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Dissertations / Theses on the topic 'Organometallic compounds'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Williams, Michael Lloyd. "New aspects of organometallic chemistry /." Title page, contents and abstract only, 1985. http://web4.library.adelaide.edu.au/theses/09PH/09phw725.pdf.

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2

Wu, Jingcun. "Photoelectron spectroscopy of organometallic compounds." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp04/mq28691.pdf.

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3

Martin, Jeffrey Thomas. "Organometallic nitrosyl hydrides of tungsten." Thesis, University of British Columbia, 1987. http://hdl.handle.net/2429/27449.

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Although hydrides of metal carbonyls are widely known, the number of hydrides in the related family of metal nitrosyls is extremely small. The preparation of a series of nitrosyl hydrides from the treatment of [CpW(NO)I₂]₂ (Cp=ƞ⁵-C₅H₅) with Na[H₂Al(OCH₂CH₂OCH₃)₂] is described. The addition of one or two equivalents of the aluminum reagent results in the formation of [CpW(NO)IH]₂ or [CpW(NO)H₂]₂ respectively. The reaction of [CpW(NO)IH]₂ with a Lewis base (L=P(OPh)₃, P(OMe)₃, PPh₃ or PMe₃) gives the monometallic CpW(NO)IHL, while [CpW(NO)H₂]₂ reacts with P(OPh)₃ or P(OMe)₃ to yield [CpW(NO)HL]₂

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4

Watkin, John Graham. "Low-valent organometallic compounds of niobium." Thesis, University of Oxford, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.236173.

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5

Tooze, R. P. "Organometallic compounds of platinum group metals." Thesis, Imperial College London, 1985. http://hdl.handle.net/10044/1/37880.

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6

Callahan, Ryan Patrick. "The synthesis of perfluorinated compounds by direct fluorination organometallic compounds and carboranes /." Access restricted to users with UT Austin EID Full text (PDF) from UMI/Dissertation Abstracts International, 2001. http://wwwlib.umi.com/cr/utexas/fullcit?p3036160.

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7

Tagg, Woo Chiat, and n/a. "Novel fluorescent organometallic materials." University of Otago. Department of Chemistry, 2009. http://adt.otago.ac.nz./public/adt-NZDU20090430.133100.

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This thesis describes the synthesis and properties of some extended donor-acceptor dyads with the donor being a ferrocenyl moiety and a fluorescent naphthalimide group as the acceptor. Two series of extended ferrocenyl-naphthalimide dyads were prepared in reasonable yield depending on the synthetic route. The first are a series of three ferrocenyl-CH=CH-spacer-C[triple bond]C-naphthalimide dyads in which the spacers are phenyl, biphenyl and anthryl and the second are a series of three ferrocenyl-C[triple bond]C-spacer-C[triple bond]C-naphthalimide dyads in which the spacers are 2,2� -bithiophe

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8

Yonchev, Raycho. "Permeation of organometallic compounds through phspholipid membranes." [S.l.] : [s.n.], 2005. http://deposit.ddb.de/cgi-bin/dokserv?idn=979680972.

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9

Lawrence, Heather Bunting Elizabeth. "Organometallic compounds with non-linear optical properties." Thesis, University of Oxford, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.276835.

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10

Rafferty, Karen. "Novel organometallic compounds as potential antitumour agents." Thesis, University of Leeds, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.487773.

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11

Davies, C. L. "Vibrational studies of inorganic and organometallic compounds." Thesis, University of Nottingham, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.380175.

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12

SoÌˆezerli, Sebnem Esen. "Organometallic compounds with bulky silyl-substituted ligands." Thesis, University of Sussex, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.388678.

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13

Quayle, Michael John. "Structural studies on organic and organometallic compounds." Thesis, University of Bristol, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.266881.

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14

McGilligan, Brian Stephen. "Organometallic and related compounds of transition metals." Thesis, Imperial College London, 1990. http://hdl.handle.net/10044/1/46441.

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15

Lee, Hui Zhi Shirley. "Organometallic compounds of osmium for cancer therapy." Palaiseau, Ecole polytechnique, 2015. https://tel.archives-ouvertes.fr/tel-01232147/document.

