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Journal articles on the topic 'Palladium-catalyzed cross-coupling reactions'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 May 2024

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1

Daley, Ryan A., and Joseph J. Topczewski. "Aryl-Decarboxylation Reactions Catalyzed by Palladium: Scope and Mechanism." Synthesis 52, no. 03 (2019): 365–77. http://dx.doi.org/10.1055/s-0039-1690769.

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Palladium-catalyzed cross-couplings and related reactions have enabled many transformations essential to the synthesis of pharmaceuticals, agrochemicals, and organic materials. A related family of reactions that have received less attention are decarboxylative functionalization reactions. These reactions replace the preformed organometallic precursor (e.g., boronic acid or organostannane) with inexpensive and readily available carboxylic acids for many palladium-catalyzed reactions. This review focuses on catalyzed reactions where the elementary decarboxylation step is thought to occur at a pa

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2

Pires, Marina, Sara Purificação, A. Santos, and M. Marques. "The Role of PEG on Pd- and Cu-Catalyzed Cross-Coupling Reactions." Synthesis 49, no. 11 (2017): 2337–50. http://dx.doi.org/10.1055/s-0036-1589498.

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Carbon–carbon and carbon–heteroatom coupling reactions are among the most important transformations in organic synthesis as they enable complex structures to be formed from readily available compounds under different routes and conditions. Several metal-catalyzed cross-coupling reactions have been developed creating many efficient methods accessible for the direct formation of new bonds between differently hybridized carbon atoms.During the last decade, much effort has been devoted towards improvement of the sustainability of these reactions, such as catalyst recovery and atom efficiency. Poly

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3

Vaaland, Ingrid Caroline, and Magne Olav Sydnes. "Consecutive Palladium Catalyzed Reactions in One-Pot Reactions." Mini-Reviews in Organic Chemistry 17, no. 5 (2020): 559–69. http://dx.doi.org/10.2174/1570193x16666190716150048.

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Combining palladium catalyzed reactions in one-pot reactions represents an efficient and economical use of catalyst. The Suzuki-Miyaura cross-coupling has been proven to be a reaction which can be combined with other palladium catalyzed reactions in the same pot. This mini-review will highlight some of the latest examples where Suzuki-Miyaura cross-coupling reactions have been combined with other palladium catalyzed reactions in one-pot reaction. Predominantly, examples with homogeneous reaction conditions will be discussed in addition to a few examples from the authors where Pd/C have been us

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4

Akkarasamiyo, Sunisa, Somsak Ruchirawat, Poonsaksi Ploypradith та Joseph S. M. Samec. "Transition-Metal-Catalyzed Suzuki–Miyaura-Type Cross-Coupling Reactions of π-Activated Alcohols". Synthesis 52, № 05 (2020): 645–59. http://dx.doi.org/10.1055/s-0039-1690740.

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The Suzuki–Miyaura reaction is one of the most powerful tools for the formation of carbon–carbon bonds in organic synthesis. The utilization of alcohols in this powerful reaction is a challenging task. This short review covers progress in the transition-metal-catalyzed Suzuki–Miyaura-type cross-coupling reaction of π-activated alcohol, such as aryl, benzylic, allylic, propargylic and allenic alcohols, between 2000 and June 2019.1 Introduction2 Suzuki–Miyaura Cross-Coupling Reactions of Aryl Alcohols2.1 One-Pot Reactions with Pre-activation of the C–O Bond2.1.1 Palladium Catalysis2.1.2 Nickel

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5

Della Ca’, Nicola. "Palladium-Catalyzed Reactions." Catalysts 11, no. 5 (2021): 588. http://dx.doi.org/10.3390/catal11050588.

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Palladium is probably the most versatile and exploited transition metal in catalysis due to its capability to promote a myriad of organic transformations both at laboratory and industrial scales (alkylation, arylation, cyclization, hydrogenation, oxidation, isomerization, cross-coupling, cascade, radical reactions, etc [...]

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6

Sain, Shalu, Sonika Jain, Manish Srivastava, Rajendra Vishwakarma, and Jaya Dwivedi. "Application of Palladium-Catalyzed Cross-Coupling Reactions in Organic Synthesis." Current Organic Synthesis 16, no. 8 (2020): 1105–42. http://dx.doi.org/10.2174/1570179416666191104093533.

