Academic literature on the topic 'Oxime synthesis'

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Journal articles on the topic "Oxime synthesis"

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Diedrichs, Nicole, Ralf Krelaus, Ina Gedrath, and Bernhard Westermann. "Kinetic resolution of oxime esters with lipases — synthesis of enantiomerically enriched building blocks with quaternary carbon centers and formal total synthesis of perhydro histrionicotoxin." Canadian Journal of Chemistry 80, no. 6 (2002): 686–91. http://dx.doi.org/10.1139/v02-097.

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Enantiomerically enriched oximes bearing stereogenic quaternary carbon centers can be obtained by lipase-catalyzed kinetic resolution of oxime esters. Substrate specificity, solvent effects, and the use of different lipases are discussed. Kinetic resolution of butyrylated oximes by lipase PS in the presence of n-butanol gave the best ee-values of both the saponified oxime and the residual oxime ester. Subsequent stereospecific Beckmann rearrangement of an enantiomerically enriched oxime provided lactams, which could be employed for the synthesis of optically active perhydro histrionicotoxin.Ke
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Ali Bawa, Ramadan, and Hana Mansoure Elmajdoub. "Synthesis of Some Bridged Unsymmetrical Terphthaloyl Oxime Esters." Academic Journal of Chemistry, no. 56 (June 10, 2020): 55–57. http://dx.doi.org/10.32861/ajc.56.55.57.

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Three unsymmetrical bridged terphthaloyl acetophenone oxime esters have been synthesized throughout an esterification process between three acetophenone oximes and the terphthaloyl chloride under mild basic conditions. Spectroscopic techniques, such as IR, HNMR and mass spectrometer, were used to confirm the structures of the desired oxime esters. The yields of the resulting oxime esters ranged from 50% to 73%.
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Canário, Catarina, Mariana Matias, Vanessa Brito, et al. "New Estrone Oxime Derivatives: Synthesis, Cytotoxic Evaluation and Docking Studies." Molecules 26, no. 9 (2021): 2687. http://dx.doi.org/10.3390/molecules26092687.

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The interest in the introduction of the oxime group in molecules aiming to improve their biological effects is increasing. This work aimed to develop new steroidal oximes of the estrane series with potential antitumor interest. For this, several oximes were synthesized by reaction of hydroxylamine with the 17-ketone of estrone derivatives. Then, their cytotoxicity was evaluated in six cell lines. An estrogenicity assay, a cell cycle distribution analysis and a fluorescence microscopy study with Hoechst 3358 staining were performed with the most promising compound. In addition, molecular dockin
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Ali Bawa, Ramadan, and Hana Mansoure Elmajdoub. "Synthesis of a Number of Unsymmetrical Bridged Terphthaloyl Acetophenone Oxime Esters." Academic Journal of Chemistry, no. 57 (August 8, 2020): 98–100. http://dx.doi.org/10.32861/ajc.57.98.100.

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A number of unsymmetrical bridged terphthaloyl acetophenone oxime esters has been synthesized throughout an esterification reaction between four different acetophenone oximes and the terphthaloyl chloride in a molar ratio of (2:1) under mild basic conditions. Spectroscopic techniques, such as IR, HNMR and mass spectrometer, were used to confirm the structures of the targeted oxime esters. The yields of the obtained oxime esters ranged from 80% to 95%.
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Arthur-Santiago, Margarita A., Rosa María Oliart-Ros, María G. Sánchez-Otero, and Gerardo Valerio-Alfaro. "Mechanochemo-enzymatic Synthesis of Aromatic Aldehyde Oxime Esters." Natural Product Communications 13, no. 7 (2018): 1934578X1801300. http://dx.doi.org/10.1177/1934578x1801300723.

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The synthesis of aromatic aldehyde oxime esters (considered fragrances, antifungal and antimicrobial compounds) was achieved by two reactions which combine the advantage of green chemistry and biocatalysis. In the first step, the mechanochemical oxime synthesis by means of grindstone milling of six solid aromatic aldehydes and hydroxylamine hydrochloride in the presence of FlorisilR, as the best support, yielded the aromatic aldehyde oximes 1–6 with high purity and good yields. In the second step the lipase catalyzed acetylation reaction at 40°C for three days of those oximes with vinyl and is
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Dhuguru, Jyothi, Eugene Zviagin, and Rachid Skouta. "FDA-Approved Oximes and Their Significance in Medicinal Chemistry." Pharmaceuticals 15, no. 1 (2022): 66. http://dx.doi.org/10.3390/ph15010066.

