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Dissertations / Theses on the topic 'Paladium and Copper Complexes'

Author: Grafiati

Published: 6 September 2023

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1

Broch, Fernanda. "Síntese, cristalografia e propriedades de ligantes triazenos mono e biscatenados e derivados complexos de Cu(II), Ni(II) e Pd(II)." Universidade Federal de Santa Maria, 2013. http://repositorio.ufsm.br/handle/1/4248.

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior<br>Triazenes are a class of compounds characterized by the presence of a diazoamino functional group (N=N N) showing remarkable ability to support the stereochemical requisites of a wide variety of metal transition complexes. They act as versatile ligands in coordination chemistry when deprotonated and have relevant biological and synthetic porperties. This work presents the synthesis and investigation of molecular and crystal structure of a new series of monotriazenes [3-(4-phenyldiazenyl)-1-(2-fluorophenyl)triazene (2b); 1-(2-chloro

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2

Dearling, Jason L. J. "Hypoxia targeting copper complexes." Thesis, University of Kent, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297352.

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3

Lu, Qin. "Copper complexes of polyazacryptands." Thesis, Open University, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.298997.

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4

Salaudeen, Abibat Abisola. "Switchable iron and copper complexes." Thesis, University of Leeds, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.522980.

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5

Heslop, Julia M. "Copper complexes with potential radiopharmaceutical applications." Thesis, University of Oxford, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.418800.

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6

Ashfield, Laura. "Copper complexes with potential biomedical applications." Thesis, University of Oxford, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.426384.

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7

Trotter, Katherine D. "Copper complexes as putative contrast agents." Thesis, University of Strathclyde, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.538815.

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8

Taylor, Michelle K. "Copper complexes as putative imaging agents." Thesis, University of Strathclyde, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.424316.

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9

Hueting, Rebekka. "Radiolabelled copper complexes for cancer imaging." Thesis, University of Oxford, 2011. http://ora.ox.ac.uk/objects/uuid:47438968-6aa3-41f5-82b4-9121dc327b53.

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Chapter One introduces molecular irnaging and the modalities available for oncological irnaging. The radioisotopes and imaging agents for Positron Emission Tomography (PET) and Single Photon Emission Computed Tomography (SPECT) are discussed together with the bifunctional chelator approach for radio labelling of biomolecules. Finally, the chemistry and radioisotopes of copper are described, and copper bis(thiosemicarbazonato) complexes introduced in the context of PET irnaging. Chapter Two describes the synthesis and characterisation of novel carboxylate- and maleirnide- functionalised bis(thi

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10

Karabaeva, Kanykey E. "Photochemistry of dipyridyl-phenanthrenedioxin-copper complexes." Bowling Green State University / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1530026213399288.

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11

Pateman, Andrew Glen. "Copper catalysed aziridination reactions." Thesis, University College London (University of London), 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.314288.

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12

Dohanosova, Jana. "Réactions domino. Réactions de cyclisation-carbonylation asymétrique catalysées par complexes de paladium(II) dans la synthèse des produits naturels." Phd thesis, Université Paris Sud - Paris XI, 2012. http://tel.archives-ouvertes.fr/tel-00703209.

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La réaction de cyclisation de type Wacker, de composés polyols et aminopolyols insaturés constitue un outil puissant et efficace pour la synthèse d'hétérocycles oxygénés ou azotés.Dans ce travail de thèse, nous proposons l'étude d'une réaction catalysée par un complexe de palladium(II) de type domino-cyclisation, mettant en jeu une réaction de couplage. Cette séquence catalytique revient à une fonctionnalisation d'un hétérocycle par une chaîne latérale, tout en créant deux centres stéréogènes en une seule étape. L'influence de la nature des réactifs mis en jeu, ainsi que des conditions expérim

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13

Mao, Zhong. "Effects of copper-ligand and copper-copper interactions on excited state properties of luminescent copper (I) complexes : structural and photophysical studies /." View the Table of Contents & Abstract, 2003. http://sunzi.lib.hku.hk/hkuto/record/B26450859.

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14

Mao, Zhong, and 毛中. "Effects of copper-ligand and copper-copper interactions on excited state properties of luminescent copper (I) complexes: structural and photophysical studies." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2003. http://hub.hku.hk/bib/B45015582.

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15

Essex, Sarah Jane. "Spectral intensities in planar copper(II) complexes." Thesis, University of Cambridge, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239622.

