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1

Ikeda, Shigeru, Tsuyoshi Takata, Takeshi Kondo, Go Hitoki, Michikazu Hara, Junko N. Kondo, Kazunari Domen, Hideo Hosono, Hiroshi Kawazoe, and Akira Tanaka. "Mechano-catalytic overall water splitting." Chemical Communications, no. 20 (1998): 2185–86. http://dx.doi.org/10.1039/a804549f.

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2

Xing, Jun, Wen Qi Fang, Hui Jun Zhao, and Hua Gui Yang. "Inorganic Photocatalysts for Overall Water Splitting." Chemistry - An Asian Journal 7, no. 4 (January 25, 2012): 642–57. http://dx.doi.org/10.1002/asia.201100772.

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3

Li, Yu Hang, Yun Wang, Li Rong Zheng, Hui Jun Zhao, Hua Gui Yang, and Chunzhong Li. "Water-soluble inorganic photocatalyst for overall water splitting." Applied Catalysis B: Environmental 209 (July 2017): 247–52. http://dx.doi.org/10.1016/j.apcatb.2017.03.001.

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4

Maeda, Kazuhiko, Kentaro Teramura, Nobuo Saito, Yasunobu Inoue, Hisayoshi Kobayashi, and Kazunari Domen. "Overall water splitting using (oxy)nitride photocatalysts." Pure and Applied Chemistry 78, no. 12 (January 1, 2006): 2267–76. http://dx.doi.org/10.1351/pac200678122267.

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Oxynitride photocatalysts with d10 electronic configuration are presented as effective non-oxide catalysts for overall water splitting. Germanium nitride (β-Ge3N4) having a band gap of 3.8-3.9 eV modified with RuO2 nanoparticles as a cocatalyst is shown to achieve stoichiometric decomposition of H2O into H2 and O2 under UV irradiation (λ > 200 nm). A novel solid solution of GaN and ZnO, (Ga1-xZnx)(N1-xOx), with a band gap of 2.4-2.8 eV (depending on composition) achieves overall water splitting under visible light (λ > 400 nm) when loaded with an appropriate cocatalyst. The narrower band gap of the solid solution is attributed to the bonding between Zn and N atoms at the top of the valence band. The photocatalytic activity of (Ga1-xZnx)(N1-xOx) for overall water splitting is strongly dependent on both the cocatalyst and the crystallinity and composition of the material. The quantum efficiency of (Ga1-xZnx)(N1-xOx) with Rh and Cr mixed-oxide nanoparticles is 2-3 % at 420-440 nm, which is the highest reported efficiency for overall water splitting in the visible-light region.
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5

Xie, Yunchao, Chi Zhang, Xiaoqing He, Tommi White, John D. Demaree, Mark Griep, and Jian Lin. "Monolithic electrochemical cells for overall water splitting." Journal of Power Sources 397 (September 2018): 37–43. http://dx.doi.org/10.1016/j.jpowsour.2018.06.099.

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6

Sun, Lan, Qiaomei Luo, Zhengfei Dai, and Fei Ma. "Material libraries for electrocatalytic overall water splitting." Coordination Chemistry Reviews 444 (October 2021): 214049. http://dx.doi.org/10.1016/j.ccr.2021.214049.

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7

Chen, Lin-Wei, and Hai-Wei Liang. "Ir-based bifunctional electrocatalysts for overall water splitting." Catalysis Science & Technology 11, no. 14 (2021): 4673–89. http://dx.doi.org/10.1039/d1cy00650a.

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8

Yu, Huidi, Yurui Xue, Lan Hui, Feng He, Chao Zhang, Yuxin Liu, Yan Fang, et al. "Graphdiyne-engineered heterostructures for efficient overall water-splitting." Nano Energy 64 (October 2019): 103928. http://dx.doi.org/10.1016/j.nanoen.2019.103928.

