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Journal articles on the topic 'Organometallic compounds. Carbonyl compounds. Complex compounds'

Author: Grafiati

Published: 4 June 2021

Last updated: 18 February 2022

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1

Endrich, K., P. Alburquerque, R. P. Korswagen, and M. L. Ziegler. "Über die Reaktionen von Phosphoryliden mit homodinuklearen Organometallverbindungen des Molybdän und Wolfram / On the Reaction of Phosphorylides with Homodinuclear Organometallic Compounds of Molybdenum and Tungsten." Zeitschrift für Naturforschung B 43, no. 10 (1988): 1293–306. http://dx.doi.org/10.1515/znb-1988-1015.

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We report first the complete study of the reactions of [CpMo(CO)2]2 (Mo≡Mo) (1, Cp = η5-C5H5) with salt-free phosphorus ylides Ph3P=CHR (2, Ph = C6H5; R = H (2a), CH3 (2b), C3H7 (2c), C6H5 (2d)) and with the Nal-adducts of the ylides Ph3P=CMe2 (Me = CH3), PhMe2P=CH2 and (PhO)3P=CH2. With 2, products of the type Cp(CO)2LMo-MoL(CO)2Cp (7, L = ylide) were obtained, and the salt adducts gave addition compounds of the type Cp(CO)2LMo-MoL(CO)2Cp-2NaI (12, L = ylide). These very reactive products represent novel bisphosphonioalkyl complexes, and were characterized by IR, mass and 1H NMR spectrometry.

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2

Cesari, Cristiana, Riccardo Conti, Andrea Cingolani, et al. "Synthesis and Reactivity of Poly(propyleneimine) Dendrimers Functionalized with Cyclopentadienone N-Heterocyclic-Carbene Ruthenium(0) Complexes." Catalysts 10, no. 2 (2020): 264. http://dx.doi.org/10.3390/catal10020264.

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Ligand design in metal chemistry is a fundamental step when pursuing compounds with specific reactivity. In this paper, the functionalization of the OH group in the lateral chain of the N-heterocyclic-carbene (NHC) ligand bound to a bis-carbonyl cyclopentadienone NHC ruthenium(0) complex allowed the decoration of five generations of poly(propyleneimine) (PPIs) dendrimers with up to 64 organometallic moieties. The coupling was achieved by employing carbonyldiimidazole and the formation of carbamate linkages between dendritic peripheral NH2 and lateral OH groups on ruthenium complexes. The synth

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3

Vizer, S. A., and K. B. Yerzhanov. "Heterocycles Synthesis at Carbonylation of Acetylenic Compounds." Eurasian Chemico-Technological Journal 5, no. 2 (2016): 145. http://dx.doi.org/10.18321/ectj294.

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The carbonylation of unsaturated hydrocarbons, alcohols, organic halides and other substrates catalyzed by transition metals, salts of transition metals and organometallic complexes is a wide used synthesis method of new carbonyl, carboxyl and alkoxy carbonyl containing compounds including creation or modificationt of heterocycles. The data about synthesis of heterocycles at carbonylation of acetylenic compounds have been appeared at last 20 years and are demonstrated in our review. Introduction of carbon monoxide in the catalytic reactions of acetylenic compounds permits to obtain in oneput p

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4

Mebi, Charles, Joshua Trujillo, and Anwar Bhuiyan. "Diironcarbonyl-coumarin complex: preparation, intramolecular electron transfer, and electro-generation of hydrogen." Open Chemistry 10, no. 4 (2012): 1218–22. http://dx.doi.org/10.2478/s11532-012-0048-8.

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AbstractA new organometallic complex coupling photoactive coumarin to a diironhexacarbonyl unit has been successfully prepared and its composition and electronic structure confirmed by elemental and spectroscopic analyses. Emission spectral analysis of the complex reveals photoinduced intramolecular electron transfer from coumarin to the iron-carbonyl moiety. The compound is electrochemically reduced at −1.24 V vs. Fc/Fc+. This reduction is irreversible, attesting to the instability of the complex. Electrochemical evolution of hydrogen in the presence of the complex has been studied and result

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5

Pedro, Filipe M., Ana M. Santos, Walter Baratta, and Fritz E. Kühn. "Organometallic Ruthenium Complexes: Application in the Olefination of Carbonyl Compounds." Organometallics 26, no. 2 (2007): 302–9. http://dx.doi.org/10.1021/om060508w.

