Academic literature on the topic 'Oxalic acid. Crystal growth'

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Journal articles on the topic "Oxalic acid. Crystal growth"

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Traquair, J. A. "Oxalic acid and calcium oxalate produced by Leucostoma cincta and L. persoonii in culture and in peach bark tissues." Canadian Journal of Botany 65, no. 9 (1987): 1952–56. http://dx.doi.org/10.1139/b87-267.

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Oxalic acid and crystals of calcium oxalate were produced during growth of Leucostoma cincta and L. persoonii on potato dextrose agar and in peach bark tissues. The identification of calcium oxalate was based on solubility characteristics, the results of KMnO4 titration, positive staining with silver nitrate – dithiooxamide, and crystal morphology as observed with light and scanning electron microscopes. Oxalic acid was detected by gas chromatography. This is the first report of oxalic acid production by both Leucostoma species causing peach canker. Calcium oxalate crystals observed on or near
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. Senthil, K., K. . Elangovan, A. . Senthil, and G. . Vinitha. "GROWTH AND CHARACTERIZATION OF N-METHYLUREA OXALIC (NMUO) ACID SINGLE CRYSTAL." Rasayan Journal of Chemistry 12, no. 03 (2019): 1262–68. http://dx.doi.org/10.31788/rjc.2019.1235174.

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Manju, T., and P. Selvarajan. "Growth and Characterization of Mono-Urea Oxalic Acid Crystals." Asian Journal of Materials Chemistry 3, no. 3 (2018): 61–67. http://dx.doi.org/10.14233/ajmc.2018.ajmc-p68.

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Tao, Feng, Zhishun Shen, Zhijun Wang, Da Shu, Qi Liu, and Yufeng Sun. "Oxalic Acid-Assisted Hydrothermal Synthesis and Luminescent of Hexagonal NaYF4:Ln3+ (Ln = Sm, Eu, Yb/Er) Micro/Nanoplates." Journal of Nanomaterials 2017 (2017): 1–10. http://dx.doi.org/10.1155/2017/5320989.

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Hexagonal NaYF4:Ln3+ micro/nanoplates were successfully synthesized via a hydrothermal method using oxalic acid as a shape modifier. X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and selected area electron diffraction (SAED) have been used to study the morphologies and crystal structure of the products. The effects of the pH values and the molar ratio of oxalic acid to NaOH on the crystal growth have been investigated in detail. The time-dependent experiments have been conducted to investigate the morphology evolution pro
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Chithambaram, V., S. Jerome Das, Sivakumar Krishnan, M. Basheer Ahamed, and R. Arivudai Nambi. "Growth and characterization of urea-oxalic acid crystals by solution growth technique." European Physical Journal Applied Physics 64, no. 2 (2013): 20201. http://dx.doi.org/10.1051/epjap/2013130108.

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Dalal, P. V. "Nucleation Controlled Growth of Cadmium Oxalate Crystals in Agar Gel and Their Characterization." Indian Journal of Materials Science 2013 (September 19, 2013): 1–5. http://dx.doi.org/10.1155/2013/682950.

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Perfect single crystals of cadmium oxalate have been grown using the slow and controlled reaction between cadmium acetate and oxalic acid in agar gel media at ambient temperature, resulting in the formation of insoluble product Cd(COO)2. Different methods for growing crystals were adopted. The optimum conditions were employed in each method by varying the concentration of gel and reactants, gel setting time, and so forth. Prismatic, transparent single crystal about 20 times larger than the crystals obtained in various other methods at the interstitial by adding impurities in the gel was obtain
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Dhivya, R., R. Ezhil Vizhi, and D. Rajan Babu. "Investigation on nucleation kinetics, growth and characterization of urea oxalic acid-ferroelectric single crystal." Journal of Crystal Growth 468 (June 2017): 84–87. http://dx.doi.org/10.1016/j.jcrysgro.2016.12.045.