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9

Takata, Tsuyoshi, Akira Tanaka, Michikazu Hara, Junko N. Kondo, and Kazunari Domen. "Recent progress of photocatalysts for overall water splitting." Catalysis Today 44, no. 1-4 (September 1998): 17–26. http://dx.doi.org/10.1016/s0920-5861(98)00170-9.

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10

Maeda, Kazuhiko, Kentaro Teramura, Nobuo Saito, Yasunobu Inoue, and Kazunari Domen. "Photocatalytic Overall Water Splitting on Gallium Nitride Powder." Bulletin of the Chemical Society of Japan 80, no. 5 (May 15, 2007): 1004–10. http://dx.doi.org/10.1246/bcsj.80.1004.

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11

Townsend, Troy K., Nigel D. Browning, and Frank E. Osterloh. "Nanoscale Strontium Titanate Photocatalysts for Overall Water Splitting." ACS Nano 6, no. 8 (July 27, 2012): 7420–26. http://dx.doi.org/10.1021/nn302647u.

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12

Fang, Siyuan, and Yun Hang Hu. "Recent progress in photocatalysts for overall water splitting." International Journal of Energy Research 43, no. 3 (October 24, 2018): 1082–98. http://dx.doi.org/10.1002/er.4259.

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13

Zhang, Qichong, Bing He, Lei Tang, Zhenyu Zhou, Lixing Kang, Juan Sun, Ting Zhang, et al. "Fully Solar-Powered Uninterrupted Overall Water-Splitting Systems." Advanced Functional Materials 29, no. 9 (January 11, 2019): 1808889. http://dx.doi.org/10.1002/adfm.201808889.

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14

Xing, Jun, Wen Qi Fang, Hui Jun Zhao, and Hua Gui Yang. "ChemInform Abstract: Inorganic Photocatalysts for Overall Water Splitting." ChemInform 43, no. 23 (May 10, 2012): no. http://dx.doi.org/10.1002/chin.201223209.

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15

Jia, Qingxin, Yugo Miseki, Kenji Saito, Hisayoshi Kobayashi, and Akihiko Kudo. "InBO3Photocatalyst with Calcite Structure for Overall Water Splitting." Bulletin of the Chemical Society of Japan 83, no. 10 (October 15, 2010): 1275–81. http://dx.doi.org/10.1246/bcsj.20100137.

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16

Niu, Ping, Junjing Dai, Xiaojuan Zhi, Zhonghui Xia, Shulan Wang, and Li Li. "Photocatalytic overall water splitting by graphitic carbon nitride." InfoMat 3, no. 9 (June 26, 2021): 931–61. http://dx.doi.org/10.1002/inf2.12219.

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17

O’Mullane, Anthony. "Exploring Materials for Overall Electrochemical Water Splitting Activity." Video Proceedings of Advanced Materials 2, no. 2 (May 1, 2021): 2021–03157. http://dx.doi.org/10.5185/vpoam.2021.03157.

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18

Hang, Lifeng, Tao Zhang, Yiqiang Sun, Dandan Men, Xianjun Lyu, Qianling Zhang, Weiping Cai, and Yue Li. "Ni0.33Co0.67MoS4 nanosheets as a bifunctional electrolytic water catalyst for overall water splitting." Journal of Materials Chemistry A 6, no. 40 (2018): 19555–62. http://dx.doi.org/10.1039/c8ta07773h.

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19

Li, Jiangtian, Mark Griep, YuSong Choi, and Deryn Chu. "Photoelectrochemical overall water splitting with textured CuBi2O4as a photocathode." Chemical Communications 54, no. 27 (2018): 3331–34. http://dx.doi.org/10.1039/c7cc09041b.

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20

Bose, Ranjith, Vasanth Rajendiran Jothi, K. Karuppasamy, Akram Alfantazi, and Sung Chul Yi. "High performance multicomponent bifunctional catalysts for overall water splitting." Journal of Materials Chemistry A 8, no. 27 (2020): 13795–805. http://dx.doi.org/10.1039/d0ta02697b.