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6

Collins, Scott, Yaping Hong, Gordon J. Hoover, and Jennifer R. Veit. "Additions of alkyllathanum triflates to carbonyl compounds: reactive organometallic nucleophiles." Journal of Organic Chemistry 55, no. 11 (1990): 3565–68. http://dx.doi.org/10.1021/jo00298a035.

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7

Jackson, WR, ID Rae, and MG Wong. "The Stereochemistry of Organometallic Compounds .XXVII. Nucleophilic and Electrophilic Substitution-Reactions of Conformationally Restricted Arenechromium Compounds." Australian Journal of Chemistry 39, no. 2 (1986): 303. http://dx.doi.org/10.1071/ch9860303.

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The regioselectivity of reaction of tricarbonyl (1,1- dimethylindane )chromium with selected electrophiles and nucleophiles has been shown to be influenced by the preferred conformation of the tricarbonylchromium group. Nucleophiles preferentially react at carbon atoms eclipsed by a chromium-carbonyl bond and electrophiles at carbon atoms in staggered positions. When similar reactions were attempted with some chelated arenechromium dicarbonyl phosphorus compounds only low yields of substitution products were obtained.

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8

Kauffmann, Thomas, Jan Jordan, and Karl-Uwe Voss. "Methylating Reductive Dimerization of Aromatic Carbonyl Compounds, a Novel Organometallic Reaction." Angewandte Chemie International Edition in English 30, no. 9 (1991): 1138–39. http://dx.doi.org/10.1002/anie.199111381.

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9

Wilgocki, M., T. Szymańska-Buzar, M. Jaroszewski, and J. J. Ziółowski. "ESR-spectroelectrochemical detection of organometallic W(+1) complex compounds." Radiation Physics and Chemistry 45, no. 6 (1995): 977. http://dx.doi.org/10.1016/0969-806x(95)93967-b.

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10

Omae, Iwao. "ChemInform Abstract: Carbonyl Group-Containing Organometallic Intramolecular-Coordination Five-Membered Ring Compounds." ChemInform 41, no. 31 (2010): no. http://dx.doi.org/10.1002/chin.201031227.

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11

Holloway, Clive E., and Milan Melník. "Organometallic and carbonyl compounds of cadmium: analysis of crystallographic and structural data." Journal of Organometallic Chemistry 522, no. 2 (1996): 167–75. http://dx.doi.org/10.1016/0022-328x(96)06157-8.

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12

Mendes-Burak, Jorge, Behnaz Ghaffari та Christophe Copéret. "Selective hydrogenation of α,β-unsaturated carbonyl compounds on silica-supported copper nanoparticles". Chemical Communications 55, № 2 (2019): 179–81. http://dx.doi.org/10.1039/c8cc08457b.

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Silica-supported copper nanoparticles prepared via surface organometallic chemistry are highly efficient for the selective hydrogenation of various α,β-unsaturated carbonyl compounds yielding the corresponding saturated esters, ketones, and aldehydes in the absence of additives.

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13

Alshakova, Iryna D., and Georgii I. Nikonov. "New Zinc Catalyst for Hydrosilylation of Carbonyl Compounds." Synthesis 51, no. 17 (2019): 3305–12. http://dx.doi.org/10.1055/s-0037-1611824.

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A new zinc complex was synthesized and applied in the catalytic hydrosilylation of carbonyl compounds. Optimization of the reaction conditions showed that the presence a substoichiometric amount of methanol accelerates the process significantly. The reaction can proceed at very low catalyst load (down to 0.1 mol%) under mild reaction conditions. The reaction tolerates the presence of C=C bonds, and thus can be useful for the synthesis of allylic alcohols from α,β-unsaturated aldehydes and ketones.

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14

KAUFFMANN, T., J. JORDAN, and K. U. VOSS. "ChemInform Abstract: Transition-Metal-Activated Organic Compounds. Part 35. Methylating Reductive Dimerization of Aromatic Carbonyl Compounds, a Novel Organometallic Reaction." ChemInform 22, no. 44 (2010): no. http://dx.doi.org/10.1002/chin.199144097.

