Academic literature on the topic 'Organocatalyst'

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Journal articles on the topic "Organocatalyst"

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Shaikh, Isak Rajjak. "Organocatalysis: Key Trends in Green Synthetic Chemistry, Challenges, Scope towards Heterogenization, and Importance from Research and Industrial Point of View." Journal of Catalysts 2014 (March 26, 2014): 1–35. http://dx.doi.org/10.1155/2014/402860.

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This paper purports to review catalysis, particularly the organocatalysis and its origin, key trends, challenges, examples, scope, and importance. The definition of organocatalyst corresponds to a low molecular weight organic molecule which in stoichiometric amounts catalyzes a chemical reaction. In this review, the use of the term heterogenized organocatalyst will be exclusively confined to a catalytic system containing an organic molecule immobilized onto some sort of support material and is responsible for accelerating a chemical reaction. Firstly, a brief description of the field is provid
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Noraishah Abdullah, Zurina Shaameri, Ahmad Sazali Hamzah, and Mohd Fazli Mohammat. "Synthesis of Trans-4-Hydroxyprolineamide and 3-Ketoproline Ethyl Ester for Green Asymmetric Organocatalysts." Journal of Advanced Research in Applied Sciences and Engineering Technology 38, no. 1 (2024): 97–108. http://dx.doi.org/10.37934/araset.38.1.97108.

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Organocatalysts have become one of the three pillars in asymmetric reactions, along with metal catalysis and enzyme catalysis. Organocatalysis is widely acknowledged in both academia and industry as a practical and advantageous synthetic method owing to its operational ease, readily available catalyst, environmentally friendly, and minimal toxicity. Much attention has been focused on the organocatalyst for its superior properties as an efficient and clean catalyst. In this work, a series of green organocatalysts of trans-4-hydroxyprolineamide were efficiently obtained in a two-step reaction ut
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Srivastava, Vivek. "Ionic liquid mediated recyclable sulphonimide based organocatalysis for aldol reaction." Open Chemistry 8, no. 2 (2010): 269–72. http://dx.doi.org/10.2478/s11532-009-0140-x.

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AbstractSulphonimide based organocatalyst was used to catalyze the aldol reaction in ionic liquid media. On the basis of yield and selectivity the ionic liquid mediated system was found superior in comparison with organic solvents. The added advantages of this ionic liquid mediated organocatalysis are easy recovery of product and the recyclability of the organocatalyst.
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Li, Feifei, Wanting Yang, Mengmeng Li, and Lin Lei. "LED-induced controlled radical polymerization with an in situ bromine–iodine transformation and block polymerization combined with ring-opening polymerization using one organocatalyst." Polymer Chemistry 10, no. 29 (2019): 3996–4005. http://dx.doi.org/10.1039/c9py00685k.

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K, Gayathiri. "A Survey on Brain Tumor Segmentation Using Deep Learning for MRI Images." International Journal for Research in Applied Science and Engineering Technology 13, no. 2 (2025): 120–25. https://doi.org/10.22214/ijraset.2025.66771.

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The synthesis of aminobenzylnaphthols by organocatalysis has generated interest due to the mild reaction conditions and environmental benefits. It has been shown that (1,4-diazacyclo[2.2.2]octane) has demonstrated high efficiency as an organocatalyst for the three component condensation reaction. These reactions lead to the synthesis of a novel class of aminobenzylnaphthols under various solvent conditions offering remarkable advantages like: mild reaction conditions, high yields, selectivity and simplicity. This protocol is particularly appealing for the synthesis of complex organic molecules
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Rani, Sushma. "Optimization of Three Components, One Pot Synthesis of Aminobenzylnaphthol Exploiting Electrophilicity of Azomethines under Varying Conditions." International Journal for Research in Applied Science and Engineering Technology 13, no. 2 (2025): 126–36. https://doi.org/10.22214/ijraset.2025.66779.

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The synthesis of aminobenzylnaphthols by organocatalysis has generated interest due to the mild reaction conditions and environmental benefits. It has been shown that (1,4-diazacyclo[2.2.2]octane) has demonstrated high efficiency as an organocatalyst for the three component condensation reaction. These reactions lead to the synthesis of a novel class of aminobenzylnaphthols under various solvent conditions offering remarkable advantages like: mild reaction conditions, high yields, selectivity and simplicity. This protocol is particularly appealing for the synthesis of complex organic molecules
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Rani, Sushma. "Optimization of Three Component, One Pot Synthesis of aminobenzylnaphthol Exploiting Electrophilicity of azomethines Under Varying Conditions." International Journal for Research in Applied Science and Engineering Technology 13, no. 6 (2025): 1432–42. https://doi.org/10.22214/ijraset.2025.72431.

