Academic literature on the topic 'Organosulfur'

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Journal articles on the topic "Organosulfur"

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Arisawa, Mieko, and Masahiko Yamaguchi. "Transition-metal-catalyzed synthesis of organosulfur compounds." Pure and Applied Chemistry 80, no. 5 (January 1, 2008): 993–1003. http://dx.doi.org/10.1351/pac200880050993.

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Rhodium complexes are efficient catalysts for the synthesis of organosulfur compounds. They catalyze the addition reaction of organosulfur groups to unsaturated compounds, the substitution of C-H with organosulfur groups, and single-bond metathesis reactions. They cleave S-S bonds and transfer the organosulfur groups to various organic and inorganic molecules, including alkynes, allenes, disulfides, sulfur, isonitriles, imines, diphosphines, thiophosphinites, hydrogen, 1-alkylthio-1-alkynes, thioesters, and allyl sulfides.
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Qiu, Yichen, Yunchao Feng, Ashley C. Lindsay, Xianhai Zeng, and Jonathan Sperry. "Synthesis of bio-based 2-thiothiophenes." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 379, no. 2209 (September 13, 2021): 20200350. http://dx.doi.org/10.1098/rsta.2020.0350.

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While the synthesis of bio-based compounds containing carbon, oxygen and (to a lesser extent) nitrogen is well studied, the production of organosulfur compounds from biomass has received virtually no attention, despite their widespread application throughout the chemical industry. Herein, we demonstrate that a range of bio-based 2-thiothiophenes are available from the biopolymer cellulose, proving that functionally diverse small-molecule organosulfurs can be prepared independent of fossil carbon. This article is part of the theme issue ‘Bio-derived and bioinspired sustainable advanced material
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Chauvin, Jean-Philippe R., Zosia A. M. Zielinski, and Derek A. Pratt. "Inspired by garlic: insights on the chemistry of sulfenic acids and the radical-trapping antioxidant activity of organosulfur compounds." Canadian Journal of Chemistry 94, no. 1 (January 2016): 1–8. http://dx.doi.org/10.1139/cjc-2015-0438.

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Organosulfur compounds have long been recognized as important antioxidants for the preservation of petroleum-derived products. It has also been suggested that the health benefits of garlic and related plant species can be ascribed to the radical-trapping antioxidant activity of some of their unique organosulfur constituents, such as allicin. This account highlights our efforts to elucidate the radical-trapping antioxidant mechanisms of allicin and related plant-derived organosulfur compounds as well as the organosulfur compounds used to preserve commercial and industrial products.
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Shine, Henry J. "Researches in organosulfur chemistry by a non-organosulfur chemist." Sulfur reports 15, no. 3 (August 1994): 381–93. http://dx.doi.org/10.1080/01961779408050635.

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Doddipatla, Srinivas, Chao He, Ralf I. Kaiser, Yuheng Luo, Rui Sun, Galiya R. Galimova, Alexander M. Mebel, and Tom J. Millar. "A chemical dynamics study on the gas phase formation of thioformaldehyde (H2CS) and its thiohydroxycarbene isomer (HCSH)." Proceedings of the National Academy of Sciences 117, no. 37 (August 28, 2020): 22712–19. http://dx.doi.org/10.1073/pnas.2004881117.

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Complex organosulfur molecules are ubiquitous in interstellar molecular clouds, but their fundamental formation mechanisms have remained largely elusive. These processes are of critical importance in initiating a series of elementary chemical reactions, leading eventually to organosulfur molecules—among them potential precursors to iron-sulfide grains and to astrobiologically important molecules, such as the amino acid cysteine. Here, we reveal through laboratory experiments, electronic-structure theory, quasi-classical trajectory studies, and astrochemical modeling that the organosulfur chemi
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Monika, Monika, Anita Dua, Sandeep Kumar, Sanjay Sharma, Sanjeev Gupta, and Ashwani Mittal. "Profiling of organosulfur compounds and amino acids in novel variety of Allium sativum (Hisar garlic 17) by HR-LCMS-QTOF." Journal of Applied and Natural Science 16, no. 1 (March 20, 2024): 315–24. http://dx.doi.org/10.31018/jans.v16i1.5386.

