Academic literature on the topic 'Organometallic synthesis'

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Journal articles on the topic "Organometallic synthesis"

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Khalid, Maher, and Shireen Mohammedand Amin Kalo. "Recent Developments in Weinreb Synthesis and Their Applications." Oriental Journal of Chemistry 35, no. 6 (2019): 1611–26. http://dx.doi.org/10.13005/ojc/350601.

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N-methoxy-N-methyl amides or Weinreb amides are worthy embranchment of amide group and their rich functional groups in organic synthesis become a strong else unfeasible conversion. Weinreb amides are produced as an intermediate product of the reaction of carboxylic acids, acid chloride or esters with organometallic reagents, which was first uncovered in 1981. The direct conversion of carboxylic acids or acid chlorides or esters to ketones or aldehydes using organometallic reagents do not lead in high yields, because the intermediate ketones are still highly reactive toward the organometallic r
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Laine, Richard M. "Transition Metal Catalysed Synthesis of Oligo- and Polysilazanes." Platinum Metals Review 32, no. 2 (1988): 64–71. http://dx.doi.org/10.1595/003214088x3226471.

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Organometallic polymer research offers many potential academic and industrial rewards because of the number of elemental variations possible. Unfortunately, there are no general synthetic methods as found for carbon based polymers. Transition metal catalysed dehydrocoupling reactions may prove to be generally applicable to the synthesis of silicon based organometallic polymers. We report here our efforts to synthesise organometallic polymers with a silicon-nitrogen backbone, polysilazanes, using the dehydrocoupling reaction. We also describe the synthesis of polysilazanes for use as precursors
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Dong, Zhi-Bing, and Jin-Quan Chen. "Recent Progress in Utilization of Functionalized Organometallic Reagents in Cross Coupling Reactions and Nucleophilic Additions." Synthesis 52, no. 24 (2020): 3714–34. http://dx.doi.org/10.1055/s-0040-1706550.

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AbstractOrganometallic compounds have become increasingly important in organic synthesis because of their high chemoselectivity and excellent reactivity. Recently, a variety of organometallic reagents were found to facilitate transition-metal-catalyzed cross-coupling reactions and nucleophilic addition reactions. Here, we have summarized the latest progress in cross-coupling reactions and in nucleophilic addition reactions with functionalized organometallic reagents present to illustrate their application value. Due to the tremendous contribution made by the Knochel group towards the developme
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Lewis, David E. "The beginnings of synthetic organic chemistry: Zinc alkyls and the Kazan' school." Bulletin for the History of Chemistry 27, no. 1 (2002): 37–42. https://doi.org/10.70359/bhc2002v027p037.

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The rise of organometallic compds. as tools in org. synthesis is probably best traced to the development of the Grignard addn. reaction in 1900 but the real origins of organometallic synthesis date from some 30 yr earlier in the city of Kazan' at European Russia's eastern frontier. Modern org. synthesis would be inconceivable without the formation of carbon-carbon bonds by the reaction between an organometallic reagent and a carbonyl compd. Thus, modern org. synthesis owes a great debt, to the chemists at Kazan' University and their pioneering chem. with zinc alkyls.
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Asaad, Noora, Ahmed Z. M. AL-Bassam, and Sahar S. M. Alabdullah. "Uses of organometallic compounds in chemical processes." International Journal of Research in Engineering and Innovation 06, no. 02 (2022): 98–103. http://dx.doi.org/10.36037/ijrei.2022.6203.

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This review is proposed to address knowledge of organometallic compounds (OMC) in chemical applications and show these compounds' depth scope in different scientific studies. This review is based on outlining the gap between the traditional preparations and green chemistry synthesis of organometallic materials purposes in the experimental section of a researcher's papers. The most comparative research considers the drawbacks of organometallic compounds, including their applications in industrial, clinical, drug forms, and chemical reactions. However, many organometallic compounds are inherentl
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AMIENS, C., and B. CHAUDRET. "ORGANOMETALLIC SYNTHESIS OF NANOPARTICLES." Modern Physics Letters B 21, no. 18 (2007): 1133–41. http://dx.doi.org/10.1142/s0217984907013833.

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Nanoparticles can be synthesized from metal-organic or organometallic precursors, either by classical thermal decomposition, ultrasound activation, photolysis as well as hydrogenation or hydrolysis reactions. The size, size distribution and more importantly surface state of these nanoparticles are much better controlled than when they are produced by chemical or electrochemical reduction of metal salts. Hence, metal or oxide nanoparticles can be obtained that are suitable for fundamental physics at the nanoscale, especially for magnetic studies. This is currently of particular interest as many
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Smith, Amos B., Melean Visnick, John N. Haseltine, and Paul A. Sprengeler. "Organometallic reagents in synthesis." Tetrahedron 42, no. 11 (1986): 2957–69. http://dx.doi.org/10.1016/s0040-4020(01)90586-1.

