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Relevant bibliographies by topics / Organozinc

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Journal articles
Dissertations / Theses
Books
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Academic literature on the topic 'Organozinc'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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Journal articles on the topic "Organozinc"

1

Chen, Yi-Hung, Mario Ellwart, Vladimir Malakhov, and Paul Knochel. "Solid Organozinc Pivalates: A New Class of Zinc Organometallics with Greatly Enhanced Air- and Moisture-Stability." Synthesis 49, no. 15 (2017): 3215–23. http://dx.doi.org/10.1055/s-0036-1588843.

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Organozinc species are powerful reagents for performing carbon–carbon and carbon–heteroatom bond-forming reactions in the presence of a transition-metal catalyst. However, extended applications of zinc reagents have been hampered by their moderate air- and moisture-stability. This short review presents our recent developments on the preparation of solid aryl, benzyl, heteroaryl, allyl zinc pivalates and zinc amide enolate reagents with greatly enhanced stability toward to air and moisture.1 Introduction2 Preparation of Organozinc Pivalates2.1 Using Organic Halides as Substrates2.2 Using a Dir

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2

Fu, Ying, Xing Ling Zhao, Hulmet Hügel, et al. "Magnesium salt promoted tandem nucleophilic addition–Oppenauer oxidation of aldehydes with organozinc reagents." Organic & Biomolecular Chemistry 14, no. 41 (2016): 9720–24. http://dx.doi.org/10.1039/c6ob01668e.

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A facile synthesis of aromatic ketones via tandem nucleophilic addition–Oppenauer oxidation of aromatic aldehydes with organozinc reagents was demonstrated. Magnesium salt in situ generated via organozinc formation is a powerful promotor for this transformation.

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Zemtsov, Artem A., Alexander D. Volodin, Vitalij V. Levin, Marina I. Struchkova та Alexander D. Dilman. "Coupling of α,α-difluoro-substituted organozinc reagents with 1-bromoalkynes". Beilstein Journal of Organic Chemistry 11 (10 листопада 2015): 2145–49. http://dx.doi.org/10.3762/bjoc.11.231.

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α,α-Difluoro-substituted organozinc reagents generated from conventional organozinc compounds and difluorocarbene couple with 1-bromoalkynes affording gem-difluorinated alkynes. The cross-coupling proceeds in the presence of catalytic amounts of copper iodide in dimethylformamide under ligand-free conditions.

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Knochel, Paul, Juan J. Almena Perea, and Philip Jones. "Organozinc mediated reactions." Tetrahedron 54, no. 29 (1998): 8275–319. http://dx.doi.org/10.1016/s0040-4020(98)00318-4.

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Le Gall, Erwan, Antoine Pignon, and Thierry Martens. "A practical route to tertiary diarylmethylamides or -carbamates from imines, organozinc reagents and acyl chlorides or chloroformates." Beilstein Journal of Organic Chemistry 7 (July 20, 2011): 997–1002. http://dx.doi.org/10.3762/bjoc.7.112.

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A practical route to tertiary diarylmethylamides or -carbamates from imines, organozinc reagents and acyl chlorides or chloroformates is described. This route involves the formation of an imine, which is used without isolation, followed by its activation by the carbonyl-containing electrophile and the trapping of the acyliminium by an organozinc reagent. Most steps are conducted concomitantly to render the procedure as practical and straightforward as possible. Therefore, the whole experimental protocol takes less than two hours.

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6

Zaragoza-Galicia, Ivann, Zaira A. Santos-Sánchez, Yazmín I. Hidalgo-Mercado, Horacio F. Olivo, and Moisés Romero-Ortega. "Synthesis of 5-Substituted 2-Pyrrolidinones by Coupling of Organozinc Reagents with Cyclic N-Acyliminium Ions." Synthesis 51, no. 24 (2019): 4650–56. http://dx.doi.org/10.1055/s-0037-1610733.

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A coupling reaction between cyclic N-acyliminium ions with organozinc reagents is described. The cyclic N-acyliminium ions, generated in situ from N-substituted-5-hydroxy-2-pyrrolidinones by treatment with boron trifluoride–diethyl ether complex or titanium tetrachloride, are trapped by the organozinc reagent, which is formed from an alkyl bromide in the presence of zinc in the same reaction medium. The N-substituted-5-allyl-2-pyrrolidinones generated using this method serve as versatile intermediates for the synthesis of azabicyclic systems with indolizidine and pyrroloazepinolizidine cores.

