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Relevant bibliographies by topics / Organocatalysis

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Academic literature on the topic 'Organocatalysis'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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Journal articles on the topic "Organocatalysis"

1

Sahoo, Biswa Mohan, and Bimal Krishna Banik. "Organocatalysis: Trends of Drug Synthesis in Medicinal Chemistry." Current Organocatalysis 6, no. 2 (2019): 92–105. http://dx.doi.org/10.2174/2213337206666190405144423.

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Background:The continuous increase in challenges associated with the effective treatment of life threatening diseases influences the development of drug therapies with suitable physicochemical properties, efficiency and selectivity. So, organocatalysis is a potential synthetic tool which is accelerating the development of new drug molecules.Methods:Organocatalysis reactions can be carried out at lower temperatures and in milder pH conditions as compared to metal based catalysed reactions. Due to ready availability of catalysts, stability, purity, low toxicity and easy in handling of the chemic

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Shaikh, Isak Rajjak. "Organocatalysis: Key Trends in Green Synthetic Chemistry, Challenges, Scope towards Heterogenization, and Importance from Research and Industrial Point of View." Journal of Catalysts 2014 (March 26, 2014): 1–35. http://dx.doi.org/10.1155/2014/402860.

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This paper purports to review catalysis, particularly the organocatalysis and its origin, key trends, challenges, examples, scope, and importance. The definition of organocatalyst corresponds to a low molecular weight organic molecule which in stoichiometric amounts catalyzes a chemical reaction. In this review, the use of the term heterogenized organocatalyst will be exclusively confined to a catalytic system containing an organic molecule immobilized onto some sort of support material and is responsible for accelerating a chemical reaction. Firstly, a brief description of the field is provid

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Noraishah Abdullah, Zurina Shaameri, Ahmad Sazali Hamzah, and Mohd Fazli Mohammat. "Synthesis of Trans-4-Hydroxyprolineamide and 3-Ketoproline Ethyl Ester for Green Asymmetric Organocatalysts." Journal of Advanced Research in Applied Sciences and Engineering Technology 38, no. 1 (2024): 97–108. http://dx.doi.org/10.37934/araset.38.1.97108.

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Organocatalysts have become one of the three pillars in asymmetric reactions, along with metal catalysis and enzyme catalysis. Organocatalysis is widely acknowledged in both academia and industry as a practical and advantageous synthetic method owing to its operational ease, readily available catalyst, environmentally friendly, and minimal toxicity. Much attention has been focused on the organocatalyst for its superior properties as an efficient and clean catalyst. In this work, a series of green organocatalysts of trans-4-hydroxyprolineamide were efficiently obtained in a two-step reaction ut

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Sánchez-Antonio, Omar, Kevin A. Romero-Sedglach, Erika C. Vázquez-Orta, and Eusebio Juaristi. "New Mesoporous Silica-Supported Organocatalysts Based on (2S)-(1,2,4-Triazol-3-yl)-Proline: Efficient, Reusable, and Heterogeneous Catalysts for the Asymmetric Aldol Reaction." Molecules 25, no. 19 (2020): 4532. http://dx.doi.org/10.3390/molecules25194532.

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Novel organocatalytic systems based on the recently developed (S)-proline derivative (2S)-[5-(benzylthio)-4-phenyl-(1,2,4-triazol)-3-yl]-pyrrolidine supported on mesoporous silica were prepared and their efficiency was assessed in the asymmetric aldol reaction. These materials were fully characterized by FT-IR, MS, XRD, and SEM microscopy, gathering relevant information regarding composition, morphology, and organocatalyst distribution in the doped silica. Careful optimization of the reaction conditions required for their application as catalysts in asymmetric aldol reactions between ketones a

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Wojaczyńska, Elżbieta, Franz Steppeler, Dominika Iwan, Marie-Christine Scherrmann, and Alberto Marra. "Synthesis and Applications of Carbohydrate-Based Organocatalysts." Molecules 26, no. 23 (2021): 7291. http://dx.doi.org/10.3390/molecules26237291.

