Academic literature on the topic 'Palladium-catalyzed arylation'

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Journal articles on the topic "Palladium-catalyzed arylation"

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Dodonova, Jelena, and Sigitas Tumkevicius. "Fused Pyrrolo[2,3-d]pyrimidines (7-Deazapurines) by Palladium-Catalyzed Direct N–H and C–H Arylation Reactions." Synthesis 49, no. 11 (2017): 2523–34. http://dx.doi.org/10.1055/s-0036-1588734.

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Palladium-catalyzed intramolecular direct C–H arylations for the synthesis of hitherto unknown fused hetero systems containing an incorporated pyrrolo[2,3-d]pyrimidine scaffold are described. Pyrimido[5′,4′:4,5]pyrrolo[2,1-a]isoindoles were synthesized from 2,4-di­arylpyrrolo[2,3-d]pyrimidines and o-bromobenzyl bromides by using a cascade N-benzylation/C–H arylation reaction sequence. A series of pyrimido[5′,4′:4,5]pyrrolo[1,2-f]phenanthridines were successfully assembled via a domino process involving the palladium-catalyzed direct double C–H arylation reactions of 2,4,7-triarylpyrrolo[2,3-d]
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Abdelmalek, Fatiha, Fazia Derridj, Safia Djebbar, Jean-François Soulé та Henri Doucet. "Efficient synthesis of π-conjugated molecules incorporating fluorinated phenylene units through palladium-catalyzed iterative C(sp2)–H bond arylations". Beilstein Journal of Organic Chemistry 11 (28 жовтня 2015): 2012–20. http://dx.doi.org/10.3762/bjoc.11.218.

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We report herein a two or three step synthesis of fluorinated π-conjugated oligomers through iterative C–H bond arylations. Palladium-catalyzed desulfitative arylation of heteroarenes allowed in a first step the synthesis of fluoroaryl-heteroarene units in high yields. Then, the next steps involve direct arylation with aryl bromides catalyzed by PdCl(C3H5)(dppb) to afford triad or tetrad heteroaromatic compounds via regioselective activation of C(sp2)–H bonds.
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Maiti, Debabrata, Sumon Basak, and Jyoti Prasad Biswas. "Transition-Metal-Catalyzed C–H Arylation Using Organoboron Reagents." Synthesis 53, no. 18 (2021): 3151–79. http://dx.doi.org/10.1055/a-1485-4666.

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AbstractAryl rings are ubiquitous in the core of numerous natural product and industrially important molecules and thus their facile synthesis is of major interest in the scientific community and industry. Although multiple strategies enable access to these skeletons, metal-catalyzed C–H activation is promising due to its remarkable efficiency. Commercially available organoboron reagents, a prominent arylating partner in the cross-coupling domain, have also been utilized for direct arylation. Organoborons are bench-stable, inexpensive, and readily available coupling partners that promise regio
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Huang, Qing, Liangxian Liu, Jiayi Zhu, Yu Chen, Feng Lin, and Baoshuang Wang. "Highly Regioselective Arylation of 1,2,3-Triazole N-Oxides with Sodium Arenesulfinates via Palladium-Catalyzed Desulfitative Cross-Coupling Reaction." Synlett 26, no. 08 (2015): 1124–30. http://dx.doi.org/10.1055/s-0034-1380186.

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A convenient and highly regioselective palladium-catalyzed direct C5-arylation of 1,2,3-triazole N-oxides was developed in the presence of silver carbonate and tripotassium phosphate. This protocol allowed use of sodium arylsulfinates, diphenylphosphine oxide, and triphenylphosphine as arylating reagents to produce 2-aryl-5-aryl-1,2,3-triazole N-oxides in good to excellent yields, providing a complement to the existing methods for the direct arylation of 1,2,3-triazole N-oxides.
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Della Ca’, Nicola. "Palladium-Catalyzed Reactions." Catalysts 11, no. 5 (2021): 588. http://dx.doi.org/10.3390/catal11050588.

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Palladium is probably the most versatile and exploited transition metal in catalysis due to its capability to promote a myriad of organic transformations both at laboratory and industrial scales (alkylation, arylation, cyclization, hydrogenation, oxidation, isomerization, cross-coupling, cascade, radical reactions, etc [...]
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Peng, Jing, Chao Chen та Chanjuan Xi. "β-Arylation of oxime ethers using diaryliodonium salts through activation of inert C(sp)–H bonds using a palladium catalyst". Chem. Sci. 7, № 2 (2016): 1383–87. http://dx.doi.org/10.1039/c5sc03903g.

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Christodoulou, Michael S., Egle M. Beccalli, and Sabrina Giofrè. "Palladium-Catalyzed Benzodiazepines Synthesis." Catalysts 10, no. 6 (2020): 634. http://dx.doi.org/10.3390/catal10060634.

