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Journal articles on the topic 'Oxazolium salts'

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Published: 4 June 2025
Last updated: 1 August 2025

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1

Gerster, Holger, and Gerhard Maas. "Diverse Reactivities of Acetylenic Iminium Salts Toward 1,3-Oxazolium-5-olates (Münchnones)." Zeitschrift für Naturforschung B 63, no. 4 (2008): 384–94. http://dx.doi.org/10.1515/znb-2008-0405.

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AbstractThe acetylenic iminium salts [(c-C3H5)C≡C-C(Ar)=N+Me2]OTf, Ar = phenyl (1a) or 2- thienyl (1b), both react in different ways with three mesoionic münchnones, namely 3-methyl-1,3-oxazolium-5-olate (2), 3-methyl-2-phenyl-1,3-oxazolium-5-olate (6) and 3-methyl-2-phenyl-4- trifluoroacetyl-1,3-oxazolium-5-olate (9). With 2, a [3+2] cycloaddition reaction followed by extrusion of CO2 yields pyrroles 5a, b. In the case of 6, the new münchnones 7a, b are obtained which result from an electrophilic substitution at C-4 by the acetylenic iminium cation. In contrast to 1a, b, the 4,4-but-2-yne 1-i
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2

Vedejs, E., and J. W. Grissom. "4-Oxazoline route to stabilized azomethine ylides. Controlled reduction of oxazolium salts." Journal of the American Chemical Society 110, no. 10 (1988): 3238–46. http://dx.doi.org/10.1021/ja00218a038.

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3

Salado, Manuel, Erfan Shirzadi, Samrana Kazim, et al. "Oxazolium Iodide Modified Perovskites for Solar Cell Fabrication." ChemPlusChem 83, no. 4 (2020): 279–84. https://doi.org/10.1002/cplu.201700471.

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Perovskites solar cells are gaining interest due to their attractive solar-to-electricity conversion efficiencies, although they suffer from certain problems, such as sub-optimal ion migration and stability issues. We studied the inclusion of a phenyloxazolium salt (2-phenyl-3-methyl-oxazolium iodide) in methyl ammonium lead triiodide (MAPbI<sub>3</sub>) based perovskite solar cells. The fabricated solar cells not only gave improved photovoltaic properties, but importantly the oxazolium cation can protect the perovskite layers from UV exposure as it down-converts electromagnetic irradiation, i
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4

Garapati, Venkata Krishna Rao, and Michel Gravel. "Oxazolium Salts as Organocatalysts for the Umpolung of Aldehydes." Organic Letters 20, no. 20 (2018): 6372–75. http://dx.doi.org/10.1021/acs.orglett.8b02636.

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5

Fisyuk, A. S., та M. A. Vorontsova. "New rearrangement of oxazolium salts into Δ3-pyrrolin-2-ones". Chemistry of Heterocyclic Compounds 33, № 7 (1997): 857–58. http://dx.doi.org/10.1007/bf02253041.

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6

Hassner, Alfred, and Bilha Fischer. "Cycloadditions. 50. Multipath reactions between intramolecularly formed oxazolium salts and nucleophiles." Journal of Organic Chemistry 57, no. 11 (1992): 3070–75. http://dx.doi.org/10.1021/jo00037a023.

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7

FISYUK, A. S., та M. A. VORONTSOVA. "ChemInform Abstract: New Rearrangement of Oxazolium Salts to Δ3-Pyrrolin-2-ones." ChemInform 29, № 2 (2010): no. http://dx.doi.org/10.1002/chin.199802106.

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8

Vedejs, E., and J. W. Grissom. "Nucleophilic addition to oxazolium salts. Stabilized azomethine ylides via 2-substituted 4-oxazolines." Journal of Organic Chemistry 53, no. 9 (1988): 1876–82. http://dx.doi.org/10.1021/jo00244a008.

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9

Hassner, Alfred, and Bilha Fischer. "Intramolecular formation of oxazolium salts and their reaction with N- and C-nucleophiles." Tetrahedron Letters 31, no. 49 (1990): 7213–14. http://dx.doi.org/10.1016/s0040-4039(00)97282-4.

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10

Korepin, A. G., P. V. Galkin, N. M. Glushakova, et al. "Preparation of quaternary ammonium salts with a perhydroimidazo[1,5-c]oxazolium molecular skeleton." Russian Chemical Bulletin 59, no. 5 (2010): 1061–62. http://dx.doi.org/10.1007/s11172-010-0207-z.