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Despite the scientific advancements, organophosphate (OP) poisoning continues to be a major threat to humans, accounting for nearly one million poisoning cases every year leading to at least 20,000 deaths worldwide. Oximes represent the most important class in medicinal chemistry, renowned for their widespread applications as OP antidotes, drugs and intermediates for the synthesis of several pharmacological derivatives. Common oxime based reactivators or nerve antidotes include pralidoxime, obidoxime, HI-6, trimedoxime and methoxime, among which pralidoxime is the only FDA-approved drug. Cepha
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Çil, Erol, Mustafa Arslan, and Ahmet Orhan Görgülü. "Synthesis and characterization of alkyl- and acyl-substituted oxime–phosphazenes." Canadian Journal of Chemistry 83, no. 12 (2005): 2039–45. http://dx.doi.org/10.1139/v05-223.

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Two oxime–cyclophosphazenes were prepared from the hexakis(4-formylphenoxy)cyclotriphosphazene (2) and hexakis(4-acetylphenoxy)cyclotriphosphazene (8). The reactions of these oximes with ethyl bromide, allyl bromide, propanoyl chloride, and acriloyl chloride were studied. Hexasubstituted compounds were obtained from the reactions of hexakis{4-[(hydroxyimino)methyl]phenoxy}cyclotriphosphazene (3) with ethyl bromide (4), allyl bromide (5), and propanoyl chloride (6), however, the oxime groups on 3 rearranged to nitrile (7) in the reaction of 3 with acriloyl chloride. Hexasubstituted compounds we
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Gulla, Mahendra, Lars Bierer, Stefan Schmidt, Leo Redcliffe, and Volker Jäger. "Bromocyclization of Unsaturated Oximes. Synthesis of Five-Membered Cyclic Nitrones (Pyrroline N-Oxides)." Zeitschrift für Naturforschung B 61, no. 4 (2006): 471–85. http://dx.doi.org/10.1515/znb-2006-0414.

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The cyclization of a ribose-derived pentenose oxime with various halogen electrophiles showed bromine to be the most effective reagent, leading to 80% of L-lyxo/D-ribo-pyrroline N-oxides in an 84:16 diastereomeric ratio. In order to explore the scope of this facile process, several other γ,δ - unsaturated oximes were submitted to this reaction. Depending on the substitution pattern, 23 - 87%, yields of pyrroline N-oxides of were registered. With α-allyl-β -ketoester oximes the alkoxycarbonyl group proved a similar (ethoxy) or even better (t-butoxy) trapping nucleophile, leading preferentially
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Ali Bawa, Ramadan, and Mona Mohammed Friwan. "Synthesis and Antifungal Study of Some Acetophenone Oximes and Their Terphthaloyl Oxime Esters." Academic Journal of Chemistry, no. 410 (October 25, 2018): 96–101. http://dx.doi.org/10.32861/ajc.510.96.101.

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Acetophenone oximes 1 – 5 along with their terphthaloyl oxime esters 6 – 10 have been synthesized in moderate to good yields. Only one oxime was formed in as E/Z two isomers in a ratio of (8:1). These resulting oxime derivatives were involved in an antifungal screening against the Aspergillus niger at concentration of 30 ppm. Two commercially available antifungal agents, clorotimazole and daktarin, were employed as references at the same concentration, 30 ppm. The antifungal results for the oxime derivatives 1 – 10 showed inhibitory levels ranging from 38% to 100%, whereas the antifungal poten
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Spahić, Zlatan, Tomica Hrenar, and Ines Primožič. "Polytopal Rearrangement Governing Stereochemistry of Bicyclic Oxime Ether Synthesis." International Journal of Molecular Sciences 23, no. 20 (2022): 12331. http://dx.doi.org/10.3390/ijms232012331.

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In the present study, four O-substituted oximes of quinuclidin-3-one were synthesized using appropriate O-substituted hydroxylamine hydrochlorides. In order to perform these reactions in a solvent, a mixture of (E) and (Z) products was yielded. Using mechanochemical and microwave synthesis, we then obtained pure (E) oximes. In almost all cases, the conversion to oxime ethers was completed. Reactions were monitored by ATR spectroscopy and the ratios of (E) and (Z) oxime ethers were deduced from 1H NMR data. Several reactions were very rapid (1 min) with 100% conversion and stereospecificity. To
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Dissertations / Theses on the topic "Oxime synthesis"

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Lightfoot, Andrew Philip. "Chiral oxime ethers : applications in synthesis." Thesis, Loughborough University, 1996. https://dspace.lboro.ac.uk/2134/28182.