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: Palladium-catalyzed cross-coupling reactions have gained a continuously growing interest of synthetic organic chemists. The present review gives a brief account of applications of the palladium-catalyzed cross-coupling reactions in comprehensive synthesis, viz., the Heck, Stille, Suzuki–Miyaura, Negishi, Sonogashira, Buchwald–Hartwig, Ullmann and the Oxidative, decarboxylative cross-coupling reactions, with particular emphasis on the synthesis of heterocyclic compounds.

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7

Mukai, Shoma, and Nathan Werner. "Synthesis and Palladium-Catalyzed Cross-Coupling of an Alkyl-Substituted Alkenylboronic Acid Pinacol Ester with Aryl Bromides." American Journal of Undergraduate Research 20, no. 1 (2023): 37–46. http://dx.doi.org/10.33697/ajur.2023.078.

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The palladium-catalyzed cross-coupling reaction of alkyl-substituted alkenylboron reagents with aryl halides is a versatile method to introduce a hydrophobic hydrocarbon chain onto organic compounds of interest. The application of the cross-coupling reaction is enabled by synthetic methods for the preparation of alkenylboron reagents. The geometrically pure, alkyl-substituted alkenylboron reagent, (E)-octenylboronic acid pinacol ester, was prepared by 9-BBN-catalyzed hydroboration reaction of 1-octene with pinacolborane in refluxing 1 M THF solution. This reagent was then evaluated in palladiu

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8

Orellana, Arturo, David Rosa, Andrei Nikolaev, and Nisha Nithiy. "Palladium-Catalyzed Cross-Coupling Reactions of Cyclopropanols." Synlett 26, no. 04 (2015): 441–48. http://dx.doi.org/10.1055/s-0034-1380156.

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9

Gagnon, A., M. Duplessis, P. Alsabeh, and F. Barabé. "Palladium-Catalyzed Cross-Coupling Reactions with Tricyclopropylbismuth." Synfacts 2008, no. 7 (2008): 0744. http://dx.doi.org/10.1055/s-2008-1077832.

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10

Len, Christophe. "Catalysts for Suzuki–Miyaura Coupling Reaction." Catalysts 10, no. 1 (2020): 50. http://dx.doi.org/10.3390/catal10010050.

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11

Wang, Jianbo, and Kang Wang. "Transition-Metal-Catalyzed Cross-Coupling with Non-Diazo Carbene Precursors." Synlett 30, no. 05 (2018): 542–51. http://dx.doi.org/10.1055/s-0037-1611020.

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Transition-metal-catalyzed cross-coupling reactions through metal carbene migratory insertion have emerged as powerful methodology for carbon–carbon bond constructions. Typically, diazo compounds (or in situ generated diazo compounds from N-tosylhydrazones) have been employed as the metal carbene precursors for this type of cross-coupling reactions. Recently, cross-coupling reactions employing non-diazo carbene precursors, such as conjugated ene-yne-ketones, allenyl ketones, alkynes, cyclopropenes, and Cr(0) Fischer carbenes, have been developed. This account will summarize our efforts in the

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12

Reymond, Sébastien, Laurent Ferrié, Amandine Guérinot, Patrice Capdevielle, and Janine Cossy. "Chemoselective reactions: Toward the synthesis of biologically active natural products with anticancer activities." Pure and Applied Chemistry 80, no. 8 (2008): 1683–91. http://dx.doi.org/10.1351/pac200880081683.

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Leucascandrolide A and migrastatin were synthesized efficiently by using chemoselective reactions such as olefin metatheses. The use of an iron-catalyzed cross-coupling reaction overcame difficulties encountered with palladium-catalyzed processes in our synthetic approach toward spirangien A.

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13

Venkata Krishna Reddy, Motakatla, Peddiahgari Vasu Govardhana Reddy, and Cirandur Suresh Reddy. "PEPPSI-SONO-SP2: a new highly efficient ligand-free catalyst system for the synthesis of tri-substituted triazine derivatives via Suzuki–Miyaura and Sonogashira coupling reactions under a green approach." New Journal of Chemistry 40, no. 6 (2016): 5135–42. http://dx.doi.org/10.1039/c5nj03299g.

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14

Kramer, Søren. "Homogeneous Gold-Catalyzed Aryl–Aryl Coupling Reactions." Synthesis 52, no. 14 (2020): 2017–30. http://dx.doi.org/10.1055/s-0039-1690882.