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Over the past few years, the biological properties of garlic have been utilized as an attractive natural alternative to many therapeutic drugs. The biological effects of garlic have been ascribed to organosulfur compounds, secondary metabolites derived from amino acids. The present study aimed to investigate the extracts of a novel garlic variety (Hisar garlic 17) after processing it as fresh, dry, heated, and aged in different solvents and then analyzed with highly sensitive and rapid technique i.e., High resolution liquid chromatograph mass spectrometer quadrupole time of flight (HR-LCMS-QTO
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Arisawa, Mieko, and Masahiko Yamaguchi. "Rhodium-Catalyzed Synthesis of Organosulfur Compounds Involving S-S Bond Cleavage of Disulfides and Sulfur." Molecules 25, no. 16 (August 7, 2020): 3595. http://dx.doi.org/10.3390/molecules25163595.

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Organosulfur compounds are widely used for the manufacture of drugs and materials, and their synthesis in general conventionally employs nucleophilic substitution reactions of thiolate anions formed from thiols and bases. To synthesize advanced functional organosulfur compounds, development of novel synthetic methods is an important task. We have been studying the synthesis of organosulfur compounds by transition-metal catalysis using disulfides and sulfur, which are easier to handle and less odiferous than thiols. In this article, we describe our development that rhodium complexes efficiently
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Islam, Fawad, and Qingle Zeng. "Advances in Organosulfur-Based Polymers for Drug Delivery Systems." Polymers 16, no. 9 (April 25, 2024): 1207. http://dx.doi.org/10.3390/polym16091207.

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Organosulfur-based polymers have unique properties that make them useful for targeted and managed drug delivery, which can improve therapy while reducing side effects. This work aims to provide a brief review of the synthesis strategies, characterization techniques, and packages of organosulfur-based polymers in drug delivery. More importantly, this work discusses the characterization, biocompatibility, controlled release, nanotechnology, and targeted therapeutic aspects of these important structural units. This review provides not only a good comprehension of organosulfur-based polymers but a
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Egbujor, Melford Chuka, Maria Petrosino, Karim Zuhra, and Luciano Saso. "The Role of Organosulfur Compounds as Nrf2 Activators and Their Antioxidant Effects." Antioxidants 11, no. 7 (June 26, 2022): 1255. http://dx.doi.org/10.3390/antiox11071255.

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Nuclear factor erythroid 2-related factor 2 (Nrf2) signaling has become a key pathway for cellular regulation against oxidative stress and inflammation, and therefore an attractive therapeutic target. Several organosulfur compounds are reportedly activators of the Nrf2 pathway. Organosulfur compounds constitute an important class of therapeutic agents in medicinal chemistry due to their ability to participate in biosynthesis, metabolism, cellular functions, and protection of cells from oxidative damage. Sulfur has distinctive chemical properties such as a large number of oxidation states and v
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Yuen, Pong Kau, and Cheng Man Diana Lau. "New approach for assigning mean oxidation number of carbons to organonitrogen and organosulfur compounds." Chemistry Teacher International 4, no. 1 (October 8, 2021): 1–13. http://dx.doi.org/10.1515/cti-2021-0015.

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Abstract Organonitrogen and organosulfur compounds are abundant in the natural environment. To understand the biological redox pathways properly, it is important for learners to be able to count the oxidation number of organic carbons. However, the process of counting is not always easy. In addition, organonitrogen and organosulfur molecules are seldom studied. To compensate these problems, this paper explores the bond-dividing method, which can effectively determine the mean oxidation number of carbons of organonitrogen and organosulfur molecules. This method uses the cleavage of carbon-sulfu
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Dissertations / Theses on the topic "Organosulfur"

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Haughey, Simon Anthony. "Chemoenzymatic synthesis of organosulfur compounds." Thesis, Queen's University Belfast, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.318731.