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15

Ochiai, Mitsuyoshi, Hisako Hashimoto, and Hiromi Tobita. "Reactions of a hydrido(hydrosilylene)ruthenium complex with carbonyl compounds." Dalton Transactions, no. 10 (2009): 1812. http://dx.doi.org/10.1039/b819229b.

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16

Chung, Jae Woo, Myoung Eun Lee, Seok Tae Kang, and Nanthi S. Bolan. "Concentration distribution of carbonyl compounds in an industrial shipbuilding complex." KSCE Journal of Civil Engineering 18, no. 4 (2013): 927–32. http://dx.doi.org/10.1007/s12205-013-1360-3.

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17

VanAtta, Sky L., Brian A. Duclos, and David B. Green. "Microwave-Assisted Synthesis of Group 6 (Cr, Mo, W) Zerovalent Organometallic Carbonyl Compounds." Organometallics 19, no. 12 (2000): 2397–99. http://dx.doi.org/10.1021/om990977g.

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18

Noyori, Ryoji, and Masato Kitamura. "Enantioselective Addition of Organometallic Reagents to Carbonyl Compounds: Chirality Transfer, Multiplication, and Amplification." Angewandte Chemie International Edition in English 30, no. 1 (1991): 49–69. http://dx.doi.org/10.1002/anie.199100491.

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19

Holloway, Clive E., and Milan Melnik. "Manganese carbonyl and organometallic compounds: Analysis and classification of crystallographic and structural data." Journal of Organometallic Chemistry 396, no. 2-3 (1990): 129–246. http://dx.doi.org/10.1016/0022-328x(90)85465-b.

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20

Gao, Shang, Yang Liu, Yuandong Shao, Dayong Jiang, and Qian Duan. "Iron carbonyl compounds with aromatic dithiolate bridges as organometallic mimics of [FeFe] hydrogenases." Coordination Chemistry Reviews 402 (January 2020): 213081. http://dx.doi.org/10.1016/j.ccr.2019.213081.

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21

Jirásko, Robert, Michal Holčapek, Lenka Kolářová, and Tushar S. Basu Baul. "Electrospray ionization-multistage tandem mass spectrometry of complex multitin organometallic compounds." Journal of Mass Spectrometry 42, no. 7 (2007): 918–28. http://dx.doi.org/10.1002/jms.1229.

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22

Kadomtsevа, A. V., I. V. Zhdanovich, M. S. Piskunovа, A. N. Lineva, A. N. Novikova, and P. A. Loginov. "ASSESSMENT OF TOXICITY OF GERMANIUM COORDINATION COMPOUNDS." Toxicological Review, no. 2 (April 28, 2019): 16–21. http://dx.doi.org/10.36946/0869-7922-2019-2-16-21.

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The synthesis of biologically active coordination compounds and the design on their basis of effective pharmacological preparations is currently the promising area. This paper presents the results of the toxicological studies on digermanium and its complex derivatives. It should be noted that the positive medical properties of organometallic compounds of germanium are confirmed by numerous studies, therefore, the development of the methods of synthesis, as well as investigations of physicochemical and pharmacological properties of these compounds are at the center of attention.

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23

Pignon, Antoine, Erwan Le Gall, and Thierry Martens. "A new manganese-mediated, cobalt-catalyzed three-component synthesis of (diarylmethyl)sulfonamides." Beilstein Journal of Organic Chemistry 10 (February 17, 2014): 425–31. http://dx.doi.org/10.3762/bjoc.10.39.

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The synthesis of (diarylmethyl)sulfonamides and related compounds by a new manganese-mediated, cobalt-catalyzed three-component reaction between sulfonamides, carbonyl compounds and organic bromides is described. This organometallic Mannich-like process allows the formation of the coupling products within minutes at room temperature. A possible mechanism, emphasizing the crucial role of manganese is proposed.

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24

Kuninobu, Yoichiro, Yuta Nishina, Atsushi Kawata, Makoto Shouho, and Kazuhiko Takai. "Rhenium-catalyzed synthesis of indene derivatives via C-H bond activation." Pure and Applied Chemistry 80, no. 5 (2008): 1149–54. http://dx.doi.org/10.1351/pac200880051149.