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Kim, Ju Hyun, Young Ok Ko, Jean Bouffard, and Sang-gi Lee. "Advances in tandem reactions with organozinc reagents." Chemical Society Reviews 44, no. 8 (2015): 2489–507. http://dx.doi.org/10.1039/c4cs00430b.

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8

Bellusˇ, Daniel, Bernd Klingert, Robert W. Lang, and Grety Rihs. "Fluorine-containing organozinc reagents." Journal of Organometallic Chemistry 339, no. 1-2 (1988): 17–22. http://dx.doi.org/10.1016/0022-328x(88)80520-5.

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9

Denes, Fabrice, Sabrina Cutri, Alejandro Perez-Luna, and Fabrice Chemla. "Radical-Polar Crossover Domino Reactions Involving Organozinc and Mixed Organocopper/Organozinc Reagents." Chemistry - A European Journal 12, no. 25 (2006): 6506–13. http://dx.doi.org/10.1002/chem.200600334.

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10

Kubisiak, Marcin, Karolina Zelga, Wojciech Bury, et al. "Development of zinc alkyl/air systems as radical initiators for organic reactions." Chemical Science 6, no. 5 (2015): 3102–8. http://dx.doi.org/10.1039/c5sc00600g.

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Dissertations / Theses on the topic "Organozinc"

1

Oates, L. J. "Solid phase chemistry of organozinc species." Thesis, University of Newcastle Upon Tyne, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.323453.

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O'Mahony, Donogh John Roger. "Rearrangement and trapping of organozinc carbenoids." Thesis, University College London (University of London), 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.308938.

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McCall, Matthew D. "Organozinc reagents : structural tailoring for synthetic applications." Thesis, University of Strathclyde, 2012. http://oleg.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=18805.

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Building on recent advances in zincate chemistry, but going beyond the state-of-the-art, this project sought to advance the understanding of the mechanisms involved in alkali metalmediated zincation (AMMZn), as well as design a new type of mixed-metal reagent, magnesium-zinc hybrids, focussing on their applications in nucleophilic additions to ketones and direct zinc-iodine exchange reactions. Unveiling two new applications of the alkali metal TMP-zincates [(THF)Li(TMP)ZntBu₂] (1) and [(TMEDA)Na(TMP)ZntBu₂] (3), reaction with trimethyl(phenoxy)silane (12) allowed the isolation of the first int

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4

Nutley, Caroline Joy. "The generation and reactivity of organozinc carbenoids." Thesis, University College London (University of London), 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.283714.

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5

Habtemariam, Abraha. "Sterically hindered organozinc compounds containing functional silicon centres." Thesis, University of Sussex, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.304970.

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Harris, Jonathan Edward. "Synthesis and characterisation studies of organozinc carboxylate complexes." Thesis, Imperial College London, 2013. http://hdl.handle.net/10044/1/12948.

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The motivation for this project lies in furthering the understanding of the structure and properties of organozinc carboxylate complexes, both as discrete complexes and as coordination compounds. The thesis centres on the interaction between organozinc complexes and CO2, the insertion of which forms an organozinc carboxylate complex. A series of arylzinc carboxylate species, of the general form [ArZn(O2CR)], have been synthesised and their solution structures have been studied by NMR spectroscopy (Ar = Ph, C6F5; R = Me, Ph, C6F5). NMR experiments indicate that the ligand stoichiometry of the c

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Deboves, Herve Jean Claude. "The application of organometallic chemistry to the synthesis of new unnatural amino acids." Thesis, University of Newcastle Upon Tyne, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.324929.

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Aqil, Rehan. "Studies on the generation and reactivity of metal carbenoids." Thesis, University College London (University of London), 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.289875.

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Reed, Mark Andrew. "Synthetic studies towards histrionicotoxin." Thesis, University of Sussex, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.310265.

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Gavryushin, Andrey. "Chiral Diphosphine Ligands and New Reactions of Organozinc Compounds." Diss., lmu, 2007. http://nbn-resolving.de/urn:nbn:de:bvb:19-65977.