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Designing highly active bifunctional electrocatalysts from Earth-abundant elements has great prospects for substituting precious-metal based catalysts in energy conversion processes, such as water splitting.
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21

Hagiwara, Hidehisa, Motonori Watanabe, Shintaro Ida, and Tatsumi Ishihara. "Overall Water Splitting on Dye-modified Inorganic Semiconductor Photocatalysts." Journal of the Japan Petroleum Institute 60, no. 1 (January 1, 2017): 10–18. http://dx.doi.org/10.1627/jpi.60.10.

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22

Hitoki, Go, Tsuyosi Takata, Shigeru Ikeda, Michikazu Hara, Junko N. Kondo, Masato Kakihana, and Kazunari Domen. "Mechano-catalytic overall water splitting on some mixed oxides." Catalysis Today 63, no. 2-4 (December 2000): 175–81. http://dx.doi.org/10.1016/s0920-5861(00)00457-0.

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23

Du, Cheng, Lan Yang, Fulin Yang, Gongzhen Cheng, and Wei Luo. "Nest-like NiCoP for Highly Efficient Overall Water Splitting." ACS Catalysis 7, no. 6 (May 17, 2017): 4131–37. http://dx.doi.org/10.1021/acscatal.7b00662.

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24

Wang, Hai-Bin, Jia-Qi Wang, Neli Mintcheva, Min Wang, Shuang Li, Jing Mao, Hui Liu, Cun-Ku Dong, Sergei A. Kulinich, and Xi-Wen Du. "Laser Synthesis of Iridium Nanospheres for Overall Water Splitting." Materials 12, no. 18 (September 18, 2019): 3028. http://dx.doi.org/10.3390/ma12183028.

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Engineering surface structure of catalysts is an efficient way towards high catalytic performance. Here, we report on the synthesis of regular iridium nanospheres (Ir NSs), with abundant atomic steps prepared by a laser ablation technique. Atomic steps, consisting of one-atom level covering the surface of such Ir NSs, were observed by aberration-corrected high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM). The prepared Ir NSs exhibited remarkably enhanced activity both for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in acidic medium. As a bifunctional catalyst for overall water splitting, they achieved a cell voltage of 1.535 V @ 10 mA/cm2, which is much lower than that of Pt/C-Ir/C couple (1.630 V @ 10 mA/cm2).
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25

Hara, Michikazu, Hironori Hasei, Masaaki Yashima, Sigeru Ikeda, Tsuyoshi Takata, Junko N. Kondo, and Kazunari Domen. "Mechano-catalytic overall water splitting (II) nafion-deposited Cu2O." Applied Catalysis A: General 190, no. 1-2 (January 2000): 35–42. http://dx.doi.org/10.1016/s0926-860x(99)00284-7.

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26

Chen, Su-Hua, Yong-Siang Jiang, and Hsin-yu Lin. "Easy Synthesis of BiVO4 for Photocatalytic Overall Water Splitting." ACS Omega 5, no. 15 (April 7, 2020): 8927–33. http://dx.doi.org/10.1021/acsomega.0c00699.

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27

Hara, Michikazu, Mutsuko Komoda, Hironori Hasei, Masaaki Yashima, Sigeru Ikeda, Tsuyoshi Takata, Junko N. Kondo, and Kazunari Domen. "A Study of Mechano-Catalysts for Overall Water Splitting." Journal of Physical Chemistry B 104, no. 4 (February 2000): 780–85. http://dx.doi.org/10.1021/jp993441h.

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28

Yang, Hongchao, Yandong Ma, Shuai Zhang, Hao Jin, Baibiao Huang, and Ying Dai. "GeSe@SnS: stacked Janus structures for overall water splitting." Journal of Materials Chemistry A 7, no. 19 (2019): 12060–67. http://dx.doi.org/10.1039/c9ta02716e.