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Rhenium complex, [ReBr(CO)3(thf)]2-catalyzed reactions between aromatic imines and either acetylenes or α,β-unsaturated carbonyl compounds gave indene derivatives in good to excellent yields. These reactions proceed via C-H bond activation, insertion of acetylenes or α,β-unsaturated carbonyl compounds, intramolecular nucleophilic cyclization, and reductive elimination. Indene derivatives were also obtained from aromatic ketones and α,β-unsaturated carbonyl compounds in the presence of catalytic amounts of the rhenium complex and p-anisidine. Sequential ruthenium-catalyzed hydroamination of aro

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25

Li, Lian-Hai, and Tak Hang Chan. "Organometallic reactions in aqueous media. Antimony-mediated allylation of carbonyl compounds with fluoride salts." Tetrahedron Letters 41, no. 26 (2000): 5009–12. http://dx.doi.org/10.1016/s0040-4039(00)00795-4.

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26

HOLLOWAY, C. E., and M. MELNIK. "ChemInform Abstract: Organometallic and Carbonyl Compounds of Cadmium: Analysis of Crystallographic and Structural Data." ChemInform 28, no. 1 (2010): no. http://dx.doi.org/10.1002/chin.199701318.

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27

Chan, Tak Hang, and Chao Jun Li. "Organometallic reactions in aqueous medium. Conversion of carbonyl compounds to 1,3-butadienes or vinyloxiranes." Organometallics 9, no. 10 (1990): 2649–50. http://dx.doi.org/10.1021/om00160a008.

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28

Lu, Wenshuo, Jihai Ma, Yang, and Tak Hang Chan. "Organometallic Reactions in Aqueous Media. Indium-Mediated 1,3-Butadien-2-ylation of Carbonyl Compounds." Organic Letters 2, no. 22 (2000): 3469–71. http://dx.doi.org/10.1021/ol000239k.

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29

Burlakov, Vladimir V., Maxim V. Andreev, Vyacheslav S. Bogdanov, Alexander F. Smol’yakov, Mariya Kh Minacheva, and Vladimir B. Shur. "Interaction of the Buchwald Seven-Membered Zirconacyclocumulene Complex with Carbonyl Compounds." Organometallics 38, no. 13 (2019): 2636–46. http://dx.doi.org/10.1021/acs.organomet.9b00190.

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30

Noe, Ralf, Doris Wingbermuehle, Gerhard Erker, Carl Krueger, and Joachim Bruckmann. "Coupling reactions of [1-(dialkylboryl)butadienyl]hafnocene complex with carbonyl compounds." Organometallics 12, no. 12 (1993): 4993–99. http://dx.doi.org/10.1021/om00036a045.

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31

Decostanzi, Mélanie, Jean-Marc Campagne, and Eric Leclerc. "Low-Temperature Intermolecular Addition of RCF2Li Compounds to Various Carbonyl Electrophiles for a Practical Synthesis of CF2-Containing Building Blocks." Synthesis 48, no. 19 (2016): 3420–28. http://dx.doi.org/10.1055/s-0035-1562786.

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The addition of various RCF2Li compounds to a wide range of carbonyl electrophiles (aldehydes, ketones, acylsilanes, esters, and lactones) is reported. The reaction proceeds at very low temperature under Barbier conditions through a Br/Li exchange from the corresponding RCF2Br compounds. In contrast with existing methods that use more stable, but less reactive, organometallic species, there is efficient addition to esters, lactones and poorly reactive ketones.

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32

Jonas, Volker, Gernot Frenking, and Manfred T. Reetz. "Theoretical Studies of Organometallic Compounds. XVII. Mechanism of the Chelation Controlled Addition of CH3TiCl3 to .alpha.-Alkoxy Carbonyl Compounds. A Theoretical Study." Organometallics 14, no. 11 (1995): 5316–24. http://dx.doi.org/10.1021/om00011a057.

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33

Dembinski, Roman, Renata Kaczmarek, Dariusz Korczyński, and Karolina Królewska-Golińska. "Organometallic Nucleosides: Synthesis and Biological Evaluation of Substituted Dicobalt Hexacarbonyl Alkynyl Modified 2′-Deoxyuridines." Proceedings 22, no. 1 (2019): 62. http://dx.doi.org/10.3390/proceedings2019022062.