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King, Alistair William Thomas. "Chemoenzymatic synthesis of chiral organosulfur compounds." Thesis, Queen's University Belfast, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.396118.

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Chowdhury, Mohima Begum Roomi. "Unsaturated organosulfur chemistry : synthesis and applications." Thesis, University College London (University of London), 2018. http://discovery.ucl.ac.uk/10045805/.

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The original focus of this thesis was ynol ether synthesis which was successful using simple and easy-to-prepare precursors (chloroacetylenes) but low yielding. Attention was then diverted to the design and synthesis of a range of thioynol ethers (alkynyl sulfides) utilising chloroacetylenes. The reaction of a chloroacetylene with a thiolate salt in the presence of an amine mediator (Me2NH or DMEDA) yielded the alkynyl sulfides in excellent yields. The alkynyl chlorides were easily prepared from the parent alkynes contrasting sharply with the cumbersome synthesis of an alkynyl sulfonamide prev
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Class, Caleb Andrew. "Predicting organosulfur chemistry in fuel sources." Thesis, Massachusetts Institute of Technology, 2015. http://hdl.handle.net/1721.1/98155.

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Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemical Engineering, 2015.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references.<br>Desulfurization of fossil fuels with supercritical water (SCW) has been the topic of many studies over the past few decades. This process does not require the use of any catalyst, eliminates the need for a hydrogen feed, and minimizes coke formation. Previous research has shown that it has the potential to be a viable commercial process, and recent experimental studies have proven that water acts as one hydrogen sou
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Shepherd, S. D. "Chemical and enzymatic synthesis of organosulfur compounds." Thesis, Anglia Ruskin University, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.396225.

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Hendrickx, Ramon Adriaan Antonius Johannes Hendrickx. "Mechanistic studies of organosulfur oxidations by dimethyldioxirane." Thesis, University of York, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.399615.

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Ramesha, A. R. "Organosulfur Reactions In Organic Synthesis With Tetrathiomolybdate." Thesis, Indian Institute of Science, 1994. https://etd.iisc.ac.in/handle/2005/107.

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Recent years have seen a dramatic expansion in synthetic and structural molybdenum - sulfur chemistry. The amplest binary Mo-S moiety in MO$ ion. The thromolybdates derived by sulfur substitution from the 0x0 analogue have interesting chemical properties. Although they have been studied extensively by synthetic inorganic chemists and bio-inorganic chemists as models for enzymes like introgenases, their reactivity towards organic substrates remamed unexplored.
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Ramesha, A. R. "Organosulfur Reactions In Organic Synthesis With Tetrathiomolybdate." Thesis, Indian Institute of Science, 1994. http://hdl.handle.net/2005/107.

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Recent years have seen a dramatic expansion in synthetic and structural molybdenum - sulfur chemistry. The amplest binary Mo-S moiety in MO$ ion. The thromolybdates derived by sulfur substitution from the 0x0 analogue have interesting chemical properties. Although they have been studied extensively by synthetic inorganic chemists and bio-inorganic chemists as models for enzymes like introgenases, their reactivity towards organic substrates remamed unexplored.
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Murray, Jane. "Selective oxidation of organosulfur substrates by hydrogen peroxide." Thesis, University of York, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.428461.

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Savoie, Paul R. "Preparation, chemistry, and characterization of hypervalent organosulfur fluorides." Thesis, State University of New York at Albany, 2015. http://pqdtopen.proquest.com/#viewpdf?dispub=3739734.

