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Journal articles on the topic 'Oxonium'

Author: Grafiati

Published: 4 June 2021

Last updated: 2 February 2022

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1

Jin, Shou-Wen, Bing-Xia Chen, Yu-Shuang Ge, Hua-Bing Yin, and Yu-Ping Fang. "Oxonium picrate." Acta Crystallographica Section E Structure Reports Online 67, no. 7 (2011): o1694. http://dx.doi.org/10.1107/s1600536811022574.

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2

Liu, Zhenfeng, and Jianyong Liu. "DFT investigation on mechanism of dirhodium tetracarboxylate-catalyzed O-H insertion of diazo compounds with H2O." Open Chemistry 8, no. 1 (2010): 223–28. http://dx.doi.org/10.2478/s11532-009-0118-8.

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AbstractThe mechanism of the dirhodium tetracarboxylate-catalyzed O-H insertion reaction of diazomethane and methyl diazoacetate with H2O has been studied in detail using DFT calculations. The rhodium catalyst and a diazo compound couple to form a rhodiumcarbene complex. Of two reaction pathways of the Rh(II)-carbene complex with H2O, the stepwise pathway is more preferable than the concerted one. Formation of a Rh(II) complex-associated oxonium ylide is an exothermal process, and direct decomposition of the ylide gives a very high barrier. The high barriers for the 1,2-H shift of Rh(II) compl

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3

Stogniy, Marina Yu, Ekaterina N. Abramova, Irina A. Lobanova, et al. "Synthesis of Functional Derivatives of 7,8-Dicarba-nido-undecaborate Anion by Ring-Opening of Its Cyclic Oxonium Derivatives." Collection of Czechoslovak Chemical Communications 72, no. 12 (2007): 1676–88. http://dx.doi.org/10.1135/cccc20071676.

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A new approach to synthesis of functional derivatives of 7,8-dicarba-nido-undecaborate anion based on ring-opening of its cyclic oxonium derivatives [10-(CH2)4O-7,8-C2B9H11] and [10-O(CH2CH2)2O-7,8-C2B9H11] with various nucleophiles was developed. Both cyclic oxonium derivatives can be obtained as single isomers by reaction of the parent anion [7,8-C2B9H12]- with mercury(II) chloride in the corresponding solvents. Mechanism of formation of the cyclic oxonium derivatives of 7,8-dicarba-nido-undecaborate anion was proposed. A series of 7,8-dicarba-nido-undecaborate derivatives with terminal carb

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4

Davey, Stephen G. "Tricyclic oxonium tamed." Nature Reviews Chemistry 3, no. 12 (2019): 669. http://dx.doi.org/10.1038/s41570-019-0150-y.

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5

Rozenberg, Kseniya A., Ramiza K. Rastsvetaeva, and Alexander P. Khomyakov. "Decationized and hydrated eudialytes. Oxonium problem." European Journal of Mineralogy 17, no. 6 (2006): 875–82. http://dx.doi.org/10.1127/0935-1221/2005/0017-0875.

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6

PETKEWICH, RACHEL. "TAMING ALKYL OXONIUM IONS." Chemical & Engineering News 86, no. 39 (2008): 10. http://dx.doi.org/10.1021/cen-v086n039.p010.

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7

Ferguson, G., J. F. Gallagher, R. Fullwood, and D. Parker. "Oxonium (R)-O-acetylmandelate." Acta Crystallographica Section C Crystal Structure Communications 48, no. 10 (1992): 1909–11. http://dx.doi.org/10.1107/s0108270192008199.

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8

Tedder, John M., and G. Stewart Walker. "Investigations of oxonium ions." Journal of the Chemical Society, Perkin Transactions 2, no. 3 (1991): 317. http://dx.doi.org/10.1039/p29910000317.

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9

Murphy, Graham K., Fredrik P. Marmsäter, and F. G. West. "Polycyclic oxonium ylides — Use of cyclic acetals as convenient scaffolds in the construction of fused bicyclic compounds containing a medium ring." Canadian Journal of Chemistry 84, no. 10 (2006): 1470–86. http://dx.doi.org/10.1139/v06-111.