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In continuation of synthetic pursuit of metallo-nucleosides, in particular dicobalt hexacarbonyl 5-alkynyl-2′-deoxyuridines, novel compounds with alkynyl groups were synthesized, starting from 5-iodo-2′-deoxyuridine. Reactions of dicobalt octacarbonyl [Co2(CO)8] with 2′-deoxy-5-oxopropynyluridines and related compounds gave dicobalt hexacarbonyl nucleoside complexes (83–31%). The growth inhibition of HeLa and K562 cancer cell lines by organometallic nucleosides was examined and compared to that by alkynyl nucleoside precursors. Coordination of the dicobalt carbonyl moiety to the 2′-deoxy-5-alk

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34

Bugarcic, Zorica, Slobodan Novokmet, and Vladan Kostic. "Selective oxidation of some primary and secondary benzylic alcohols to the corresponding carbonyl compounds with a Cu(III) complex." Journal of the Serbian Chemical Society 70, no. 5 (2005): 681–86. http://dx.doi.org/10.2298/jsc0505681b.

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The selective oxidation of benzylic alcohols to the corresponding carbonyl compounds is described. In alkaline solution, the oxidation reagent potassium tetrasodium diperiodatocuprate(III) dodecahydrate (KNa4[Cu(HIO6)2[12H2O] reacts with primary and secondary benzylic alcohols whereby good yields of the corresponding carbonyl compounds are obtained. The presented method provides for the selective oxidation of the benzylic hydroxyl group in compounds containing other types of alcoholic functional groups.

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35

Gebhardt, Benjamin, Zois Syrgiannis, Claudia Backes, Ralf Graupner, Frank Hauke, and Andreas Hirsch. "Carbon Nanotube Sidewall Functionalization with Carbonyl Compounds—Modified Birch Conditions vs the Organometallic Reduction Approach." Journal of the American Chemical Society 133, no. 20 (2011): 7985–95. http://dx.doi.org/10.1021/ja2016872.

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36

HOLLOWAY, C. E., and M. MELNIK. "ChemInform Abstract: Manganese Carbonyl and Organometallic Compounds: Analysis and Classification of Crystallographic and Structural Data." ChemInform 22, no. 2 (2010): no. http://dx.doi.org/10.1002/chin.199102379.

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37

NOYORI, R., and M. KITAMURA. "ChemInform Abstract: Enantioselective Addition of Organometallic Reagents to Carbonyl Compounds: Chirality Transfer, Multiplication and Amplification." ChemInform 22, no. 14 (2010): no. http://dx.doi.org/10.1002/chin.199114331.

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38

Ugo, R., C. Dossi, and R. Psaro. "Molecular metal carbonyl clusters and volatile organometallic compounds for tailored mono and bimetallic heterogeneous catalysts." Journal of Molecular Catalysis A: Chemical 107, no. 1-3 (1996): 13–22. http://dx.doi.org/10.1016/1381-1169(95)00162-x.

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39

Jang, Sumin, and Hyunwoo Kim. "Chiral 1H NMR Analysis of Carbonyl Compounds Enabled by Cationic Cobalt Complex." Organic Letters 22, no. 11 (2020): 4185–89. http://dx.doi.org/10.1021/acs.orglett.0c01256.

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40

Shibata, Takanori, Kyoji Tsuchikama, and Yusuke Yoshinami. "Rhodium-Complex-Catalyzed [2+2+2] Cycloaddition of Diynes and Carbonyl Compounds." Synlett 2007, no. 9 (2007): 1395–98. http://dx.doi.org/10.1055/s-2007-980352.

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41

Phukan, Prodeep, and A. Sudalai. "Chemoselective Transfer Hydrogenation of Carbonyl Compounds Catalyzed by Macrocyclic Nickel (II)Complex." Synthetic Communications 30, no. 13 (2000): 2401–5. http://dx.doi.org/10.1080/00397910008086882.

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42

Yanagisawa, Akira, Nan Yang, and Kentaro Bamba. "Asymmetric Allylation of Carbonyl Compounds Catalyzed by a Chiral Phosphine-Silver Complex." European Journal of Organic Chemistry 2017, no. 45 (2017): 6614–18. http://dx.doi.org/10.1002/ejoc.201701177.