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11

HASSNER, A., and B. FISCHER. "ChemInform Abstract: Cycloadditions. Part 50. Multipath Reactions Between Intramolecularly Formed Oxazolium Salts and Nucleophiles." ChemInform 23, no. 45 (2010): no. http://dx.doi.org/10.1002/chin.199245190.

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12

Korepin, A. G., P. V. Galkin, N. M. Glushakova, et al. "ChemInform Abstract: Preparation of Quaternary Ammonium Salts with a Perhydroimidazo[1,5-c]oxazolium Molecular Skeleton." ChemInform 42, no. 18 (2011): no. http://dx.doi.org/10.1002/chin.201118114.

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13

Moschny, Torsten, and Horst Hartmann. "A Simple Route to NewN(3)-Substituted 5-Aryl-2-(dialkylamino)-1,3-oxazolium Salts andN(1)-Substituted 4-Aryl-2-(dialkylamino)-1H-imidazoles." Helvetica Chimica Acta 82, no. 11 (1999): 1981–93. http://dx.doi.org/10.1002/(sici)1522-2675(19991110)82:11<1981::aid-hlca1981>3.0.co;2-t.

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14

Babaev, E. V. "2-halogen-substituted pyridinium-N-phenacylides and their cycloiminium and acyclic analogs: 1. Synthesis of the parent salts, their betaine-ylides, and oxazolium analogs." Review Journal of Chemistry 1, no. 2 (2011): 161–91. http://dx.doi.org/10.1134/s2079978011010018.

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15

Moschny, Torsten, and Horst Hartmann. "ChemInform Abstract: A Simple Route to New N(3)-Substituted 5-Aryl-2-(dialkylamino)-1,3-oxazolium Salts and N(1)-Substituted 4-Aryl-2-(dialkylamino)-1H-imidazoles." ChemInform 31, no. 16 (2010): no. http://dx.doi.org/10.1002/chin.200016118.

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16

R., K. BANSAL, B. JAIN C., and GUPTA NEELIMA. "Synthesis of New 2-Oxazolinium Salts and their Betaine Structure." Journal of Indian Chemical Society Vol. 71, April 1994 (1994): 203–4. https://doi.org/10.5281/zenodo.5894250.

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17

Ren, Li, Austin C. Chen, Andreas Decken, and Cathleen M. Crudden. "Chiral bidentate N-heterocyclic carbene complexes of Rh and Pd." Canadian Journal of Chemistry 82, no. 12 (2004): 1781–87. http://dx.doi.org/10.1139/v04-165.

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The synthesis of a new chiral, bidentate oxazoline/imidazolidene carbene precursor is described. This species is reacted with various metal salts in the presence of a base to generate rhodium and palladium complexes, which are characterized spectroscopically and crystallographically.Key words: chiral N-heterocyclic carbene, rhodium, palladium, oxazolidine, asymmetric catalysis.
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18

Nuyken, Oskar, Gerhard Maier, Aurelia Groß, and Herbert Fischer. "Systematic investigations on the reactivity of oxazolinium salts." Macromolecular Chemistry and Physics 197, no. 1 (1996): 83–95. http://dx.doi.org/10.1002/macp.1996.021970106.

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19

Stenczel, Tamás Károly, Ádám Sinai, Zoltán Novák, and András Stirling. "DFT calculations on the mechanism of copper-catalysed tandem arylation–cyclisation reactions of alkynes and diaryliodonium salts." Beilstein Journal of Organic Chemistry 14 (July 12, 2018): 1743–49. http://dx.doi.org/10.3762/bjoc.14.148.

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We present a computational mechanistic study on the copper(III)-catalysed carboarylation–ring closure reactions leading to the formation of functionalised heterocycles. We have performed DFT calculations along selected routes and compared their free energy profiles. The calculations considered two viable options for the underlying mechanism which differ in the order of the oxazoline ring formation and the aryl transfer steps. In our model transformation, it was found that the reaction generally features the aryl transfer–ring closing sequence and this sequence shows very limited sensitivity to
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20

Shono, Tatsuya, Naoki Kise, Ryoji Nomura, and Ayuko Yamanami. "Reductive homo-coupling of 2-aryl-2-oxazolinium salts." Tetrahedron Letters 34, no. 22 (1993): 3577–80. http://dx.doi.org/10.1016/s0040-4039(00)73640-9.

