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Journal articles on the topic 'Organometallic ; Thorium'

Author: Grafiati
Published: 4 June 2021
Last updated: 8 February 2022

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1

Leigh, G. J. "Gmelin handbook of inorganic and organometallic chemistry, 8th edition, thorium, thorium carbides, supplement volume C6." Journal of Organometallic Chemistry 463, no. 1-2 (December 1993): C11. http://dx.doi.org/10.1016/0022-328x(93)83431-t.

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2

Pool, Jaime A., Brian L. Scott, and Jaqueline L. Kiplinger. "Carbon–nitrogen bond cleavage in pyridine ring systems mediated by organometallic thorium(iv) complexes." Chemical Communications, no. 20 (2005): 2591. http://dx.doi.org/10.1039/b502439k.

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3

Monreal, Marisa J., Lani A. Seaman, George S. Goff, Ryszard Michalczyk, David E. Morris, Brian L. Scott, and Jaqueline L. Kiplinger. "New Twists and Turns for Actinide Chemistry: Organometallic Infinite Coordination Polymers of Thorium Diazide." Angewandte Chemie 128, no. 11 (February 10, 2016): 3695–700. http://dx.doi.org/10.1002/ange.201510851.

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4

Monreal, Marisa J., Lani A. Seaman, George S. Goff, Ryszard Michalczyk, David E. Morris, Brian L. Scott, and Jaqueline L. Kiplinger. "New Twists and Turns for Actinide Chemistry: Organometallic Infinite Coordination Polymers of Thorium Diazide." Angewandte Chemie International Edition 55, no. 11 (February 10, 2016): 3631–36. http://dx.doi.org/10.1002/anie.201510851.

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5

Inman, Christopher J., and F. Geoffrey N. Cloke. "The experimental determination of Th(iv)/Th(iii) redox potentials in organometallic thorium complexes." Dalton Transactions 48, no. 29 (2019): 10782–84. http://dx.doi.org/10.1039/c9dt01553a.

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6

Ossola, F., G. Rossetto, P. Zanella, G. Paolucci, and R. D. Fischer. "Organometallic amides of uranium(IV) and thorium(IV) involving one, two, or three cyclopentadienyl ligands." Journal of Organometallic Chemistry 309, no. 1-2 (January 1986): 55–63. http://dx.doi.org/10.1016/s0022-328x(00)99573-1.

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7

Jantunen, Kimberly C., Raymond J. Batchelor, and Daniel B. Leznoff. "Synthesis, Characterization, and Organometallic Derivatives of Diamidosilyl Ether Thorium(IV) and Uranium(IV) Halide Complexes." Organometallics 23, no. 9 (April 2004): 2186–93. http://dx.doi.org/10.1021/om0343115.

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8

Leigh, G. J. "Gmelin Handbook of Inorganic and Organometallic Chemistry, 8th edition Th, Thorium, Supplement Volume D4, Chromatography, Chemistry in Nonaqueous Solutions." Journal of Organometallic Chemistry 452, no. 1-2 (June 1993): C11. http://dx.doi.org/10.1016/0022-328x(93)83209-e.

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9

Shilova, Inessa Vladimirovna, Natal'ya Vladimirovna Baranovskaja, Rustam Niyazovich Mustafin, and Nikolay Innokent'yevich Suslov. "FEATURES OF THE COMPOSITION MACRO ELEMENTS AND TRACE ELEMENTS OF THE EXTRACT OF ALFREDIA CERNUA (L.) CASS., POSSESSING PSYCHOTROPIC EFFECT." chemistry of plant raw material, no. 4 (December 27, 2019): 191–98. http://dx.doi.org/10.14258/jcprm.2019045422.

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The 95% ethanol extract of Alfredia drooping Alfredia cernua (L.) Cass. (Asteraceae) aerial part exhibits pronounced antidepressant, nootropic and anxiolytic activity. The aim of the work was the qualitative and quantitative analysis of macro-, trace and ultra trace elements of the pharmacologically active extract of the aerial part of the plant. The study of the elemental composition of the extract was performed after ashing using instrumental neutron activation analysis with irradiation with thermal neutrons. The study found 26 elements, of which eight are (conditionally) essential, two macro elements and four trace elements. The obtained results indicate the prevalence of Alfredia cernua of calcium, zinc, sodium, strontium, bromine, as well as iron, barium, cobalt, chromium and lanthanum in the pharmacologically active extract. The extract concentrates a specific group of elements (zinc, cobalt, thorium, hafnium, bromine, chromium, lutetium, lanthanum, strontium, samarium) in comparison with the feedstock, which can be explained by the formation of strong organometallic compounds and chelate complexes. Macro-, trace and ultra trace elements can have a significant impact on metabolic processes, nervous, immune, endocrine, cardiovascular systems, they are an integral part of enzymes, give other biologically active substances an easily digestible form and potentiate their effects.
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10

Blake, Paul C., Michael F. Lappert, Richard G. Taylor, Jerry L. Atwood, and Hongming Zhang. "Some aspects of the coordination and organometallic chemistry of thorium and uranium (MIII, MIV, UV) in +3 and +4 oxidation states." Inorganica Chimica Acta 139, no. 1-2 (December 1987): 13–20. http://dx.doi.org/10.1016/s0020-1693(00)84028-1.