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Chapter One reviews the literature, discussing the role of nucleophilic additions to oximes and their derivatives. This introduction is primarily concerned with the formation of new carbon–carbon bonds, this is achieved by the addition of organometallic reagents to the carbon–nitrogen double bond functionality of oximes and their derivatives.
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Laurent, Pierre. "Asymmetric synthesis using chiral oxime ethers." Thesis, University of Exeter, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.248161.

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Hunt, James Charles Atlee. "Chiral oxime ethers in asymmetric synthesis." Thesis, University of Exeter, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.302639.

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Cooper, Tracey Sara. "Synthesis of amino acids from chiral oxime ethers." Thesis, University of Exeter, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.432786.

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Gridley, Jonathan James. "Synthesis towards orthogonally protected β mannosamine derivatives." Thesis, University of Reading, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.269741.

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Whittaker, Ruth Eleanor. "An investigation of reactions directed towards the synthesis of 2-methyl-2-(methylthio)propanal oxime." Thesis, Rhodes University, 1995. http://hdl.handle.net/10962/d1004980.

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The processes leading to the formation of 2-methyl-2-(methylthio)propanal oxime, known industrially as aldicarb oxime, have been studied. The three stages of the synthesis, viz., chlorination, thiomethylation and oximation have been thoroughly investigated, with the aim of optimising the yield and purity of aldicarb oxime. Attention has been focused on the chlorination step, and the effects of altering various conditions have been determined; the reaction has been carried out in the absence and presence of heat, solvent and buffer, and the extent of chlorine addition has also been varied. Thes
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Idris, Musa A. "Stereoselective addition reactions of diethylzinc with nitrones, imines and oxime o-ethers." Thesis, University of Sussex, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.341803.

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Moore, Peter Robert. "Organic synthesis through radical cyclisation reactions." Thesis, University of Exeter, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.337802.

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Portela-Cubillo, Fernando. "Oxime derivatives : versatile reagents for radical-mediated syntheses of heterocycles." Thesis, St Andrews, 2009. http://hdl.handle.net/10023/856.

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Acord, Douglas A. "The synthesis and study of 5-oxime-2-methoxy-1,3-xylyl-18-crown-5." Muncie, Ind. : Ball State University, 2009. http://cardinalscholar.bsu.edu/634.

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Books on the topic "Oxime synthesis"

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A, Titheradge Michael, ed. Nitric oxide protocols. Humana Press, 1998.

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Rodríguez, José A., and Marcos Fernández-García, eds. Synthesis, Properties, and Applications of Oxide Nanomaterials. John Wiley & Sons, Inc., 2006. http://dx.doi.org/10.1002/0470108975.

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Bennett, Helen Louise. Synthesis and characterisation of mixed metal oxide fluorides. University of Birmingham, 1998.

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Wiegerink, Remco J. Analysis and synthesis of MOS translinear circuits. Kluwer Academic, 1993.

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Iman, Sasan. Logic synthesis for low power VLSI designs. Kluwer Academic Publishers, 1998.

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Kissick, Judith Louise. Synthesis and characterisation of new mixed metal oxide fluorides. University of Birmingham, 1997.

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Jean, Corbin, and United States. National Aeronautics and Space Administration., eds. Synthesis and thermal stability of graphite oxide-like materials. National Aeronautics and Space Administration, 1997.

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Palatnikov, M. N. Segnetoėlektricheskie tverdye rastvory na osnove oksidnykh soedineniĭ niobii︠a︡ i tantala: Sintez, issledovanii︠a︡ strukturnogo upori︠a︡dochenii︠a︡ i fizicheskikh kharakteristik. Nauka. Peterburgskoe otd-nie, 2001.

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Wright, Adrian Jerome. Synthesis and characterisation of new phases related to oxide superconductors. University of Birmingham, 1995.

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Alias, Siti Salwa, and Ahmad Azmin Mohamad. Synthesis of Zinc Oxide by Sol–Gel Method for Photoelectrochemical Cells. Springer Singapore, 2014. http://dx.doi.org/10.1007/978-981-4560-77-1.

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Book chapters on the topic "Oxime synthesis"

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Yokoshima, Satoshi. "Construction of Quinoline N-Oxides and Synthesis of Aurachins A and B: Discovery, Application, and Mechanistic Insight." In Modern Natural Product Synthesis. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-1619-7_17.

