Relevant bibliographies by topics / Oxidative arylation

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  2. Dissertations / Theses
  3. Book chapters

Academic literature on the topic 'Oxidative arylation'

Author: Grafiati
Published: 7 July 2024
Last updated: 31 July 2025

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Journal articles on the topic "Oxidative arylation"

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Zhou, Yao, Ya Wang, Zhiyi Song, Tamaki Nakano, and Qiuling Song. "Cu-catalyzed C–N bond cleavage of 3-aminoindazoles for the C–H arylation of enamines." Organic Chemistry Frontiers 7, no. 1 (2020): 25–29. http://dx.doi.org/10.1039/c9qo01177c.

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Wei, Xiao-Hong, Gang-Wei Wang, and Shang-Dong Yang. "Enantioselective synthesis of arylglycine derivatives by direct C–H oxidative cross-coupling." Chemical Communications 51, no. 5 (2015): 832–35. http://dx.doi.org/10.1039/c4cc07361d.

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A new method for the synthesis of chiral α-amino acid derivatives by enantioselective C–H arylation of N-aryl glycine esters with aryl boric acids by direct C–H oxidative cross-coupling has been performed. This work successfully integrates the direct C–H oxidation with asymmetric arylation and exhibits excellent enantioselectivity.
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Park, Soo J., Jason R. Price, and Matthew H. Todd. "Oxidative Arylation of Isochroman." Journal of Organic Chemistry 77, no. 2 (2011): 949–55. http://dx.doi.org/10.1021/jo2021373.

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Singh, Keisham. "Recent Advances in C–H Bond Functionalization with Ruthenium-Based Catalysts." Catalysts 9, no. 2 (2019): 173. http://dx.doi.org/10.3390/catal9020173.

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The past decades have witnessed rapid development in organic synthesis via catalysis, particularly the reactions through C–H bond functionalization. Transition metals such as Pd, Rh and Ru constitute a crucial catalyst in these C–H bond functionalization reactions. This process is highly attractive not only because it saves reaction time and reduces waste,but also, more importantly, it allows the reaction to be performed in a highly region specific manner. Indeed, several organic compounds could be readily accessed via C–H bond functionalization with transition metals. In the recent past, trem
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Yu, Congjun, and Frederic W. Patureau. "Regioselective Oxidative Arylation of Fluorophenols." Angewandte Chemie International Edition 58, no. 51 (2019): 18530–34. http://dx.doi.org/10.1002/anie.201910352.

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Chen, Wei W., Nahiane Pipaon Fernández, Marta Díaz Baranda, et al. "Exploring benzylic gem-C(sp3)–boron–silicon and boron–tin centers as a synthetic platform." Chemical Science 12, no. 31 (2021): 10514–21. http://dx.doi.org/10.1039/d1sc01741a.

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This work explores divergent reactivity of the benzylic gem-boron–silicon and boron–tin double nucleophiles, including the arylation of the C–B bond with Ar–Cl, along with a complementary oxidative λ<sup>3</sup>-iodane-guided arylation of the C–Si/Sn moiety.
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Ho, Nga Kim T., Beate Neumann, Hans-Georg Stammler, et al. "Nickel-catalysed direct C2-arylation of N-heterocyclic carbenes." Dalton Transactions 46, no. 36 (2017): 12027–31. http://dx.doi.org/10.1039/c7dt03099a.

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Direct C2-arylation of NHCs to C2-arylated imidazolium salts (III) is achieved using Ni-catalysis. The dinuclear Ni(i) species I undergoes oxidative addition with ArX to give the Ni(ii) intermediate II. Reductive elimination delivers the arylation product III and regenerates the catalyst I.
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Hata, Kazuhiro, Hideto Ito, Yasutomo Segawa, and Kenichiro Itami. "Pyridylidene ligand facilitates gold-catalyzed oxidative C–H arylation of heterocycles." Beilstein Journal of Organic Chemistry 11 (December 28, 2015): 2737–46. http://dx.doi.org/10.3762/bjoc.11.295.

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Triaryl-2-pyridylidene effectively facilitates the gold-catalyzed oxidative C–H arylation of heteroarenes with arylsilanes as a unique electron-donating ligand on gold. The employment of the 2-pyridylidene ligand, which is one of the strongest electron-donating N-heterocyclic carbenes, resulted in the rate acceleration of the C–H arylation reaction of heterocycles over conventional ligands such as triphenylphosphine and a classical N-heterocyclic carbene. In situ observation and isolation of the 2-pyridylidene-gold(III) species, as well as a DFT study, indicated unusual stability of gold(III)
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Chen, Kai, Xin Li, Shuo-Qing Zhang та Bing-Feng Shi. "Palladium-catalyzed C(sp3)–H arylation of lactic acid: efficient synthesis of chiral β-aryl-α-hydroxy acids". Organic Chemistry Frontiers 3, № 2 (2016): 204–8. http://dx.doi.org/10.1039/c5qo00319a.