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Hanson, J. R. "Organometallic reagents in synthesis." Journal of Organometallic Chemistry 493, no. 1-2 (1995): C29. http://dx.doi.org/10.1016/0022-328x(95)90879-j.

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Heinze, Katja. "Solid-Phase Organometallic Synthesis." Chemistry - A European Journal 7, no. 13 (2001): 2922–32. http://dx.doi.org/10.1002/1521-3765(20010702)7:13<2922::aid-chem2922>3.0.co;2-m.

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Rightmire, Nicholas R., and Timothy P. Hanusa. "Advances in organometallic synthesis with mechanochemical methods." Dalton Transactions 45, no. 6 (2016): 2352–62. http://dx.doi.org/10.1039/c5dt03866a.

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Mechanochemical methods of synthesis (specifically grinding and milling) have not yet been widely used by organometallic chemists, but there is growing interest in their potential. This Perspective surveys recent developments in the field, describing the outcomes of organometallic reactions conducted in the absence of solvents.
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Dissertations / Theses on the topic "Organometallic synthesis"

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Zini, Simone. "Synthesis of manganese organometallic complexes." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2021. http://amslaurea.unibo.it/22235/.

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Il presente lavoro di tesi si inserisce in un progetto di ricerca volto alla sintesi di nuovi complessi di metalli di transizione per lo sviluppo di catalizzatori da impiegare in reazioni di catalisi omogenea. In particolare il mio progetto si è concentrato sulla sintesi di complessi organometallici di manganese con leganti carbenici N-eterociclici (NHC). La scelta dei leganti è stata effettuata in modo tale da poter avere leganti chelanti NHC di tipo MIC (mesoionic carbene) sintetizzati tramite cicloaddizione tra un alchino ed un azide catalizzata da rame (CuAAC) e N-alchilazione. Lo studio d
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Lee, Peter D. "Organometallic synthesis in supercritical fluids." Thesis, University of Nottingham, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.336862.

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Berridge, Rory. "The synthesis of novel organometallic materials." Thesis, Sheffield Hallam University, 2001. http://shura.shu.ac.uk/19349/.

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Due to their highly interesting electroactive properties, complexes based on the sulphur heterocycle DMIT have been studied extensively for several decades. The literature is abundant with materials exhibiting semiconducting and metallic properties and up to early 2000 there are eight examples of DMIT based superconductors. In the case of the DMIT complexes, previous work has been constrained to the variation of the transition metal and/or the counter-anion. The work herein concerns the synthesis of a novel series of electroactive ligands, similar to the well-known DMIT species. In contrast to
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Abdelsalam, Mansour. "Synthesis of piperidines using organometallic chemistry." Thesis, University of Sheffield, 2013. http://etheses.whiterose.ac.uk/4069/.

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Ashcroft, R. C. "Organometallic precursors for pillared clay synthesis." Thesis, Aston University, 1993. http://publications.aston.ac.uk/9773/.

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The synthetic hectorite, laponite has been used within the paper industry to produce mildly conducting paper for use in electrographic printing. The aim of this research was to modify laponite in order to improve the electrical conductivity. In a continuation of a previous investigation involving organotin intercalation of laponite, the organotin precursor (p-CH3,OC6H4)4Sn was synthesised and characterised using Mass Spectroscopy, Infrared Spectroscopy and elemental analysis. Results of intercalation with this compound and a range of organobismuth and organoantimony compounds suggested that a
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Lee, Linda I.-Lin. "Synthesis and reactivity of organometallic enediynes /." Diss., Connect to a 24 p. preview or request complete full text in PDF format. Access restricted to UC campuses, 2001. http://wwwlib.umi.com/cr/ucsd/fullcit?p3025940.

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Atefi, Farzad. "Synthesis and reactions of organometallic porphyrins." Thesis, Queensland University of Technology, 2007. https://eprints.qut.edu.au/17563/1/Farzad_Atefi_Thesis.pdf.

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This thesis reports progress in three major aspects of σ-bonded organometallic porphyrins that are described in the published papers found in chapters 4, 5 and 6. meso-Iodoporphyrins, which were prepared in a rapid, selective and high yielding methodology from the respective 1-palladioporphyrins or bromoporphyrins, are important starting materials for further functionalisations of porphyrins. Their utility was confirmed in a palladium-catalysed coupling reaction and this novel synthetic strategy could potentially be applied for iodine/bromine exchange on other organic substrates.. A 1-pal
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Atefi, Farzad. "Synthesis and reactions of organometallic porphyrins." Queensland University of Technology, 2007. http://eprints.qut.edu.au/17563/.