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Thanasekaran, Pounraj, Chih-Ming Liu, Jhen-Fu Cho, and Kuang-Lieh Lu. "Melamine-promoted crystal growth of calcium oxalate monohydrate from calcium nitrate and oxalic acid." Inorganic Chemistry Communications 17 (March 2012): 84–87. http://dx.doi.org/10.1016/j.inoche.2011.12.020.

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Abdel-Ghafar, H. M., M. A. M. Ibrahim, H. El-Shall, and A. K. Ismail. "Innovative findings about ferrous oxalate dihydrate crystallization in simulated dihydrate phosphoric acid product." Water Science and Technology 77, no. 12 (2018): 2940–45. http://dx.doi.org/10.2166/wst.2018.294.

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Abstract The basic fundamentals of ferrous oxalate dihydrate (FeC2O4.2H2O) crystallization including supersaturation, nucleation and crystal growth in simulated dihydrate phosphoric acid product with and without cetyl pyridinium chloride (CPC) additive were studied. Oxalic acid and ferrous sulfate heptahydrate crystals were mixed with dilute phosphoric acid (28% P2O5) at 60 °C and the turbidity of the reaction mixture was measured at different time intervals. Induction time of ferrous oxalate dihydrate crystals was calculated at different supersaturation ratios ranging from 2.5 to 6.7. With in
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Fomina, M., S. Hillier, J. M. Charnock, K. Melville, I. J. Alexander, and G. M. Gadd. "Role of Oxalic Acid Overexcretion in Transformations of Toxic Metal Minerals by Beauveria caledonica." Applied and Environmental Microbiology 71, no. 1 (2005): 371–81. http://dx.doi.org/10.1128/aem.71.1.371-381.2005.

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ABSTRACT The fungus Beauveria caledonica was highly tolerant to toxic metals and solubilized cadmium, copper, lead, and zinc minerals, converting them into oxalates. This fungus was found to overexcrete organic acids with strong metal-chelating properties (oxalic and citric acids), suggesting that a ligand-promoted mechanism was the main mechanism of mineral dissolution. Our data also suggested that oxalic acid was the main mineral-transforming agent. Cadmium, copper, and zinc oxalates were precipitated by the fungus in the local environment and also in association with the mycelium. The prese
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Dissertations / Theses on the topic "Oxalic acid. Crystal growth"

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Elliott, Mary Alice. "Crystal aging of terephthalic acid." Thesis, Georgia Institute of Technology, 1985. http://hdl.handle.net/1853/10935.

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Dutt, Yougesh Chander. "Crystal growth of monosodium urate monohydrate." Thesis, University of British Columbia, 1985. http://hdl.handle.net/2429/24633.

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Hyperuricemia and local temperature changes in the joints of the extremities are known to be responsible, in part, for the development of gouty arthritis. No satisfactory explanation is yet available for (1) the selective deposition of monosodium urate monohydrate (MSUM) crystals in connective tissues (2) the increased incidence of gout in the later years of life and (3) the increased incidence of MSUM crystal deposition in connective tissues after trauma and in joints with preexisting disease. It is possible that the alterations in composition of the non-fibrillar matrix of cartilage and syno
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Eaton, Gregory K. "Oxalic acid production by the ectomycorrhizal fungus Hebeloma westraliensis and its role in the nutrient acquisition and growth of Eucalyptus diversicolor in calcareous soil." Thesis, Virginia Tech, 1994. http://hdl.handle.net/10919/41292.

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This work includes an introduction and literature review of mycorrhizal enhancement of the mineral nutrition of host plants. Particular attention was paid to the role of mycorrhizae in acquiring P from inorganic phosphates. Two experiments were designed to study a mechanism by which the ectomycorrhizal fungus Hebeloma westraliensis can enhance the availability and absorption of P from Ca phosphate by <u>Eucalyptus diversicolor</u> in calcareous soil. Chapter 2 reports on a study on the growth and oxalic acid production of <u>H. westraliensis</u> in calcareous and noncalcareous liquid media. Ox
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Walker, Elaine M. "Modelling the effect of growth envirnoment on the crystallisation of molecular organic compounds." Thesis, University of Strathclyde, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.360150.