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29

Wang, Qian, Mamiko Nakabayashi, Takashi Hisatomi, Song Sun, Seiji Akiyama, Zheng Wang, Zhenhua Pan, et al. "Oxysulfide photocatalyst for visible-light-driven overall water splitting." Nature Materials 18, no. 8 (June 17, 2019): 827–32. http://dx.doi.org/10.1038/s41563-019-0399-z.

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30

Takata, Tsuyosi, Shigeru Ikeda, Akira Tanaka, Michikazu Hara, Junko N. Kondo, and Kazunari Domen. "Mechano-catalytic overall water splitting on some oxides (II)." Applied Catalysis A: General 200, no. 1-2 (August 2000): 255–62. http://dx.doi.org/10.1016/s0926-860x(00)00628-1.

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31

Hildebrandt, Nils C., Julia Soldat, and Roland Marschall. "Layered Perovskite Nanofibers via Electrospinning for Overall Water Splitting." Small 11, no. 17 (December 15, 2014): 2051–57. http://dx.doi.org/10.1002/smll.201402679.

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32

Menezes, Prashanth W., Arindam Indra, Ivelina Zaharieva, Carsten Walter, Stefan Loos, Stefan Hoffmann, Robert Schlögl, Holger Dau, and Matthias Driess. "Helical cobalt borophosphates to master durable overall water-splitting." Energy & Environmental Science 12, no. 3 (2019): 988–99. http://dx.doi.org/10.1039/c8ee01669k.

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A unique class of bifunctional robust materials was discovered which not only facilitates both the electrocatalytic oxidation and reduction of water to oxygen and hydrogen but also combines outstanding performance and energetic efficiency with remarkable long-term stability.
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33

Ikeda, Shigeru, Tsuyoshi Takata, Mutsuko Komoda, Michikazu Hara, Junko N. Kondo, Kazunari Domen, Akira Tanaka, Hideo Hosono, and Hiroshi Kawazoe. "Mechano-catalysis—a novel method for overall water splitting." Physical Chemistry Chemical Physics 1, no. 18 (1999): 4485–91. http://dx.doi.org/10.1039/a903543e.

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34

Lao, Jie, Dong Li, Chunli Jiang, Rong Luo, Hui Peng, Ruijuan Qi, Hechun Lin, Rong Huang, Geoffrey I. N. Waterhouse, and Chunhua Luo. "Efficient overall water splitting using nickel boride-based electrocatalysts." International Journal of Hydrogen Energy 45, no. 53 (October 2020): 28616–25. http://dx.doi.org/10.1016/j.ijhydene.2020.07.171.

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35

Wu, Zhengcui, Jingjing Li, Zexian Zou, and Xia Wang. "Folded nanosheet-like Co0.85Se array for overall water splitting." Journal of Solid State Electrochemistry 22, no. 6 (January 22, 2018): 1785–94. http://dx.doi.org/10.1007/s10008-018-3885-3.

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36

Zhang, Lei, Yiyi Li, Jiehai Peng, and Kun Peng. "Bifunctional NiCo2O4 porous nanotubes electrocatalyst for overall water-splitting." Electrochimica Acta 318 (September 2019): 762–69. http://dx.doi.org/10.1016/j.electacta.2019.06.128.

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37

Takanabe, Kazuhiro, and Kazunari Domen. "Preparation of Inorganic Photocatalytic Materials for Overall Water Splitting." ChemCatChem 4, no. 10 (August 20, 2012): 1485–97. http://dx.doi.org/10.1002/cctc.201200324.

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38

Kan, Shuting, Mengying Xu, Wenshuai Feng, Yufeng Wu, Cheng Du, Xiaohui Gao, Yimin A. Wu, and Hongtao Liu. "Tuning Overall Water Splitting on an Electrodeposited NiCoFeP Films." ChemElectroChem 8, no. 3 (February 2021): 539–46. http://dx.doi.org/10.1002/celc.202001501.

