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Journal articles on the topic 'Oxidation of Acrylic Acid'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Widi, Restu Kartiko. "KINETIC INVESTIGATION OF CARBON DIOXIDE, ACETIC ACID, ACRYLIC ACID FORMATION ON DILUTED AND LEACHED MoVTeNb CATALYST." Indonesian Journal of Chemistry 12, no. 2 (2012): 131–34. http://dx.doi.org/10.22146/ijc.21352.

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Reaction kinetics for the oxidation of propane over diluted-leached MoVTeNb is described. This paper is focused on the study of determination of the orders of carbon dioxide, acetic acid and acrylic acid formation. Deep oxidation of propane to carbon dioxide is first order with respect to hydrocarbon, and partial order (0.31) with respect to oxygen. The selective oxidation of propane to acrylic acid is partial order (0.49) with respect to hydrocarbon and partial order (0.09) with respect to oxygen.

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2

Ai, M. "Oxidation of propane to acrylic acid." Catalysis Today 13, no. 4 (1992): 679–84. http://dx.doi.org/10.1016/0920-5861(92)80109-z.

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3

Roman, Nebesnyi, Pikh Zorian, Kubitska Iryna, Orobchuk Oksana, and Lukyanchuk Andrii. "ACRYLIC ACID SYNTHESIS BY OXIDATIVE CONDENSATION OF METHANOL AND ACETIC ACID ON B–P–V–W–OX/SIO2 CATALYST." Eastern-European Journal of Enterprise Technologies 1, no. 6 (97) (2019): 21–27. https://doi.org/10.15587/1729-4061.2019.156764.

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The process of oxidative condensation of methanol with acetic acid to acrylic acid on B–P–V–W–Ox/SiO<sub>2</sub> catalyst modified by hydrothermal method has been studied. Modification of the catalyst by hydrothermal treatment of the carrier changes its physical and chemical properties, and therefore its catalytic properties. The influence of the main technological parameters – temperature, contact time and ratio of reagents on the selectivity and yield of the reaction products and on the conversion of acetic acid has been studied when hydrothermally treated

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4

Ishikawa, Satoshi, and Wataru Ueda. "Microporous crystalline Mo–V mixed oxides for selective oxidations." Catalysis Science & Technology 6, no. 3 (2016): 617–29. http://dx.doi.org/10.1039/c5cy01435b.

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Recent developments of crystalline Mo<sub>3</sub>VO<sub>x</sub> catalysts (MoVO), a new type of oxidation catalysts for selective oxidations of ethane to ethene and of acrolein to acrylic acid, are reviewed.

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5

Wu, Shu Tao, Qi Ming She, Riccardo Tesser, Martino Di Serio, and Chun Hui Zhou. "Catalytic glycerol dehydration-oxidation to acrylic acid." Catalysis Reviews 62, no. 4 (2020): 481–523. http://dx.doi.org/10.1080/01614940.2020.1719611.

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6

Švachula, Jiří, Antonín Tockstein, and Josef Tichý. "Determination of rate equations of catalytic oxidation of propene to acrolein and acrylic acid in the gas phase." Collection of Czechoslovak Chemical Communications 51, no. 8 (1986): 1579–86. http://dx.doi.org/10.1135/cccc19861579.

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The kinetics of propene catalytic oxidation to acrolein and acrylic acid was studied in a flow-circulation reactor over a multicomponent oxide catalyst containing molybdenum, cobalt, nickel, iron, bismuth, and potassium. The rate equations were found for the total formation of acrolein and acrylic acid.

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7

Nebesnyi, Roman, Volodymyr Ivasiv, Zoryan Pikh, et al. "Low Temperature Acrolein to Acrylic Acid Oxidation with Hydrogen Peroxide on Se-Organic Catalysts." Chemistry & Chemical Technology 13, no. 1 (2019): 38–45. http://dx.doi.org/10.23939/chcht13.01.038.

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8

Maugans, C., and B. Kumfer. "The use of catalyst to enhance the wet oxidation process." Water Science and Technology 55, no. 12 (2007): 189–93. http://dx.doi.org/10.2166/wst.2007.405.