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The synthesis of aminobenzylnaphthols by organocatalysis has generated interest due to the mild reaction conditions and environmental benefits. It has been shown that (1,4-diazacyclo[2.2.2]octane) has demonstrated high efficiency as an organocatalyst for the three component condensation reaction. These reactions lead to the synthesis of a novel class of aminobenzylnaphthols under various solvent conditions offering remarkable advantages like: mild reaction conditions, high yields, selectivity and simplicity. This protocol is particularly appealing for the synthesis of complex organic molecules
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Malamiri, Fatemeh, Samad Khaksar, Rashid Badri, and Elham Tahanpesar. "Organocatalytic Combinatorial Synthesis of Quinazoline, Quinoxaline and Bis(indolyl)methanes." Combinatorial Chemistry & High Throughput Screening 23, no. 1 (2020): 83–88. http://dx.doi.org/10.2174/1386207323666191213123026.

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Aim and Objective: An efficient and practical procedure for the synthesis of heterocyclic compounds such as quinazolines, quinoxalines and bis(indolyl)methanes was developed using 3,5-bis(trifluoromethyl) phenyl ammonium hexafluorophosphate (BFPHP) as a novel organocatalyst. Material and Method: All of the obtained products are known compounds and identified by IR, 1HNMR, 13CNMR and melting points. Results: Various products were obtained in good to excellent yields under reaction conditions. Conclusion: The BFPHP organocatalyst demonstrates a novel class of non-asymmetric organocatalysts, whic
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Brozinski, Hannah L., Joshua P. Delaney, and Luke C. Henderson. "A Snapshot of Ionic-Liquid-Tagged Proline-Based Organocatalysts." Australian Journal of Chemistry 66, no. 8 (2013): 844. http://dx.doi.org/10.1071/ch13218.

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This highlight focuses on the developments in ionic-liquid (IL)-tagged proline-based organocatalysts. An overview of catalyst structure and application to asymmetric transformations is provided, and a representative synthesis of an IL-tagged organocatalyst is also discussed.
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Fredriksen, Kim A., Tor E. Kristensen, and Tore Hansen. "Combined bead polymerization and Cinchona organocatalyst immobilization by thiol–ene addition." Beilstein Journal of Organic Chemistry 8 (July 20, 2012): 1126–33. http://dx.doi.org/10.3762/bjoc.8.125.

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In this work, we report an unusually concise immobilization of Cinchona organocatalysts using thiol–ene chemistry, in which catalyst immobilization and bead polymerization is combined in a single step. A solution of azo initiator, polyfunctional thiol, polyfunctional alkene and an unmodified Cinchona-derived organocatalyst in a solvent is suspended in water and copolymerized on heating by thiol–ene additions. The resultant spherical and gel-type polymer beads have been evaluated as organocatalysts in catalytic asymmetric transformations.
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Dissertations / Theses on the topic "Organocatalyst"

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Spears, Richard J. "Organocatalyst-mediated cross aldol ligation of proteins." Thesis, University of York, 2018. http://etheses.whiterose.ac.uk/22155/.

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The chemical modification of proteins to produce protein bioconjugates has revolutionised the field of chemical biology, with wide-ranging applications in cell biology and chemical medicine. Of particular note are bioconjugates linked by carbon-carbon (C-C) bonds, which are highly prized due to their hydrolytic stability. Current strategies for their synthesis, however, suffer from a number of practical limitations, such as utilising acidic/basic conditions, showing reduced reactivity in the presence of oxygen, and requiring large concentrations of chemical probe in high molar excess. This the
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Harris, David T. "New Nucleophilic Organocatalysts." Thesis, The University of Arizona, 2011. http://hdl.handle.net/10150/144597.