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39

Bao, Kai, Yaotian Yan, Tao Liu, Tianxiong Xu, Jian Cao, and Junlei Qi. "Constructing NiS–VS heterostructured nanosheets for efficient overall water splitting." Inorganic Chemistry Frontiers 7, no. 24 (2020): 4924–29. http://dx.doi.org/10.1039/d0qi00239a.

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40

Maeda, Kazuhiko. "Photocatalytic properties of rutile TiO2 powder for overall water splitting." Catal. Sci. Technol. 4, no. 7 (2014): 1949–53. http://dx.doi.org/10.1039/c4cy00251b.

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41

Fan, Yanfei, Yan Liu, Hongyu Cui, Wen Wang, Qiaoyan Shang, Xifeng Shi, Guanwei Cui, and Bo Tang. "Photocatalytic Overall Water Splitting by SrTiO3 with Surface Oxygen Vacancies." Nanomaterials 10, no. 12 (December 21, 2020): 2572. http://dx.doi.org/10.3390/nano10122572.

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Strontium Titanate has a typical perovskite structure with advantages of low cost and photochemical stability. However, the wide bandgap and rapid recombination of electrons and holes limited its application in photocatalysis. In this work, a SrTiO3 material with surface oxygen vacancies was synthesized via carbon reduction under a high temperature. It was successfully applied for photocatalytic overall water splitting to produce clean hydrogen energy under visible light irradiation without any sacrificial reagent for the first time. The photocatalytic overall water splitting ability of the as-prepared SrTiO3-C950 is attributed to the surface oxygen vacancies that can make suitable energy levels for visible light response, improving the separation and transfer efficiency of photogenerated carriers.
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42

Xiao, Kang, Jin-Xin Wei, Wen-Kai Han, and Zhao-Qing Liu. "Bimetallic sulfide interfaces: Promoting destabilization of water molecules for overall water splitting." Journal of Power Sources 487 (March 2021): 229408. http://dx.doi.org/10.1016/j.jpowsour.2020.229408.

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43

Higashi, Tomohiro, Yutaka Sasaki, Yudai Kawase, Hiroshi Nishiyama, Masao Katayama, Kazuhiro Takanabe, and Kazunari Domen. "Surface-Modified Ta3N5 Photoanodes for Sunlight-Driven Overall Water Splitting by Photoelectrochemical Cells." Catalysts 11, no. 5 (April 30, 2021): 584. http://dx.doi.org/10.3390/catal11050584.

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The development of visible-light-responsive semiconductor-based photoelectrodes is a prerequisite for the construction of efficient photoelectrochemical (PEC) cells for solar water splitting. Surface modification with an electrocatalyst on the photoelectrode is effective for maximizing the water splitting efficiency of the PEC cell. Herein, we investigate the effects of surface modification of Ta3N5 photoanodes with electrocatalysts consisting of Ni, Fe, and Co oxides, and their mixture, on the PEC oxygen evolution reaction (OER) performance. Among the investigated samples, NiFeOx-modified Ta3N5 (NiFeOx/Ta3N5) photoanodes showed the lowest onset potential for OER. A PEC cell with a parallel configuration consisting of a NiFeOx/Ta3N5 photoanode and an Al-doped La5Ti2Cu0.9Ag0.1S5O7 (LTCA:Al) photocathode exhibited stoichiometric hydrogen and oxygen generation from water splitting, without any external bias voltage. The solar-to-hydrogen energy conversion efficiency (STH) of this cell for water splitting was found to be 0.2% at 1 min after the start of the reaction. In addition, water splitting by a PEC cell with a tandem configuration incorporating a NiFeOx/Ta3N5 transparent photoanode prepared on a quartz insulating substrate as a front-side electrode and a LTCA:Al photocathode as a back side electrode was demonstrated, and the STH was found to be 0.04% at the initial stage of the reaction.
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44

Liang, Shuqin, Meizan Jing, Tiju Thomas, Jian Liu, Haichuan Guo, J. Paul Attfield, Ali Saad, Hangjia Shen, and Minghui Yang. "FeNi3–FeNi3N – a high-performance catalyst for overall water splitting." Sustainable Energy & Fuels 4, no. 12 (2020): 6245–50. http://dx.doi.org/10.1039/d0se01491e.