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Sullivan, Rachel. "Molecules, clusters and crystals : the crystallisation of p-aminobenzoic acid from solution." Thesis, University of Manchester, 2015. https://www.research.manchester.ac.uk/portal/en/theses/molecules-clusters-and-crystals-the-crystallisation-of-paminobenzoic-acid-from-solution(ec826e71-782f-4bb0-9dc2-48cf94a7c941).html.

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Nucleation is a key step in the crystallisation process, where a new crystalline solid phase is created from a supersaturated solution. The applications of crystallisation as a purification and separation technique span many industries, yet still no definitive molecular mechanism for nucleation exists. This PhD is part of a critical mass research project involving researchers from both the Universities of Manchester and Leeds. The aim is to reveal the relationship between structural components of the nucleation transition state, solution phase molecular self-assembly and nano cluster formation
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Holmbäck, Xiomara. "Drowning-out crystallisation of benzoic acid : Influence of processing conditions and solvent composition on crystal size and shape." Doctoral thesis, KTH, Chemical Engineering and Technology, 2002. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3448.

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<p>The aim of the present investigation is to increase theunderstanding of the role played by the solvent in inhibitingor enhancing crystal growth. Drowning-out crystallizationexperiments has been performed by the controlled addition ofwater or ethanol water mixtures to a saturated solution ofbenzoic acid in ethanol-water mixtures. Crystal habitcontrolling factors have been identified.Seededcrystallization experiments have been carried out to evaluatethe effect of solvent composition on crystal habit at constantsupersaturation. The solubility of benzoic acid inethanol-water mixtures at the wor
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Gaines, Etienne. "The nucleation and growth of meta-aminobenzoic acid : a density functional theory and molecular dynamics study." Thesis, Queen Mary, University of London, 2018. http://qmro.qmul.ac.uk/xmlui/handle/123456789/54056.

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Controlling crystal polymorphism, the ability of a molecule to crystallise in different solid forms, is one of the grand, ongoing challenges in materials science. In the pharmaceutical industry particularly, where up to half of the active pharmaceutical active ingredients exhibit polymorphic behaviour, it is of paramount importance to rationalise the impact of experimental conditions, such as the nature of the solvent, on the obtainment of a specific c crystal form. As strategies for the selection of polymorphs is still, by and large, based on a trial-and-error approach, it is necessary to acq
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Ibrahim, Mohamed Asim Y. "Co-processing of drugs and co-crystal formers and its effect on pharmaceutical dosage-form performance. Co-crystallization of urea/ 2-methoxybenzamide, caffeine/ malonic acid, caffeine/ oxalic acid and theophylline/ malonic acid systems: Solid-state characterization including imaging, thermal, X-ray and Raman spectroscopic techniques with subsequent evaluation of tableting behaviour." Thesis, University of Bradford, 2008. http://hdl.handle.net/10454/12760.

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This dissertation has focused on the solid-state characterization of different co-crystal system as well as the effect of co-crystallization of these systems on pharmaceutical dosage form performance. Urea/ 2-MB, caffeine/ malonic acid, caffeine/ oxalic acid and theophylline/ malonic acid co-crystals were prepared using co-grinding- and co-precipitation techniques. In addition, the synthesis of co-crystals through two novel methods has been demonstrated. This includes compaction and convection mixing. The solid-state characterization of the co-crystals has been carried out using XRPD, Raman sp
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Ibrahim, Mohamed Asim Yousif. "Co-processing of drugs and co-crystal formers and its effect on pharmaceutical dosage-form performance : co-crystallization of urea/2-methoxybenzamide, caffeine/malonic acid, caffeine/oxalic acid and theophylline/malonic acid systems : solid-state characterization including imaging, thermal, X-ray and Raman spectroscopic techniques with subsequent evaluation of tableting behaviour." Thesis, University of Bradford, 2008. http://hdl.handle.net/10454/12760.