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Organocatalysis is a very useful tool for the asymmetric synthesis of biologically or pharmacologically active compounds because it avoids the use of noxious metals, which are difficult to eliminate from the target products. Moreover, in many cases, the organocatalysed reactions can be performed in benign solvents and do not require anhydrous conditions. It is well-known that most of the above-mentioned reactions are promoted by a simple aminoacid, l-proline, or, to a lesser extent, by the more complex cinchona alkaloids. However, during the past three decades, other enantiopure natural compou

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Martelli, Lorena S. R., Ingrid V. Machado, Jhonathan R. N. dos Santos, and Arlene G. Corrêa. "Recent Advances in Greener Asymmetric Organocatalysis Using Bio-Based Solvents." Catalysts 13, no. 3 (2023): 553. http://dx.doi.org/10.3390/catal13030553.

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Efficient synthetic methods that avoid the extensive use of hazardous reagents and solvents, as well as harsh reaction conditions, have become paramount in the field of organic synthesis. Organocatalysis is notably one of the best tools in building chemical bonds between carbons and carbon-heteroatoms; however, most examples still employ toxic volatile organic solvents. Although a portfolio of greener solvents is now commercially available, only ethyl alcohol, ethyl acetate, 2-methyltetrahydrofuran, supercritical carbon dioxide, ethyl lactate, and diethyl carbonate have been explored with chir

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Sinibaldi, Arianna, Valeria Nori, Andrea Baschieri, Francesco Fini, Antonio Arcadi, and Armando Carlone. "Organocatalysis and Beyond: Activating Reactions with Two Catalytic Species." Catalysts 9, no. 11 (2019): 928. http://dx.doi.org/10.3390/catal9110928.

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Since the beginning of the millennium, organocatalysis has been gaining a predominant role in asymmetric synthesis and it is, nowadays, a foundation of catalysis. Synergistic catalysis, combining two or more different catalytic cycles acting in concert, exploits the vast knowledge acquired in organocatalysis and other fields to perform reactions that would be otherwise impossible. Merging organocatalysis with photo-, metallo- and organocatalysis itself, researchers have ingeniously devised a range of activations. This feature review, focusing on selected synergistic catalytic approaches, aims

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Reyes, Efraim, Liher Prieto, and Andrea Milelli. "Asymmetric Organocatalysis: A Survival Guide to Medicinal Chemists." Molecules 28, no. 1 (2022): 271. http://dx.doi.org/10.3390/molecules28010271.

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Majority of drugs act by interacting with chiral counterparts, e.g., proteins, and we are, unfortunately, well-aware of how chirality can negatively impact the outcome of a therapeutic regime. The number of chiral, non-racemic drugs on the market is increasing, and it is becoming ever more important to prepare these compounds in a safe, economic, and environmentally sustainable fashion. Asymmetric organocatalysis has a long history, but it began its renaissance era only during the first years of the millennium. Since then, this field has reached an extraordinary level, as confirmed by the awar

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Kalek, Marcin, Manoj Ghosh, and Adam Rajkiewicz. "Organocatalytic Group Transfer Reactions with Hypervalent Iodine Reagents." Synthesis 51, no. 02 (2018): 359–70. http://dx.doi.org/10.1055/s-0037-1609639.

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In recent years, a plethora of synthetic methods that employ hypervalent iodine compounds donating an atom or a group of atoms to an acceptor molecule have been developed. Several of these transformations utilize organocatalysis, which complements well the economic and environmental advantages offered by iodine reagents. This short review provides a systematic survey of the organocatalytic approaches that have been used to promote group transfer from hypervalent iodine species. It covers both the reactions in which an organocatalyst is applied to activate the acceptor, as well as those that ex

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K, Gayathiri. "A Survey on Brain Tumor Segmentation Using Deep Learning for MRI Images." International Journal for Research in Applied Science and Engineering Technology 13, no. 2 (2025): 120–25. https://doi.org/10.22214/ijraset.2025.66771.