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This review is focused on palladium-catalyzed reactions as efficient strategies aimed at the synthesis of different classes of benzodiazepines. Several reaction typologies are reported including hydroamination, amination, C–H arylation, N-arylation, and the Buchwald–Hartwig reaction, depending on the different substrates identified as halogenated starting materials (activated substrates) or unactivated unsaturated systems, which then exploit Pd(0)- or Pd(II)-catalytic species. In particular, the use of the domino reactions, as intra- or intermolecular processes, are reported as an efficient an
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Du, Zhengyin, Hua Feng, Fangli Gang, Yang Che, and Ying Fu. "Palladium-Catalyzed Regioselective C-5 Arylation of 1,2,3-Triazoles with Diaryliodonium Salts." Synlett 28, no. 13 (2017): 1624–29. http://dx.doi.org/10.1055/s-0036-1588815.

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An effective method for C-5 arylation of 1,4-disubstituted 1,2,3-triazoles and C-5 regioselective arylation of 1-substituted 1,2,3-triazoles via sp2 C–H activation with palladium as a catalyst and diaryliodonium salts as arylating reagents is described. Various electron-rich and electron-deficient substituents attached to triazoles and diaryliodonium salts were tolerable to give the desired products with good isolated yields in 24 hours under air atmosphere.
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Liu, Ren-Rong, Teng-Fei Xu, Yong-Gang Wang, Bin Xiang, Jian-Rong Gao, and Yi-Xia Jia. "Palladium-catalyzed dearomative arylalkynylation of indoles." Chemical Communications 52, no. 94 (2016): 13664–67. http://dx.doi.org/10.1039/c6cc06262h.

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Dyker, Gerald, Stefan Borowski, Gerald Henkel, Andreas Kellner, Ina Dix, and Peter G. Jones. "Palladium-catalyzed arylation of butadiynes." Tetrahedron Letters 41, no. 43 (2000): 8259–62. http://dx.doi.org/10.1016/s0040-4039(00)01474-x.

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Dissertations / Theses on the topic "Palladium-catalyzed arylation"

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Sävmarker, Jonas. "Palladium-Catalyzed Carbonylation and Arylation Reactions." Doctoral thesis, Uppsala universitet, Avdelningen för organisk farmaceutisk kemi, 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-167720.

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Palladium-catalyzed reactions have found widespread use in contemporary organic chemistry due to their impressive range of functional group tolerance and high chemo- and regioselectivity. The pioneering contributions to the development of the Pd-catalyzed C-C bond forming cross-coupling reaction were rewarded with the Nobel Prize in Chemistry in 2010. Today, this is a rapidly growing field, and the development of novel methods, as well as the theoretical understanding of the various processes involved are of immense importance for continued progress in this field. The aim of the work presented
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Niwa, Takashi. "Studies on Palladium-Catalyzed Benzylic Arylation." 京都大学 (Kyoto University), 2009. http://hdl.handle.net/2433/77959.

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Kyoto University (京都大学)<br>0048<br>新制・課程博士<br>博士(工学)<br>甲第14583号<br>工博第3051号<br>新制||工||1454(附属図書館)<br>26935<br>UT51-2009-D295<br>京都大学大学院工学研究科材料化学専攻<br>(主査)教授 大嶌 幸一郎, 教授 檜山 爲次郎, 教授 松原 誠二郎<br>学位規則第4条第1項該当
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Lafrance, Marc. "Development of new palladium-catalyzed arylation reactions." E-theses uOttawa (Restricted to University of Ottawa), 2008. https://login.proxy.bib.uottawa.ca/login?url=http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:NR41635.

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Fujino, Daishi. "Studies on Palladium-Catalyzed Arylative Cyclization Reactions." 京都大学 (Kyoto University), 2014. http://hdl.handle.net/2433/188508.

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Duvall, Bridget Rebecca. "Efforts toward (+)-7-deoxypancratistatin featuring a palladium catalyzed allylic arylation." College Park, Md. : University of Maryland, 2005. http://hdl.handle.net/1903/2336.

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Thesis (M.S.)--University of Maryland, College Park, 2005.<br>Thesis research directed by: Dept. of Chemistry and Biochemistry. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.
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Mo, Jun. "Palladium catalyzed heck arylation of electron-rich olefins by aryl halides." Thesis, University of Liverpool, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.433729.

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Rousseaux, Sophie. "Palladium-Catalyzed C(sp2)-C(sp3) Bond Formation." Thèse, Université d'Ottawa / University of Ottawa, 2012. http://hdl.handle.net/10393/23058.

