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Journal articles on the topic 'Palladium catalyzed reaction'

Author: Grafiati

Published: 4 June 2025

Last updated: 1 August 2025

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1

Vaaland, Ingrid Caroline, and Magne Olav Sydnes. "Consecutive Palladium Catalyzed Reactions in One-Pot Reactions." Mini-Reviews in Organic Chemistry 17, no. 5 (2020): 559–69. http://dx.doi.org/10.2174/1570193x16666190716150048.

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Combining palladium catalyzed reactions in one-pot reactions represents an efficient and economical use of catalyst. The Suzuki-Miyaura cross-coupling has been proven to be a reaction which can be combined with other palladium catalyzed reactions in the same pot. This mini-review will highlight some of the latest examples where Suzuki-Miyaura cross-coupling reactions have been combined with other palladium catalyzed reactions in one-pot reaction. Predominantly, examples with homogeneous reaction conditions will be discussed in addition to a few examples from the authors where Pd/C have been us

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2

Christodoulou, Michael S., Egle M. Beccalli, and Sabrina Giofrè. "Palladium-Catalyzed Benzodiazepines Synthesis." Catalysts 10, no. 6 (2020): 634. http://dx.doi.org/10.3390/catal10060634.

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This review is focused on palladium-catalyzed reactions as efficient strategies aimed at the synthesis of different classes of benzodiazepines. Several reaction typologies are reported including hydroamination, amination, C–H arylation, N-arylation, and the Buchwald–Hartwig reaction, depending on the different substrates identified as halogenated starting materials (activated substrates) or unactivated unsaturated systems, which then exploit Pd(0)- or Pd(II)-catalytic species. In particular, the use of the domino reactions, as intra- or intermolecular processes, are reported as an efficient an

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3

Mukai, Shoma, and Nathan Werner. "Synthesis and Palladium-Catalyzed Cross-Coupling of an Alkyl-Substituted Alkenylboronic Acid Pinacol Ester with Aryl Bromides." American Journal of Undergraduate Research 20, no. 1 (2023): 37–46. http://dx.doi.org/10.33697/ajur.2023.078.

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The palladium-catalyzed cross-coupling reaction of alkyl-substituted alkenylboron reagents with aryl halides is a versatile method to introduce a hydrophobic hydrocarbon chain onto organic compounds of interest. The application of the cross-coupling reaction is enabled by synthetic methods for the preparation of alkenylboron reagents. The geometrically pure, alkyl-substituted alkenylboron reagent, (E)-octenylboronic acid pinacol ester, was prepared by 9-BBN-catalyzed hydroboration reaction of 1-octene with pinacolborane in refluxing 1 M THF solution. This reagent was then evaluated in palladiu

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4

Yang, Jia, Tieqiao Chen, Yongbo Zhou, Shuangfeng Yin, and Li-Biao Han. "Palladium-catalyzed dehydrogenative coupling of terminal alkynes with secondary phosphine oxides." Chemical Communications 51, no. 17 (2015): 3549–51. http://dx.doi.org/10.1039/c4cc09567g.

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The palladium-catalyzed dehydrogenative coupling of alkynes with secondary phosphine oxides is developed. Thus, in the presence of a silver additive, palladium acetate could efficiently catalyze the dehydrocoupling of secondary phosphine oxides with a variety of alkynes to produce the corresponding alkynylphosphine oxides in high yields. A reaction mechanism is proposed.

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5

Peng, Jin-Bao, Xin-Lian Liu, Lin Li, and Xiao-Feng Wu. "Palladium-catalyzed enantioselective carbonylation reactions." Science China Chemistry 65, no. 3 (2022): 441–61. http://dx.doi.org/10.1007/s11426-021-1165-6.

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AbstractCarbonylation, one of the most powerful approaches to the preparation of carbonylated compounds, has received significant attention from researchers active in various fields. Indeed, impressive progress has been made on this subject over the past few decades. Among the various types of carbonylation reactions, asymmetric carbonylation is a straightforward methodology for constructing chiral compounds. Although rhodium-catalyzed enantioselective hydroformylations have been discussed in several elegant reviews, a general review on palladium-catalyzed asymmetric carbonylations is still mi

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6

P., G. More, V. Dalave N., S. Lawand A., and M. Nalawade A. "Palladium catalyzed cross-coupling reactions of organomercurials." Journal of Indian Chemical Society Vol. 86, Jan 2009 (2009): 68–71. https://doi.org/10.5281/zenodo.5807134.