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The synthesis of aminobenzylnaphthols by organocatalysis has generated interest due to the mild reaction conditions and environmental benefits. It has been shown that (1,4-diazacyclo[2.2.2]octane) has demonstrated high efficiency as an organocatalyst for the three component condensation reaction. These reactions lead to the synthesis of a novel class of aminobenzylnaphthols under various solvent conditions offering remarkable advantages like: mild reaction conditions, high yields, selectivity and simplicity. This protocol is particularly appealing for the synthesis of complex organic molecules

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Dissertations / Theses on the topic "Organocatalysis"

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He, Hao. "Organocatalysis : hydrazine and sulfonimide as new functionalities in asymmetric organocatalysis." HKBU Institutional Repository, 2009. http://repository.hkbu.edu.hk/etd_ra/1104.

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Bécart, Diane. "Bioinspired catalysis using oligourea helical foldamers." Thesis, Bordeaux, 2017. http://www.theses.fr/2017BORD0717/document.

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Catalyse et repliement sont deux notions intimement liées dans la Nature à travers les protéines et les enzymes, puis par extension, avec les catalyseurs synthétiques conçus par les chimistes. Des briques élémentaires artificielles ont été développées depuis deux décennies afin de synthétiser de nouvelles architectures moléculaires ayant une forte propension à se replier, appelées foldamères. Dans de nombreux systèmes biomimétiques inspirés par les biopolymères, la stabilisation d’une forme repliée résulte de la formation d’un fort réseau de liaisons H. Ces squelettes repliés apportent plusieu

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Liu, Chunhui. "Computational studies on organocatalysis." Doctoral thesis, Universitat Rovira i Virgili, 2013. http://hdl.handle.net/10803/129287.

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Durant molt temps, catàlisi homogènia ha estat gairebé sinònim amb catàlisi amb met¬alls de transició, amb un petit espai reservat a la biocatàlisi. Les coses han canviat molt en els últims anys. Des d'aproximadament l'any 2000, l'organocatàlisi, on el catalitzador és una molècula orgànica petita, sovint amb propietats quirals, ha crescut ràpidament fins a esdevenir un dels camps més importants de la química orgànica. A mesura que el camp de la investigació s'expandeix, el coneixement mecanístic esdevé més crítica per entendre les subtileses de la reacció i ajudar en el desenvolupament de proc

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Thomson, James E. "Î²-amino acid organocatalysis." Thesis, University of Oxford, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.442988.

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Jin, X. "Asymmetric organocatalysis in flow." Thesis, University of Cambridge, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.605607.

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This thesis is divided into two sections. In Section I, the desymmetrisation of a <i>meso-</i>cyclic anhydride was described. However, the transformation requires extremely low temperatures (-55°C) and a long reaction time (96 h) in order to achieve high enantioselectivity, which is not feasible for transfer into a continuous flow system. Later on, the work turned to investigation of its application towards the synthesis of chiral cyclopentanes using new enabling technologies. In Section II, the enantioselective Michael addition of aldehydes to nitroethylene in flow was described. The process

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Taylor, James Edward. "New applications of organocatalysis." Thesis, University of Bath, 2011. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.547629.

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New applications of organocatalysis, in particular the use of the bicyclic amidine DBN (1,5-diazabicyclo[4.3.0]non-5-ene) and then iodide as nucleophilic catalysts for Friedel-Crafts reactions, have been investigated. Firstly, the use of amidines and guanidines as nucleophilic catalysts is reviewed. Amidines and guanidines are traditionally thought of as strong, non-nucleophilic bases. However, there is increasing evidence to suggest that amidines and guanidines are actually strong nucleophiles and can act as catalysts in a number of reactions. The development of the first organocatalytic Frie

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Dingwall, Paul. "Mechanistic insights into organocatalysis." Thesis, Imperial College London, 2013. http://hdl.handle.net/10044/1/22181.