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Synthesis of biaryl motifs are crucial for the development and synthesis of pharmaceuticals, natural products, and functional materials. During the last decade, gold-catalyzed aryl–aryl coupling reactions have evolved from a curiosity to a well-established research field. This review summarizes the field from early examples up to the latest developments. Facile C–H functionalization and orthogonal reactivity compared to many other types of transition metal catalysis, for example, palladium catalysis, makes gold-catalyzed aryl–aryl coupling reactions highly appealing and valuable.1 Introduction

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15

MIYAURA, Norio. "Palladium-Catalyzed Cross-Coupling Reactions in Organic Syntheses." TRENDS IN THE SCIENCES 16, no. 5 (2011): 13–17. http://dx.doi.org/10.5363/tits.16.5_13.

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16

Bew, Sean, and J. Sweeney. "Palladium-Catalyzed Cross-Coupling Reactions of 3-Tributylstannylsulfolene." Synlett 1997, no. 11 (1997): 1273–74. http://dx.doi.org/10.1055/s-1997-1020.

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17

Miyaura, Norio, and Akira Suzuki. "Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds." Chemical Reviews 95, no. 7 (1995): 2457–83. http://dx.doi.org/10.1021/cr00039a007.

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18

So, Chau Ming, and Fuk Yee Kwong. "Palladium-catalyzed cross-coupling reactions of aryl mesylates." Chemical Society Reviews 40, no. 10 (2011): 4963. http://dx.doi.org/10.1039/c1cs15114b.

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19

Hillerich, Jens, and Herbert Plenio. "Continuous biphasic catalysis: palladium catalyzed cross coupling reactions." Chemical Communications, no. 24 (2003): 3024. http://dx.doi.org/10.1039/b310504k.

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20

Nicolaou, K. C., Paul G. Bulger, and David Sarlah. "Palladium-Catalyzed Cross-Coupling Reactions in Total Synthesis." Angewandte Chemie International Edition 44, no. 29 (2005): 4442–89. http://dx.doi.org/10.1002/anie.200500368.

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21

Kang, Dongjin, Dahan Eom, Hyunseok Kim, and Phil Ho Lee. "Palladium-Catalyzed Multialkynyl Cross-Coupling Reactions with Tetraalkynylindates." European Journal of Organic Chemistry 2010, no. 12 (2010): 2330–36. http://dx.doi.org/10.1002/ejoc.201000027.

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22

Salih, Kifah S. M., and Younis Baqi. "Microwave-Assisted Palladium-Catalyzed Cross-Coupling Reactions: Generation of Carbon–Carbon Bond." Catalysts 10, no. 1 (2019): 4. http://dx.doi.org/10.3390/catal10010004.

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Cross-coupling reactions furnishing carbon–carbon (C–C) bond is one of the most challenging tasks in organic syntheses. The early developed reaction protocols by Negishi, Heck, Kumada, Sonogashira, Stille, Suzuki, and Hiyama, utilizing palladium or its salts as catalysis have, for decades, attracted and inspired researchers affiliated with academia and industry. Tremendous efforts have been paid to develop and achieve more sustainable reaction conditions, such as the reduction in energy consumption by applying the microwave irradiation technique. Chemical reactions under controlled microwave c

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23

Ackermann, Lutz, Robert Born, Julia H. Spatz, Andreas Althammer, and Christian J. Gschrei. "Air-stable phosphine oxides as preligands for catalytic activation reactions of C-Cl, C-F, and C-H bonds." Pure and Applied Chemistry 78, no. 2 (2006): 209–14. http://dx.doi.org/10.1351/pac200678020209.

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Studies on the use of easily accessible heteroatom-substituted secondary phosphine oxides as preligands for cross-coupling reactions are described. These air-stable sterically hindered phosphine oxides allow for efficient palladium-catalyzed Suzuki- and nickel-catalyzed Kumada-coupling reactions using electronically deactivated aryl chlorides. In addition, they enable nickel-catalyzed coupling reactions of magnesium organyls with aryl fluorides at ambient temperature, and ruthenium-catalyzed coupling reactions of aryl chlorides via C-H bond activation. Finally, the application of modular diami

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24

Surasani, Rajendra, Dipak Kalita, A. V. Dhanunjaya Rao, and K. B. Chandrasekhar. "Palladium-catalyzed C–N and C–O bond formation of N-substituted 4-bromo-7-azaindoles with amides, amines, amino acid esters and phenols." Beilstein Journal of Organic Chemistry 8 (November 19, 2012): 2004–18. http://dx.doi.org/10.3762/bjoc.8.227.

