.201300283.

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22

Eaborn, Colin. "Organoboron Compounds in Organic Synthesis." Journal of Organometallic Chemistry 284, no. 2 (April 1985): C43. http://dx.doi.org/10.1016/0022-328x(85)87227-2.

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23

Tsuchikawa, Masahiro, Aya Takao, Takashi Funaki, Hideki Sugihara, and Katsuhiko Ono. "Multifunctional organic dyes: anion-sensing and light-harvesting properties of curcumin boron complexes." RSC Advances 7, no. 58 (2017): 36612–16. http://dx.doi.org/10.1039/c7ra06778j.

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24

Valadbeigi, Younes. "Organometallic acids with azaborine, oxaborine, azaborole and oxaborole scaffolds." New Journal of Chemistry 42, no. 23 (2018): 18777–86. http://dx.doi.org/10.1039/c8nj05151h.

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25

ZAIDLEWICZ, M. "ChemInform Abstract: Synthesis with Organoboranes. Part 5. Hydroxymethylation and Formylation of Cycloalkenes via Allylic Organopotassium and Organoboron Compounds." ChemInform 22, no. 34 (August 22, 2010): no. http://dx.doi.org/10.1002/chin.199134134.

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26

Jin, R. F. "Theoretical study of the optical and charge transport properties of π-conjugated three-coordinate organoboron compounds as organic light-emitting diodes materials." RSC Advances 6, no. 110 (2016): 108209–16. http://dx.doi.org/10.1039/c6ra24301k.

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27

Zhang, Zhenyu, Zuolun Zhang, Hongyu Zhang, and Yue Wang. "2-(2-Hydroxyphenyl)imidazole-based four-coordinate organoboron compounds with efficient deep blue photoluminescence and electroluminescence." Dalton Transactions 47, no. 1 (2018): 127–34. http://dx.doi.org/10.1039/c7dt03702c.

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28

Huang, Zheng, Ziqing Zuo, Huanan Wen, and Guixia Liu. "Cobalt-Catalyzed Hydroboration and Borylation of Alkenes and Alkynes." Synlett 29, no. 11 (April 23, 2018): 1421–29. http://dx.doi.org/10.1055/s-0037-1609682.

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Incorporation of the boryl moiety across a carbon–carbon multiple bond is a powerful method for the synthesis of organoboron compounds. This kind of transformation could be realized with high chemo-, regio-, and stereoselectivity by using an appropriate transition-metal catalyst. This account summarizes the latest advances from our group in the area of cobalt-catalyzed hydroboration and borylation of alkenes and alkynes, which lead to the formation of a variety of organoboron compounds, including alkylboronates, 1,1,1-tris(boronates), 1,1-diborylalkenes, and 1,1-diboronates.1 Introduction2 Cobalt-Catalyzed Hydroboration of Alkenes3 Cobalt-Catalyzed Dehydrogenative Borylations-Hydroboration4 Cobalt-Catalyzed Double Dehydrogenative Borylations of 1-Alkenes5 Cobalt-Catalyzed Hydroboration of Terminal Alkynes6 Summary and Outlook

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29

Yoshida, Hiroto, Yuki Takemoto, Shintaro Kamio, Itaru Osaka, and Ken Takaki. "Copper-catalyzed direct borylation of alkyl, alkenyl and aryl halides with B(dan)." Organic Chemistry Frontiers 4, no. 7 (2017): 1215–19. http://dx.doi.org/10.1039/c7qo00084g.

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30

Zhang, Zhenyu, Zuolun Zhang, Kaiqi Ye, Jingying Zhang, Hongyu Zhang, and Yue Wang. "Diboron complexes with bis-spiro structures as high-performance blue emitters for OLEDs." Dalton Transactions 44, no. 32 (2015): 14436–43. http://dx.doi.org/10.1039/c5dt02093j.

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31

Kliegel, Wolfgang, Hans-Walter Motzkus, Klaus Drückler, Steven J. Rettig, and James Trotter. "Structural studies of organoboron compounds. XXXVII. 8,8-Pentamethylene-6-phenyl-6,9-epoxy-5,7-dioxa-8-azonia-6-borata-6,7,8,9-tetrahydro-5H-benzocycloheptene." Canadian Journal of Chemistry 68, no. 1 (January 1, 1990): 64–68. http://dx.doi.org/10.1139/v90-013.