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Wet oxidation tests were performed on two pure compound streams: acetic acid and ammonia; and on two wastewater streams: acrylic acid wastewater and sulphide laden spent caustic. Test results showed that Mn/Ce and Pt/TiO2 were effective catalysts that greatly enhanced acetic acid, ammonia and acrylic acid wastewater destruction. However, the Mn/Ce catalyst performance appears to be inhibited by concentrated salts dissolved in solution. This could limit the applicability of this catalyst for the treatment of brackish wastewaters. Zr, Ce and Ce nanoparticles were also shown to exhibit some catal

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9

Wang, Ke, Wen Sheng Li, and Xiao Ping Zhou. "Acrylic Acid Oxidation to Synthesize Methyl 3,3-dimethoxypropionate." Catalysis Letters 105, no. 1-2 (2005): 89–92. http://dx.doi.org/10.1007/s10562-005-8010-4.

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10

Gong, Y. M., S. Z. Wang, X. Y. Tang, D. H. Xu, and H. H. Ma. "Supercritical water oxidation of acrylic acid production wastewater." Environmental Technology 35, no. 7 (2013): 907–16. http://dx.doi.org/10.1080/09593330.2013.856925.

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11

Premlall, Kiara Capreece, and David Lokhat. "Reducing Energy Requirements in the Production of Acrylic Acid: Simulation and Design of a Multitubular Reactor Train." Energies 13, no. 8 (2020): 1971. http://dx.doi.org/10.3390/en13081971.

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Acrylic acid, a versatile chemical intermediate, is typically manufactured via a two-step process involving the selective oxidation of propylene and acrolein. This work presents an optimized simulation on Aspen Plus® (AspenTech, Bedford, MA, USA) of the production of acrylic acid, with focus on the optimum design and operation of the reactor train, and modification for reduction in energy usage. In the propylene oxidation reactor, an inert pre-heating zone was designed to make use of the excess energy present in the exothermic process fluid and carried within the molten salt cooling fluid circ

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12

Chabukswar, Vasant, and Ganesh Sable. "Chemical Oxidative Synthesis and Characteristion of Organica acid Doped Soluble Conducting Poly(o-anisidine)." Chemistry & Chemical Technology 3, no. 2 (2009): 95–99. http://dx.doi.org/10.23939/chcht03.02.095.

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Synthesis of poly(o-anisidine) with and without acrylic acid doping is carried out by chemical oxidative polymerization method. This is a new polymerization method for the direct synthesis of the emeraldine salt of poly(o-anisidine), i.e. it is directly soluble in known organic solvent such as m-cresol, N-methyl pyrrolidone (NMP), DMSO, DMF, etc. without the need for a conversion of salt phase to base form. The reaction is unique since it eliminates the post processing step which involves neutralization of emeraldine salt to form emeraldine base and again reprotonating the base with a secondar

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13

Li, Shuangming, Yongwei Liu, Yaoxin Fan, et al. "Facile sub-/supercritical water synthesis of nanoflake MoVTeNbOx-mixed metal oxides without post-heat treatment and their catalytic performance." RSC Advances 10, no. 65 (2020): 39922–30. http://dx.doi.org/10.1039/d0ra06877b.

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14

Heine, Christian, Michael Hävecker, Annette Trunschke, Robert Schlögl, and Maik Eichelbaum. "The impact of steam on the electronic structure of the selective propane oxidation catalyst MoVTeNb oxide (orthorhombic M1 phase)." Physical Chemistry Chemical Physics 17, no. 14 (2015): 8983–93. http://dx.doi.org/10.1039/c5cp00289c.

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15

FANG, Wen, Qingjie GE, Jiafeng YU, and Hengyong XU. "Propane Selective Oxidation to Acrylic Acid over Combined Catalysts." CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) 32, no. 6 (2014): 1022–26. http://dx.doi.org/10.3724/sp.j.1088.2011.10136.

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16

Andrushkevich, T. V., and G. Ya Popova. "Mechanism of heterogeneous oxidation of acrolein to acrylic acid." Russian Chemical Reviews 60, no. 9 (1991): 1023–34. http://dx.doi.org/10.1070/rc1991v060n09abeh001126.

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17

Godefroy, A., G. S. Patience, T. Tzakova, D. Garrait, and J. L. Dubois. "Reactor Technologies for Propane Partial Oxidation to Acrylic Acid." Chemical Engineering & Technology 32, no. 3 (2009): 373–79. http://dx.doi.org/10.1002/ceat.200800309.