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Cis-platin and its derivatives are the most currently used for cancer treatment. Inspired by these metallodrugs, organometallic compounds (Ti, Ru, Fe, Rh, Au…) have been developed over the years as potential candidates for anticancer drugs, some of these have entered clinical trials. Jaouen and co-workers have developed novel therapeutic agents based on ferrocene compounds analogous to tamoxifen, which show high anti-proliferative effects against two types of breast cancer cells, namely the ER+ breast carcinoma (MCF-7) and the ER- breast carcinoma (MDA-MB-231). Similarly, Leong’s group has fou

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16

Karunatilaka, Chandana. "Rotational Spectroscopy and Structures of Organometallic Compounds." Diss., The University of Arizona, 2007. http://hdl.handle.net/10150/193621.

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High-resolution pulsed beam Fourier Transform Microwave Spectroscopy (PBFTMS) technique has been used to investigate the rotational spectra, molecular structures and electronic charge distribution of organometallic and organic molecules. The thesis reports high-resolution rotational spectral findings for nine different asymmetric-top molecules in the singlet electronic ground state including: Cyclopentadienyltungstentricarbonylhydride, Bis-(cyclopentadienyl)tungstendihydride, Tetracarbonylethyleneosmium, two substituted Ferrocenes and an organic keto-enol tautomeric system, Z-2-Hydroxypyridin

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17

Drouin, Brian James. "Microwave spectra and structures of organometallic compounds." Diss., The University of Arizona, 1999. http://hdl.handle.net/10150/284416.

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The technique of pulsed-beam Fourier transform microwave spectroscopy is applied to gas-phase organometallic systems for elucidation of fundamental structural properties of the compounds. Ten organometallic species with significant catalytic and reactive properties are examined and presented. This work includes complete three-dimensional structural determinations of; methylrheniumtrioxide, cyclopentadienylthallium, tetracarbonyldihydroiron, tetracarbonyldihydroruthenium and tetracarbonylethyleneiron. Quadrupole coupling parameters are presented and discussed for the compounds; methylrheniumtri

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18

Agarwalla, Uday Sankar. "Oxygenation Reactions of Organic and Organometallic Compounds." Thesis, University of North Bengal, 2014. http://hdl.handle.net/123456789/1485.

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19

Wong, Chun Kin. "The chemistry of organometallic derivatives of oligoacetylenic silanes." HKBU Institutional Repository, 2002. http://repository.hkbu.edu.hk/etd_ra/424.

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20

Mock, Michael T. "Synthesis and reactivity of thioether-supported organoiron and low-valent iron complexes and cyanide-bridged binuclear complexes." Access to citation, abstract and download form provided by ProQuest Information and Learning Company; downloadable PDF file, 282 p, 2008. http://proquest.umi.com/pqdweb?did=1481668291&sid=19&Fmt=2&clientId=8331&RQT=309&VName=PQD.

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21

Peatt, Anna C. (Anna Clare-Doreen) 1976. "New reaction media for organometallic chemistry." Monash University, School of Chemistry, 2003. http://arrow.monash.edu.au/hdl/1959.1/5829.

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22

Yau, Benita Chui Kam. "Organometallic chemistry of phosphine complexes of iron and ruthenium." Thesis, The University of Sydney, 1992. https://hdl.handle.net/2123/26717.

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This thesis describes two projects involving the organometallic chemistry of iron and ruthenium complexes with DMPE ligands [DMPE = 1,2-bis(dimethylphosphino)ethane]. The first study involves an investigation into the kinetics and mechanisms of OH bond activation reactions of [Fe(DMPE)2]. The second project involves an investigation into the synthesis of RuH2(DMPE)2, the formation and properties of trans-[RuH(n2-H2)(DMPE)2]*, and the reactions of RuH2(DMPE)2 with alkyl and aryl thiols. In Part I of this work, the kinetics of the cis/trans isomerization of FeH(C6H5)(DMPE)2 and FeD(C6D5)(DMPE

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23

Li, Jian-Jun. "Platinum(II) hydroxo, oxo, amido, imido and hydrazido complexes /." free to MU campus, to others for purchase, 1996. http://wwwlib.umi.com/cr/mo/fullcit?p9720553.

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24

Siddiqui, Rehan Ahmad. "Experimental investigations of thermodynamic properties of organometallic compounds." Dresden TUDpress, 2009. http://d-nb.info/1000184366/04.

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25

Wallner, Olov. "Palladium-Catalyzed Synthesis and Transformations of Organometallic Compounds." Doctoral thesis, Stockholm : Dept. of Organic Chemistry, Stockholm University, 2006. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-804.

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26

Walker, Neil M. "Low-valent organometallic compounds of zirconium and hafnium." Thesis, University of Oxford, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.238179.