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With a resurgence of interest at the turn of the millennium, organocatalysis has become an established field in chemical research. Proline, in particular, has played a central role in the profusion of research. As the archetypal organocatalyst, proline mediated transformations have acted as a point of reference against which the performance of new developments in the field are benchmarked and compared. The field as a whole has benefited from a timely merging of complementary experimental, kinetic, and computational studies, through which a comprehensive picture of reaction mechanisms has been

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Montroni, Elisa <1986&gt. "New Methods in Organocatalysis." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2014. http://amsdottorato.unibo.it/6336/1/Montroni_Elisa_tesi.pdf.

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In the following chapters new methods in organocatalysis are described. The design of new catalysts is explored starting from the synthesis and the study of ion tagged prolines to their applications and recycle, then moving to the synthesis of new bicyclic diarylprolinol silyl ethers and their use in organocatalytic transformations. The study of new organocatalytic reaction is also investigated, in particular bifunctional thioureas are employed to catalyse the conjugate addition of nitro compounds to 3-yilidene oxindoles in sequential and domino reactions. Finally, preliminary results on pho

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Montroni, Elisa <1986&gt. "New Methods in Organocatalysis." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2014. http://amsdottorato.unibo.it/6336/.

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In the following chapters new methods in organocatalysis are described. The design of new catalysts is explored starting from the synthesis and the study of ion tagged prolines to their applications and recycle, then moving to the synthesis of new bicyclic diarylprolinol silyl ethers and their use in organocatalytic transformations. The study of new organocatalytic reaction is also investigated, in particular bifunctional thioureas are employed to catalyse the conjugate addition of nitro compounds to 3-yilidene oxindoles in sequential and domino reactions. Finally, preliminary results on pho

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Sasso, d'Elia Cecilia. "Organocatalyse et multiple bond-forming transformations (MBFTs) comme outils pour le contrôle de la chiralité." Thesis, Aix-Marseille, 2017. http://www.theses.fr/2017AIXM0371.

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Depuis des dizaines d’années, les chimistes organiciens ont accru leurs capacités à synthétiser des molécules complexes de manière exponentielle par le développement de nouvelles méthodes toujours plus élaborées. Malgré ces accomplissements, le challenge de synthétiser de nouvelles molécules toujours plus complexes de manière sélective et efficace reste toujours d’actualité. Dans le premier chapitre, nous introduirons la notion de chiralité de manière générale. Ensuite, les différentes stratégies pour contrôler la chiralité en synthèse organique seront exposées, en se focalisant plus particuli

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Books on the topic "Organocatalysis"

1

Reetz, M. T., B. List, S. Jaroch, and H. Weinmann, eds. Organocatalysis. Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-73495-6.

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T, Reetz Manfred, and Ernst Schering Research Foundation, eds. Organocatalysis. Springer, 2008.

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List, Benjamin, ed. Asymmetric Organocatalysis. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-02815-1.

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Torres, Ramon Rios, ed. Stereoselective Organocatalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118604755.

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Dalko, Peter I., ed. Comprehensive Enantioselective Organocatalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527658862.

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Biju, Akkattu T. N-Heterocyclic Carbenes in Organocatalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2018. http://dx.doi.org/10.1002/9783527809042.

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Pellissier, Hélène. Recent developments in asymmetric organocatalysis. RSC Pub., 2010.

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Keiji, Maruoka, ed. Science of synthesis: Asymmetric organocatalysis. Georg Thieme, 2012.

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Waser, Mario. Asymmetric Organocatalysis in Natural Product Syntheses. Springer Vienna, 2012. http://dx.doi.org/10.1007/978-3-7091-1163-5.

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Domínguez de María, Pablo, ed. Ionic Liquids in Biotransformations and Organocatalysis. John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9781118158753.

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Book chapters on the topic "Organocatalysis"

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Zhang, Wei. "Fluorous Organocatalysis." In Topics in Current Chemistry. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/128_2011_257.

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Liu, W. J., N. Li, and L. Z. Gong. "Asymmetric Organocatalysis." In Asymmetric Catalysis from a Chinese Perspective. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-19472-6_6.