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Condensation of equimolar amounts of salicylaldehyde, N-hydroxypiperidine, and phenylboronic acid yields the title compound. Crystals of 8,8-pentamethylene-6-phenyl-6,9-epoxy-5,7-dioxa-8-azonia-6-borata-6,7,8,9-tetrahydro-5H-benzocycloheptene are monoclinic, a = 12.773(1), b = 11.9600(7), c = 10.6411(6) Å, β = 103.786(7)°, Z = 4, space group P21/c. The structure was solved by direct methods and was refined by full-matrix least-squares procedures to R = 0.039 and Rw = 0.047 for 2420 reflections with I ≥ 3σ(I). The compound has a bridged heterocyclic B,N-betaine structure with a PhB(OR)3 anionic centre. Bond lengths (corrected for libration) include: B—O(aryl C) = 1.481(2), B—O(alkyl C) = 1.488(2), B—O(N) = 1.539(2), and B—C = 1.591(2) Å. Keywords: organoboron, boron compounds, crystal structure.

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32

Brothers, Penelope J. "Tripping the Light Fantastic: Organoboron Compounds." Elements 13, no. 4 (August 1, 2017): 255–60. http://dx.doi.org/10.2138/gselements.13.4.255.

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Small molecules containing boron can play all sorts of roles in chemistry, biology and materials science. Molecular boron compounds display a wide range of unusual and fascinating structures, and their chemical reactivity can be very different from that of boron's next-door neighbour carbon. Some of the reasons for this will be considered and illustrated through applications in energy, medicine and new materials. The boron dipyrrins, also known as BODIPYs, are a prime example. They are strongly fluorescent when excited by illumination and are widely used as fluorescent tags in biology and as biosensors. More recently, they have been studied for their energy transfer properties in light-harvesting applications.

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33

He, Zhi, Piera Trinchera, Shinya Adachi, Jeffrey D. St. Denis, and Andrei K. Yudin. "Oxidative Geminal Functionalization of Organoboron Compounds." Angewandte Chemie International Edition 51, no. 44 (October 4, 2012): 11092–96. http://dx.doi.org/10.1002/anie.201206501.

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34

He, Zhi, Piera Trinchera, Shinya Adachi, Jeffrey D. St. Denis, and Andrei K. Yudin. "Oxidative Geminal Functionalization of Organoboron Compounds." Angewandte Chemie 124, no. 44 (October 4, 2012): 11254–58. http://dx.doi.org/10.1002/ange.201206501.

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35

Suzuki, Akira. "Organoboron compounds in new synthetic reactions." Pure and Applied Chemistry 57, no. 12 (January 1, 1985): 1749–58. http://dx.doi.org/10.1351/pac198557121749.

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36

Suzuki, Akira. "New synthetic transformations via organoboron compounds." Pure and Applied Chemistry 66, no. 2 (January 1, 1994): 213–22. http://dx.doi.org/10.1351/pac199466020213.

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37

Liu, Fangbin, Zicheng Ding, Jun Liu, and Lixiang Wang. "An organoboron compound with a wide absorption spectrum for solar cell applications." Chemical Communications 53, no. 90 (2017): 12213–16. http://dx.doi.org/10.1039/c7cc07494h.

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38

Li, Huan, Yan Zhang, and Jianbo Wang. "ChemInform Abstract: Reaction of Diazo Compounds with Organoboron Compounds." ChemInform 45, no. 5 (January 16, 2014): no. http://dx.doi.org/10.1002/chin.201405243.

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39

Wen, Lu, Haiyan Zhang, Jiping Wang, and Fanke Meng. "Cu-catalyzed regioselective borylcyanation of 1,3-dienes." Chemical Communications 54, no. 91 (2018): 12832–35. http://dx.doi.org/10.1039/c8cc07032f.

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Catalytic regioselective generation of an allyl–Cu complex through Cu–B(pin) (pin = pinacolato) addition to 1,3-dienes followed by reaction with an electrophilic cyanation reagent to afford multifunctional organoboron compounds is presented.

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40

Wei, Lanfeng, Yu Wei, Jinli Zhang, and Liang Xu. "Visible-light-mediated organoboron-catalysed metal-free dehydrogenation of N-heterocycles using molecular oxygen." Green Chemistry 23, no. 12 (2021): 4446–50. http://dx.doi.org/10.1039/d1gc01063h.