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Cyclic mixed acetals with pendant diazoketone side chains undergo efficient rearrangement to ether-bridged cyclooctanoid and cycloheptanoid systems upon treatment with Cu(hfacac)2. Stevens [1,2]-shift of an oxonium ylide furnishes the major product, in some cases accompanied by minor amounts of a product resulting from [1,2]-shift of a sulfonium ylide. These results demonstrate that hetero-substituted carbons are suitable migrating groups for the Stevens [1,2]-shift of oxonium ylides. In cases employing a mixed thioacetal, the resulting sulfide served as a trigger for cleavage of the bridging

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10

Chênevert, Robert, Daniel Chamberland, Michel Simard, and François Brisse. "Complexes of 18-crown-6 with oxonium ions derived from transition metal chlorides and hydrochloric acid: 18-crown-6.H3O+. FeCl4−, 18-crown-6.H3O+.InCl4−, (18-crown-6.H3O+)2.Pd2Cl62−." Canadian Journal of Chemistry 67, no. 1 (1989): 32–36. http://dx.doi.org/10.1139/v89-006.

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The macrocyclic polyether 18-crown-6 forms complexes with hydrates of strong acids derived from transition metal chlorides and hydrochloric acid. The following charged-component complexes have been isolated and characterized: 18-crown-6.H3O+.FeCl4−, 18-crown-6.H3O+.InCl4−, and (18-crown-6.H3O+)2.Pd2Cl62−. X-ray diffraction study of the palladium complex is reported. The oxonium ion is located at the center of the macrocyclic ether cavity and the symmetry of the ring is close to D3d. Keywords: 18-crown-6 complexes, oxonium ions, X-ray diffraction, crystal structure

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11

Larson, E. M., K. D. Abney, A. C. Larson, and P. G. Eller. "Structure of oxonium hexafluoroantimonate(V)." Acta Crystallographica Section B Structural Science 47, no. 2 (1991): 206–9. http://dx.doi.org/10.1107/s0108768190011806.

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12

Du, Qinghua, Dawei Song, Wansheng You, Yi Zhao, Tingting Gan, and Limei Dai. "Synthesis, Crystal Structure and Electrochemical Properties of a New Adduct of Benzo-15-crown-5 and H3PMo12O40." Zeitschrift für Naturforschung B 64, no. 3 (2009): 274–80. http://dx.doi.org/10.1515/znb-2009-0304.

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A new crown ether-POM (POM = polyoxometalate) adduct with the molecular formula [(C14- H20O5)4(H3O)3]PMo12O40 ・ 0.5CH3CN (1) was isolated from the mixed solvent of acetonitrile and methanol. The adduct is constructed from Keggin [PMo12O40]3− anions and [(C14H20O5)- (H3O+)] and [(C14H20O5)2(H3O+)] cations via electrostatic and hydrogen bonding interactions. The supramolecular interactions combine the crown ether with oxonium ions. In the [(C14H20O5)- (H3O+)] moieties, the oxonium ions reside out of the planes defined by the oxygen atoms of the crown ether. The [(C14H20O5)2(H3O+)] moieties exhib

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13

Fonari, M. S., N. G. Furmanova, Wen-Jwu Wang, et al. "Crystal structures of benzo-18-crown-6 complexes with oxonium hexafluorotantalate and oxonium hexafluoroniobate." Crystallography Reports 51, no. 5 (2006): 804–10. http://dx.doi.org/10.1134/s1063774506050099.

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14

Parmar, Swati, Shiv Pal, Abhijit Biswas, et al. "Designing a new family of oxonium-cation based structurally diverse organic–inorganic hybrid iodoantimonate crystals." Chemical Communications 55, no. 52 (2019): 7562–65. http://dx.doi.org/10.1039/c9cc03485d.

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15

Lobanova, Irina, Irina Kosenko, Julia Laskova, et al. "Synthesis and the structure of 8-tetrahydrofuronium and 8-tetrahydropyronium derivatives of iron bis(dicarbollide)(-I) and their cleavage reactions." Dalton Transactions 44, no. 4 (2015): 1571–84. http://dx.doi.org/10.1039/c4dt03015j.