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This dissertation has focused on the solid-state characterization of different co-crystal system as well as the effect of co-crystallization of these systems on pharmaceutical dosage form performance. Urea/ 2-MB, caffeine/ malonic acid, caffeine/ oxalic acid and theophylline/ malonic acid co-crystals were prepared using co-grinding- and co-precipitation techniques. In addition, the synthesis of co-crystals through two novel methods has been demonstrated. This includes compaction and convection mixing. The solid-state characterization of the co-crystals has been carried out using XRPD, Raman sp
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Zhang, Shuo. "Physical properties and crystallization of theophylline co-crystals." Licentiate thesis, KTH, Transport Phenomena, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-13255.

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<p>This work focuses on the physical properties and crystallization of theophyline co-crystals. Co-crystals of theophylline with oxalic acid, glutaric acid and maleic acid have been investigated.</p><p>The DSC curves of these co-crystals show that their first endothermic peaks are all lower than the melting temperature of theophylline. The decomposition temperature of theophylline – oxalic acid co-crystal is at about 230 °C, determined by DSC together with TGA. After decomposition, the remaining theophylline melts at about 279 °C, which is higher than the known melting temperature of theophyll
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Books on the topic "Oxalic acid. Crystal growth"

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Dalbeth, Nicola. Epidemiology. Oxford University Press, 2016. http://dx.doi.org/10.1093/med/9780198748311.003.0003.

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The aetiopathogenesis of gout is initiated by urate overproduction and uric acid under-excretion, leading to hyperuricaemia. Foods such as seafood, red meat, beer, and sugar-sweetened beverages contribute to overproduction. Under-excretion is mediated by renal and gut uric acid transporters such as SLC2A9, ABCG2, and URAT1. In hyperurcaemia, there is formation of monosodium urate (MSU) crystals in joints, with acute gouty arthritis mediated by the innate immune system occurring in response to these crystals. Factors such as urate concentration, proteins present in synovial fluid, temperature,
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Book chapters on the topic "Oxalic acid. Crystal growth"

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Matthews, P., and J. W. L. Wilson. "The Effect of Uric Acid on the Inhibition of Hydroxyapatite Crystal Growth." In Urolithiasis. Springer US, 1989. http://dx.doi.org/10.1007/978-1-4899-0873-5_40.

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Omorogbe, Stanley O., Areguamen I. Aigbodion, Hilary I. Ifijen, Aline Simo, Nosa L. Ogbeide-Ihama, and Esther U. Ikhuoria. "Low-Temperature Synthesis of Superparamagnetic Fe3O4 Morphologies Tuned Using Oleic Acid as Crystal Growth Modifiers." In TMS 2020 149th Annual Meeting & Exhibition Supplemental Proceedings. Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-36296-6_58.

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Dhanaraj, P. V., and N. P. Rajesh. "Effect of Amino Acid Additives on Crystal Growth Parameters and Properties of Ammonium Dihydrogen Phosphate Crystals." In Crystallization and Materials Science of Modern Artificial and Natural Crystals. InTech, 2012. http://dx.doi.org/10.5772/28417.

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Riès-Kautt, M., and A. Ducruix. "From Solution to Crystals With a Physico-Chemical Aspect." In Crystallization of Nucleic Acids and Proteins. Oxford University Press, 1999. http://dx.doi.org/10.1093/oso/9780199636792.003.0014.