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16

Theobald, Mark Brian Michael. "New copper-64 complexes for imaging hypoxia." Thesis, University of Oxford, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.555310.

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Chapter One gives an overview of medical imaging techniques, focusing on and comparing the nuclear imaging techniques of single photon emission computed tomography (SPECT) and positron emission tomography (PET). The applications of copper radioisotopes in nuclear medicine are presented, in particular the development of copper bis(thiosemicarbazonate) complexes for use as hypoxia imaging agents. Hypoxia and current strategies for its diagnosis are also discussed. Chapter Two describes the introduction of a new linker to bis(thiosemicarbazone) ligands along with the subsequent synthesis and char

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17

Milne, Paul Edward Young. "Polynuclear copper-lanthanoid complexes of pyridone ligands." Thesis, University of Edinburgh, 1993. http://hdl.handle.net/1842/15394.

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The crystal structures of several copper and mixed copper-lanthanoid complexes are reported, using the 6-chloro and 6-methyl derivatives of 2-pyridone as a ligand. With 6-chloro-2-pyridone, a novel dimeric copper complex results, which has been structually and physically studied. This species, under certain conditions, exhibits a dissociation reaction which has been examined using U.V.-vis. and E.P.R. spectroscopy and by cyclic voltammetry. Reaction of this dimeric copper compound with methanol and ethylene glycol results in the formation of tetranuclear and polymeric copper complexes respecti

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18

Coombs, Timothy David. "Copper complexes of functionalised N-donor ligands." Thesis, University of Bath, 2002. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.394172.

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19

LO, PRESTI ELIANA. "CHIRAL COPPER COMPLEXES AS TYROSINASE BIOMIMETIC SYSTEMS." Doctoral thesis, Università degli studi di Pavia, 2017. http://hdl.handle.net/11571/1203322.

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20

Woollard-Shore, John. "Towards functional models of copper metalloenzymes." Thesis, University of Essex, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.364506.

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21

Fotsing, Kamte Marcellin M. "Electrosynthesis and mechanism of copper(I) nitrile complexes." [S.l. : s.n.], 2004. http://deposit.ddb.de/cgi-bin/dokserv?idn=974106666.

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22

Claughton, Hannah J. "Towards radiopharmaceuticals based on copper bis(thiosemicarbazone) complexes." Thesis, University of Oxford, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.442381.

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23

Roach, Benjamin David. "Phenolic oxime copper complexes : a gas phase investigation." Thesis, University of Edinburgh, 2011. http://hdl.handle.net/1842/7582.

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This thesis explores the use of mass spectrometry to define the strengths, and understand solution phase speciation of phenolic oxime-based solvent extractants of the types used in the hydrometallurgical recovery of copper. Chapter 1 reviews briefly the current extraction technology for copper and focuses on hydrometallurgy and the use of phenolic oximes such as 5-nonylsalicylaldoxime. The modification of the latter to improve extraction efficiency is discussed, focussing on the introduction of X-substituents in the 3 position of the benzene ring. Modern mass spectrometry techniques are also d

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24

Strassl, Florian [Verfasser]. "Copper Dioxygen Complexes for Multiphase Flows / Florian Strassl." München : Verlag Dr. Hut, 2019. http://d-nb.info/1194289118/34.

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25

Quinlan, D. J. "Hydrogen bonding in N-ligated copper(II) complexes." Thesis, University of Nottingham, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.262983.

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26

Sylvestre, Isabelle. "Copper complexes of new biologically relevant phenol ligands." Thesis, University of Leeds, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.410895.

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27

Baxter, Christopher W. "Synthesis and structural studies of polynuclear copper complexes." Thesis, University of Edinburgh, 2004. http://hdl.handle.net/1842/14925.

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This thesis investigates the effect of varying the ligand component in a cluster forming reaction recently developed for the synthesis of molecules with general formula, [Cu<sub>x+y</sub>(C≡CR)<sub>x</sub>(hfac)<sub>y</sub>] where hfac is 1,1,1,5,5,5-hexafluoropentanedione and C≡CR is a straight chain terminal alkynyl ligand (R = -C<sub>3</sub>H<sub>7</sub>, -C<sub>4</sub>H<sub>9</sub>, -C<sub>5</sub>H<sub>11</sub>, - C<sub>6</sub>H<sub>13</sub>). Using the ‘bulky’ alkynyl ligands, 3,3-dimethyl-1-butyne (<sup>t</sup>BuC≡CH) and trimethylsilylacetylene (Me<sub>3</sub>SiC≡CH) has led to the suc

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28

Voyé, Alexander. "Diamino diamide copper complexes as anti-arthritic agents." Doctoral thesis, University of Cape Town, 1993. http://hdl.handle.net/11427/17515.