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27

Tolun, E. "Fast atom bombardment mass spectrometry of organometallic compounds." Thesis, University of Kent, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.370368.

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28

Armishaw, Olga Anne. "Molecular studies of organometallic carbohydrates and related compounds." Thesis, Robert Gordon University, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.360997.

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29

Jones, M. H. "Thermal decomposition of inorganic and organometallic tin compounds." Thesis, City University London, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.356325.

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30

Mills, Graham Paul. "The low pressure pyrolysis of various organometallic compounds." Thesis, University of Leicester, 1995. http://hdl.handle.net/2381/33814.

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The pyrolysis mechanisms of many organometallic compounds are of great interest because of their potential use as precursors in the production of semiconductor materials, particularly compound semiconductors of elements from groups HI and V of the periodic table. Often there are competing molecular and radical processes contributing to the overall decomposition mechanisms. This study used electron spin resonance detection of radical intermediates coupled with final product analysis to determine the relative importance of these processes. The very low pressure pyrolyses of triethylgallium, trie

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31

McKiernan, John William. "SPECIATION OF ORGANOMETALLIC COMPOUNDS USING MASS SPECTROMETRIC DETECTION." University of Cincinnati / OhioLINK, 2000. http://rave.ohiolink.edu/etdc/view?acc_num=ucin962988114.

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32

Yu, Liwen. "A Computational Study on 18+δ Organometallics". Thesis, University of North Texas, 2002. https://digital.library.unt.edu/ark:/67531/metadc3101/.

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The B3LYP density functional has been used to calculate properties of organometallic complexes of Co(CO)3 and ReBr(CO)3, with the chelating ligand 2,3-bisphosphinomaleic anhydride, in 19- and 18-electron forms. The SBKJC-21G effective core potential and associated basis set was used for metals (Co/Re) and the 6-31G* basis set was used for all other elements. The differences of bond angles, bond distances, natural atomic charges and IR vibrational frequencies were compared with the available experimental parameters. The differences between the 19- and 18-electron systems have been analyzed.

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33

Frazier, Joy Faith. "Organo-iridium compounds : synthesis, characterization and reactivity /." Thesis, This resource online, 1991. http://scholar.lib.vt.edu/theses/available/etd-08222009-040309/.

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34

Hunter, Allen Dale. "Aspects of the organometallic nitrosyl chemistry of Cr, Mo and W." Thesis, University of British Columbia, 1985. http://hdl.handle.net/2429/25824.

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The principal organometallic products resulting from the reactions of Na[(ƞ⁵-C₅H₄R)Cr(CO)₃] (R = H or Me) with allyl chlorides in THF are the green, dimeric [(ƞ⁵-C₅H₄R)Cr(CO)₃]₂ complexes (51-67% yields). The red organometallic by-products usually formed during these conversions are novel (ƞ⁶-6-alkenylfulvene)Cr(C0)₃ complexes (5-8% yields) which have been characterized completely by conventional spectroscopic methods. Dark green [W(N0)₂Cl₂]n may be synthesized in high yields by two preparative methods. The first method involves treatment of WCl₆ in CH₂Cl₂ with an excess of NO, and it proceed

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35

Cloete, Jezreel. "Synthesis and applications of functionalized pyridinyl imine complexes of palladium." Thesis, University of the Western Cape, 2005. http://etd.uwc.ac.za/index.php?module=etd&amp.

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The synthesis and characterization of pyridinyl &alpha<br>-diimine Pd(II) complexes having a functionalized hydrocarbon attached to the imino nitrogen was performed. The catalytic activity of these complexes were then evaluated in the polymerization of ethylene and in the Heck coupling reaction of methyl acrylate with iodobenzene.<br /> <br /> Unconjugated &beta<br>-diimine complexes of palladium were also synthesized and their activities towards ethylene polymerization and the Heck coupling of methyl acrylate and iodobenzene also evaluated and compared to that of the &alpha<br>-diimine comple

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36

Makanjee, Che Azad. "An experimental and theoretical investigation of unstable Fischer chromium carbene complexes." Thesis, Rhodes University, 2013. http://hdl.handle.net/10962/d1002953.

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This organometallic study involves the use organostannanes and organolithiums as precursors to chromium Fischer carbene complexes. Fischer carbenes are typically electrophilic and are stabilized by a single π-donor substituent, and contain low oxidation state metals (often but not always from Group 6). They are highly reactive and can give access to a range of biologically active compounds through cyclopropanations, insertions, coupling and photochemical reactions. Synthesis and characterization of three MOM-protected α-alkoxy organostannanes was successfully carried out via a nucleophilic add

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37

Wassink, Berend. "The redox chemistry of a variety of organometallic dinitrosyl complexes of Cr, Mo and W." Thesis, University of British Columbia, 1985. http://hdl.handle.net/2429/25993.