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16

Shi, Taoda, Shenghan Teng, Alavala Gopi Krishna Reddy, et al. "Catalytic asymmetric synthesis of 2,5-dihydrofurans using synergistic bifunctional Ag catalysis." Organic & Biomolecular Chemistry 17, no. 38 (2019): 8737–44. http://dx.doi.org/10.1039/c9ob01903k.

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17

Oliver, Katherine W., Steven J. Rettig, Robert C. Thompson, James Trotter, and Shihua Xia. "Synthesis of perfluorodiphenylphosphinic acid and its potassium and oxonium salts; crystal structure of oxonium perfluorodiphenylphosphinate." Journal of Fluorine Chemistry 83, no. 1 (1997): 47–50. http://dx.doi.org/10.1016/s0022-1139(96)03562-2.

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18

Hosseini, Seyedeh Nargess, Jeffrey R. Johnston, and F. G. West. "Evidence for heterolytic cleavage of a cyclic oxonium ylide: implications for the mechanism of the Stevens [1,2]-shift." Chemical Communications 53, no. 94 (2017): 12654–56. http://dx.doi.org/10.1039/c7cc07716e.

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19

Rajasekhar, Tota, Jack Emert, and Rudolf Faust. "Synthesis of highly reactive polyisobutylene by catalytic chain transfer in hexanes at elevated temperatures; determination of the kinetic parameters." Polymer Chemistry 8, no. 18 (2017): 2852–59. http://dx.doi.org/10.1039/c7py00415j.

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20

Cheng, Hin-Soon, and Teck-Peng Loh. "General and practical approach to the syntheses of linear homoallylic alcohols." Pure and Applied Chemistry 77, no. 7 (2005): 1199–206. http://dx.doi.org/10.1351/pac200577071199.

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We have demonstrated that metal-mediated allylation of aldehydes can afford γ-homoallylic alcohols or α-linear homoallylic alcohols by judicious choice of the solvents. A new mechanism has been proposed to account for this new α-selective metal-mediated allylation reaction. On the other hand, the metal-mediated prenylation under the same conditions to obtain α-prenyl alcohols was unsuccessful. Detailed mechanistic studies have resulted in the discovery of a new method to obtain compounds with diverse structures via an oxonium-ene cyclization. Suppressing the oxonium-ene reaction during the rea

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21

Bowen, Richard D., William HC Martin, Charles E. Hudson та David J. McAdoo. "Experimental and computational evidence for C=O π-bonding in [CH2OH]+ and related oxonium ions". European Journal of Mass Spectrometry 26, № 3 (2020): 187–94. http://dx.doi.org/10.1177/1469066719894969.

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The question of whether [CH2OH]+ should be described as the hydroxymethyl cation, +CH2OH, or protonated formaldehyde, CH2=OH+, is reconsidered in the light of experimental information and new computational evidence. Previous arguments that the charge distribution in [CH2OH]+ may be probed by considering the incremental stabilisation of [CH2OH]+ induced by homologation on carbon (to give [CH3CHOH]+) or oxygen (to produce [CH2OCH3]+) are critically examined. Cation stabilisation energies are shown to be better indicators of the nature of these oxonium ions. Further insight into the structure of

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22

Lielpetere, Anna, and Aigars Jirgensons. "Carbenium ion formation by fragmentation of electrochemically generated oxonium ions." Organic & Biomolecular Chemistry 16, no. 28 (2018): 5094–96. http://dx.doi.org/10.1039/c8ob01339j.

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23

Roskamp, Eric J., and Carl R. Johnson. "Generation and rearrangements of oxonium ylides." Journal of the American Chemical Society 108, no. 19 (1986): 6062–63. http://dx.doi.org/10.1021/ja00279a077.

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24

Bon, V. V., A. V. Dudko, A. N. Kozachkova, and V. I. Pekhnyo. "Oxonium ammonio(cyclopropyl)methylenebis(hydrogenphosphonate) monohydrate." Acta Crystallographica Section E Structure Reports Online 64, no. 12 (2008): o2344. http://dx.doi.org/10.1107/s1600536808037094.

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25

Haley, Michael M. "Taming the Highly Reactive Oxonium Ion." Angewandte Chemie International Edition 48, no. 9 (2009): 1544–45. http://dx.doi.org/10.1002/anie.200805417.