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41

Gribanova, Tatyana N., Ruslan M. Minyaev, and Vladimir I. Minkin. "Planar Tetracoordinate Carbon in Organoboron Compounds: ab initio Computational Study." Collection of Czechoslovak Chemical Communications 64, no. 11 (1999): 1780–89. http://dx.doi.org/10.1135/cccc19991780.

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Ab initio MP2(full)/6-311++G** calculations revealed that 1,2-diboraspiro[2.2]pent-4-ene (11) and two of its isomers 14 and 15 possess stable structures with planar tetracoordinate carbon. These compounds and some of their derivatives, 21 and 22, can be regarded as the first computationally found organoboron compounds with the planar tetracoordinate carbon.

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42

Yuan, Huanxiang, Lifang Wang, Shuhong Li, Haiyan Liang, Chichong Lu, Yibo Wang, and Cui-Hua Zhao. "The preparation of organoboron-based stilbene nanoparticles for cell imaging." Journal of Materials Chemistry B 4, no. 33 (2016): 5515–18. http://dx.doi.org/10.1039/c6tb01208f.

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In this work, a series of nanoparticles were prepared assembled by a highly emissive solid-state organoboron-based stilbene (OBS) and PS-PEG-COOH via regulating the ratio of these two compounds using a co-precipitation method.

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43

Xi, He, Yang Liu, Chun-Xue Yuan, Ye-Xin Li, Lei Wang, Xu-Tang Tao, Xiao-Hua Ma, Chun-Fu Zhang, and Yue Hao. "Through space charge-transfer emission in lambda (Λ)-shaped triarylboranes and the use in fluorescent sensing for fluoride and cyanide ions." RSC Advances 5, no. 57 (2015): 45668–78. http://dx.doi.org/10.1039/c5ra07912h.

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By introducing a twisted and non-conjugated Λ-shaped TB scaffold to triarylboranes, we provide an efficient strategy to develop a new class of organoboron compounds applied as colorimetric and ratiometric fluorescent sensors for fluoride and cyanide.

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44

Joshi, Prerna, Raman Vedarajan, and Noriyoshi Matsumi. "A crystalline low molecular weight cyclic organoboron compound for efficient solid state lithium ion transport." Chemical Communications 51, no. 81 (2015): 15035–38. http://dx.doi.org/10.1039/c5cc04753f.

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45

Takahashi, Daisuke, Masamichi Tanaka, and Kazunobu Toshima. "Regioselective and Stereoselective Glycosylations Utilizing Organoboron Compounds." Trends in Glycoscience and Glycotechnology 30, no. 174 (May 25, 2018): E55—E62. http://dx.doi.org/10.4052/tigg.1817.2e.

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46

Takahashi, Daisuke, Masamichi Tanaka, and Kazunobu Toshima. "Regioselective and Stereoselective Glycosylations Utilizing Organoboron Compounds." Trends in Glycoscience and Glycotechnology 30, no. 174 (May 25, 2018): J31—J38. http://dx.doi.org/10.4052/tigg.1817.2j.

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47

Lalic, Gojko, and Richard Rucker. "Copper-Catalyzed Electrophilic Amination of Organoboron Compounds." Synlett 24, no. 03 (December 12, 2012): 269–75. http://dx.doi.org/10.1055/s-0032-1317744.

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48

Hosoi, Kohei, Yu Kuriyama, Shinsuke Inagi, and Toshio Fuchigami. "ChemInform Abstract: Electrochemical Hydroxylation of Organoboron Compounds." ChemInform 41, no. 25 (June 22, 2010): no. http://dx.doi.org/10.1002/chin.201025051.

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49

Dhital, Raghu Nath, and Hidehiro Sakurai. "ChemInform Abstract: Oxidative Coupling of Organoboron Compounds." ChemInform 45, no. 36 (August 21, 2014): no. http://dx.doi.org/10.1002/chin.201436256.

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50

Inagi, Shinsuke, and Toshio Fuchigami. "Electrochemical properties and reactions of organoboron compounds." Current Opinion in Electrochemistry 2, no. 1 (April 2017): 32–37. http://dx.doi.org/10.1016/j.coelec.2017.02.007.

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