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Simple and efficient procedures for palladium-catalyzed cross-coupling reactions of N-substituted 4-bromo-7-azaindole (1H-pyrrole[2,3-b]pyridine), with amides, amines, amino acid esters and phenols through C–N and C–O bond formation have been developed. The C–N cross-coupling reaction of amides, amines and amino acid esters takes place rapidly by using the combination of Xantphos, Cs2CO3, dioxane and palladium catalyst precursors Pd(OAc)2/Pd2(dba)3. The combination of Pd(OAc)2, Xantphos, K2CO3 and dioxane was found to be crucial for the C–O cross-coupling reaction. This is the first report on

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25

Beletskaya, Irina P., and Alexei D. Averin. "New trends in the cross-coupling and other catalytic reactions." Pure and Applied Chemistry 89, no. 10 (2017): 1413–28. http://dx.doi.org/10.1515/pac-2016-1110.

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AbstractA mini-review covers the latest achievements in the field of metal-mediated cross-coupling reactions among which are palladium-catalyzed Heck, Suzuki, cyanation and amination reactions. The aspects of the application of Pd nanoparticles (PdNPs) are discussed. The possibilities of the applications of Cu(I)-catalyzed reactions are described. Special emphasis is made on the synthesis of polymacrocyclic compounds like porphyrin dyads and triads, polyazacryptands bearing fluorophore groups using catalytic methods. The application of Pd-catalyzed CH-activation reactions for porphyrin modific

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26

Koranne, Anushka, Shrishty Turakhia, Vikesh Kumar Jha, et al. "The Mizoroki–Heck reaction between in situ generated alkenes and aryl halides: cross-coupling route to substituted olefins." RSC Advances 13, no. 32 (2023): 22512–28. http://dx.doi.org/10.1039/d3ra03533f.

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This review covers palladium-catalyzed typical Mizoroki–Heck cross-coupling reactions of aryl halides with in situ generated alkenes, to form substituted olefins unlike direct cross-coupling of alkenes with aryl halides in Heck olefination.

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27

Odell, Luke, Mats Larhed, and Linda Åkerbladh. "Palladium-Catalyzed Molybdenum Hexacarbonyl-Mediated Gas-Free Carbonylative Reactions." Synlett 30, no. 02 (2018): 141–55. http://dx.doi.org/10.1055/s-0037-1610294.

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This account summarizes Pd(0)-catalyzed Mo(CO)6-mediated gas-free carbonylative reactions published in the period October 2011 to May 2018. Presented reactions include inter- and intramolecular carbonylations, carbonylative cross-couplings, and carbonylative multicomponent reactions using Mo(CO)6 as a solid source of CO. The presented methodologies were developed mainly for small-scale applications, avoiding the problematic use of gaseous CO in a standard laboratory. In most cases, the reported Mo(CO)6-mediated carbonylations were conducted in sealed vials or by using two-chamber solutions.1 I

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28

Friesen, Richard W., Richard W. Loo, and Claudio F. Sturino. "The preparation of C-aryl glucals via palladium-catalyzed cross-coupling methods." Canadian Journal of Chemistry 72, no. 5 (1994): 1262–72. http://dx.doi.org/10.1139/v94-160.

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The C-aryl glucals 17–31 have been prepared by the palladium-catalyzed cross coupling of 1-tributylstannyl-3,4,6-tri-O-(tert-butyldimethylsilyl)-D-glucal (11) and aryl bromides. The major by-product in all of these reactions is the dimer 33, the product of homocoupling of 11. Alternatively, the C-aryl glucals 34–40 can be obtained from the palladium-catalyzed coupling of 1-iodo-3,4,6-tri-O-(triisopropylsilyl)-D-glucal (16) and a variety of metalated aromatics, including ArZnCl, ArB(OH)2, and ArB(OMe)2. The advantages of the latter procedure include superior coupling yields under milder reactio

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29

Taskin, Meltem, Alice Cognigni, Ronald Zirbs, Erik Reimhult, and Katharina Bica. "Surface-active ionic liquids for palladium-catalysed cross coupling in water: effect of ionic liquid concentration on the catalytically active species." RSC Advances 7, no. 65 (2017): 41144–51. http://dx.doi.org/10.1039/c7ra07757b.