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45

Zhang, Chao, Yurui Xue, Lan Hui, Yan Fang, Yuxin Liu, and Yuliang Li. "Graphdiyne@NiOx(OH)y heterostructure for efficient overall water splitting." Materials Chemistry Frontiers 5, no. 14 (2021): 5305–11. http://dx.doi.org/10.1039/d1qm00466b.

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A new GDY@NiOx(OH)y heterostructure was synthesized by creatively incorporating GDY with NiOx(OH)y for efficient water splitting. The mixed valence states and facilitated charge transfer behavior significantly improve the catalytic activity.
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46

Shao, Dawei, Lingcheng Zheng, Deqiang Feng, Jie He, Rui Zhang, Hui Liu, Xinghua Zhang, et al. "TiO2–P3HT:PCBM photoelectrochemical tandem cells for solar-driven overall water splitting." Journal of Materials Chemistry A 6, no. 9 (2018): 4032–39. http://dx.doi.org/10.1039/c7ta09367e.

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47

Du, Xiaoqiang, Jiaxin Li, Kaicheng Tong, and Xiaoshuang Zhang. "Coupling Co2P/CoSe2 heterostructure nanoarrays for boosting overall water splitting." Dalton Transactions 50, no. 19 (2021): 6650–58. http://dx.doi.org/10.1039/d1dt00857a.

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Results demonstrate that Co2P/CoSe2-300//Co2P/CoSe2-300 pairs display superior water splitting performance while requiring a cell voltage of 1.52 V only to drive a current density of 20 mA cm−2.
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48

Zhang, Chunyang, Sanket Bhoyate, Chen Zhao, Pawan Kahol, Nikolaos Kostoglou, Christian Mitterer, Steven Hinder, et al. "Electrodeposited Nanostructured CoFe2O4 for Overall Water Splitting and Supercapacitor Applications." Catalysts 9, no. 2 (February 13, 2019): 176. http://dx.doi.org/10.3390/catal9020176.

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To contribute to solving global energy problems, a multifunctional CoFe2O4 spinel was synthesized and used as a catalyst for overall water splitting and as an electrode material for supercapacitors. The ultra-fast one-step electrodeposition of CoFe2O4 over conducting substrates provides an economic pathway to high-performance energy devices. Electrodeposited CoFe2O4 on Ni-foam showed a low overpotential of 270 mV and a Tafel slope of 31 mV/dec. The results indicated a higher conductivity for electrodeposited compared with dip-coated CoFe2O4 with enhanced device performance. Moreover, bending and chronoamperometry studies suggest excellent durability of the catalytic electrode for long-term use. The energy storage behavior of CoFe2O4 showed high specific capacitance of 768 F/g at a current density of 0.5 A/g and maintained about 80% retention after 10,000 cycles. These results demonstrate the competitiveness and multifunctional applicability of the CoFe2O4 spinel to be used for energy generation and storage devices.
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49

Liang, Hanfeng, Appala N. Gandi, Dalaver H. Anjum, Xianbin Wang, Udo Schwingenschlögl, and Husam N. Alshareef. "Plasma-Assisted Synthesis of NiCoP for Efficient Overall Water Splitting." Nano Letters 16, no. 12 (November 9, 2016): 7718–25. http://dx.doi.org/10.1021/acs.nanolett.6b03803.

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50

Guan, Cao, Wen Xiao, Haijun Wu, Ximeng Liu, Wenjie Zang, Hong Zhang, Jun Ding, Yuan Ping Feng, Stephen J. Pennycook, and John Wang. "Hollow Mo-doped CoP nanoarrays for efficient overall water splitting." Nano Energy 48 (June 2018): 73–80. http://dx.doi.org/10.1016/j.nanoen.2018.03.034.

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