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26

TEDDER, J. M., and G. S. WALKER. "ChemInform Abstract: Investigations of Oxonium Ions." ChemInform 22, no. 23 (2010): no. http://dx.doi.org/10.1002/chin.199123088.

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27

Mascal, Mark, Nema Hafezi, Nabin K. Meher, and James C. Fettinger. "Oxatriquinane and Oxatriquinacene: Extraordinary Oxonium Ions." Journal of the American Chemical Society 130, no. 41 (2008): 13532–33. http://dx.doi.org/10.1021/ja805686u.

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28

Mazumder, G., M. De, S. K. Mazumder, and A. Mukhopadhyay. "Oxonium 5-aminouracil-6-sulfonate hydrate." Acta Crystallographica Section C Crystal Structure Communications 57, no. 5 (2001): 562–63. http://dx.doi.org/10.1107/s010827010001742x.

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29

Marsh, R. E. "Structure of oxonium pentafluorozirconate dihydrate. Corrigendum." Acta Crystallographica Section C Crystal Structure Communications 45, no. 6 (1989): 980. http://dx.doi.org/10.1107/s0108270188014672.

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30

Vícha, Robert, Marek Nečas, Zuzana Kozubková, and Milan Potáček. "[1-(1-Adamantylamino)ethylidene]oxonium methanesulfonate." Acta Crystallographica Section E Structure Reports Online 65, no. 6 (2009): o1307. http://dx.doi.org/10.1107/s1600536809017632.

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In the title salt, C12H20NO+·CH3SO3−, the [1-(1-adamantylamino)ethylidene]oxonium cations and methanesulfonate anions are linked into chains along theaaxisviaO—H...O and N—H...O hydrogen bonds. All non-H atoms of the acetamido group are essentially planar, with a maximum deviation of 0.0085 (12) Å. In comparison with related structures, the carbonyl C=O bond is slightly elongated [1.249 (2) Å], whereas the amide C—N bond is shortened [1.292 (2) Å].

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31

Krebs, Bernt, Illenora Beckmann, Stefan Bonmann, Sven Hasche, and Oliver Reich. "New Oxonium Halochalcogenates(IV) and -(II)." Phosphorus, Sulfur, and Silicon and the Related Elements 136, no. 1 (1998): 513–16. http://dx.doi.org/10.1080/10426509808545985.

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32

Marouani, Houda, Mohamed Rzaigui, and Salem S. Al-Deyab. "Bis(oxonium) tetrakis(o-toluidinium) cyclohexaphosphate." Acta Crystallographica Section E Structure Reports Online 66, no. 3 (2010): o702. http://dx.doi.org/10.1107/s1600536810006537.

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33

Vandavasi, Jaya Kishore, Wan-Ping Hu, Siva Senthil Kumar Boominathan, Bing-Chun Guo, Cheng-Tien Hsiao, and Jeh-Jeng Wang. "Au(i)-catalyzed synthesis of 8-oxabicyclo[3.2.1]oct-2-enes and 9-oxabicyclo[3.3.1]nona-2,6-dienes from enynol via oxonium/Prins-type cyclization." Chemical Communications 51, no. 62 (2015): 12435–38. http://dx.doi.org/10.1039/c5cc02847g.

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34

Yang, Long, Jinliang Yang, Jun Nie, and Xiaoqun Zhu. "Temperature controlled cationic photo-curing of a thick, dark composite." RSC Advances 7, no. 7 (2017): 4046–53. http://dx.doi.org/10.1039/c6ra25346f.

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In this research, temperature controlled cationic mechanism resolved the issues of light penetration in colored thick composites due to the sustained stability of the secondary oxonium ions species at low temperature.

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35

Pirro, Martina, Yassene Mohammed, Arnoud H. de Ru, et al. "Oxonium Ion Guided Analysis of Quantitative Proteomics Data Reveals Site-Specific O-Glycosylation of Anterior Gradient Protein 2 (AGR2)." International Journal of Molecular Sciences 22, no. 10 (2021): 5369. http://dx.doi.org/10.3390/ijms22105369.