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21

Csámpai, A., K. Körmendy, P. Sohár, and F. Ruff. "Bromoalkylphthalazinones and isomeric oxazolinium salts as intermediates and synthons." Tetrahedron 45, no. 17 (1989): 5539–48. http://dx.doi.org/10.1016/s0040-4020(01)89500-4.

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22

Holerca, Marian N., and Virgil Percec. "1H NMR Spectroscopic Investigation of the Mechanism of 2-Substituted-2-Oxazoline Ring Formation and of the Hydrolysis of the Corresponding Oxazolinium Salts." European Journal of Organic Chemistry 2000, no. 12 (2000): 2257–63. http://dx.doi.org/10.1002/1099-0690(200006)2000:12<2257::aid-ejoc2257>3.0.co;2-2.

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23

Otulakowski, Łukasz, Maciej Kasprów, Aleksandra Strzelecka, Andrzej Dworak, and Barbara Trzebicka. "Thermal Behaviour of Common Thermoresponsive Polymers in Phosphate Buffer and in Its Salt Solutions." Polymers 13, no. 1 (2020): 90. http://dx.doi.org/10.3390/polym13010090.

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Thermoresponsive polymers are a promising material for drug nanocarrier preparation, which makes the study of their aggregation in physiological conditions very important. In this paper, the thermal behaviour of the thermoresponsive polymers poly(N-isopropylacrylamide), poly(2-isopropyl-2-oxazoline-co-2-n-propyl-2-oxazoline) and poly[(2-hydroxyethyl methacrylate)-co-oligo(ethylene glycol) methyl ether methacrylate] were studied in phosphate buffer (PBS) and solutions of its salts in concentration as in PBS. The thermal response of the polymers was measured using UV-Vis and dynamic light scatte
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24

Oestreich, Martin, Dou Hong, Wenbin Mao, and Elisabeth Irran. "Enantioselective, Copper-Catalyzed Addition of Nucleophilic Silicon to Alkenyl-Substituted Phosphine Oxides." Synthesis 54, no. 08 (2021): 2049–56. http://dx.doi.org/10.1055/a-1701-7500.

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AbstractAn enantioselective β-silylation of α,β-unsaturated phosphine oxide derivatives using a silylboronic ester as the silicon pronucleophile is reported. The reaction is catalyzed by copper salts in the presence of chiral pyridine–oxazoline (PyOx) ligands. Good to high enantioselectivities (≤95% ee) are obtained for β-aryl-substituted acceptors whereas alkyl residues in the β-position led to a lower ee value for 1° and no reaction for 2° and 3°. The new method represents another way of accessing α-chiral silanes and complements the known β-borylation.
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25

Kirila, Tatyana, Anna Smirnova, Alla Razina, Andrey Tenkovtsev, and Alexander Filippov. "Influence of Salt on the Self-Organization in Solutions of Star-Shaped Poly-2-alkyl-2-oxazoline and Poly-2-alkyl-2-oxazine on Heating." Polymers 13, no. 7 (2021): 1152. http://dx.doi.org/10.3390/polym13071152.

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The water–salt solutions of star-shaped six-arm poly-2-alkyl-2-oxazines and poly-2-alkyl-2-oxazolines were studied by light scattering and turbidimetry. The core was hexaaza[26]orthoparacyclophane and the arms were poly-2-ethyl-2-oxazine, poly-2-isopropyl-2-oxazine, poly-2-ethyl-2-oxazoline, and poly-2-isopropyl-2-oxazoline. NaCl and N-methylpyridinium p-toluenesulfonate were used as salts. Their concentration varied from 0–0.154 M. On heating, a phase transition was observed in all studied solutions. It was found that the effect of salt on the thermosensitivity of the investigated stars depen
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26

BANSAL, R. K., C. B. JAIN, and N. GUPTA. "ChemInform Abstract: Synthesis of New 2-Oxazolinium Salts and Their Betaine Structure." ChemInform 26, no. 21 (2010): no. http://dx.doi.org/10.1002/chin.199521136.

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27

John, Matthew P., Stephen A. Hermitage, and James R. Titchmarsh. "Preparation of 1,2,4-trisubstituted imidazoles by ammonolysis of N-(2-oxoalkyl)oxazolinium salts." Tetrahedron Letters 43, no. 39 (2002): 6997–99. http://dx.doi.org/10.1016/s0040-4039(02)01586-1.