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Books on the topic "Organozinc"

1

Organozinc reagents in organic synthesis. CRC Press, 1996.

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Rappoport, Zvi, and Ilan Marek, eds. The Chemistry of Organozinc Compounds. John Wiley & Sons, Ltd, 2006. http://dx.doi.org/10.1002/9780470093399.

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3

Paul, Knochel, and Jones Philip 1971-, eds. Organozinc reagents: A practical approach. Oxford University Press, 1999.

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4

Zvi, Rappoport, and Marek Ilan, eds. The chemistry of organozinc compounds. John Wiley & Sons, Ltd, 2006.

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5

Rappoport, Zvi, and Ilan Marek. Chemistry of Organozinc Compounds: R-Zn. Wiley & Sons, Incorporated, John, 2007.

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6

(Editor), Paul Knochel, and Philip Jones (Editor), eds. Organozinc Reagents: A Practical Approach (The Practical Approach in Chemistry Series). Oxford University Press, USA, 1999.

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7

(Editor), Zvi Rappoport, and Ilan Marek (Editor), eds. The Chemistry of Organozinc Compounds: R-Zn (Chemistry of Functional Groups). Wiley, 2007.

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8

1939-, Wardell J. L., ed. Organometallic compounds of zinc, cadmium, and mercury. Chapman and Hall, 1985.

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Book chapters on the topic "Organozinc"

1

Ley, Steven V., and Caroline M. R. Low. "Organozinc Reagents." In Reactivity and Structure Concepts in Organic Chemistry. Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-642-74672-7_8.

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2

Nakamura, Eiichi. "Organozinc Chemistry." In Organometallics in Synthesis: A Manual. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118750421.ch5.

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3

Knochel, Paul. "Organomagnesium and Organozinc Chemistry." In Organometallics in Synthesis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118484722.ch2.

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4

Matsubara, Seijiro. "Organozinc Reagent in Flow Chemistry." In Middle Molecular Strategy. Springer Singapore, 2021. http://dx.doi.org/10.1007/978-981-16-2458-2_14.

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5

Knochel, Paul. "New Preparations and Reactions of Organozinc Reagents." In Selective Reactions of Metal-Activated Molecules. Springer Berlin Heidelberg, 1998. http://dx.doi.org/10.1007/978-3-662-00975-8_17.

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6

Knochel, Paul, Andreas Boudier, Lars O. Bromm, et al. "New Stereoselective Transformations Involving Organoboranes and Organozinc Compounds." In ACS Symposium Series. American Chemical Society, 2001. http://dx.doi.org/10.1021/bk-2001-0783.ch003.

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7

Lei, Aiwen, Zhiliang Huang, and Dong Liu. "Application of Organozinc Reagents in Oxidative Coupling Reactions." In Zinc Catalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2015. http://dx.doi.org/10.1002/9783527675944.ch11.

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8

Chemla, Fabrice, Franck Ferreira, Olivier Jackowski, Laurent Micouin, and Alejandro Perez-Luna. "Carbon-Carbon Bond Forming Reactions Mediated by Organozinc Reagents." In Metal-Catalyzed Cross-Coupling Reactions and More. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527655588.ch4.

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9

Knochel, Paul. "Carbon-Carbon Bond Formation Reactions Mediated by Organozinc Reagents." In Metal-Catalyzed Cross-Coupling Reactions. Wiley-VCH Verlag GmbH, 2007. http://dx.doi.org/10.1002/9783527612222.ch9.

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10

Jacob, K., and K. H. Thiele. "By Organomercury, Organocadmium or Organozinc Compounds with the Metal." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145241.ch170.

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Conference papers on the topic "Organozinc"

1

Sachini, Maraisa, and Diogo S. Lüdtke. "Synthesis of Optically Sugar Alcohols by Diastereoselective Addition of Organozinc Reagents." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_201391520343.

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Jr., Palimécio G. Guerrero, Paulo R. de Oliveira, Adriano C. M. Baroni, Francisco A. Marques, Gabriela R. Hurtado, and Miguel J. Dabdoub. "Total synthesis of targretin via palladium catalyzed crosscoupling reaction of a vinyl organozinc intermediate." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0324-1.

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