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<p> Since the discovery of the pentafluorosulfanyl (SF<sub>5</sub>) group around the 1960s, progress in exploring the chemistry of aliphatic SF<sub> 5</sub>-containing compounds stagnated because of a lack of efficient synthetic methods. More recent developments in the preparations of SF<sub>5</sub>-containing compounds afforded easier access to these compounds, and sparked great interest in exploring their chemistry. Chapter 1 discusses the development of efficient methods used to prepare SF<sub>5</sub>-containing aliphatic compounds. </p><p> This dissertation investigates the combination o
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Books on the topic "Organosulfur"

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Cremlyn, R. J. W. An introduction to organosulfur chemistry. Chichester: Wiley, 1996.

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B, Page Philip C., ed. Organosulfur chemistry. Berlin: Springer, 1999.

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Philip, Page, ed. Organosulfur chemistry. London: Academic Press, 1995.

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Page, Philip C. B., ed. Organosulfur Chemistry I. Berlin, Heidelberg: Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/3-540-48956-8.

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Page, Philip C. B., ed. Organosulfur Chemistry II. Berlin, Heidelberg: Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/3-540-48986-x.

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Saul, Patai, and Rappoport Zvi, eds. The Chemistry of sulphur-containing functional groups. Chichester [England]: Wiley, 1993.

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International Symposium on Organic Sulfur Chemistry (13th 1988 Odense, Denmark). Developments in the organic chemistry of sulfur: Proceedings of the XIII International Symposium on the Organic Chemistry of Sulfur, 7-12 August, 1988, Odense, Denmark. New York: Gordon and Breach, 1989.

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Anisimov, A. V. Molekuli͡a︡rnye peregruppirovki seroorganicheskikh soedineniĭ: Organicheskie sulʹfidy. Moskva: Izd-vo Moskovskogo universiteta, 1989.

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Mikołajczyk, Marian. Chiral sulfur reagents: Applications in asymmetric and stereoselective synthesis. Boca Raton: CRC Press, 1997.

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Berwe, Hermann. Stannathiaadamantane: Synthese, Eigenschaften und Strukturen. Bochum: D. Winkler, 1986.

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Book chapters on the topic "Organosulfur"

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Furka, Árpád. "Organosulfur Compounds." In SpringerBriefs in Molecular Science, 69–80. Cham: Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-030-06004-6_5.

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Mikołajczyk, Marian, and Jozef Drabowicz. "Chiral Organosulfur Compounds." In Topics in Stereochemistry, 333–468. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470147221.ch5.

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Lea, Michael A. "Organosulfur Compounds and Cancer." In Advances in Experimental Medicine and Biology, 147–54. Boston, MA: Springer US, 1996. http://dx.doi.org/10.1007/978-1-4613-0399-2_12.

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Bischoff, Karyn. "Glucosinolates and Organosulfur Compounds." In Nutraceuticals in Veterinary Medicine, 113–19. Cham: Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-030-04624-8_9.

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Rauchfuss, T. B. "With Organosulfur Anions [RS]-." In Inorganic Reactions and Methods, 109–15. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145203.ch85.

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Zhao, Ming Ming, Shi Hang Xiong, Guan Ding Zhao, and Hua Yu. "Organosulfur Compounds in Food." In Handbook of Dietary Phytochemicals, 1–21. Singapore: Springer Singapore, 2019. http://dx.doi.org/10.1007/978-981-13-1745-3_41-1.

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Zhao, Ming Ming, Shi Hang Xiong, Guan Ding Zhao, and Hua Yu. "Organosulfur Compounds in Food." In Handbook of Dietary Phytochemicals, 1741–61. Singapore: Springer Singapore, 2021. http://dx.doi.org/10.1007/978-981-15-4148-3_41.

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Sagdic, Osman, and Fatih Tornuk. "Antimicrobial Properties of Organosulfur Compounds." In Dietary Phytochemicals and Microbes, 127–56. Dordrecht: Springer Netherlands, 2012. http://dx.doi.org/10.1007/978-94-007-3926-0_4.

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Towl, A. D. C. "In Hydrolyses of Organosulfur Compounds." In Inorganic Reactions and Methods, 186. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145159.ch122.