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Biological macromolecules follow the same thermodynamic rules as inorganic or organic small molecules concerning supersaturation, nucleation, and crystal growth (1). Nevertheless macromolecules present particularities, because the intramolecular interactions responsible of their tertiary structure, the intermolecular interactions involved in the crystal contacts, and the interactions necessary to solubilize them in a solvent are similar. Therefore these different interactions may become competitive with each other. In addition, the biological properties of biological macromolecules may be conserved although the physico-chemical properties, such as the net charge, may change depending on the crystallization conditions (pH, ionic strength, etc.). A charged biological macromolecule requires counterions to maintain the electroneutrality of the solution; therefore it should be considered as a protein (or nucleic acid) salt with its own physico-chemical properties, depending on the nature of the counterions. To crystallize a biological macromolecule, its solution must have reached supersaturation which is the driving force for crystal growth. The understanding of the influence of the crystallization parameters on protein solubility of model proteins is necessary to guide the preparation of crystals of new proteins and their manipulation. Only the practical issues are developed in this chapter, and the reader should refer to recent reviews (2-4) for a description of the fundamental physical chemistry underlying crystallogenesis. The solubilization of a solute (e.g. a biological macromolecule) in an efficient solvent requires solvent-solute interactions, which must be similar to the solvent-solvent interactions and to the solute-solute interactions of the compound to be dissolved. All of the compounds of a protein solution (protein, water, buffer, crystallizing agents, and others) interact with each other via various, often weak, types of interactions: monopole-monopole, monopole-dipole, dipole-dipole, Van der Waals hydrophobic interactions, and hydrogen bonds. Solubility is defined as the amount of solute dissolved in a solution in equilibrium with its crystal form at a given temperature. For example, crystalline ammonium sulfate dissolves at 25°C until its concentration reaches 4.1 moles per litre of water, the excess remaining non-dissolved. More salt can be dissolved when raising the temperature, but if the temperature is brought back to 25°C, the solution becomes supersaturated, and the excess of salt crystallizes until its concentration reaches again its solubility value at 25°C (4.1 moles per litre of water).
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Mark, James E., Dale W. Schaefer, and Gui Lin. "Copolymers and Interpenetrating Networks." In The Polysiloxanes. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780195181739.003.0010.

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Random copolymers are prepared by the copolymerization of a mixture of cyclic oligomers. Although the resulting polymer can be quite blocky (figure 8.1), taking the reaction to equilibrium can give a polymer that is essentially random in its chemical sequencing. One reason for preparing copolymers is to introduce functional species, such as hydrogen or vinyl side groups, along the chain backbone to facilitate cross linking. Another reason is the introduction of sufficient chain irregularity to make the polymer inherently noncrystallizable. Specific examples of comonomers include imides, perylenediimide, urethane-ureas, epoxies, other siloxanes, amides, styrene, divinylbenzene, acrylics, silsesquioxanes, polythiophenes, and poly(lactic acid). One novel combination is the preparation of polysiloxanebased episulfide resins. An unusual application is the use of monomethylitaconate- grafted polymethylsiloxane to induce crystal growth of CaCO3. Polysiloxanes containing thermally curable brenzoxazine moieties in the main chain are also in the category. These and other copolymers have been extensively characterized by nuclear magnetic resonance (NMR) spectroscopy. The sequential coupling of functionally terminated chains of different chemical structure can be used to make block copolymers, including those in which one or more of the blocks is a polysiloxane. If the blocks are relatively long, separation into a two-phase system invariably occurs. Frequently, one block will be in a continuous phase and the other will be dispersed in domains having an average size the order of a few hundred angstroms. Such materials can have unique mechanical properties not available from homopolymer species. Sometimes similar properties can be obtained by the simple blending of two or more polymers. Examples of blocks used with polydimethylsiloxane (PDMS) include imides, epoxies, butadienes, ε-caprolactones, amides having trichlorogermyl pendant groups, urethanes, ureas, poly(ethylene glycols), polystyrene, vinyl acetates, acrylates or methacrylates, 2-vinylpyridine, and even other polysiloxanes. Some results have also been reported for polyesters, polyethers, hydroxyethers of bisphenol A, bisphenol A arylene ether sulfones, vinylpyridinebenzoxazines, methyloxazolines, terpyridines, polysulfones, &amp;gamma;-benzyl-Lglutamate, and carboranes. Two other examples are foamed polypropylene and melamine resins. Even ABA, ABC triblock copolymers, and ABCBA pentablock copolymers involving PDMS have been reported.
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Conference papers on the topic "Oxalic acid. Crystal growth"

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Lestari, Fitri, and Kumala Dewi. "Effects of humic acid on vegetative growth, yield, oxalic acid and betacyanin content of red amaranth (Amaranthus tricolor L.)." In THE 6TH INTERNATIONAL CONFERENCE ON BIOLOGICAL SCIENCE ICBS 2019: “Biodiversity as a Cornerstone for Embracing Future Humanity”. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0015774.