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43

Shashikumar, K., Suraj B. Maldode, Sachinkumar Sajjanar, et al. "Phosphine‐Free Ruthenium Complex for Hydrogenation of Carbonyl Compounds: Synthesis and Applications." ChemistrySelect 6, no. 32 (2021): 8411–15. http://dx.doi.org/10.1002/slct.202101775.

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44

Cheng, Jie, Jianwei Shao, Yifei Ye, et al. "Microfluidic Preconcentration Chip with Self-Assembled Chemical Modified Surface for Trace Carbonyl Compounds Detection." Sensors 18, no. 12 (2018): 4402. http://dx.doi.org/10.3390/s18124402.

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Carbonyl compounds in water sources are typical characteristic pollutants, which are important indicators in the health risk assessment of water quality. Commonly used analytical chemistry methods face issues such as complex operations, low sensitivity, and long analysis times. Here, we report a silicon microfluidic device based on click chemical surface modification that was engineered to achieve rapid, convenient and efficient capture of trace level carbonyl compounds in liquid solvent. The micro pillar arrays of the chip and microfluidic channels were designed under the basis of finite elem

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45

Musaev, Yurii I., Eleonora B. Musaeva, Svetlana Yu Khashirova, Marina O. Sanakoeva, and Artur E. Baykaziev. "Synthesis of Aromatic Diketoximes and their Complexes with Nickel Salts." Key Engineering Materials 869 (October 2020): 571–76. http://dx.doi.org/10.4028/www.scientific.net/kem.869.571.

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The diketoximes of 4,4'-diacetyldiphenyl oxide and 4,4'-diacetyldiphenyl sulfide were synthesized, the possibility of their use for the synthesis of simple and complex polyesters and polypyrroles, as well as the ability to complex with nickel salts. Organic chemistry used oximes in the 19th century, afterward, as an analytical reagent in the 20th century. Currently, oximes are superior to carbonyl compounds and alcohols in the variety of reactions and the widespread use in synthetic chemistry. Oximes easily turn into other classes of organic compounds – amines, cyano and nitro compounds, carbo

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46

Lu, Wenshuo, Jihai Ma, Yang Yang, and Tak Hang Chan. "ChemInform Abstract: Organometallic Reactions in Aqueous Media. Indium-Mediated 1,3-Butadien-2-ylation of Carbonyl Compounds." ChemInform 32, no. 12 (2001): no. http://dx.doi.org/10.1002/chin.200112067.

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47

Li, Lian-Hai, and Tak Hang Chan. "ChemInform Abstract: Organometallic Reactions in Aqueous Media. Antimony-Mediated Allylation of Carbonyl Compounds with Fluoride Salts." ChemInform 31, no. 40 (2000): no. http://dx.doi.org/10.1002/chin.200040054.

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48

Li, Lian-Hai, and Tak Hang Chan. "Organometallic reactions in aqueous media Antimony-mediated allylation of carbonyl compounds and the nature of allylstibine intermediates." Canadian Journal of Chemistry 79, no. 11 (2001): 1536–40. http://dx.doi.org/10.1139/v01-128.

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Commercial antimony metal, in aqueous 1 M H(D)Cl solution, reacts with allyl bromide and aldehydes to give the corresponding homoallylic alcohols in good yield. The reaction proceeds through the formation of allylstibine intermediates. The structures of the allylstibine intermediates are likely to be allylstibine dibromide and diallylstibine bromide.Key words: allylation reaction, aqueous organometallic reactions, homoallylic alcohols, allylstibine dibromide, diallylstibine bromide.

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49

Rest, G., L. B. Jensen, S. Abdel Azeim, P. Mourgues, and H. E. Audier. "Reactions of [NH3+·, H2O] with carbonyl compounds: A McLafferty rearrangement within a complex?" Journal of the American Society for Mass Spectrometry 15, no. 7 (2004): 966–71. http://dx.doi.org/10.1016/j.jasms.2004.05.001.

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50

Takaya, Hikaru, Sachiko Kojima, and Shun-Ichi Murahashi. "Rhodium Complex-Catalyzed Reaction of Isonitriles with Carbonyl Compounds: Catalytic Synthesis of Pyrroles." Organic Letters 3, no. 3 (2001): 421–24. http://dx.doi.org/10.1021/ol0069296.

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