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Developments in mass spectrometry (MS)-based analyses of glycoproteins have been important to study changes in glycosylation related to disease. Recently, the characteristic pattern of oxonium ions in glycopeptide fragmentation spectra had been used to assign different sets of glycopeptides. In particular, this was helpful to discriminate between O-GalNAc and O-GlcNAc. Here, we thought to investigate how such information can be used to examine quantitative proteomics data. For this purpose, we used tandem mass tag (TMT)-labeled samples from total cell lysates and secreted proteins from three d

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36

Zhang, Han-Yue, Si-Qi Lu, Xin Chen, Ren-Gen Xiong, and Yuan-Yuan Tang. "The first high-temperature multiaxial ferroelectric host–guest inclusion compound." Chemical Communications 55, no. 77 (2019): 11571–74. http://dx.doi.org/10.1039/c9cc05900h.

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A host–guest inclusion compound, 18-crown-6 oxonium tetrachloride-gallium(iii), was shown to undergo a 4/mmmFmm2-type ferroelectric phase transition with four crystallographically equivalent polarization directions at 337 K.

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37

Tanaka, Rikako, and Nobuyuki Matsushita. "Crystal structure of bis(1-ethylpyridinium) dioxonium hexacyanidoferrate(II)." Acta Crystallographica Section E Crystallographic Communications 73, no. 2 (2017): 219–22. http://dx.doi.org/10.1107/s2056989017000810.

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The title compound, (C7H10N)2(H3O)2[Fe(CN)6] or (Etpy)2(H3O)2[Fe(CN)6] (Etpy+is 1-ethylpyridinium), crystallizes in the space groupPnnm. The FeIIatom of the [Fe(CN)6]4−anion lies on a site with site symmetry ..2/m, and has an octahedral coordination sphere defined by six cyanido ligands. Both the Etpy+and the oxonium cations are located on a mirror plane. In the crystal, electron-donor anions of [Fe(CN)6]4−and electron-acceptor cations of Etpy+are each stacked parallel to thebaxis, resulting in a columnar structure with segregated moieties. The crystal packing is stabilized by a three-dimensio

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38

Yin, Xinru, Aimin Xu, Jidi Hu, Ming Bao, Wenhao Hu, and Yu Qian. "A Rh(ii)/phosphoric acid co-catalyzed three-component reaction of diazo-ketones with alcohols and azonaphthalenes: access to indole derivatives via a formal [3 + 2]-cycloaddition." Organic & Biomolecular Chemistry 18, no. 48 (2020): 9805–9. http://dx.doi.org/10.1039/d0ob02189j.

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Rh(ii)/Phosphoric Acid co-catalyzed muti-component annulation was well established as a new efficient route to construct 1-amino-indole derivatives via dearomatization/rearomatization/cyclization process with in situ formed oxonium ylide.

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39

Bennett, Trystan, Alexander J. Falcinella, Reuben J. White, et al. "The effect of counter ions on the far-infrared spectra of tris(triphenylphosphinegold)oxonium dimer salts." RSC Advances 5, no. 91 (2015): 74499–505. http://dx.doi.org/10.1039/c5ra11599j.

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The far-infrared spectra of two tris(triphenylphosphinegold)oxonium dimer salts in the 50–800 cm<sup>−1</sup> region were recorded using synchrotron-based IR radiation, and comprehensively assigned utilising density functional theory calculations.

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40

Parker, Stewart F., and Shrey Shah. "Characterisation of hydration water in Nafion membrane." RSC Advances 11, no. 16 (2021): 9381–85. http://dx.doi.org/10.1039/d1ra00791b.

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Hydration of fully dried Nafion membrane results in the formation of oxonium ions of increasing complexity, up to H<sub>9</sub>O<sub>4</sub><sup>+</sup>. Beyond this, water behaves as the bulk liquid.

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41

Hilmey, David G., Peter R. Selvaraj та Leo A. Paquette. "Synthesis and Lewis acid induced isomerization of mono-, di-, and tri-spiro α-keto tetrahydro-furans and -pyrans". Canadian Journal of Chemistry 84, № 10 (2006): 1388–96. http://dx.doi.org/10.1139/v06-103.