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Sankari, R. Siva, and Rajesh Narayana Perumal. "Crystal growth, structure analysis and characterisation of 2 - (1, 3 - dioxoisoindolin - 2 - yl) acetic acid single crystal." In SOLID STATE PHYSICS: Proceedings of the 58th DAE Solid State Physics Symposium 2013. AIP Publishing LLC, 2014. http://dx.doi.org/10.1063/1.4872918.

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Inbaseelan, C. Ranjith Dev, and S. Saravanan. "Growth, optical and structural reports on new glycine D-tartaric acid complex crystal." In PROCEEDING OF INTERNATIONAL CONFERENCE ON RECENT TRENDS IN APPLIED PHYSICS AND MATERIAL SCIENCE: RAM 2013. AIP, 2013. http://dx.doi.org/10.1063/1.4810717.

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Zachova, J., Josef Stepanek, and N. P. Zaitseva. "Application of high-rate crystal growth technique to single crystals of nucleic acid bases." In USSR - DL tentative, edited by Sergei A. Akhmanov and Victor N. Zadkov. SPIE, 1991. http://dx.doi.org/10.1117/12.47498.

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Mahadevan, M., M. Arivanandhan, K. Elangovan, P. Anandan, and K. Ramachandran. "Growth, optical, ICP and thermal studies of nonlinear optical single crystal: Sodium acid phthalate (NaAP)." In INTERNATIONAL CONFERENCE ON FUNCTIONAL MATERIALS, CHARACTERIZATION, SOLID STATE PHYSICS, POWER, THERMAL AND COMBUSTION ENERGY: FCSPTC-2017. Author(s), 2017. http://dx.doi.org/10.1063/1.4990175.

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Jauhar, RO MU, Paavai Era, and P. Murugakoothan. "Growth, optimized molecular geometry, natural bonding orbitals and dielectric studies of imidazolium diphenylacetate diphenylacetic acid single crystal." In DAE SOLID STATE PHYSICS SYMPOSIUM 2017. Author(s), 2018. http://dx.doi.org/10.1063/1.5028974.

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Senthil, K., R. Gnanadeepam, K. Elangovan, and A. Senthil. "Effect of cyclohexylamine on growth, structural, spectral, optical and mechanical properties of potassium acid phthalate (KAP) single crystal." In 7TH NATIONAL CONFERENCE ON HIERARCHICALLY STRUCTURED MATERIALS (NCHSM-2019). AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5114607.

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Wullur, Christian Wely, and Peter Sahupala. "The Effect of Citric Acid (C6H8O7) and Flow Rate to the Growth and Transformation of Crystal Phase of CaCO3." In Proceedings of the International Conference on Science and Technology (ICST 2018). Atlantis Press, 2018. http://dx.doi.org/10.2991/icst-18.2018.59.

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Slathia, Goldy, Harjinder Singh, E. Ramya, D. Narayana Rao, and K. K. Bamzai. "Crystal growth of semiorganic complex- samarium chloride coordinated thiourea-L-tartaric acid and its studies on structure and optical characteristics." In DAE SOLID STATE PHYSICS SYMPOSIUM 2016. Author(s), 2017. http://dx.doi.org/10.1063/1.4980603.

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Korinko, Paul S. "Microstructural Evolution During a Solid State Tube Pinch Weld." In ASME 2020 Pressure Vessels & Piping Conference. American Society of Mechanical Engineers, 2020. http://dx.doi.org/10.1115/pvp2020-21308.

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Abstract Microstructure development is examined for a specialized spot weld that is used as a solid-state closure process for stainless steel tubing, referred to as pinch welding. In order to elucidate the microstructural evolution of the weld, a series of test welds were made at nominal conditions using both tubes, used in test articles and production like components. These pinch welds normally terminate after twelve cycles of a 60 Hz AC weld process. In this study, tubes with different thermal processing history were welded from one to twelve cycles and the microstructure and weld variables
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