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11

Cantat, Thibault, Christopher R. Graves, Kimberly C. Jantunen, Carol J. Burns, Brian L. Scott, Eric J. Schelter, David E. Morris, P. Jeffrey Hay, and Jaqueline L. Kiplinger. "Evidence for the Involvement of 5f Orbitals in the Bonding and Reactivity of Organometallic Actinide Compounds: Thorium(IV) and Uranium(IV) Bis(hydrazonato) Complexes." Journal of the American Chemical Society 130, no. 51 (December 24, 2008): 17537–51. http://dx.doi.org/10.1021/ja8067287.

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12

LeFurgey, A., and P. Ingram. "Electron Probe X-Ray Microanalysis in Pathology and Research." Microscopy and Microanalysis 19, S4 (August 2013): 1–2. http://dx.doi.org/10.1017/s1431927613000627.

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A variety of frequently encountered clinical problems lend themselves readily to investigation by analytical electron microscopy. e.g., a combination of scanning or transmission electron microscopy and energy dispersive x-ray microanalysis. The most common application is identification of xenobiotics or exogenous substances, such as localization and quantitation of inorganic particulates in lung tissues in patients with pneumoconiosis; identification of foreign materials within granulomas; and analysis of foreign bodies. Electron probe X-ray microanalysis (EPXMA) is also useful in the study of tissue reactions to various surgical implants of foreign materials. A variety of metals and other elements may be detected with energy dispersive X-ray analysis, including copper in tissues of patients with Wilson’s disease, thorium and gadolinium in patients injected with radiographic contrast agents (Figure 1), or gold in patients treated with long-term chrysotherapy. Endogenous particulates such as urinary calculi (Figure 2), gallstones, intraarticular and periarticular crystalline deposits in patients with rheumatic disease, dystrophic or metastatic calcifications, and hemosiderin may be analyzed rapidly and efficiently by means of EDX. Certain organometallic drugs such as amiodarone (iodine) or sodium stibogluconate (antimony) may also be detected in human tissues. Analytical electron microscopy has been a useful adjunct to forensic pathology for many years in diverse areas such as identification of trace evidence constituents or detection of arsenic or lead in victims with heavy metal poisoning. The detailed elucidation of anatomic, physiologic, and pathologic conditions provided by analytical electron microscopy is a useful diagnostic and investigative tool in clinical medicine; the analytical results often have diagnostic, therapeutic, and/or medicolegal implications. This imaging technology should grow in utility in the future as it is complemented by other techniques such as mass spectrometry, and laser Raman and infrared microspectroscopy.
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13

Di Bella, Santo, Antonino Gulino, Giuseppe Lanza, Ignazio L. Fragala, and Tobin J. Marks. "Photoelectron spectroscopy of f element organometallic complexes. 11. An investigation of the electronic structure of some tris(.eta.5-cyclopentadienyl)thorium(IV) and -uranium(IV) complexes by relativistic effect core potential ab initio calculations and gas-phase UV photoelectron spectroscopy." Journal of Physical Chemistry 97, no. 45 (November 1993): 11673–76. http://dx.doi.org/10.1021/j100147a020.

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14

Pyykko, Pekka, Liisa J. Laakkonen, and Kazuyuki Tatsumi. "REX calculations. 12. Iteration parameters for the 5f-element organometallics of thorium-neptunium. Geometries of thorium dioxide and uranyl ion revisited." Inorganic Chemistry 28, no. 10 (May 1989): 1801–5. http://dx.doi.org/10.1021/ic00309a009.

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15

Maier, Ralph, Basil Kanellakopulos, Christos Apostolidis, Daniel Meyer, and Jean Rebizant. "Molecular structure and charge distribution in organometallics of the 4f and 5f elements V: crystal and molecular structure of tetrakis(ν5-cyclopentadienyl)-thorium(IV) and the temperature dependence of its electrical dipole moment." Journal of Alloys and Compounds 190, no. 2 (January 1993): 269–71. http://dx.doi.org/10.1016/0925-8388(93)90410-o.

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