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Querard, Pierre, Inna Perepichka, Eli Zysman-Colman, and Chao-Jun Li. "Copper-catalyzed asymmetric sp3 C–H arylation of tetrahydroisoquinoline mediated by a visible light photoredox catalyst." Beilstein Journal of Organic Chemistry 12 (December 6, 2016): 2636–43. http://dx.doi.org/10.3762/bjoc.12.260.

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This report describes a highly enantioselective oxidative sp3 C–H arylation of N-aryltetrahydroisoquinolines (THIQs) through a dual catalysis platform. The combination of the photoredox catalyst, [Ir(ppy)2(dtbbpy)]PF6, and chiral copper catalysts provide a mild and highly effective sp3 C–H asymmetric arylation of THIQs.
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Dissertations / Theses on the topic "Oxidative arylation"

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Persson, Andreas K. Å. "Palladium(II)-Catalyzed Oxidative Cyclization Strategies : Selective Formation of New C-C and C-N Bonds." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-75435.

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The main focus of this thesis has been directed towards preparation and oxidative carbocyclization of en-, dien- and aza-enallenes. In the first part of this thesis, a stereoselective oxidative carbocyclization of dienallenes was realized. By employing cheap and readily available palladium trifluoroacetate we were able to efficiently cyclize a variety of dienallenes into hydroxylated carbocycles in high yield and high selectivity. This oxidative process was compatible with two different reoxidation protocols: one relying on p-benzoquinone (BQ) as the oxidant and the other employing molecular o
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Jiang, Tuo. "Palladium(II)-Catalyzed Oxidative Carbocyclization : Stereoselective Formation of C–C and C–B Bonds." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-108669.

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Transition metal catalysis has emerged as one of the most versatile methods for the selective formation of carbon–carbon and carbon–heteroatom bonds. In particular, oxidative carbon–carbon bond forming reactions have been widely studied due to their atom economic feature. This thesis has been focused on the development of new palladium(II)-catalyzed carbocyclization reactions under oxidative conditions. The first part of the thesis describes the palladium(II)-catalyzed oxidative carbocyclization-borylation and -arylation of enallenes. In these reactions, the (σ-alkyl)palladium(II) intermediate
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Zeineddine, Abdallah. "Harnessing the reactivity of gold via ligand design : stabilization of reactive intermediates and development of new Au(I)/Au(III) catalytic pathways." Thesis, Toulouse 3, 2017. http://www.theses.fr/2017TOU30308/document.

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Ce travail de thèse porte sur la chimie organométallique des complexes d'or(I) et sur l'étude de leurs réactivités. Plus particulièrement, le travail présenté ici dans ce manuscrit avait pour objectif d'approfondir nos connaissances sur l'impact des ligands utilisés sur la réactivité de l'or vis-à-vis (i) de l'addition oxydante intermoléculaire et (ii) la possibilité de stabiliser des intermédiaires d'or(I) hautement réactifs. Dans la première partie de ce manuscrit, l'addition oxydante intermoléculaire des halogénures d'aryle (iodure et bromure) à des complexes moléculaires d'or(I) a été étud
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Nassiri, Sarah. "Fonctionnalisations régiosélectives de N-oxyde de pyrazolopyridines via des réactions de C-H activation pallado-catalysées." Electronic Thesis or Diss., Orléans, 2024. https://theses.univ-orleans.fr/prive/accesESR/2024ORLE1007_va.pdf.

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Les réactions de C-H activation représentent aujourd’hui une approche attrayante pour l’élaboration de nouveaux systèmes hétérocycliques pouvant avoir des applications dans divers domaines notamment en biologie et en pharmacie. L’objectif de cette thèse est le développement de nouvelles stratégies permettant de fonctionnaliser sélectivement des hétérocycles azotés par des réactions de C-H activation au moyen de la catalyse à base de métaux de transition.Dans la première partie, nous avons mis au point une méthodologie de synthèse, permettant la fonctionnalisation régiosélective en ortho de la
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Jalalian, Nazli. "Development and Applications of Hypervalent Iodine Compounds : Powerful Arylation and Oxidation Reagents." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-75810.