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This thesis reports progress in three major aspects of σ-bonded organometallic porphyrins that are described in the published papers found in chapters 4, 5 and 6. meso-Iodoporphyrins, which were prepared in a rapid, selective and high yielding methodology from the respective 1-palladioporphyrins or bromoporphyrins, are important starting materials for further functionalisations of porphyrins. Their utility was confirmed in a palladium-catalysed coupling reaction and this novel synthetic strategy could potentially be applied for iodine/bromine exchange on other organic substrates.. A 1-pal
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Qin, J. "Studies in organometallic solid state chemistry." Thesis, University of Oxford, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.379942.

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Stewart, A. S. J. "Organometallic derivatives of amino acids and peptides." Thesis, Robert Gordon University, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.376684.

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Books on the topic "Organometallic synthesis"

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1938-, King R. B., and Eisch John J. 1930-, eds. Organometallic syntheses. Elsevier Science, 1986.

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Bruce, King R., and Eisch John J, eds. Organometallic syntheses: Volume 3. Elsevier, 1986.

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Sanshiro, Komiya, ed. Synthesis of organometallic compounds: A practical guide. Wiley, 1997.

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Pomogaĭlo, A. D. Synthesis and polymerization of metal-containing monomers. CRC Press, 1994.

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Meng, Weidong. Organometallic approaches to the synthesis of tridachiapyrones. University of East Anglia, 1990.

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Dʹi︠a︡konov, Vladimir A. Dzhemilev reaction in organic and organometallic synthesis. Nova Science Publishers, 2009.

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Dʹi︠a︡konov, Vladimir A. Dzhemilev reaction in organic and organometallic synthesis. Nova Science Publishers, 2010.

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D, Garnovskiĭ A., and Kharissov Boris I, eds. Direct synthesis of coordination and organometallic compounds. Elsevier, 1999.

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Trost, Hans Klaus. Metallorganische Verbindungen nach Mass: Technik und Chemie der Metallatomsynthese. VDI Verlag, 1992.

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Pfeffer, Michel, and Jairton Dupont. Palladacycles: Synthesis, characterization and applications. Wiley-VCH, 2008.

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Book chapters on the topic "Organometallic synthesis"

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Schmalz, Hans-Günther, Battsengel Gotov, and Andreas Böttcher. "Natural Products Synthesis." In Topics in Organometallic Chemistry. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/b94494.

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Starowieyski, K. B. "Organometallic compounds: synthesis and properties." In Chemistry of Aluminium, Gallium, Indium and Thallium. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-2170-5_6.

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Bunz, Uwe, Viola Francke, Markus Klapper, Frank Uckert, and Klaus Müllen. "Polymer Synthesis with Organometallic Intermediates." In Organic Synthesis via Organometallics OSM 5. Springer Berlin Heidelberg, 1997. http://dx.doi.org/10.1007/978-3-642-49348-5_2.

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Ripin, David H. Brown. "Synthesis of “Nucleophilic” Organometallic Reagents." In Practical Synthetic Organic Chemistry. John Wiley & Sons, Inc., 2011. http://dx.doi.org/10.1002/9781118093559.ch12.

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Norman, Richard, and James M. Coxon. "Formation of carbon—carbon bonds: organometallic reagents." In Principles of Organic Synthesis. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-2166-8_6.

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Woodward, Simon. "The Primary Organometallic in Copper-Catalyzed Reactions." In Copper-Catalyzed Asymmetric Synthesis. Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527664573.ch1.

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Lubineau, A., J. Augé, and Y. Queneau. "Carbonyl additions and organometallic chemistry in water." In Organic Synthesis in Water. Springer Netherlands, 1998. http://dx.doi.org/10.1007/978-94-011-4950-1_4.

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Khan, I. A., H. S. Ahuja, K. W. Bagnall, and Lee Sinf. "43. Uranium(IV) Chloride for Organometallic Synthesis." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132524.ch43.

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Hughes, Alan N. "Bis(diphenylphosphino)methane in Organometallic Synthesis." In ACS Symposium Series. American Chemical Society, 1992. http://dx.doi.org/10.1021/bk-1992-0486.ch014.

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Jones, William D., Valerie L. Chandler, Robert P. Duttweiler, et al. "Organometallic Transformations via C-H Bond Activation." In Organometallics in Organic Synthesis 2. Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-642-74269-9_11.

