Academic literature on the topic 'Oxidy oceli'

Streszczenie Podmínky aplikace vysoce legovaných austenitických ocelí lze rozdělit podle charakteru a mechanismu tvorby ochranné vrstvy, která brání jejich intenzivnější celkové korozi. Při vzniku ochranné, pasivační vrstvy mechanismem nízkoteplotní oxidace (tj. do teplot 200-300°C) mají oceli charakter materiálů korozivzdorných. Při vyšších aplikačních teplotách, kdy ochranná oxidická vrstva má charakter oxidu vysokoteplotního (při teplotách nad 300°C), slouží tyto oceli jako materiály žárovzdorné či žáropevné. Dosažení optimální korozní odolnosti v obou aplikačních oblastech závisí mj. na stavu povrchu, avšak odlišným způsobem. Rozhodující vlivy stavu povrchu jsou diskutovány v tomto článku.

Použití superkritické vody v energetice je motivováno zvýšením tepelné účinnosti energetického cyklu. Důsledkem vyšší účinnosti je snížení specifi ckých emisí CO2. Superkritické energetické cykly byly proto zařazeny mezi čisté uhelné technologie (CCT - Clean Coal Technology). Vzhledem ke korozní agresivitě superkritické vody je základním požadavkem volba správného konstrukčního materiálu. Všechny typy ocelí, testovaných v této studii, byly použity při konstrukci komponent superkritického energetického bloku. Ke studiu byly vybrány celkem čtyři typy žáropevných ocelí, z toho dva typy austenitických ocelí a dva typy feriticko-martenzitických ocelí. Vzorky těchto ocelí byly exponovány za superkritických podmínek (580 °C, 25 MPa) v experimentální smyčce po dobu 12 až 50 hodin. Zároveň byl zkoumán vliv počáteční fáze expozic - tedy vliv ohřevu z okolní teploty na provozní parametry. Chemické složení a přenosové vlastnosti oxidických vrstev, tvořících se během interakce se superkritickou vodou (SCW), byly studovány ex-situ pomocí elektrochemických metod a povrchových analýz (XPS a Ramanova spektroskopie). Elektrochemické testy zahrnovaly Mott-Schottkyho analýzu založenou na měření impedance v závislosti na elektrodovém potenciálu. Tvar Mott-Schottkyho závislostí sloužil ke kvantitativní charakterizaci polovodivého chování oxidů. Oxidy na všech typech ocelí vykazovaly polovodivé chování jak typu N, tak typu P. Vlastnosti oxidů, zejména hustota poruch a chemické složení, závisí významně na způsobu najetí krátkodobé superkritické expozice.

Background In most publications about myasthenia, monitoring neuromuscular blockade during anesthesia is recommended. In healthy patients, the relation of blockade between muscles has been established, but there is little information about the relation in myasthenic patients. Our objective was to investigate whether the relation between the orbicularis oculi and adductor pollicis muscles is the same in healthy patients and myasthenic patients. Methods After anesthesia was induced with 4-6 mg/kg thiopental and 2 microg/kg fentanyl, followed by 2% sevoflurane and 60% nitrous oxide in oxygen, 10 healthy patients and 10 myasthenic patients received 0. 025 and 0.01 mg/kg vecuronium, respectively. Neuromuscular monitoring was performed with use of accelerometry at the orbicularis oculi and the adductor pollicis muscles by stimulating the temporal branch of the facial nerve and the ulnar nerve. Results The relation of blockade between these two muscles was not the same in healthy patients and myasthenic patients: in healthy patients, the maximum neuromuscular blockade with 0.025 mg/kg vecuronium was less in the orbicularis oculi than in the adductor pollicis (median 72% vs. 91%; P < 0.05); in contrast, in myasthenic patients, the blockade with 0.01 mg/kg vecuronium was greater in the orbicularis oculi than in the adductor pollicis (median 96% vs. 62%; P < 0.05). Conclusion Neuromuscular monitoring at the orbicularis oculi may overestimate blockade in myasthenic patients. Extubation must be performed when the muscle most sensitive to neuromuscular blocking agents is recovered. Therefore, neuromuscular monitoring at the orbicularis oculi is recommended to avoid persistent neuromuscular blockade in patients with myasthenia gravis.