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AbstractA method to synthesize 3-hydroxyquinoline N-oxides from ketones having a 2-nitrophenyl group at the α-position relative to the carbonyl group was developed. The substrates were easily prepared via a SNAr reaction or a Sonogashira coupling, and treatment with sodium tert-butoxide in dimethyl sulfoxide produced the corresponding quinoline N-oxides. The method was successfully applied to the total synthesis of aurachins A and B. On the basis of the quinoline N-oxide synthesis, related reactions of α-(2-nitrophenyl)ketones, including nitrone formation and photoinduced rearrangement, were a
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Denniston, Michael L., Donald R. Martin, and C. David Schmulbach. "Methyldiphenylphosphine Oxide and Dimethylphenylphosphine Oxide." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132487.ch50.

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Blanchard, Arthur A., C. M. Mason, and Robert L. Barnard. "Nitric Oxide [Nitrogen(II) Oxide]." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132333.ch37.

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Gao, Wei. "Synthesis, Structure, and Characterizations." In Graphene Oxide. Springer International Publishing, 2015. http://dx.doi.org/10.1007/978-3-319-15500-5_1.

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Baudisch, Oskar, Walter H. Hartung, and W. O. Milligan. "Gamma Ferric Oxide Monohydrate and Gamma Ferric Oxide." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132326.ch65.

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Herrell, A. Y., R. H. Busey, K. H. Gayer, K. Schwochau, and S. Gutzeit. "Technetium(VII) Oxide." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132487.ch41.

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Seppelt, Konrad, F. Tanzella, and Neil Bartlett. "Sulfur Tetrafluoride Oxide." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132517.ch8.

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Wilson, William W., Karl O. Christe, and Roland Bougon. "Tungsten Tetrafluoride Oxide." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132555.ch12.

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Lange, Willy, H. S. Booth, and Fred E. Kendall. "Porous Boron Oxide." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132333.ch7.

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Hammer, Robert N., Jacob Kleinberg, Henry F. Holtzclaw, and K. W. R. Johnson. "Silver(II) Oxide." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132357.ch3.

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Conference papers on the topic "Oxime synthesis"

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Nair, Hari. "MOCVD synthesis and in situ processing of heterostructures and polymorphs of gallium oxide." In Oxide-based Materials and Devices XVI, edited by Féréchteh H. Teherani and David J. Rogers. SPIE, 2025. https://doi.org/10.1117/12.3050045.

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Shakirzyanov, R. I., Yuriy A. Garanin, Artem L. Kozlovskiy, Dmitriy I. Shlimas, Maxim V. Zdorovets, and Dilnaz K. Zhamikhanova. "Study of Phase Composition and Microstructure of Porous Alumina Ceramics Derived from Hydrothermal Powders." In 2024 8th International Conference on Materials Engineering and Nano Sciences & 2024 8th International Conference on Material Engineering and Manufacturing. Trans Tech Publications Ltd, 2024. http://dx.doi.org/10.4028/p-k3kqa8.

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Conventional ceramic technology is a widespread technique for synthesizing a large range of materials for household use and engineering applications. However, for advanced technical ceramics different approaches should be used in order to obtain materials with unique physical properties. Despite the well-known technology for the synthesis of alumina-based ceramics, there are a lot of challenges in optimizing manufacturing conditions or integrating the newest technologies. In particular, there are still some challenges in sintering porous bulk ceramics. In this paper, we report on synthesizing
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Tso, J., and S. Que Hee. "222. Synthesis of Aldehyde Oxime Standards." In AIHce 1997 - Taking Responsibility...Building Tomorrow's Profession Papers. AIHA, 1999. http://dx.doi.org/10.3320/1.2765350.

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García-Melchor, Max, Jonathan Sharp, Anna Ciotti, Hayley Andrews, Shaktiswaran R. Udayasurian, and Tengfei Li. "Decarbonizing Chemical Synthesis: Nitrate Electroreduction to Cyclohexanone Oxime on Zn-Cu Alloys." In Materials for Sustainable Development Conference (MATSUS Fall 24). FUNDACIO DE LA COMUNITAT VALENCIANA SCITO, 2024. https://doi.org/10.29363/nanoge.matsusfall.2024.409.

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Ryu, Ilhyong, Sunggak Kim, Hiroki Kuriyama, Hironari Miyazato, Mitsuo Komatsu, and Joo-Yong Yoon. "Novel Synthesis of a,b-Diketoesters from a,a-Dioxo-type Oximes or Oxime Ethers via Zinc-Induced Deoximation." In The 4th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01829.