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Basak, Puja, and Pranab Ghosh. "Green Organocatalysis." In Green Organic Reactions. Springer Singapore, 2021. http://dx.doi.org/10.1007/978-981-33-6897-2_9.

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Rios, Ramon, and Xavier Companyó. "Introduction: A Historical Point of View." In Stereoselective Organocatalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118604755.ch01.

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Moyano, Albert. "Activation Modes In Asymmetric Organocatalysis." In Stereoselective Organocatalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118604755.ch02.

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Gryko, Dorota, and Dominika Walaszek. "C-C Bond Formation by Aldol Reaction." In Stereoselective Organocatalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118604755.ch03.

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Córdova, Armando. "Examples of Metal-Free Direct Catalytic Asymmetric Mannich-Type Reactions Using Aminocatalysis." In Stereoselective Organocatalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118604755.ch04.

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Zhang, Yong, and Wei Wang. "CC Bond Formation by Michael Reaction." In Stereoselective Organocatalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118604755.ch05.

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Franzéen, Johan. "CC Bond Formation By Diels-Alder and Other Pericyclic Reactions." In Stereoselective Organocatalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118604755.ch06.

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Chen, Xiang-Yu, and Song Ye. "N-Heterocyclic Carbene-Catalyzed C-C Bond Formation." In Stereoselective Organocatalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118604755.ch07.

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Conference papers on the topic "Organocatalysis"

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LIST, BENJAMIN. "CHALLENGES FOR ORGANOCATALYSIS." In 24th International Solvay Conference on Chemistry. WORLD SCIENTIFIC, 2018. http://dx.doi.org/10.1142/9789813237179_0010.

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GRUBBS, ROBERT H. "HOMOGENEOUS CATALYSIS: ORGANOMETALLIC CATALYSIS AND ORGANOCATALYSIS." In 24th International Solvay Conference on Chemistry. WORLD SCIENTIFIC, 2018. http://dx.doi.org/10.1142/9789813237179_0001.

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JØRGENSEN, KARL ANKER. "ORGANOCATALYSIS — FROM LABORATORY SCALE TO INDUSTRIAL PROCESSES." In 24th International Solvay Conference on Chemistry. WORLD SCIENTIFIC, 2018. http://dx.doi.org/10.1142/9789813237179_0005.

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Gonçalves, A. C., and A. A. Dos Santos. "Seleno-amino acid-based helical polymers for organocatalysis and functionalization of nanoparticles." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_201391516843.

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Simões, Juliana B., Ângelo de Fátima, Adão A. Sabino, et al. "Organocatalysis in the Three-Component Povarov Reaction and Mechanistic Investigation by Mass Spectrometry." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013912173359.

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Cassaro, R. F., G. Sakae, L. M. Takata, A. dos Santos, R. A. Gariani, and R. C. Bazito. "Investigation of proline derivatives for the efficient organocatalysis of an Aldol type reaction in supercritical CO2." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_201382017856.

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Cossío, Fernando, Maddalen Agirre, Maria de Gracia Retamosa, and Andrea Ruiz-Olalla. "Dimers Derived From Densely Substituted Unnatural Prolines As Precursors Of γ‑Peptides And Their Use In Organocatalysis." In MOL2NET 2016, International Conference on Multidisciplinary Sciences, 2nd edition. MDPI, 2016. http://dx.doi.org/10.3390/mol2net-02-08011.

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Estévez, Ramón J., Rosalino Balo, Andrés Fernández, and Juan C. Estévez. "Organocatalytic Properties of 3,4-Dihydroxyprolines." In International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2023. http://dx.doi.org/10.3390/ecsoc-27-16117.

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Soares, Bruna Miranda, and Andréa Maria Aguilar. "Studies in Organocatalysts Synthesis for Direct Aldol Reaction." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0252-1.

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Deobald, Anna Maria, Arlene G. Corrêa, and Márcio W. Paixão. "Application of New Organocatalysts on Asymmetric Epoxidation of Chalcones." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0188-2.

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