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28

Shono, Tatsuya, Shigenori Kashimura, Yoshihide Yamaguchi, Osamu Ishige, Hiroshi Uyama, and Fumitaka Kuwata. "Formation of a Novel Acyl Anion Equivalent by the Electroreduction of Oxazolinium Salts." Chemistry Letters 16, no. 8 (1987): 1511–12. http://dx.doi.org/10.1246/cl.1987.1511.

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29

Fehlhammer, Wolf Peter, Hans Hoffmeister, Uwe Eckert, and Christian Robl. "Bor-stabilisierte Carbene, III [3 + 2]-Cycloadditionen an Borio-Nitrilylide / Boron-Stabilized Carbenes, III [3 + 2]-Cycloadditions to Borio Nitrile Ylides." Zeitschrift für Naturforschung B 48, no. 11 (1993): 1448–60. http://dx.doi.org/10.1515/znb-1993-1102.

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The borio nitrile ylides Li[Ph3B—C =N—CH—R] (R = CO2Et, Tos) react with various dipolarophiles regio- and site-specifically to give boron complexes of carbenoid five-membered heterocycles which have been alkylated in order to accomplish their isolation. Thus, isocyanates and isothiocyanates/trialkyloxonium salts give rise to the imidazoline-2-ylidene complexes 2-5, CS2/Et3O+ to the thiazoline-2-ylidene complex 6 and acetone/Et3O+ to the oxazoline-2-ylidene complexes 7a,b. Aryldiazonium ions are added regiospecifically in the “wrong” orientation that leads to mesoionic 1,2,4-triazolium-3-ato-tr
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30

Lee, Chil-Won, Hyung-Seok Park, and Myoung-Seon Gong. "Humidity sensitive properties of quaternary ammonium salts containing polyelectrolytes crosslinked with 2-oxazoline crosslinker." Sensors and Actuators B: Chemical 109, no. 2 (2005): 256–63. http://dx.doi.org/10.1016/j.snb.2004.12.057.

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31

Kosulina, T. P., K. S. Pushkareva, N. I. Bychenko, I. P. Morenets, and V. G. Kul'nevich. "2-Methyl-4(5H)-oxazolonium salts in reaction with ethyl orthoformate and aromatic amines." Chemistry of Heterocyclic Compounds 35, no. 5 (1999): 635–36. http://dx.doi.org/10.1007/bf02324655.

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32

Gossage, Robert A., Hilary A. Jenkins, and J. Wilson Quail. "Oxazoles XXI. Three Ester Ammonium Salts Resulting from the Rupture of an Oxazoline Ring." Journal of Chemical Crystallography 40, no. 3 (2009): 272–77. http://dx.doi.org/10.1007/s10870-009-9645-6.

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33

Kuai, Hai-Wei, Xiao-Chun Cheng, and Xiao-Hong Zhu. "Synthesis, structural characterization, and properties of three Ag(I) complexes with oxazoline-containing chiral ligands." Zeitschrift für Naturforschung B 76, no. 5 (2021): 327–31. http://dx.doi.org/10.1515/znb-2021-0020.

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Abstract The two enantiopure chiral organic ligands 2-[(S)-4-isopropyl-2-oxazolyl]quinoline (L1) and 2-[(S)-4-benzyl-2-oxazolyl]quinoline (L2) react with different silver salts to give rise to three new silver complexes [Ag(L1)2](SbF6) (1), [Ag(L1)(CH3CN)](ClO4) (2), and [Ag(L2)(NO3)] (3), which have been characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental and thermogravimetric analyses. Complexes 1–3 all display discrete mononuclear structures. The nonlinear optical properties of 1–3 were investigated.
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34

Miura, Yuji, Tomoyuki Mochida, Satoshi Motodate, and Keisuke Kato. "Synthesis and thermal properties of salts comprising cationic bis(oxazoline)-AuIII complexes and fluorinated anions." Polyhedron 113 (July 2016): 1–4. http://dx.doi.org/10.1016/j.poly.2016.04.012.

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35

SHONO, T., N. KISE, R. NOMURA, and A. YAMANAMI. "ChemInform Abstract: Electroorganic Chemistry. Part 142. Reductive Homo-Coupling of 2-Aryl- 2-oxazolinium Salts." ChemInform 24, no. 33 (2010): no. http://dx.doi.org/10.1002/chin.199333159.

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36

Ammar, Hamed Ben, Bechir Ben Hassine, Cédric Fischmeister, Pierre H. Dixneuf, and Christian Bruneau. "Imidazolium-Oxazoline Salts in Ruthenium-Catalyzed Allylic Substitution and Cross Metathesis of Formed Branched Isomers." European Journal of Inorganic Chemistry 2010, no. 30 (2010): 4752–56. http://dx.doi.org/10.1002/ejic.201000718.