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Pang, Yu-Lian, and Ying-Quan Zou. "Synthesis and photopolymerization kinetics of a novel oxime ester sulfonic acid photoacid generator." In SPIE Advanced Lithography, edited by Mark H. Somervell and Thomas I. Wallow. SPIE, 2012. http://dx.doi.org/10.1117/12.916239.

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Akila, A., A. Revathi, S. Ponnuswamy, and D. Sudha. "Synthesis, characterization and biological evaluation of 3-isopropyl-2,6-diphenylpiperidin-4-oxime complexes." In INTELLIGENT BIOTECHNOLOGIES OF NATURAL AND SYNTHETIC BIOLOGICALLY ACTIVE SUBSTANCES: XIV Narochanskie Readings. AIP Publishing, 2023. http://dx.doi.org/10.1063/5.0178894.

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Dekamin, Mohammad, and Neda Nazary. "Synthesis of Acetaminophen by Liquid Phase Beckmann Rearrangement of 4-Hydroxyacetophenone Oxime over Nano-Ordered Zn-MCM-41." In The 14th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2010. http://dx.doi.org/10.3390/ecsoc-14-00446.

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Latif, Ahmed, Tímea Gonda, Norbert Kúsz, Ágnes Kulmány, István Zupkó, and Attila Hunyadi. "Synthesis and evaluation cytotoxic and antioxidant effects of naringenin oxime relative to naringenin on human cancer cell lines." In Fiatal Gyógynövénykutatók Fóruma. Magyar Gyógyszerésztudományi Társaság Gyógynövény Szakosztálya, 2018. http://dx.doi.org/10.14232/fgykf.2018.b3.

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Esparza, Kevin, Virginia Marañón, Corinna Enríquez, et al. "Synthesis and characterization of SnO2/graphene transparent conducting films." In Oxide-based Materials and Devices X, edited by Ferechteh H. Teherani, David C. Look, and David J. Rogers. SPIE, 2019. http://dx.doi.org/10.1117/12.2508030.

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Reports on the topic "Oxime synthesis"

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Koh, John T. Design and Synthesis of Bifunctional Oxime Reactivators of OP- inhibited Cholinesterase. Defense Technical Information Center, 2013. http://dx.doi.org/10.21236/ada602407.

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Yoon, Wonki, and Waltraud M. Kriven. Synthesis and Mirostructural Design of Oxide Fibers. Defense Technical Information Center, 2005. http://dx.doi.org/10.21236/ada450946.

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Harreld, John H., Winny Dong, and Bruce Dunn. Ambient Pressure Synthesis of Aerogel-like Vanadium Oxide and Molybdenum Oxide. Defense Technical Information Center, 1998. http://dx.doi.org/10.21236/ada340483.

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Petrovic, J. J., R. S. Romero, D. Mendoza, A. M. Kukla, R. C. Hoover, and K. J. McClellan. Synthesis and properties of erbium oxide single crystals. Office of Scientific and Technical Information (OSTI), 1999. http://dx.doi.org/10.2172/334209.

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Ramanathan, Shriram. Photo-Activated Synthesis of Functional Oxide Thin Films. Defense Technical Information Center, 2010. http://dx.doi.org/10.21236/ada534012.

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Babcock, L. M. Synthesis and characterization of Group 4 organometal oxide complexes. Office of Scientific and Technical Information (OSTI), 1988. http://dx.doi.org/10.2172/6181619.

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Craig E. Barnes. NANOSTRUCTURED METAL OXIDE CATALYSTS VIA BUILDING BLOCK SYNTHESES. Office of Scientific and Technical Information (OSTI), 2013. http://dx.doi.org/10.2172/1067473.

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Ramani, Vijay K. Synthesis and Characterization of Mixed-Conducting Corrosion Resistant Oxide Supports. Office of Scientific and Technical Information (OSTI), 2015. http://dx.doi.org/10.2172/1326167.

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Dong, Winny, and Bruce Dunn. Sol-Gel Synthesis and Characterization of Molybdenum Oxide/Polypyrrole Hybrids. Defense Technical Information Center, 2001. http://dx.doi.org/10.21236/ada389627.

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McHale, Jr., James M. Solution based synthesis of perovskite-type oxide films and powders. Office of Scientific and Technical Information (OSTI), 1995. http://dx.doi.org/10.2172/10114240.

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