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18

Chi, Hui, Liqin Cao, and Jide Wang. "Synthesis of cross-linked copolymers of the (3-(2-pyridyl) acrylic acid)–copper(ii) complex in supercritical carbon dioxide for the catalytic oxidation of benzyl alcohol." RSC Advances 6, no. 6 (2016): 4434–41. http://dx.doi.org/10.1039/c5ra23546d.

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19

Botti, Sabina, Francesca Bonfigli, Rosaria D’Amato, Jasmine Rodesi, and Maria Gabriella Santonicola. "Poly(Acrylic Acid)/TiO2 Nanocomposite Hydrogels for Paper Artwork Cleaning and Protection." Molecules 30, no. 1 (2024): 75. https://doi.org/10.3390/molecules30010075.

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Paper-based artworks are prone to natural aging processes driven by chemical and biological processes. Numerous treatments have been developed to mitigate deterioration and prevent irreversible damage. In this study, we investigated the use of poly(acrylic acid)/TiO2 composite hydrogels, combining their cleaning and protective functions in a minimally invasive treatment. Hydrogels allow for controlled water flow and photocatalytic TiO2 nanoparticles enhance the hydrogel’s efficacy by enabling the removal of oxidation products and inactivating biological contaminants. Furthermore, this innovati

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20

Sanjeeva Reddy, Ch. "Homogeneous catalysis of manganese(II) in acid bromate oxidation of olefinic acids." Collection of Czechoslovak Chemical Communications 53, no. 12 (1988): 3138–48. http://dx.doi.org/10.1135/cccc19883138.

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Manganese(II)-catalysed acid bromate oxidation of acrylic trans-crotonic and trans-cinnamic acids, in the presence of mercury(II), a bromide ion scavenger, exhibits first order in concentration of bromate, and reaches an upper limit with increase in substrate as well as catalyst concentration. Oxidation rate increases with acidity and is not altered when deuterium replaces either α or β proton of the olefinic acid. The catalytic effect of Mn(II) is displayed by its complex forming ability and the proposed mechanism assumes the oxidation of the formed Mn(II)-substrate π complex to Mn(III)-subst

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21

Lin, Manhua Mandy. "Selective oxidation of propane to acrylic acid with molecular oxygen." Applied Catalysis A: General 207, no. 1-2 (2001): 1–16. http://dx.doi.org/10.1016/s0926-860x(00)00609-8.

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22

P., VEERASOMAIAH, BAL REDDY K., SETHURAM B, and NAVANEETH RAO T. "Oxidation of some Organic Compounds by Osmium(VIII) in H2SO4-HOAc Medium. A Kinettc Study." Journal of Indian Chemical Society Vol. 66, Nov 1989 (1989): 755–58. https://doi.org/10.5281/zenodo.5959207.

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Department of Chemistry, Osmania University, Hyderabad-500 007 <em>Manuscript received 26 October 1988, revised 27 March 1989, accepted 21 June 1989</em> Oxidation of some unsaturated compounds, viz allyl alcoho', acrolein, acrylic acid, maleic acid and cinnamic acid by Os<sup>VIII</sup> has been studied in H<sub>2</sub>SO<sub>4</sub> - HOAc medium The order in [Os<sup>VIII</sup>] and [substrate] is unity each in all the cases except acrolein and acryhe acid where the order is fractional Increasing percentage of acetic acid decreased the rate The psuedo-first order rate cons

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23

Ju, Xiaohui, Marie Hubalek Kalbacova, Břetislav Šmíd, et al. "Correction: Poly(acrylic acid)-mediated synthesis of cerium oxide nanoparticles with variable oxidation states and their effect on regulating the intracellular ROS level." Journal of Materials Chemistry B 9, no. 40 (2021): 8530. http://dx.doi.org/10.1039/d1tb90156g.

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Correction for ‘Poly(acrylic acid)-mediated synthesis of cerium oxide nanoparticles with variable oxidation states and their effect on regulating the intracellular ROS level’ by Xiaohui Ju et al., J. Mater. Chem. B, 2021, 9, 7386–7400, DOI: 10.1039/D1TB00706H.

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24

Chabukswar, Vasant, and Sanjay Bhavsar. "Synthesis and Characterization of Organically Soluble and Electrically Conducting Acids Doped Polyaniline." Chemistry & Chemical Technology 4, no. 4 (2010): 277–80. http://dx.doi.org/10.23939/chcht04.04.277.