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The first part of this thesis describes the efficient synthesis of several hypervalent iodine(III) compounds. Electron-rich diaryliodonium salts have been synthesized in a one-pot procedure, employing mCPBA as the oxidant. Both symmetric and unsymmetric diaryliodonium tosylates can be isolated in high yields. An in situ anion exchange also enables the synthesis of previously unobtainable diaryliodonium triflates. A large-scale protocol for the synthesis of a derivative of Koser’s reagent, that is an isolable intermediate in the diaryliodonium tosylate synthesis, is furthermore described. The l
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Blons, Charlie. "Complexes organométalliques d'or(III) et de cuivre(III) et leur réactivité vis-à-vis des substrats π". Thesis, Toulouse 3, 2018. http://www.theses.fr/2018TOU30248/document.

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Cette thèse porte sur la synthèse de composés d'Au(III) et de Cu(III) ainsi que sur l'étude de leur stabilité et de leur réactivité vis-à-vis de substrats p. Une approche conjointe expérimentale et théorique a été exploitée afin d'accéder à des complexes capables d'induire des processus d'insertion migratoire. Le premier chapitre aborde de manière globale la chimie organométallique de l'or et du cuivre sur le plan bibliographique. L'importance du degré d'oxydation +III est mis en évidence par la description des principaux exemples ayant contribué à la compréhension des processus associés à l'a
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Sawalha, Ansam Feras. "Species susceptibility to nephrotoxicity by hydroquinone and hydroquinone-glutathione conjugates : role of oxidation, specific cytochrome P450 isoforms, and tissue arylation /." Digital version accessible at:, 1998. http://wwwlib.umi.com/cr/utexas/main.

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Batail, Nelly. "La catalyse au palladium pour l'obtention d'indoles fonctionnalisés : application à une synthèse monotope d'indoloquinones par catalyse hétérogène." Phd thesis, Université Claude Bernard - Lyon I, 2010. http://tel.archives-ouvertes.fr/tel-00713118.

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Depuis le début des années 1990, l'hétéroannélation de Larock est apparue comme une méthode de choix pour obtenir, en une seule étape, des indoles 2,3-disubstitués. Cependant, bien qu'efficace, certains inconvénients restaient associés à cette stratégie comme l'utilisation d'un système catalytique homogène associé à l'emploi de sels. Pour cette raison, nous avons développé une nouvelle méthodologie sans sels ou additifs par catalyse hétérogène. Différents catalyseurs commerciaux ou faciles d'accès (Pd/C ou [Pd]/NaY) ainsi que de nouveaux complexes au palladium immobilisés sur SBA-15 ont été te
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Book chapters on the topic "Oxidative arylation"

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Thomas, R. D. "By Oxidative Arylation off Ln(I) Halides by Arylmercurials." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145241.ch79.

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Hopkinson, M. N., and V. Gouverneur. "Oxidative Arylation with Arylsilanes Using Selectfluor." In Compounds of Groups 12 and 11 (Zn, Cd, Hg, Cu, Ag, Au). Georg Thieme Verlag KG, 2011. http://dx.doi.org/10.1055/sos-sd-103-00065.

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Hopkinson, M. N., and V. Gouverneur. "Oxidative Arylation with Arylboronic Acids Using Selectfluor." In Compounds of Groups 12 and 11 (Zn, Cd, Hg, Cu, Ag, Au). Georg Thieme Verlag KG, 2011. http://dx.doi.org/10.1055/sos-sd-103-00061.

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Taber, Douglass F. "Functionalization and Homologation of Alkenes." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0029.

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Masahito Ochiai developed (Org. Highlights, March 24, 2008) the iodosobenzene-mediated cleavage of alkenes to keto aldehydes. Thottumkara K. Vinod of Western Illinois University described (Org. Lett. 2010, 12, 5640) a modified protocol that delivered the keto acid 2. Chi-Ming Che of the University of Hong Kong established (J. Am. Chem. Soc. 2010, 132, 13229) a method for the preparative scale Fe-catalyzed cis dihydroxylation of an alkene 3. Ilhyong Ryu of Osaka Prefecture University devised (Synlett 2010, 2014) a practical procedure for the free radical addition of HBr to an alkene 5. Tetsuo O
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Seibel, Zara M., and Tristan H. Lambert. "Construction of Alkylated Stereocenters." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0035.