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30

Shimizu, Masaki, Ikuhiro Nagao, Shin-ichi Kiyomoto, and Tamejiro Hiyama. "New Synthesis of Dibenzofulvenes by Palladium-Catalyzed Double Cross-Coupling Reactions." Australian Journal of Chemistry 65, no. 9 (2012): 1277. http://dx.doi.org/10.1071/ch12060.

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Palladium-catalyzed double cross-coupling reactions of 1,1-bis(pinacolato)borylalk-1-enes with 2,2′-dibromobiaryls and of 9-stannafluorenes with 1,1-dibromoalk-1-enes have been demonstrated to serve as new synthetic methods for dibenzofulvenes.

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31

Stein, A. L., F. N. Bilheri, and G. Zeni. "Application of organoselenides in the Suzuki, Negishi, Sonogashira and Kumada cross-coupling reactions." Chemical Communications 51, no. 85 (2015): 15522–25. http://dx.doi.org/10.1039/c5cc06347g.

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32

Zhang, He. "A new protocol for synthesizing diarylmethanes using a benzyltitanium reagent as a nucleophile." Journal of Chemical Research 46, no. 2 (2022): 174751982210919. http://dx.doi.org/10.1177/17475198221091941.

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The first palladium-catalyzed cross-coupling of various substituted benzyltitaniums with aryl triflates is presented for the synthesis of diarylmethanes in yields of up to 94% through highly selective C–O bond functionalization. The benzyltitaniums act as nucleophiles to realize the C(sp2)–C(sp3) cross-coupling with high efficiency in short reaction times. The reactions proceed at 60°C and show excellent functional groups tolerance.

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33

Ohashi, Masato, and Sensuke Ogoshi. "Palladium-Catalyzed Cross-Coupling Reactions of Perfluoro Organic Compounds." Catalysts 4, no. 3 (2014): 321–45. http://dx.doi.org/10.3390/catal4030321.

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34

Wipf, Peter, and Kara George. "Regioselective Palladium-Catalyzed Cross-Coupling Reactions of 2,4,7-Trichloroquinazoline." Synlett 2010, no. 04 (2010): 644–48. http://dx.doi.org/10.1055/s-0029-1219391.

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35

Schoenebeck, Franziska, and K. N. Houk. "Ligand-Controlled Regioselectivity in Palladium-Catalyzed Cross Coupling Reactions." Journal of the American Chemical Society 132, no. 8 (2010): 2496–97. http://dx.doi.org/10.1021/ja9077528.

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36

Sun, Feiye, Lily Lv, Min Huang, Zhaohui Zhou, and Xiangdong Fang. "Palladium-Catalyzed Cross-Coupling Reactions of 4a,8a-Azaboranaphthalene." Organic Letters 16, no. 19 (2014): 5024–27. http://dx.doi.org/10.1021/ol502339h.

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37

Ali, Hasrat, Samia Ait-Mohand, Simon Gosselin, Johan E. van Lier, and Brigitte Guérin. "Phthalocyanine-Peptide Conjugates via Palladium-Catalyzed Cross-Coupling Reactions." Journal of Organic Chemistry 76, no. 6 (2011): 1887–90. http://dx.doi.org/10.1021/jo102083g.

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38

Lautens, Mark, Zafar Qureshi, and Christina Toker. "Secondary Alkyl Groups in Palladium-Catalyzed Cross-Coupling Reactions." Synthesis 49, no. 01 (2016): 1–16. http://dx.doi.org/10.1055/s-0035-1561625.

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39

Zhang, Liang, Jiang Qing, Pengyuan Yang, and Jie Wu. "Palladium-Catalyzed Hiyama Cross-Coupling Reactions of Aryl Mesylates." Organic Letters 10, no. 21 (2008): 4971–74. http://dx.doi.org/10.1021/ol802049t.

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40

Ruiz-Castillo, Paula, and Stephen L. Buchwald. "Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions." Chemical Reviews 116, no. 19 (2016): 12564–649. http://dx.doi.org/10.1021/acs.chemrev.6b00512.