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Emeraldin salt of polyaniline was synthesized by chemical oxidative polymerization method; this salt is soluble in common organic solvents. The obtained results are discussed with reference to lactic acid doped polyaniline. It has been observed that acrylic acid doped polyaniline is comparatively more soluble than polyaniline doped with lactic acid in common organic solvent such as m-cresol, NMP (N-methyl pyrrolidinone), DMSO, DMF, etc. The acrylic acid doped polymer prepared using lactic acid is comparatively more soluble in m-cresol and NMP than the polyaniline without acrylic acid. UV-Visib

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25

Vida, Norbert, Jiří Václavík, and Petr Beier. "Synthesis and reactivity of aliphatic sulfur pentafluorides from substituted (pentafluorosulfanyl)benzenes." Beilstein Journal of Organic Chemistry 12 (January 20, 2016): 110–16. http://dx.doi.org/10.3762/bjoc.12.12.

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Oxidation of 3- and 4-pentafluorosulfanyl-substituted anisoles and phenols with hydrogen peroxide and sulfuric acid provided a mixture of SF5-substituted muconolactone, maleic, and succinic acids. A plausible mechanism for the formation of the aliphatic SF5 compounds was presented and their chemical reactivity was investigated. SF5-substituted para-benzoquinone was synthesized; its oxidation led to an improved yield of 2-(pentafluorosulfanyl)maleic acid. The reaction of SF5-substituted maleic anhydride and para-benzoquinone with cyclopentadiene afforded the Diels–Alder adducts. Decomposition o

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26

Yang, Sungpil, Minsu Kim, Sungeun Yang, Dae Sung Kim, Won Jae Lee, and Hyunjoo Lee. "Production of acrylic acid from biomass-derived allyl alcohol by selective oxidation using Au/ceria catalysts." Catalysis Science & Technology 6, no. 10 (2016): 3616–22. http://dx.doi.org/10.1039/c5cy02099a.

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27

Davis, Joshua T., Paul D. Hamilton, and Nathan Ravi. "Poly(acrylamide co-acrylic acid) for use as an in situ gelling vitreous substitute." Journal of Bioactive and Compatible Polymers 32, no. 5 (2017): 528–41. http://dx.doi.org/10.1177/0883911516688482.

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Our objective is to improve on our previous work developing thiol-containing water-soluble copolyacrylamides that form hydrogels in situ for use as vitreous substitutes. In this study, we evaluate the incorporation of acrylic acid by varying the feed ratio of acrylic acid monomer from 0 to 40 mol% in combination with acrylamide, and bis-acryloylcystamine as the reversible cross-linker. After polymerization, the formed copolymer hydrogels were reduced with dithiothreitol to cleave the disulfide cross-linkers. Purified, lyophilized copolymers were made in a concentration range of 12.5–17.5 mg/mL

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28

Dvořák, Dalimil, Miloš Buděšínský, David Šaman, and Zdeněk Arnold. "Benzylidenemalonaldehydes: A redox reaction during the attempted cycloaddition on nitrosobenzene." Collection of Czechoslovak Chemical Communications 50, no. 10 (1985): 2260–64. http://dx.doi.org/10.1135/cccc19852260.

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Reaction of p-chlorobenzylidenemalonaldehyde with nitrosobenzene represents a reduction-oxidation process leading to 2-formyl-3-anilino-3-(4-chlorophenyl)acrylic acid (III). The structure of the product, including two intramolecular hydrogen bonds, has been proved by analysis of the 1H and 13C NMR spectra of the acid III, its deuterated form and the methyl ester obtained by reaction with diazomethane.

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29

Winnik, Françoise M., André Morneau, Alicja M. Mika, et al. "Polyacrylic acid pore-filled microporous membranes and their use in membrane-mediated synthesis of nanocrystalline ferrihydrite." Canadian Journal of Chemistry 76, no. 1 (1998): 10–17. http://dx.doi.org/10.1139/v97-210.