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Acyl-transfer reactions have become commonplace in organic synthesis and organocatalysis of these reactions is becoming increasingly popular. 4-Dimethylaminopyridine has proven to be very useful in acylations; over the recent years chiral and more reactive analogs have received much attention. Interestingly, catalysis of acyl-transfers by diamines has also been shown to be effective. We present the synthesis of several DMAP analogs containing heteroatoms near the nucleophilic nitrogen. These analogs of DMAP vary from basic amidines, oxazolines, and amines, to alcohols, and fluoro-derivatives a
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Xuereb, David J. "Strategies for organocatalyst heterogenisation and performance in selective transformations." Thesis, University of Southampton, 2012. https://eprints.soton.ac.uk/350681/.

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Various organocatalysts are successfully heterogenised to robust inorganic frameworks, such as mesoporous silicas, by following a developed methodology of covalent tethering. The structural integrity of the organocatalyst, the nature of the active-sites and verifying the covalent anchoring were characterised through spectroscopic and physical measurements. The benefits of a heterogeneous system were exemplified through recovery and recycle experiments as well as directly measuring improvements in activity and selectivity in catalytic reactions. The immobilisation technique was applied to coval
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Mahé, Olivier. "Synthèse organocatalytique de δ2-pyrazolines par addition d’aza-michael et développement d’organocatalyseurs hétérogènes à base de chitosane". Thesis, Rouen, INSA, 2011. http://www.theses.fr/2011ISAM0018.

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Une synthèse racémique organocatalytique de pyrazolines 3,5-diaryl a été développée, grâce à l'utilisation d'une guanidine comme catalyseur. Ensuite, une synthèse énantiosélective de n-boc pyrazolines 3,5-diaryl a été mise au point sous catalyse par transfert de phase, atteignant des excès énantiomériques jusqu'à 94 %. Des réactions de transprotection du groupement Boc ont permis l'accès à une variété de substituants sur l'azote N1 de la pyrazoline. Ces développements ont été exploités dans la synthèse d'une pyrazoline biologiquement active. Nous avons exploité un biopolymère chiral, le chitos
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Fleischer, Ivana [Verfasser]. "Combinatorial Organocatalyst Development and Screening of Conjugate Additions / Ivana Fleischer." München : Verlag Dr. Hut, 2010. http://d-nb.info/1009484958/34.

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Akkoca, Hasan Ufuk. "Synthesis Of Bifunctional 2-aminodmap/prolinamide Organocatalysts And Their Use In Asymmetric Michael Reaction To Afford Warfarin." Master's thesis, METU, 2010. http://etd.lib.metu.edu.tr/upload/12613984/index.pdf.

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In the first part of this thesis, the construction of the novel bifunctional proline-(1R,2R)-2-aminoDMAP organocatalyst backbone is described. Target compound has both Lewis base and Br&oslash<br>nsted acid catalaphoric sites. The Lewis base site is synthesized via selective mono-N-pyridilization of trans-(1R,2R)-cyclohexane-1,2-diamine by Cu catalysis and Br&oslash<br>nsted acid site is subsequently introduced by anchoring L-proline unit. In the second part, catalytic activities of organocatalysts are tested in asymmetric Michael addition reaction between a cyclic 1,3-dicarbonyl compound 4-hy
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Lagarde, Florian. "Nouveaux catalyseurs confinés pour la valorisation du CO2." Thesis, Ecole centrale de Marseille, 2018. http://www.theses.fr/2018ECDM0011/document.

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Les azaphosphatranes sont des entités relativement peu utilisées en catalyse organique. Cependant, ils se sont révélés être de bons catalyseurs pour la réaction de couplage entre des époxydes et le dioxyde de carbone pour former des carbonates cycliques. Les travaux de cette thèse portent sur l'optimisation de la réactivité des azaphosphatranes pour la synthèse de carbonates cycliques. Tout d'abord, une étude du confinement à différentes échelles a été réalisée. Les catalyseurs ont été étudiés en présence de silice mésoporeuse de type SBA-15 qui exacerbent leur activité. L'ajout d'un solvant o
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Lamprianidis, Panagiotis. "Photoredox catalysis with 10-phenyl-10H- phenothiazine and synthesis of a photocatalytic chiral proline-based organocatalyst." Thesis, KTH, Organisk kemi, 2020. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-293510.