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41

Vashchenko, Valery, Alexander Krivoshey, Irina Knyazeva, Alexey Petrenko, and John W. Goodby. "Palladium-catalyzed Suzuki cross-coupling reactions in a microemulsion." Tetrahedron Letters 49, no. 9 (2008): 1445–49. http://dx.doi.org/10.1016/j.tetlet.2008.01.013.

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42

Morita, David K., Scott A. David, William Tumas, David K. Morita, David R. Pesiri, and William H. Glaze. "Palladium-catalyzed cross-coupling reactions in supercritical carbon dioxide." Chemical Communications, no. 13 (1998): 1397–98. http://dx.doi.org/10.1039/a802621a.

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43

Rosa, David, Andrei Nikolaev, Nisha Nithiy, and Arturo Orellana. "ChemInform Abstract: Palladium-Catalyzed Cross-Coupling Reactions of Cyclopropanols." ChemInform 46, no. 19 (2015): no. http://dx.doi.org/10.1002/chin.201519306.

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44

KALININ, V. N., F. S. DENISOV, and YU N. BUBOV. "ChemInform Abstract: Allylboranes in Palladium-Catalyzed Cross-Coupling Reactions." ChemInform 28, no. 9 (2010): no. http://dx.doi.org/10.1002/chin.199709062.

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45

Nawaz, Muhammad, Ihsan Ullah, Obaid-ur-Rahman Abid, et al. "Synthesis of functionalized para- and meta-terphenyls based on site-selective Suzuki cross-coupling reactions of bis(triflates) of methyl 2,5-dihydroxybenzoate and methyl 2,4-dihydroxybenzoate." Canadian Journal of Chemistry 91, no. 11 (2013): 1048–58. http://dx.doi.org/10.1139/cjc-2013-0201.

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The palladium(0)-catalyzed Suzuki cross-coupling reaction of the bis(triflates) of methyl 2,5-dihydroxybenzoate and methyl 2,4-dihydroxybenzoate afforded para- and meta-terphenyls, respectively. The reactions proceeded with very good site selectivity in favor of the sterically less hindered carbon atom.

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46

Wang, Tao, Shuwu Yang, Silin Xu, Chunyu Han, Ge Guo, and Junfeng Zhao. "Palladium catalyzed Suzuki cross-coupling of benzyltrimethylammonium salts via C–N bond cleavage." RSC Advances 7, no. 26 (2017): 15805–8. http://dx.doi.org/10.1039/c7ra02549a.

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A Pd catalyzed Suzuki cross-coupling of a benzyltrimethylammonium salt is described. This reaction offers a highly efficient approach to diarylmethanes and also paves the way for the application of benzyltrimethylammonium salts in Pd catalyzed cross-coupling reactions.

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47

Ma, Cong, Chuan-Qi Zhao, Yi-Qian Li, et al. "Palladium-catalyzed C–H activation/C–C cross-coupling reactions via electrochemistry." Chemical Communications 53, no. 90 (2017): 12189–92. http://dx.doi.org/10.1039/c7cc07429h.

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48

Schmidt, Bernd, Nastja Riemer, Christin Coswig, and Mike Shipman. "Palladium-Catalyzed Cross-Coupling of Arenediazonium Salts with Organoindium or Organobismuth Reagents." Synlett 29, no. 18 (2018): 2427–31. http://dx.doi.org/10.1055/s-0037-1611001.

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49

Miao, Hui, Fenhua Wang, Shuangliu Zhou, Guangchao Zhang, and Yang Li. "Palladium-catalyzed Hiyama coupling reaction of arylsulfonyl hydrazides under oxygen." Organic & Biomolecular Chemistry 13, no. 16 (2015): 4647–51. http://dx.doi.org/10.1039/c5ob00139k.

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Palladium-catalyzed Hiyama cross-coupling reactions of various arylsulfonyl hydrazides with a wide variety of aryl silanes have been achieved in good to excellent yields under simple aerobic conditions.

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50

Zhou, Qi, Yunpeng Gao, Yiyang Xiao, et al. "Palladium-catalyzed carbene coupling of N-tosylhydrazones and arylbromides to synthesize cross-conjugated polymers." Polymer Chemistry 10, no. 5 (2019): 569–73. http://dx.doi.org/10.1039/c8py01529e.

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Palladium-catalyzed cross-coupling reactions of N-tosylhydrazones and arylbromides have been applied for the first time in the synthesis of cross-conjugated polymers, namely poly(arylene-1,1-vinylidene)s (iso-PAVs).

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