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A series of cation-exchange membranes were obtained by photoinitiated grafting of acrylic acid onto a polypropylene microporous support having 0.2 µm diameter pores. The poly(acrylic acid) was shown to be contained within the pores of the membrane. The ion-exchange capacities of these "pore-filled" membranes ranged from 65 to 80% of the theoretical values calculated on the basis of their measured graft yields, with water contents ranging from 72 to 77%. The membranes exhibited a chemical valve effect of flux as a function of pH. Treatment of a poly(acrylic acid) grafted membrane with a solutio

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30

Ueda, Wataru, and Yasuhiro Suzuki. "Partial Oxidation of Propane to Acrylic Acid over Reduced Heteropolymolybdate Catalysts." Chemistry Letters 24, no. 7 (1995): 541–42. http://dx.doi.org/10.1246/cl.1995.541.

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31

Andrushkevich, T. V. "Heterogeneous Catalytic Oxidation of Acrolein to Acrylic Acid: Mechanism and Catalysts." Catalysis Reviews 35, no. 2 (1993): 213–59. http://dx.doi.org/10.1080/01614949308014606.

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32

Ai, Mamoru. "Selective oxidation of acrolein to acrylic acid by V2O5-P2O5 catalysts." Applied Catalysis 27, no. 1 (1986): 167–79. http://dx.doi.org/10.1016/s0166-9834(00)81055-6.

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33

Tichý, Josef. "Oxidation of acrolein to acrylic acid over vanadium-molybdenum oxide catalysts." Applied Catalysis A: General 157, no. 1-2 (1997): 363–85. http://dx.doi.org/10.1016/s0926-860x(97)00025-2.

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34

Landi, G., L. Lisi, and G. Russo. "Oxidation of propane and propylene to acrylic acid over vanadyl pyrophosphate." Journal of Molecular Catalysis A: Chemical 239, no. 1-2 (2005): 172–79. http://dx.doi.org/10.1016/j.molcata.2005.06.018.

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35

Ai, Mamoru. "Oxidation of propane to acrylic acid on V2O5–P2O5-based catalysts." J. Chem. Soc., Chem. Commun., no. 10 (1986): 786–87. http://dx.doi.org/10.1039/c39860000786.

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36

Pozdeeva, N. N., and E. T. Denisov. "Mechanism of hydroquinone-inhibited oxidation of acrylic acid and methyl methacrylate." Kinetics and Catalysis 52, no. 4 (2011): 506–12. http://dx.doi.org/10.1134/s0023158411040136.

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37

Shi, Qi, Qing Luo Meng, and Nong Wang. "The Preparation of Calcium Carbonate Modified High Water-Absorbing Resin." Advanced Materials Research 1035 (October 2014): 296–302. http://dx.doi.org/10.4028/www.scientific.net/amr.1035.296.

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The poly (sodium acrylate/acrylic acid) water-absorbing resin was prepared by aqueous solution polymerization with acrylic acid (AA) as the monomer, calcium carbonate as the modified additives, N, N-methylene double acrylamide (NMBA) as cross-linking agent, ammonium persulfate (APS)/sodium sulfite oxidation reduction type initiator. It was found that the adsorption performance of absorbent resin modified by calcium carbonate strengthened obviously. Orthogonal and single factor experiment were used to establish the optimum parameters related to the product preparation. The best process conditio

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38

Chabukswar, Vasant, and Anjali Athawale. "Synthesis and characterization studies of organically soluble acrylic acid doped polydiphenylamine." Chemistry & Chemical Technology 2, no. 4 (2008): 257–62. http://dx.doi.org/10.23939/chcht02.04.257.

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Polydiphenylamine (PDPA) doped with acrylic acid was synthesized by oxidative chemical polymerization. This is a new chemical polymerization method developed for the direct synthesis of emeraldine salt form of polydiphenylamine which exhibits remarkably improved solubility in a common organic solvent. These polymers have been characterized by the physical techniques such as UV-visible, FTIR, XRD and conductivity measurement. The results are discussed with reference to the H2SO4 doped polydiphenylamine. The use of functionalized acrylic acid (AA) made it possible to obtain the polymer in doped

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39

Chang, C. Y., C. C. Wang, D. J. Chang, and J. S. Chang. "Combined Fenton-MF process increases acrylonitrile removal." Water Science and Technology 47, no. 9 (2003): 179–84. http://dx.doi.org/10.2166/wst.2003.0520.