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Hirohisa Ohmiya and Masaya Sawamura at Hokkaido University reported (Angew. Chem. Int. Ed. 2013, 52, 5350) the copper-catalyzed, γ-selective allylation of terminal alkyne 1 to produce the chiral skipped enyne 3 with high ee. A method to synthe­size asymmetric skipped diene 6 via copper-catalyzed allylic allylation of diene 4 was developed (Chem. Commun. 2013, 49, 3309) by Ben L. Feringa at the University of Groningen. Prof. Feringa also disclosed (J. Am. Chem. Soc. 2013, 135, 2140) the regi­oselective and enantioselective allyl–allyl coupling of bromide 7 with allyl Grignard under Cu catalysis
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Taber, Douglass F. "Selective Functionalization of C–H Bonds." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0019.

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Jianhui Huang and Kang Zhao of Tianjin University devised (Chem. Commun. 2013, 49, 1211) a protocol for the oxidation of a terminal alkene 1 to the valuable four-carbon synthon 2. M. Christina White of the University of Illinois effected (J. Am. Chem. Soc. 2013, 135, 7831) the oxidation of the terminal alkene 3 to the enone 4. Miquel Costas of the Universitat de Girona developed (J. Org. Chem. 2013, 78, 1421; Chem. Eur. J. 2013, 19, 1908) a family of Fe catalysts for the oxidation of methylenes to ketones. Depending on the catalyst, any of the three ketones from the oxidation of 5, including 6
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"Synthetic Methods for Diaryl Ether Preparation Using Arylating Reagents." In Methodologies in Ether Synthesis. Royal Society of Chemistry, 2024. http://dx.doi.org/10.1039/9781837675166-00078.

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Diaryl ethers are one of the most essential intermediates for organic synthesis in the fields of medicine, agrochemistry, and polymer sciences. There are many naturally occurring biologically active compounds bearing a diaryl ether group including the antibiotic vancomycin, perrottetines, and chloropeptins (anti-HIV agents). This chapter presents efficient and practical synthetic methods for the synthesis of diaryl ethers including Ullmann-type reactions of aryl halides which are achieved using copper catalysts, Buchwald–Hartwig cross-couplings of aryl halides in the presence of palladium cata
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Taber, Douglass F. "C–H Functionalization: The Ono/Kato/Dairi Synthesis of Fusiocca-1,10(14)-diene-3,8β,16-triol." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0018.

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Theodore A. Betley of Harvard University devised (J. Am. Chem. Soc. 2011, 133, 4917) an iron catalyst for inserting the nitrene from 2 into the C–H of 1 to give 3. Bernhard Breit of the Freiburg Institute for Advanced Studies uncovered (J. Am. Chem. Soc. 2011, 133, 2386) a Rh catalyst that effected the intriguing hydration of a terminal alkyne 4 to the allylic ester 5. Yian Shi of Colorado State University specifically oxidized (Org. Lett. 2011, 13, 1548) one of the two allylic sites of 6 to give 7. Kálmán J. Szabó of Stockholm University optimized (J. Org. Chem. 2011, 76, 1503) the allylic ox
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Taber, Douglass F. "C–H Functionalization: The Shaw Synthesis of E-δ-Viniferin." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0022.

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Thomas Lectka of Johns Hopkins University reported (J. Org. Chem. 2014, 79, 8895) a simple protocol for free radical monofluorination, exemplified by the conversion of 1 to 2. Michael K. Hilinski of the University of Virginia used (Org. Lett. 2014, 16, 6504) a catalytic amount of the ketone 4 to mediate the oxidation of 3 to 5. Oxidation of 3 with DMDO gave the regioisomeric tertiary alcohol (not illustrated). Jeung Gon Kim and Sukbok Chang of KAIST used (Chem. Commun. 2014, 50, 12073) an Ir catalyst to convert 6 selectively to the primary sulfonamide 7. Paul J. Chirik of Princeton University
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Lambert, Tristan H. "Flow Chemistry." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0016.

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Although photocatalytic chemistry has been the subject of intense interest recently, the rate of these reactions is often slow due to the limited penetration of light into typical reaction media. Peter H. Seeberger at the Max-Planck Institute for Colloids and Surfaces in Potsdam and the Free University of Berlin showed (Chem. Sci. 2012, 3, 1612) that Ru(bpy)32+-catalyzed reactions such as the reduction of azide 1 to 2 can be achieved in as little as 1 min residence time using continuous flow, as opposed to the 2 h batch reaction time previously reported. The benefits of flow on a number of str
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