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The stereoselectivity of the acid-catalyzed ring expansion of dihydrofuranyl and dihydropyranyl 1,2-adducts to spirocyclic ketones 8 and 9 has been examined. These substrates have become readily available by the utilization of 1,3-dichloroacetone as a synthetic equivalent of cyclopropanone. The kinetically controlled isomerizations result in ring expansion to dispirocyclopentanones. Third-stage conversion to trispirocyclohexanones was shown to be possible in select examples. On a different front, the syn and anti pairs proved capable of interconversion by heating in the presence of boron trifl

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42

Vandavasi, Jaya Kishore, Wan-Ping Hu, Siva Senthil Kumar Boominathan, Bing-Chun Guo, Cheng-Tien Hsiao, and Jeh-Jeng Wang. "Correction: Au(i)-catalyzed synthesis of 8-oxabicyclo[3.2.1]oct-2-enes and 9-oxabicyclo[3.3.1]nona-2,6-dienes from enynol via oxonium/Prins-type cyclization." Chemical Communications 51, no. 64 (2015): 12872. http://dx.doi.org/10.1039/c5cc90329g.

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Correction for ‘Au(i)-catalyzed synthesis of 8-oxabicyclo[3.2.1]oct-2-enes and 9-oxabicyclo[3.3.1]nona-2,6-dienes from enynol via oxonium/Prins-type cyclization’ by Jaya Kishore Vandavasi et al., Chem. Commun., 2015, DOI: 10.1039/c5cc02847g.

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43

Oku, Akira, Takashi Mori, and Yuichi Sawada. "Design of Ethereal Oxonium Ylides for Synthesis." Journal of Synthetic Organic Chemistry, Japan 58, no. 10 (2000): 934–44. http://dx.doi.org/10.5059/yukigoseikyokaishi.58.934.

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44

Brogan, John B., Cary B. Bauer, Robin D. Rogers, and Charles K. Zercher. "Selectivity in the rearrangements of oxonium ylides." Tetrahedron Letters 37, no. 29 (1996): 5053–56. http://dx.doi.org/10.1016/0040-4039(96)01015-5.

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45

Heshmat, Mojgan, and Timofei Privalov. "Surprisingly Flexible Oxonium/Borohydride Ion Pair Configurations." Journal of Physical Chemistry A 122, no. 15 (2018): 3713–27. http://dx.doi.org/10.1021/acs.jpca.7b11851.

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46

Burcat, Alexander, and Elke Goos. "The Ideal Gas Thermochemistry of Oxonium Cations." Journal of Chemical & Engineering Data 61, no. 4 (2016): 1361–67. http://dx.doi.org/10.1021/acs.jced.5b00061.

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47

Charpin, P., M. Lance, M. Nierlich, J. Vigner, and J. Lambard. "Structures of oxonium pentafluorozirconate mono- and dihydrates." Acta Crystallographica Section C Crystal Structure Communications 44, no. 10 (1988): 1698–701. http://dx.doi.org/10.1107/s0108270188005797.

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48

Simonsen, O. "Structure of an oxonium salt crystal complex." Acta Crystallographica Section C Crystal Structure Communications 48, no. 10 (1992): 1900–1902. http://dx.doi.org/10.1107/s0108270192006449.

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49

Leduc, M., and A. L. Beauchamp. "Bis(9-methylhypoxanthinium) oxonium hexachlororuthenate(III) trihydrate." Acta Crystallographica Section C Crystal Structure Communications 50, no. 11 (1994): 1683–86. http://dx.doi.org/10.1107/s0108270194004130.

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50

Liang, Wen-Xian, Gang Wang, and Zhi-Rong Qu. "Oxonium 2-carboxy-3-(2-furyl)acrylate." Acta Crystallographica Section E Structure Reports Online 65, no. 6 (2009): o1310. http://dx.doi.org/10.1107/s1600536809017760.

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In the title compound, H3O+·C8H5O5−, neighbouring cations and anions are linked by O—H...O hydrogen bonds, forming a one-dimensional chain framework along [001]. The crystal structure is further stabilized by π–π interactions, with centroid–centroid distances of 3.734 (3) Å.

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