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The Fenton oxidation process is possessed of the advantages of both oxidation and coagulation processes. In addition to these functions, Fenton's reagent is also a typical initiator of polymerization. The application of the Fenton-microfiltration process for removal of acrylonitrile (AN), which is the major raw material for manufacturing ABS resins, was investigated. As for Fenton oxidation, in the range of pH 2 to pH 4, AN removal efficiency increased as the pH increased. In experiments of the same initial molar ratio of [FeSO4]0/[H2O2]0, the higher dosage can obtain the higher removal effici

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40

Lu, Quanlin, Rong Liu, and Guofan Xia. "Sequential Dehydration and Oxidation of Biodiesel-derived Crude Glycerol into Acrylic Acid." Russian Journal of Applied Chemistry 91, no. 2 (2018): 235–44. http://dx.doi.org/10.1134/s1070427218020118.

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41

Gong, Wei-Jin, Fang Li, and Dan-Li Xi. "Supercritical Water Oxidation of Acrylic Acid Production Wastewater in Transpiring Wall Reactor." Environmental Engineering Science 26, no. 1 (2009): 131–36. http://dx.doi.org/10.1089/ees.2007.0279.

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42

Hess, Christian, Ming Hoong Looi, Sharifa Bee Abd Hamid, and Robert Schlögl. "Importance of nanostructured vanadia for selective oxidation of propane to acrylic acid." Chem. Commun., no. 4 (2006): 451–53. http://dx.doi.org/10.1039/b512175b.

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43

YU, Zhen-xing, Wei ZHENG, Wen-long XU, Yu-hang ZHANG, Hong-ying FU, and Ping ZHANG. "Effect of preparation conditions on selective oxidation of propane to acrylic acid." Transactions of Nonferrous Metals Society of China 19 (September 2009): s476—s479. http://dx.doi.org/10.1016/s1003-6326(10)60092-1.

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44

Landi, G., L. Lisi, and J. C. Volta. "Role of water in the partial oxidation of propane to acrylic acid." Catalysis Today 91-92 (July 2004): 275–79. http://dx.doi.org/10.1016/j.cattod.2004.03.043.

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45

Pozdeeva, N. N., and E. T. Denisov. "Kinetics and mechanism of the oxidation of acrylic acid and methyl methacrylate." Kinetics and Catalysis 51, no. 2 (2010): 211–18. http://dx.doi.org/10.1134/s0023158410020072.

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46

Black, Kurt A., and Lavorgie Finch. "Acrylic acid oxidation and tissue-to-blood partition coefficients in rat tissues." Toxicology Letters 78, no. 1 (1995): 73–78. http://dx.doi.org/10.1016/0378-4274(94)03233-w.

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47

Tichý, J., J. Švachula, J. Machek, and N. Ch Allachverdova. "Catalytic oxidation of acrolein to acrylic acid over a molybdenum-vanadium catalyst." Reaction Kinetics and Catalysis Letters 31, no. 1 (1986): 159–66. http://dx.doi.org/10.1007/bf02062527.

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48

Drochner, Alfons, Philip Kampe, Nadine Menning, Nina Blickhan, Tim Jekewitz, and Herbert Vogel. "Acrolein Oxidation to Acrylic Acid on Mo/V/W-Mixed Oxide Catalysts." Chemical Engineering & Technology 37, no. 3 (2014): 398–408. http://dx.doi.org/10.1002/ceat.201300797.

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49

Zheng, Wei, Zhenxing Yu, Ping Zhang, et al. "Selective oxidation of propane to acrylic acid over mixed metal oxide catalysts." Journal of Natural Gas Chemistry 17, no. 2 (2008): 191–94. http://dx.doi.org/10.1016/s1003-9953(08)60050-x.

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50

GIRDHARI, L. AGRAWAL, and BUXY PRATIBHA. "Kinetic and Mechanistic Study of the Oxidation of Acrylic Acid by Molybdate Catalysed Hydrogen Peroxide." Journal of Indian Chemical Society Vol. 63, Nov 1986 (1986): 974–76. https://doi.org/10.5281/zenodo.6295857.

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Department of Chemistry, Dr. Hari Singh Gear Vishwavidyalaya, Sagar-470 003 <em>Manuscript received 19 August 1985, revised 17 June 1986, accepted 30 October 1986</em> Kinetic studies of the oxidation of acrylic acid by molybdate catalysed hydrogen peroxide at pH 4.0 have been carried out. The reaction is first order with respect to the substrate and catalyst, but independent of the hydrogen peroxide concentration. The rate of reaction is pH dependent. Variation of the ionic strength of the medium has no pronounced effect on the rate. Activation parameters have been evaluated and a probable me

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