Background Some studies suggest that the orbicularis oculi is resistant to neuromuscular blocking drugs and behaves like laryngeal muscles. Others report little or no difference between the orbicularis oculi and the adductor pollicis. These discrepancies could be related to the exact site of recording. The purpose of this study was to compare two monitoring sites around the eye with the adductor pollicis and the laryngeal adductor muscles. Methods After institutional approval and informed consent, the evoked response to train-of-four stimulation was measured in 12 patients by acceleromyography at the thumb (adductor pollicis), the eyelid (orbicularis oculi), and the superciliary arch (corrugator supercilii) after 0.5 mg/kg rocuronium during propofol-fentanyl-nitrous oxide anesthesia. In 12 other patients, laryngeal adductor neuromuscular blockade was assessed via the cuff of the tracheal tube and compared with the adductor pollicis and the corrugator supercilii after 0.6 mg/kg rocuronium. Results After 0.5 mg/kg, maximum blockade (%T1, mean +/- SD) was less at the corrugator supercilii (80+/-20%) than at the adductor pollicis (100+/-1%) and the orbicularis oculi (93+/-8%) (P < 0.01). Clinical duration (25%T1) was shorter at the corrugator supercilii (12+/-7 min) than at the adductor pollicis (25+/-4 min) and orbicularis oculi (24+/-10 min) (P < 0.01). After 0.6 mg/kg, maximum blockade was similar at the corrugator supercilii (88+/-8%) and the laryngeal adductor muscles (89+/-11%). Clinical duration at the corrugator supercilii and the laryngeal adductors was 17+/-7 and 17+/-10 min, respectively. Conclusions Muscles around the eye vary in their response to rocuronium. The response of the superciliary arch (corrugator supercilii) reflects blockade of laryngeal adductor muscles. However, the eyelid (orbicularis oculi) and thumb (adductor pollicis) have similar sensitivities.

Functional role and anatomic location of nitroxidergic nerves were determined in dog retinal arteries and arterioles. Isolated retinal central arteries responded to nicotine with relaxations that were not influenced by atropine, timolol, or indomethacin and damage of the endothelium, but were abolished by hexamethonium, methylene blue, and oxyhemoglobin. The relaxation was abolished by NG-nitro-L-arginine (L-NNA), a nitric oxide (NO) synthase inhibitor, and was restored by L-arginine. Relaxations caused by NO were not affected by L-NNA. Transmural electrical stimulation at 5 Hz relaxed the strips; the relaxation was abolished by L-NNA and tetrodotoxin. In anesthetized dogs, intraarterial injections of nicotine dilated retinal arterioles in the fundus oculi. This effect was abolished by L-NNA and restored by L-arginine. Intravenous injections of L-NNA constricted retinal arterioles, the effect being prevented by hexamethonium. There were nerve bundles and fibers containing NO synthase immunoreactivity in the adventitia and media in the retinal artery. These findings are consistent with our hypothesis that NO liberated from vasodilator nerves acts as neurotransmitter in dog retinal arteries and arterioles, and the arteriolar muscle tone is regulated by vasodilator nerve activity in vivo.

Abstract The Cameroon Line was created by the rejuvenation, at the beginning of the opening of the Atlantic Ocean, of a Pan-African N070 degrees E fracture zone [Moreau et al., 1987], which acted as a huge lithospheric crack taping a hot asthenospheric zone [Deruelle et al., 1998; Marzoli et al., 2000]. The Kokoumi anorogenic pluton belongs to the E-W Garoua rift structure, which represents the easternmost extension of the Benue trough. The Garoua rift opened during the Neocomian-Lower Aptian ages [Benkhelil, 1988] through the rejuvenation of Pan-African normal faults. The rift subsided, was partially filled by conglomerates and sandstones, and the ensemble was folded in the Cretaceous period [Guiraud, 1993]. Post-Cretaceous faulting affected these sediments. Intrusion of the Kokoumi anorogenic complex through the Cretaceous sandstones was favoured by N-S, N070 degrees E, E-W and N135 degrees E faults and N030 degrees E extension [Moreau et al., 1987]. The Kokoumi complex was first described by Koch [1959]. It is composed of a plutonic gabbro-nepheline monzosyenite-nepheline syenite series and of lamprophyric dykes (monchiquites and camptonites). One trachyte dyke is also observed. The gabbros are olivine (Fo 70 )-, nepheline-, or kaersutite-bearing gabbros. They also contain Ti-Al-rich diopside, Ti-rich biotite, titanite, ilmenite, Ti-magnetite and apatite. The nepheline monzosyenites contain diopside, Fe-diopside, kaersutite, Fe-kaersutite, titanite and apatite. The nepheline syenites contain aegirine-augite, F-rich arfvedsonite and aenigmatite. Kaersutite and clinopyroxene predominate in the lamprophyres. Monchiquites and gabbros, camptonites and monzosyenites, display respective similar mineralogy. Monchiquites contain carbonate ocelli. The trachyte does not contain ferromagnesian minerals. For gabbros and monchiquites, equilibrium Fe-Ti oxide temperatures are between 650 and 750 degrees C (+ or -40 degrees C) and oxygen fugacities between 10 (super -15) and 10 (super -14) (+ or -0.5 X 10 (super -15) ) atmospheres, according to Spencer and Lindsley [1981]. Nepheline crystallized below 700 degrees C, according to Hamilton [1961]. All the rocks (except the trachyte) are nepheline normative (Ne 6 to Ne 40 ). Major and trace element distributions in MgO-element diagrams for the two series merge together into a single trend, from monchiquites to nepheline syenites. Nevertheless, the monchiquites trends have different slopes. We deduce the evolution from gabbros to nepheline syenites on the one hand and from monchiquites to camptonites on the other from primitive mantle normalized multi-element diagrams. Multi-element diagrams for the trachyte and the nepheline syenite are strictly similar. Patterns for Kokoumi gabbros are similar to those for basalts of the Kapsiki plateau [Ngounouno et al., 2000] and the Garoua rift [Ngounouno et al., 1997] with typical negative K and positive Zr and Ti anomalies. Patterns for nepheline monzosyenites display negative anomalies in Sr, P, Eu and Ti and those for nepheline syenites and trachyte display greater anomalies in these elements and Ba. Compared to gabbros, nepheline monzosyenites are enriched in all REE with a concave upward pattern and no Eu-anomaly. Nepheline syenites have a range of broadly similar REE patterns to nepheline monzosyenites with steep slope from La to Sm, strong Eu negative anomaly (Eu/Eu (super *) nearly equal 0.15) and heavy-REE spoon-shape. REE patterns for monchiquites, camptonites, and trachyte are respectively similar to those for gabbros, monzosyenites, and nepheline syenite. Initial Sr-isotope ratios of 0.7033 (recalculated from the measured ratios for an age of 39 Ma for plutonic rocks and 20 Ma for the lamprophyres and the trachyte) are similar to those obtained for basalts from the continental segment of the Cameroon Line [Halliday et al., 1988; Ngounouno et al., 2000; Demaiffe et al., unpubl.], whereas nepheline syenites and trachyte are distinctly more radiogenic with values between 0.7128 and 0.7251. Amphibole and whole-rock K-Ar analyses (table III) yield 39.0+ or -0.9 Ma and 36.6+ or -0.9 Ma respectively. Since amphibole is a reliable chronometer in K-Ar dating, we propose the first age as the probable time of emplacement of the gabbros. Whole-rock analysis of nepheline syenite 99 displays an age of 33.1+ or -0.5 Ma. Field and geochemical observations suggest that gabbros and nepheline syenite are cogenetic and hence contemporaneous.