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White, Curt M., L. J. Douglas, R. R. Anderson, C. E. Schmidt, and R. J. Gray. "Organosulfur Constituents in Rasa Coal." In Geochemistry of Sulfur in Fossil Fuels, 261–86. Washington, DC: American Chemical Society, 1990. http://dx.doi.org/10.1021/bk-1990-0429.ch016.

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Conference papers on the topic "Organosulfur"

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Matzka, Marco, Marianna Lucio, Basem Kanawati, Eric Quirico, Lydie Bonal, Stefan Loehle, and Philippe Schmitt-Kopplin. "Profiling of magnesium organosulfur chemistry in meteorites." In Goldschmidt2021. France: European Association of Geochemistry, 2021. http://dx.doi.org/10.7185/gold2021.4692.

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Rahman, Ramees K., Abhijeet G. Raj, and Salisu Ibrahim. "Formation of Mercaptans and Organosulfur Species in Claus Process." In Abu Dhabi International Petroleum Exhibition & Conference. Society of Petroleum Engineers, 2017. http://dx.doi.org/10.2118/188255-ms.

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Hsu, C. W., David P. Baldwin, Chung-Lin Liao, and Cheuk Yiu Ng. "Nonresonant two-photon pulsed field ionization studies of organosulfur molecules and radicals." In OE/LASE '94, edited by John W. Hepburn. SPIE, 1994. http://dx.doi.org/10.1117/12.178108.

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Patsis, Amanda, Cody Sheik, and Cara Santelli. "Metagenomic analyses reveal the role of organosulfur in deep subsurface biogeochemical sulfur cycling." In Goldschmidt2023. France: European Association of Geochemistry, 2023. http://dx.doi.org/10.7185/gold2023.18440.

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Renjana, Elga, and Eris Septiana. "In silico study of the organosulfur compounds of garlic (Allium sativum L.) as antihypertensive." In PROCEEDINGS OF THE 9TH INTERNATIONAL SYMPOSIUM ON INNOVATIVE BIOPRODUCTION INDONESIA ON BIOTECHNOLOGY AND BIOENGINEERING 2022: Strengthening Bioeconomy through Applied Biotechnology, Bioengineering, and Biodiversity. AIP Publishing, 2023. http://dx.doi.org/10.1063/5.0182896.

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Ahillah, Nurul, Sri Rahayu Lestari, and Abdul Gofur. "Single bulb garlic organosulfur compounds in inhibiting angiotensin-converting enzyme (ACE) as hypertension therapeutic strategies: An in silico study." In INTERNATIONAL CONFERENCE ON LIFE SCIENCES AND TECHNOLOGY (ICoLiST 2020). AIP Publishing, 2021. http://dx.doi.org/10.1063/5.0052658.

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Sa'adah, Nur Alfi Maghfirotus, Bella Aulia, Dimas Nur Ramadhani, Maria Dwi Cahyani, Muhammad Mauludi Zulkifli, Siti Nur Arifah, Mochammad Fitri Atho'illah, Sri Rahayu Lestari та Abdul Gofur. "In silico study of potential organosulfur and flavonoids compounds in garlic (Allium sativum L.) as inhibitor of α-glucosidase enzyme". У THE 4TH INTERNATIONAL CONFERENCE ON LIFE SCIENCE AND TECHNOLOGY (ICoLiST). AIP Publishing, 2023. http://dx.doi.org/10.1063/5.0113522.

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Sumei, Li, Shi Quan, Zhang Hongan, Xu Tianwu, Chen Xianfei, and Ji Hong. "Characteristics and Significances of Organosulfur Compounds in Typical Saline Lacustrine Oils From Bohai Bay Basin Identified by ESI FT-ICR MS." In 29th International Meeting on Organic Geochemistry. European Association of Geoscientists & Engineers, 2019. http://dx.doi.org/10.3997/2214-4609.201902795.