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Conference papers on the topic "Organometallic synthesis"

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Santos, Fernanda M., and João H. C. Batista. "Functionalization of aromatic nitriles using hindered organometallic bases." In 15th BMOS - Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-15th_bmos_2.

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Garcia, M. Helena, Paulo J. Mendes, Pedro Florindo, and Tiago Silva. "Design and synthesis of NLO efficient organometallic molecules." In PROCEEDINGS OF THE INTERNATIONAL CONFERENCE OF COMPUTATIONAL METHODS IN SCIENCES AND ENGINEERING 2010 (ICCMSE-2010). AIP Publishing LLC, 2015. http://dx.doi.org/10.1063/1.4906731.

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Fernández-Figueiras, Adolfo, Fátima Lucio, Paula Munín, et al. "SYNTHESIS OF IMINOPHOSPHORANES AS LIGANDS FOR ORGANOMETALLIC COMPOUNDS." In The 20th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2016. http://dx.doi.org/10.3390/ecsoc-20-a016.

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Pina, Evelyn Mirella Lopes, Natália de Araujo Pereira, Rafael Augusto Soldi, and Giuliano Cesar Clososki. "Preparation and preliminiar evaluation of new organometallic bases from cis-2,6-dimethylpiperidine." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013915232924.

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Tagmatarchis, Nikos, and Kosmas Prassides. "Synthesis and characterization of organometallic compounds of fullerene derivatives." In ELECTRONIC PROPERTIES OF NOVEL MATERIALS--SCIENCE AND TECHNOLOGY OF MOLECULAR NANOSTRUCTURES. ASCE, 1999. http://dx.doi.org/10.1063/1.59779.

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Morales, M. P., A. G. Roca, and C. J. Serna. "Synthesis of Monodispersed Magnetite Particles from Different Organometallic Precursors." In INTERMAG 2006 - IEEE International Magnetics Conference. IEEE, 2006. http://dx.doi.org/10.1109/intmag.2006.376279.

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Bouachrine, M., J. P. Lère-Porte, J. Moreau, F. Serein-Spirau, and T. Lakhlifi. "An Organometallic Selective Synthesis of Conjugated Polymers with Improved Physical Properties." In The 8th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2004. http://dx.doi.org/10.3390/ecsoc-8-01994.

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Kazimova, Nargiz, Nuria Romero, Carlos A. Campos-Roldán, Marjorie Cavarroc, Sara Cavaliere, and Karine Philippot. "Organometallic Synthesis Applied To Pt-Based Nanocatalysts for Oxygen Reduction Reaction." In The 10th World Congress on Recent Advances in Nanotechnology. Avestia Publishing, 2025. https://doi.org/10.11159/icnnfc25.131.

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Yang, Hongwei, Weiling Luan, and Shan-Tung Tu. "Large-Scale Synthesis of Monodisperse Nanocrystals via Microreaction." In 2007 First International Conference on Integration and Commercialization of Micro and Nanosystems. ASMEDC, 2007. http://dx.doi.org/10.1115/mnc2007-21605.

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A microfluidic reactor was set up to synthesize quantum dots (QDs) in large scale. The increased reaction channels in an individual reactor lead to improved throughput while maintaining sufficient residence time for the nucleation and growth of QDs. Uniform reaction conditions in the four capillaries realized by our set-up result in superior stability of the whole system. Organometallic synthesis of CdSe was chosen as a model system to evaluate the reactor, the absorption spectra of samples collected from different streams at various time intervals are indistinguishable from each other. By sys
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Saliba, Sarmenio, Fabienne Gauffre, Myrtil L. Kahn, et al. "Synthesis of metal oxide nanoparticles by organometallic approach: From molecule to devices." In 2016 IEEE Nanotechnology Materials and Devices Conference (NMDC). IEEE, 2016. http://dx.doi.org/10.1109/nmdc.2016.7777146.

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Reports on the topic "Organometallic synthesis"

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Wright, Michael E., and Edward G. Toplikar. Organometallic Nonlinear Optical (NLO) Polymers. 2. Synthesis of Main-Chain Organometallic Polymers and a Structural Study of Ferrocene NLO-Phores. Defense Technical Information Center, 1992. http://dx.doi.org/10.21236/ada250655.

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Tour, James M. Organometallics for Conducting Polymer Synthesis and Starburst Polymer Synthesis. Defense Technical Information Center, 1991. http://dx.doi.org/10.21236/ada235933.

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Nolan, Steven. Synthetic and Thermodynamic Investigations of Ancillary Ligand Influence on Catalytic Organometallic Systems. Final Report. Office of Scientific and Technical Information (OSTI), 2003. http://dx.doi.org/10.2172/821151.

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Synthesis and properties of novel organometallic polymers. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/6243167.

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