This diploma thesis is dealing with the impact of oxide scales on heat conduction. One of the main tools that were used are numerical simulations. Heat conduction is modelled by solving partial differential equations. Regression models and artificial neural networks are used for the prediction of the influence of oxides on cooling intensity. Determination of the conditions when the cooling was intensified and comparison of individual methods of prediction are the main results of the thesis.

Doctoral thesis was focused on preparing of new advanced ODS steels for use in heavy metal liquids enviroments. Possibility of new course for creating oxide dispersion in microstructure was verified by the course of internal oxidation of elements. By the internal oxidation method were prepared new ODS steels strengthened by complex oxides which were created by elements of IIIB and IVB group of elements. Based on analysis of damage ODS steels in LBE were designed surface protection of ODS steel by the oxide layer. The ODS steel protected by oxide layer was subjected to a corrosion test in LBE. For the experiments were chosen class of chromium steels: ferritic-martensitic steel 9Cr1WMnVTa and ferritic steels 14CrWTi and 17Cr1Mo. Steels without oxide dispersion and steel strenghtened by the dispersion based on Y-Ti-O oxides were prepared. On the steels were made series of mechanic tests which should reveal the effectivity of oxide dispersion on the strenght of steel prepared by the internal oxidation method and by the direct addition of oxide elements. It was found that significantly harder oxide material couldn't be fully disrupted through the mechanical alloying and fine oxide dispersion couldn't be created. There was verified fine oxide dispersion could be created by the internal oxidation method and by the direct adding of oxide elements. Same kind of steels strenghtened by new kind of complex oxides based on Y, Ce, Hf, La, Sc and Zr were prepared. The chemical analyses have proven that all added elements could created complex oxide by the reaction with yttrium. The computational analyses for observing of matrix influence and oxide phase influence on strenghtening of steels were performed. These computational analyses were based on microstructural analyses of ODS steels. There was found that the oxide particles could very effectively improve strenght of steels at room temperature and especialy at high temperature. Based on corrosion tests of 14Cr ODS steel in liquid Pb and LBE enviroment were designed surface protection of ODS steel. The effectiveness of protective layer was verified by the high temperature corrosion test of PM2000 in LBE. No damage of oxide layer was observed although Pb and Bi diffused through protective layer.

This Master’s thesis is related to corrosion degradation processes on metal surfaces exposed in different environments. The theoretical part is concern with basic principles in electrochemical and atmospheric corrosion. Practical part describes experimentation of corrosion process of aluminium (99,5) and low carbon steel (11321) in two different atmospheric environments. The conclusion of thesis includes evaluations of the results from practical part and comparison with the theoretical part.