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An understanding of the electrochemical properties of organometallic nitrosyl compounds provides a good understanding of their chemistry and a more rational way to approach synthetic investigations. Cyclic voltammetry studies of [(ƞ)⁵-C₅H₅)Cr(NO)₂]₂ in CH₂Cl₂ and CH₃CN reveal that the dimer undergoes a single two-electron oxidation to form [(ƞ⁵⁻C₅H₅)Cr(NO)₂]⁺ which is reduced to [(ƞ⁵-C₅H₅)Cr(NO)₂]• (or [(ƞ⁵-C₅H₅)Cr(NO)₂(CH₃CN)]• in the presence of CH₃CN) in a subsequent reduction step. The radical couples to form [(ƞ⁵-C₅H₅)Cr(NO)₂]₂ or decomposes. The dimer also is reversibly reduced in a one

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38

Habrych, Malgorzata. "Mixed-ligand strategy for the preparation of manganese based single-molecule magnets." [Gainesville, Fla.] : University of Florida, 2004. http://purl.fcla.edu/fcla/etd/UFE0004815.

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39

Gorden, John David. "Low valent and mixed valent cyclopentadienyl complexes of the group 13 elements." Access restricted to users with UT Austin EID Full text (PDF) from UMI/Dissertation Abstracts International, 2001. http://wwwlib.umi.com/cr/utexas/fullcit?p3036602.

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40

Ross, Jennifer Nicola. "Alkoxy- substituted aryl- and benzyl- organotin compounds." Thesis, University of Aberdeen, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.324880.

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New organotin compounds containing alkoxy- functionalities have been prepared. The methods of preparation of the tetraorganotin species have involved three routes. Hydrostannation reactions using triphenyltin hydride have resulted in the synthesis of triphenyltin derivatives of a series of alkoxy- substituted allyl ethers. The addition of tin IV chloride, diphenyltin dichloride and phenyltin trichloride to alkoxy- substituted aryl- and benzyl- Grignard reagents have also been successful. Alkoxy- substituted benzyltin compounds have been prepared by following an alternative preparation of benzy

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41

Reade, Thomas James. "Photoactive metal-organic frameworks and related compounds." Thesis, University of Nottingham, 2014. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.755818.

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42

Turnbull, Anthony James. "Chemistry of acetylenic iron complexes." Thesis, The University of Sydney, 2000. https://hdl.handle.net/2123/27771.

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The work presented in this thesis describes the synthesis, properties and characterisation of a number of acetylide substituted iron tetraphosphine complexes. The aim of the program was to synthesise oligomeric polynuclear species where organometallic units were linked by organic acetylenic spacer units. Anunderlyingobjective of theprogrammevas to construct condensed organometallic systems in a controlled fashion. A variety of precursors to acetylenic compounds was synthesised . The complexes synthesised all contained the iron(Il) dmpe and depe skeletons (dmpe = 1,2-bis( dimethylphosphino )e

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43

Cooke, Jason. "Fe(CO)¦4(eta²-alkyne) compounds, an organometallic renaissance." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp02/NQ34751.pdf.

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44

Lind, Per. "Organic and organometallic compounds for nonlinear absorption of light." Doctoral thesis, Umeå : Department of Chemistry, Umeå University, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-965.

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45

Wong, L.-L. "Studies in reactivity and dynamic processes of organometallic compounds." Thesis, University of Oxford, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.382707.

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46

Stevenson, Maya. "The study of structure and dynamics in organometallic compounds." Thesis, University of Oxford, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.302332.

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47

Podesta, David Mark. "Thermolysis and autoxidation of selected group IVB organometallic compounds." Thesis, University of Nottingham, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.293619.

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48

Bedson, Thomas Robert. "Nanostructure fabrication using electron beam irradiation of organometallic compounds." Thesis, University of Birmingham, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.369333.

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49

Hart, Suzanne L. "Synthesis and applications of chiral-at-titanium organometallic compounds." Thesis, University of Warwick, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.245941.

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50

El-Hamruni, Salima Maherize. "Organometallic compounds containing the (dimethylaminodimethylsilyl)bis(trimethylsilyl) methyl ligand." Thesis, University of Sussex, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.326949.

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