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Photoredox catalysis applications for the purpose of new synthetic routes in organic and sustainable chemistry are hot topics in organic synthesis today. In the present study, the synthesis of a chiral proline-based organocatalyst functionalized with 10-phenyl-10H phenothiazine (PTH) photocatalytic moietiesis investigated and attempted for the first time. PTH, an organic photocatalyst, isstudied for its photocatalytic activity in different organic reactions, such as dehalogenation of aromatic halides and the pinacol coupling reaction between aromatic aldehydes. These transformations are otherw
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Ortayli, Oytun. "Asymmetric Synthesis Of 1,4-diamine Based Chiral Ligand And Organocatalyst And Their Applications." Master's thesis, METU, 2010. http://etd.lib.metu.edu.tr/upload/12612335/index.pdf.

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Novel 1,4-chiral diamine ligand possessing a trans-9,10-dihydro-9,10-ethanoanthracene backbone was synthesized. The synthetic plan involves first LiAlH4 reduction of the Diels-Alder adduct obtained by reaction of dimenthyl fumarate and anthracene, which is followed by reacting the corresponding alcohol and subsequent attachment of mesylate and triflate units to get good leaving groups which are available substances for introducing nitrogen units via SN2 type reactions. Consequently, by using dimesyl ester and ditriflate esters five catalysts 27, 29, 30, 33 and 38 were synthesized. The first fo
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Joyce, Jesse Jo. "The Development and Use of Chiral 4-Dimethylaminopyridine-N-Oxide as an Organocatalyst." Thesis, North Dakota State University, 2018. https://hdl.handle.net/10365/29269.

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Document incorrectly classified as a dissertation on title page (decision to classify as a thesis from NDSU Graduate School)<br>Organocatalysis is a field that has bloomed over the last decades. With the field’s promise of being able to mimic nature and afford products in a synergistic manner to traditional Lewis acid catalysis, several interesting discoveries have been made. Owing to the vastness of the field as it exists today, this document will focus on two main aspects; cinchona alkaloid (and derivatives) as used in common carbon-carbon bond forming reactions and kinetic resolution via 4-
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Books on the topic "Organocatalyst"

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Reetz, M. T., B. List, S. Jaroch, and H. Weinmann, eds. Organocatalysis. Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-73495-6.

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T, Reetz Manfred, and Ernst Schering Research Foundation, eds. Organocatalysis. Springer, 2008.

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List, Benjamin, ed. Asymmetric Organocatalysis. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-02815-1.

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Torres, Ramon Rios, ed. Stereoselective Organocatalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118604755.

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Dalko, Peter I., ed. Comprehensive Enantioselective Organocatalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527658862.

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Biju, Akkattu T. N-Heterocyclic Carbenes in Organocatalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2018. http://dx.doi.org/10.1002/9783527809042.

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Pellissier, Hélène. Recent developments in asymmetric organocatalysis. RSC Pub., 2010.

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Keiji, Maruoka, ed. Science of synthesis: Asymmetric organocatalysis. Georg Thieme, 2012.

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Waser, Mario. Asymmetric Organocatalysis in Natural Product Syntheses. Springer Vienna, 2012. http://dx.doi.org/10.1007/978-3-7091-1163-5.

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Domínguez de María, Pablo, ed. Ionic Liquids in Biotransformations and Organocatalysis. John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9781118158753.

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Book chapters on the topic "Organocatalyst"

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Huang, Yi-Bo, Wen-Bin Yi, and Chun Cai. "Thiourea Based Fluorous Organocatalyst." In Topics in Current Chemistry. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/128_2011_248.

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Haraguchi, Naoki, and Shinichi Itsuno. "Polymer-Immobilized Chiral Organocatalyst." In Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis. John Wiley & Sons, Inc., 2011. http://dx.doi.org/10.1002/9781118063965.ch2.

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Sparr, Christof, Lucie E. Zimmer, and Ryan Gilmour. "Exploiting Fluorine Conformational Effects in Organocatalyst Design: The Fluorine-Iminium IonGauche Effect." In Asymmetric Synthesis II. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527652235.ch16.

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Zhang, Wei. "Fluorous Organocatalysis." In Topics in Current Chemistry. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/128_2011_257.

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Liu, W. J., N. Li, and L. Z. Gong. "Asymmetric Organocatalysis." In Asymmetric Catalysis from a Chinese Perspective. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-19472-6_6.

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Basak, Puja, and Pranab Ghosh. "Green Organocatalysis." In Green Organic Reactions. Springer Singapore, 2021. http://dx.doi.org/10.1007/978-981-33-6897-2_9.