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Includes bibliographical references.<br>This thesis describes the investigation of a series of diamino diamide copper(II) complexes with respect to their potential as anti-inflammatory agents in the treatment of rheumatoid arthritis. Several physico-chemical techniques were employed in the investigation including glass electrode potentiometry, UV/VIS spectroscopy, molecular mechanics calculations, speciation modelling as well as X-ray crystallography. Animal experiments were also carried out.

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29

Wang, Jun. "Silica Supported Copper Complexes and their Biomimetic Activities." W&M ScholarWorks, 2003. https://scholarworks.wm.edu/etd/1539626826.

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30

Bahgat, Sofi-Rosamelia. "Beta-diketiminato copper complexes in C-H bond amination." Connect to Electronic Thesis (CONTENTdm), 2010. http://worldcat.org/oclc/646165084/viewonline.

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31

Bell, Zoe Rachel. "Lanthanide and copper complexes of new multidentate encapsulating ligands." Thesis, University of Bristol, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.324327.

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32

Mickenberg, Seth F. (Seth Fox). "Tuning the photophysical properties of amidophosphine complexes of copper." Thesis, Massachusetts Institute of Technology, 2009. http://hdl.handle.net/1721.1/49753.

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Thesis (S.M.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2009.<br>Vita.<br>Includes bibliographical references (leaves 23-24).<br>A series of monomeric copper complexes that allow for the tuning of the emission properties is reported. Luminescence lifetimes up to 150 [mu]s are observed in benzene solution at ambient temperature, which are comparable to the lifetimes of the longest-lived previously reported copper luminophores. These complexes also exhibit quantum yields up to 0 = 0.70 at 298 K. The results of time-dependent density functional theory (TDDFT) calculations indica

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33

Dunbar, Lynsey. "The development of copper complexes as medical imaging agents." Thesis, University of Strathclyde, 2015. http://oleg.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=24947.

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Studies building on existing research into the development of in vivo oxidant sensors which could be used as magnetic resonance (MR) imaging agents for the early detection of oxidative stress have been carried out. A series of N₂S₂ copper macrocyclic systems have been synthesised building on previous studies. The compounds have been modified at various positions to further enhance the suitability of these species as magnetic resonance imaging agents. The modifications include the introduction of oxo and sulfur based pendant arms at the nitrogen donor atoms, the introduction electron withdrawin

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34

Hammouda, Ahmed N. H. "Development of copper peptide complexes as anti-Inflammatory drugs." Doctoral thesis, University of Cape Town, 2015. http://hdl.handle.net/11427/15744.

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Copper complexes have been reported to have anti-inflammatory activities for the alleviation of inflammation associated with rheumatoid arthritis (RA). The present study focuses on the design of new drugs that could be used to change the bioavailability of copper and hence alleviate inflammation. The ligands chosen were sarcosyl-L-histidyl-L-lysine, sarcosyl-Llysyl- L-histidine, sarcosyl-L-histidyl-L-histidine, sarcosyl-L-lysyl-L-lysine and sarcosyl-Lglycyl- L-histidine. Equilibrium constants of H+, Cu(II), Ni(II) and Zn(II) with the peptides were measured in aqueous solution at 25±0.01oC and

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35

Ireland, David Rey. "Copper(II) and Ruthenium(II) Complexes from Polydentate Ligands." University of Dayton / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1523008522727672.

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36

Vance, Michael Alan. "Spectroscopic studies of structural and functional binuclear copper model complexes of coupled binuclear copper proteins /." May be available electronically:, 2007. http://proquest.umi.com/login?COPT=REJTPTU1MTUmSU5UPTAmVkVSPTI=&clientId=12498.

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37

Ellul, Charles. "Trimetallic N-heterocyclic carbene complexes." Thesis, University of Bath, 2011. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.538279.

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38

Garrido, Barros Pablo. "Molecular Water Oxidation Catalysts Based on Copper and Nickel Complexes." Doctoral thesis, Universitat Rovira i Virgili, 2018. http://hdl.handle.net/10803/665124.