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37

Sun, Zhankui, Shouyun Yu, Zuoding Ding, and Dawei Ma. "Enantioselective Addition of Activated Terminal Alkynes to 1-Acylpyridinium Salts Catalyzed by Cu−Bis(oxazoline) Complexes." Journal of the American Chemical Society 129, no. 30 (2007): 9300–9301. http://dx.doi.org/10.1021/ja0734849.

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38

Kosulina, T. P., K. S. Pushkareva, N. I. Bychenko, I. P. Morenets, and V. G. Kul'nevich. "ChemInform Abstract: 2-Methyl-4(5H)-oxazolonium Salts in Reaction with Ethyl Orthoformate and Aromatic Amines." ChemInform 31, no. 11 (2010): no. http://dx.doi.org/10.1002/chin.200011116.

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39

Rueda, Juan Carlos. "Polimeros termoconmutables." Revista de la Sociedad Química del Perú 87, no. 2 (2021): 95. http://dx.doi.org/10.37761/rsqp.v87i2.346.

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En años recientes, una de las áreas de los polímeros más ampliamente investigadas, por las importantes aplicaciones tecnológicas a que pueden dar lugar, es la síntesis de macromoléculas conmutables o sensibles a cambios en el medio ambiente tales como; por ejemplo, temperatura, pH, luz, y campo eléctrico o magnético. Este tipo de polímeros, conmutables o sensibles, tienen alto potencial para aplicaciones en biomateriales, en microsistemas, sensores y catálisis, entre otros. Entre los polímeros conmutables que más se han investigado se encuentran los polímeros termosensibles&#x0D; Se pueden obt
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40

Forsee, Jennifer E. "Reactions of Oxazolinium and Dihydrooxazinium Salts Prepared by an Azide Insertion Sequence: pH Control of Product Distribution." Synlett 1998, no. 11 (1998): 1258–60. http://dx.doi.org/10.1055/s-1998-1925.

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41

Shono, Tatsuya, Shigenori Kashimura, Yoshihide Yamaguchi, and Fumitaka Kuwata. "Michael addition of novel acyl anion equivalents generated by the electroreduction of oxazolinium salts to activated olefins." Tetrahedron Letters 28, no. 38 (1987): 4411–14. http://dx.doi.org/10.1016/s0040-4039(00)96524-9.

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42

Madalan, Augustin M, Céline Réthoré, Marc Fourmigué, et al. "Order Versus Disorder in Chiral Tetrathiafulvalene-Oxazoline Radical-Cation Salts: Structural and Theoretical Investigations and Physical Properties." Chemistry - A European Journal 16, no. 2 (2010): 528–37. http://dx.doi.org/10.1002/chem.200901980.

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43

Bloksma, Meta M., Daniël J. Bakker, Christine Weber, Richard Hoogenboom, and Ulrich S. Schubert. "The Effect of Hofmeister Salts on the LCST Transition of Poly(2-oxazoline)s with Varying Hydrophilicity." Macromolecular Rapid Communications 31, no. 8 (2010): 724–28. http://dx.doi.org/10.1002/marc.200900843.

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44

Dioukhane, Khadim, Younas Aouine, Salaheddine Boukhssas, Asmae Nakkabi, Hassane Faraj, and Anouar Alami. "Synthesis and Characterization of a Novel Biheterocyclic -amino Acid Precursor of the Triazole-Tetrazole Type, via the Copper (I) Catalyzed Alkyne-Azide Cycloaddition Reaction (CuAAC)." European Journal of Advanced Chemistry Research 2, no. 2 (2021): 7–15. http://dx.doi.org/10.24018/ejchem.2021.2.2.53.

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In this paper, we describe the regioselective synthesis of a novel tri-heterocyclic compound, a biheterocyclic amino acid precursor, derived from both triazole and tetrazole. The key step of our synthesis approach was the Huigsen 1,3-dipolar cycloaddition reaction, catalyzed by the copper (I) formed in situ by reduction of Cu(II) salts (CuSO4), 5H2O) by sodium ascorbate, and using as dipole the oxazoline azide derivative 4-(azidomethyl)-4-ethyl-2-phenyl-4,5-dihydrooxazole (4) and as dipolarophile 5-(4-methoxyphenyl)-2-(prop-2-yn-1-yl)-2H-tetrazole (3). The Cu(I) catalysis allowed us to carry o
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45

Réthoré, Céline, Narcis Avarvari, Enric Canadell, Pascale Auban-Senzier, and Marc Fourmigué. "Chiral Molecular Metals: Syntheses, Structures, and Properties of the AsF6-Salts of Racemic (±)-, (R)-, and (S)-Tetrathiafulvalene−Oxazoline Derivatives." Journal of the American Chemical Society 127, no. 16 (2005): 5748–49. http://dx.doi.org/10.1021/ja0503884.