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Sundararajan, Desikan, and Abdul-Majeed Azad. "Development of Logistic Fuel Desulfurizers Endowed With Nanoartifacts." In ASME 2008 6th International Conference on Fuel Cell Science, Engineering and Technology. ASMEDC, 2008. http://dx.doi.org/10.1115/fuelcell2008-65138.

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Sulfur content in the logitstic fuels such as diesel, jet fuel and coal poses great challenge, as it leads to severe deactivation and poisioning of the reforming catalysts. The utilization of logistic fuel in high efficiency fuel cells as hydrogen-rich reformates, therefore, necessitates that the sulfur (mostly present as organosulfur species) be either eliminated totally, or its level be reduced below such levels as not to mitigate the long-term sustained performance of the reforming catalysts. Besides, SOFC anodes are also quickly poisoned by sulfur present even in trace amounts (1–2 ppm). T
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Ekoue-Kovi, Kekeli, Sankaran Murugesan, Onome Ugono, Sai Pinappu, and Jerry Weers. "Novel Environmentally Responsible Solvents for Sulfur Removal in Oil and Gas Applications." In SPE International Conference on Oilfield Chemistry. SPE, 2023. http://dx.doi.org/10.2118/213824-ms.

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Abstract The removal of unreactive or non-acidic sulfur species to meet fuel specifications remains a challenge in the oil and gas industry. This is especially the case with the recent introduction of IMO 2020 restrictions in the use of marine fuels to those that have sulfur contents from 3.5% down to 0.5%. This has led refiners to seek alternative sulfur removal technologies that can be used in addition to the conventional desulfurization process. Formulations of cyclic organic carbonates (COCs) were developed in combinations with environmentally friendly lactones and glycol ethers and are sh
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Reports on the topic "Organosulfur"

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Ternay, Andrew L., and Jr. Organosulfur Compounds as ChemDefense Agents - Mustard. Fort Belvoir, VA: Defense Technical Information Center, September 2001. http://dx.doi.org/10.21236/ada409740.

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Hsu, Chia-Wei. Photodissociation and photoionization of organosulfur radicals. Office of Scientific and Technical Information (OSTI), May 1994. http://dx.doi.org/10.2172/10190413.

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Ruscic, B., and J. Berkowitz. Photoionization studies of organosulfur transient species. Office of Scientific and Technical Information (OSTI), March 1994. http://dx.doi.org/10.2172/10132759.

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Woods, Nina Tani. Characterization of organosulfur monolayer formation at gold electrodes. Office of Scientific and Technical Information (OSTI), August 1996. http://dx.doi.org/10.2172/383576.

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Cheung, Yu San. Single- and multi-photon ionization studies of organosulfur species. Office of Scientific and Technical Information (OSTI), February 1999. http://dx.doi.org/10.2172/350831.

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Purdy, R. F., B. Ward, and J. E. Lepo. Microbial extraction of sulfur from model coal organosulfur compounds. Office of Scientific and Technical Information (OSTI), December 1991. http://dx.doi.org/10.2172/10175584.

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Kilbane, J. J. II. Microbial strain improvement for organosulfur removal from coal. [Rhodococcus rhodochrous]. Office of Scientific and Technical Information (OSTI), January 1991. http://dx.doi.org/10.2172/5792238.

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Eliel, Ernest L. Neighboring Group Participation in Solvolysis of Organosulfur and Related Compounds. Fort Belvoir, VA: Defense Technical Information Center, August 1985. http://dx.doi.org/10.21236/ada161458.

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Kilbane, J. J. II. Microbial strain improvement for organosulfur removal from coal. Technical report, September 1--November 30, 1991. Office of Scientific and Technical Information (OSTI), December 1991. http://dx.doi.org/10.2172/10122904.

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Kilbane, J. J. II, and K. Ho. Microbial strain improvement for organosulfur removal from coal. Technical report, December 1, 1992--February 28, 1993. Office of Scientific and Technical Information (OSTI), May 1993. http://dx.doi.org/10.2172/10149989.

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