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Aquesta Tesi Doctoral es centra en l’estudi de catalitzadors moleculars per a l’oxidació d’aigua basats en coure i níquel, ja que la seva gran abundància i baix cost els fa potencials candidats pel seu ús en sistemes catalítics. Tot i així, avui en dia hi ha una important mancança d’informació respecte als seus mecanismes de reacció i els factors que influeixen la seva activitat. Per això, en primer lloc, es desenvolupen nous catalitzadors moleculars basats en el coure com a centre metàl·lic. L’estudi mecanístic d’aquests catalitzadors revela l’important rol que té l’oxidació del lligand

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39

Fung, Chi-ming Kelvin. "Synthesis and applications of copper hydride complexes in reductive reactions." Click to view the E-thesis via HKUTO, 2005. http://sunzi.lib.hku.hk/hkuto/record/B36388208.

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40

Löw, Sabine [Verfasser]. "Synthesis, characterization and reactivity of Copper Cluster Complexes / Sabine Löw." Gießen : Universitätsbibliothek, 2014. http://d-nb.info/1068590750/34.

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41

Lankes, Christian [Verfasser], and Oliver [Akademischer Betreuer] Reiser. "Photoredox Catalysis Using Copper Complexes / Christian Lankes ; Betreuer: Oliver Reiser." Regensburg : Universitätsbibliothek Regensburg, 2018. http://d-nb.info/1178115178/34.

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42

Bonnitcha, Paul D. "Synthesis and evaluation of novel copper complexes to target hypoxia." Thesis, University of Oxford, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.509896.

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43

Fung, Chi-ming Kelvin, and 馮志明. "Synthesis and applications of copper hydride complexes in reductive reactions." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2005. http://hub.hku.hk/bib/B36388208.

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44

Stroud, Joanne. "Dinuclear copper complexes with planar, neutral, N-donor, bridging ligands." Thesis, University of Nottingham, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.282624.

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45

Madzivire, Cecilia Rutendo. "Ruthenium and copper complexes for anti-cancer and catalytic applications." Thesis, University of Leeds, 2018. http://etheses.whiterose.ac.uk/21035/.

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This thesis details the synthesis, characterisation and evaluation of novel β-bis-ketoiminate ruthenium(II) and β-bis-ketoiminate copper(II) complexes for their biological and chemical applications. The anti-cancer, anti-bacterial and anti-fungal and catalytic activity of these complexes was investigated, with lead complexes undergoing further mechanistic investigations. Chapter 1 contains the background introduction to the project, through literature research of similar work as well as the aims of this project. Chapter 2 presents the synthesis and characterisation of novel β-bis-ketoiminate r

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46

Betts, Helen May. "Novel copper-64 complexes for applications in positron emission tomography." Thesis, University of Oxford, 2009. http://ora.ox.ac.uk/objects/uuid:8e10fd02-8f20-43d6-8b32-d99e897257cc.

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47

Dalle, Kristian Erwin. "Bioinspired Activation of Oxygen with Pyrazole-Supported Dinuclear Copper Complexes." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2014. http://hdl.handle.net/11858/00-1735-0000-002B-7C1A-B.

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48

Betancourt, Daniel. "Copper bis(phenanthroline) complexes as simple models for molecular transducers." Tallahassee, Fla. : Florida State University, 2008. http://purl.fcla.edu/fsu/lib/digcoll/undergraduate/honors-theses/368250.

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Thesis (Honors paper)--Florida State University, 2008.<br>Advisor: Dr. Kenneth Goldsby, Florida State University, College of Arts and Sciences, Dept. of Chemistry and Biochemistry. Includes bibliographical references.

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49

Seeba, Marten. "Bioinspired dinuclear copper complexes for catalytic oxidation of phenolic substrates." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2017. http://hdl.handle.net/11858/00-1735-0000-002E-E4DC-8.

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50

Magni, M. "COPPER AND RUTHENIUM COMPLEXES IN SENSITIZED SOLAR CELLS AND OPTOELECTRONICS." Doctoral thesis, Università degli Studi di Milano, 2015. http://hdl.handle.net/2434/333099.

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In perfect harmony with the "Year of Light (IYL 2015)", the thesis has been entirely centered on the concept of Light involving the development of transition metal complexes for both the conversion of light into electric energy through dye-sensitized solar cells and, conversely, the production of light starting from electricity by fabrication of electroluminescent devices. The main part of the thesis has been devoted to the sunlight-to-electricity conversion, a target that is well contextualized within the global commitment for the progressive increase of the percentage of electric energy prod

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