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46

FORSEE, J. E., B. T. SMITH, K. E. FRANK, and J. AUBE. "ChemInform Abstract: Reactions of Oxazolinium and Dihydrooxazinium Salts Prepared by an Azide Insertion Sequence: pH Control of Product Distribution." ChemInform 30, no. 8 (2010): no. http://dx.doi.org/10.1002/chin.199908067.

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47

Prem, Markus, Werner Bauer, Kurt Polbom, and Wolfgang Beck. "Metallkomplexe von biologisch wichtigen Liganden, CVI [1]. Metallkomplexe von Donor-substituierten Oxazolin-5-onen sowie von Bis(oxazolin-5-onen) / Metal Complexes of Biologically Important Ligands CVI [1], Metal Complexes of Donor Substituted Oxazolones and of Bis(oxazolones)." Zeitschrift für Naturforschung B 53, no. 9 (1998): 965–72. http://dx.doi.org/10.1515/znb-1998-0906.

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A series of chelate complexes 1-12 of Cu(II), Ni(II), Pd(II), and Ru(III) with the anion of 2-(2′-hydroxyphenyl)-5(4H)-oxazolone and with 2-(2′-aminophenyl)-5(4H)-oxazolone were prepared from metal salts or from chloro-bridged complexes [(R3P)MCl2]2 (M = Pd, Pt) and [(p-cymene)RuCl2]2. Nucleophilic addition of α-amino acid esters to the bis-chelate complexes M(oxophenyloxazolone)2(M = Ni, Cu) gave the dipeptide derivatives 13-18. Dinuclear Pd(II) and Pt(II) chelate complexes 19-23 were obtained from phenylene- and ethylenebridged bis(oxazolones). The structures of (Et3P)(Cl)Pd(O,N-oxophenyloxa
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48

He, Yang, and Wanting Sun. "Synthesis of monodisperse SnCo nanoparticles in triethylene glycol and its carbon composites for advanced lithium-ion batteries." Functional Materials Letters 13, no. 08 (2020): 2050038. http://dx.doi.org/10.1142/s1793604720500381.

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The tin-based materials are one kind of the most promising high-capacity anode candidates for advanced Li-ion energy storage systems. However, they still face the problem of large volume expansion during charge–discharge processes, which causes rapid capacity decay and thus largely limit their serving life in practical application. In this work, ultra-fined SnCo alloy particles were successfully synthesized by a facile reduction of metal salts in triethylene glycol (TEG) solution, and then SnCo-anchored carbon composites were obtained through the calcination of SnCo-doped poly-(2-ethyl-2-oxazo
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49

Dockendorff, Chris, Eric Greve, and Jacob Porter. "DFT-Assisted Design and Evaluation of Bifunctional Amine/Pyridine-Oxazoline Metal Catalysts for Additions of Ketones to Unactivated Alkenes and Alkynes." Synthesis 51, no. 02 (2018): 450–62. http://dx.doi.org/10.1055/s-0037-1610285.

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Abstract:
Bifunctional catalyst systems for the direct addition of ­ketones to unactivated alkenes/alkynes were designed and modeled by density functional theory (DFT). The designed catalysts possess bidentate ligands suitable for binding of pi-acidic group 10 metals capable of activating alkenes/alkynes, and a tethered organocatalyst amine to ­activate the ketone via formation of a nucleophilic enamine intermediate. The structures of the designed catalysts before and after C–C bond formation were optimized using DFT, and reaction steps involving group 10 metals were predicted to be significantly exergo
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50

Riobé, François, Flavia Piron, Céline Réthoré, et al. "Radical cation salts of BEDT-TTF, enantiopure tetramethyl-BEDT-TTF, and TTF-Oxazoline (TTF-Ox) donors with the homoleptic TRISPHAT anion." New Journal of Chemistry 35, no. 10 (2011): 2279. http://dx.doi.org/10.1039/c1nj20310j.

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