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Sereda, Oksana, Sobia Tabassum, and René Wilhelm. "Lewis Acid Organocatalysts." In Topics in Current Chemistry. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/128_2008_17.

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Sereda, Oksana, Sobia Tabassum, and René Wilhelm. "Lewis Acid Organocatalysts." In Topics in Current Chemistry. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-02815-1_17.

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Siyutkin, Dmitry E., Alexander S. Kucherenko, and Sergei G. Zlotin. "Ionic Liquid Organocatalysts." In Comprehensive Enantioselective Organocatalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527658862.ch22.

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Harned, Andrew M. "Other Nonnitrogenous Organocatalysts." In Nonnitrogenous Organocatalysis. CRC Press, 2017. http://dx.doi.org/10.1201/9781315371238-8.

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Conference papers on the topic "Organocatalyst"

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Sarkar, Subhankar, Rana Chatterjee, Anindita Mukherjee, Sougata Santra, Grigory V. Zyryanov, and Adinath Majee. "Zwitterionic molten salt: An efficient organocatalyst for the one-pot synthesis of propargylamines." In PROCEEDINGS OF INTERNATIONAL CONFERENCE ON RECENT TRENDS IN MECHANICAL AND MATERIALS ENGINEERING: ICRTMME 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0018526.

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Khaksar, Samad, and Roshanak Najafi Moghaddamnejad. "Pentafluorophenylammonium triflate (PFPAT): an efficient, practical, and cost-effective organocatalyst for bigginelli reaction." In The 15th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2011. http://dx.doi.org/10.3390/ecsoc-15-00581.

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Camargo, Leandro R. Simon, Rodrigo C. da Silva, Arlene G. Corrêa, Julio Z. Schpector, and Márcio W. Paixão. "Proline and Steroids: An important synergism acting as organocatalyst in enantioselective green aldol reaction." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0069-1.

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Mudila, Harish, Himanshu Kapoor та Parteek Prasher. "One pot green synthesis of α-aminophosphonates with D-Malic acid as an organocatalyst". У RECENT ADVANCES IN FUNDAMENTAL AND APPLIED SCIENCES: RAFAS2016. Author(s), 2017. http://dx.doi.org/10.1063/1.4990356.

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Abdullah, Noraishah, Zurina Shaameri, Ahmad Sazali Hamzah та Mohd Fazli Mohammat. "Asymmetric michael addition of cyclohexanones to trans-β-nitrostyrene catalyzes by prolineamide-based organocatalyst". У INTERNATIONAL CONFERENCE ON APPLIED COMPUTATIONAL INTELLIGENCE AND ANALYTICS (ACIA-2022). AIP Publishing, 2023. http://dx.doi.org/10.1063/5.0127594.

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Dekamin, Mohammadghorban, ٍEhsan Valiey, and Zahra Alirezvani. "Alkaline functionalized chitosan as highly efficient organocatalyst for the synthesis of 3-indole derivatives." In The 21st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2017. http://dx.doi.org/10.3390/ecsoc-21-04740.

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Dekamin, Mohammad, Mohammad Eslami, and ali Maleki. "Aqueous Synthesis of 2-Amino-tetrahydrobenzo[b]pyrans by a Green, Efficient and Simple Organocatalyst." In The 16th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2012. http://dx.doi.org/10.3390/ecsoc-16-01115.

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Almeida, Camila Guimarães de, Isabella Flores de Souza, Sergio Antônio Fernandes, and Mireille Le Hyaric. "p-Sulfonic acid calix[4]arene as a new reusable organocatalyst for the transesterification of vegetable oil." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013819104715.

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Dekamin, Mohammad, M. Reza Naimi-Jamal, Mehdi Farahmand, and Zahra Karimi. "Highly turnover number cyanosilylation of carbonyl compounds catalyzed by tetraethylammonium 2- (hydroxycarbamoyl)benzoate as a bifunctional organocatalyst: The role of hydrogen bonding." In The 13th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2009. http://dx.doi.org/10.3390/ecsoc-13-00194.

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Dekamin, Mohammad, Negin Rostami, and Ehsan Valiey. "Urea-Functionalized chitosan as efficient and recoverable organocatalyst for the convenient synthesis of pyrimido[4,5-<em>b</em>]quinoline-2,4-dione derivatives." In The 24th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2020. http://dx.doi.org/10.3390/ecsoc-24-08454.

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