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Palladium-catalyzed reactions for carbon-carbon bond formation have had a significant impact on the field of organic chemistry in recent decades. Illustrative is the 2010 Nobel Prize, awarded for “palladium-catalyzed cross couplings in organic synthesis”, and the numerous applications of these transformations in industrial settings. This thesis describes recent developments in C(sp2)-C(sp3) bond formation, focusing on alkane arylation reactions and arylative dearomatization transformations. In the first part, our contributions to the development of intramolecular C(sp3)-H arylation reactions
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Beydoun, Kassem. "Palladium catalyzed direct arylation of heteroaromatics via C-H bond activation : a green access to fine chemicals and materials." Rennes 1, 2012. http://www.theses.fr/2012REN1S174.

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During this thesis, we were interested in the C-H bonds activation catalyzed by palladium catalysts such PdCl(C₃H₅)(dppb) and ligand-free or ligand associated Pd(OAc)₂ for the préparation of biaryls. This method is considered as cost effective and environmentally attractive compared to other types of couplings such as Suzuki, Stille, or Negishi. First we demonstrated that it is possible to apply C-H bond activation method for the direct arylation of formyl or acetyl halothiophene derivatives. The corresponding products could be further functionalized due to the presence of the halo and carbony
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Jiang, Tuo. "Palladium(II)-Catalyzed Oxidative Carbocyclization : Stereoselective Formation of C–C and C–B Bonds." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-108669.

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Transition metal catalysis has emerged as one of the most versatile methods for the selective formation of carbon–carbon and carbon–heteroatom bonds. In particular, oxidative carbon–carbon bond forming reactions have been widely studied due to their atom economic feature. This thesis has been focused on the development of new palladium(II)-catalyzed carbocyclization reactions under oxidative conditions. The first part of the thesis describes the palladium(II)-catalyzed oxidative carbocyclization-borylation and -arylation of enallenes. In these reactions, the (σ-alkyl)palladium(II) intermediate
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Persson, Andreas K. Å. "Palladium(II)-Catalyzed Oxidative Cyclization Strategies : Selective Formation of New C-C and C-N Bonds." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-75435.

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The main focus of this thesis has been directed towards preparation and oxidative carbocyclization of en-, dien- and aza-enallenes. In the first part of this thesis, a stereoselective oxidative carbocyclization of dienallenes was realized. By employing cheap and readily available palladium trifluoroacetate we were able to efficiently cyclize a variety of dienallenes into hydroxylated carbocycles in high yield and high selectivity. This oxidative process was compatible with two different reoxidation protocols: one relying on p-benzoquinone (BQ) as the oxidant and the other employing molecular o
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Book chapters on the topic "Palladium-catalyzed arylation"

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Fagnou, Keith. "Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation." In C-H Activation. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/128_2009_14.

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Busacca, Carl A., and Chris H. Senanayake. "Developing Palladium-Catalyzed Arylations of Carbonyl-Activated CH Bonds." In Transition Metal-Catalyzed Couplings in Process Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527658909.ch03.

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Camp, J. E. "Palladium-Catalyzed N-Arylation." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles. Georg Thieme Verlag KG, 2012. http://dx.doi.org/10.1055/sos-sd-117-00133.

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Stará, I. G., and I. Starý. "Intramolecular Palladium-Catalyzed Arylation." In Monocyclic Arenes, Quasiarenes, and Annulenes. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-045-01231.

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Schatz, J., and M. Seler. "Palladium-Catalyzed Direct Arylation." In Fully Unsaturated Small-Ring Heterocycles and Monocyclic Five-Membered Hetarenes with One Heteroatom. Georg Thieme Verlag KG, 2011. http://dx.doi.org/10.1055/sos-sd-109-00215.

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Malleron, J. L., J. C. Fiaud, and J. Y. Legros. "Tandem Carbonylation-Arylation with Alkynes." In Handbook of Palladium-Catalyzed Organic Reactions. Elsevier, 1997. http://dx.doi.org/10.1016/b978-012466615-3/50024-0.

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Austin, D. J., and S. M. Miller. "Palladium-Catalyzed Arylation with α-Anilinoalkenenitriles." In Three Carbon-Heteroatom Bonds: Esters and Lactones; Peroxy Acids and R(CO)OX Compounds; R(CO)X, X=S, Se, Te. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-021-00090.

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Kim, S., and J. Y. Yoon. "Palladium-Catalyzed Arylation of N-Unsubstituted Hydrazones." In Heteroatom Analogues of Aldehydes and Ketones. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-027-00606.

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Sato, R., and T. Kimura. "N-Arylation by Palladium-Catalyzed Cross Coupling." In Sulfur, Selenium, and Tellurium. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-039-00921.

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Eames, J. "Palladium-Catalyzed Vinylic Arylation of Allylic Alcohols." In Alcohols. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-036-00356.

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Conference papers on the topic "Palladium-catalyzed arylation"

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Rampon, Daniel S., Ludger A. Wessjohann, and Paulo H. Schneider. "Palladium-Catalyzed Direct Arylation of Selenophene." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013915174110.

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