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Department of Chemistry, Solapur University, Solapur-413 255, Maharashtra, India <em>Fax</em> : 91-217-2744770 Ramkrishna Paramhansa College, Osmanabad-413 501, Maharashtra, India <em>Manuscript received 31 January 2008, accepted 9 September 2008</em> The palladium catalyzed cross-coupling reactions of methyl mercury iodide provide a mild, selective and general method for the construction of new C-C bond i.e. for the synthesis of arenes. The reaction proceeds in DMF, in the presence of a nucleophilic catalyst (iodide ion), at room temperature under argon atmosphere. Pd<sup>0</sup> which is gen

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7

Rifhat Bibi, Rifhat Bibi, Muhammad Yaseen Muhammad Yaseen, Haseen Ahmad Haseen Ahmad, Ismat Ullah Khan Ismat Ullah Khan, Shaista Parveen Shaista Parveen, and Abbas Hassan Abbas Hassan. "Palladium Catalyzed Synthesis of Phenylquinoxaline-Alkyne Derivatives via Sonogashira Cross Coupling Reaction." Journal of the chemical society of pakistan 43, no. 1 (2021): 95. http://dx.doi.org/10.52568/000550.

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Transition metals mediated cross coupling methodologies provide an extremely powerful versatile pathway in organic syntheses undoubtedly, a facile route for syntheses and derivatization of biologically important heterocycles from easily available precursors. Sonogashira coupling reaction, a leading method to Csp-Csp2 bond formation is one of the most important and rapid pathways to couple aryl/vinyl halides with terminal alkynes. Current research study deals with the synthesis of alkyne substituted quinoxaline derivatives. The quinoxalines class of aromatic heterocycles exhibits a wide variety

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8

Rifhat Bibi, Rifhat Bibi, Muhammad Yaseen Muhammad Yaseen, Haseen Ahmad Haseen Ahmad, Ismat Ullah Khan Ismat Ullah Khan, Shaista Parveen Shaista Parveen, and Abbas Hassan Abbas Hassan. "Palladium Catalyzed Synthesis of Phenylquinoxaline-Alkyne Derivatives via Sonogashira Cross Coupling Reaction." Journal of the chemical society of pakistan 43, no. 1 (2021): 95. http://dx.doi.org/10.52568/000550/jcsp/43.01.2021.

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Transition metals mediated cross coupling methodologies provide an extremely powerful versatile pathway in organic syntheses undoubtedly, a facile route for syntheses and derivatization of biologically important heterocycles from easily available precursors. Sonogashira coupling reaction, a leading method to Csp-Csp2 bond formation is one of the most important and rapid pathways to couple aryl/vinyl halides with terminal alkynes. Current research study deals with the synthesis of alkyne substituted quinoxaline derivatives. The quinoxalines class of aromatic heterocycles exhibits a wide variety

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9

Rifhat Bibi, Rifhat Bibi, Muhammad Yaseen Muhammad Yaseen, Haseen Ahmad Haseen Ahmad, Ismat Ullah Khan Ismat Ullah Khan, Shaista Parveen Shaista Parveen, and Abbas Hassan Abbas Hassan. "Palladium Catalyzed Synthesis of Phenylquinoxaline-Alkyne Derivatives via Sonogashira Cross Coupling Reaction." Journal of the chemical society of pakistan 43, no. 1 (2021): 95. http://dx.doi.org/10.52568/000009.

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Transition metals mediated cross coupling methodologies provide an extremely powerful versatile pathway in organic syntheses undoubtedly, a facile route for syntheses and derivatization of biologically important heterocycles from easily available precursors. Sonogashira coupling reaction, a leading method to Csp-Csp2 bond formation is one of the most important and rapid pathways to couple aryl/vinyl halides with terminal alkynes. Current research study deals with the synthesis of alkyne substituted quinoxaline derivatives. The quinoxalines class of aromatic heterocycles exhibits a wide variety

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10

Baranano, David, Grace Mann, and John F. Hartwig. "Nickel and Palladium-Catalyzed Cross-Couplings that Form Carbon-Heteroatom and Carbon-Element Bonds." Current Organic Chemistry 1, no. 3 (1997): 287–305. http://dx.doi.org/10.2174/1385272801666220124194647.

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The transition-metal catalyzed addition of heteroatom nucleophiles to aryl and vinyl halides is reviewed. This chemistry typically involves a nickel- or palladium-based catalyst containing phosphine ligands. In recently developed palladium-catalyzed chemistry, aryl halides react with amines in the presence of base to form arylamines. In similar chemistry catalyzed by both nickel and palladium, aryl and vinyl halides react with alkali metal or tin thiolates or selenides to form aryl and vinyl sulfides, while the reaction of different phosphorus compounds, such as phosphides, phosphonates, and

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11

Len, Christophe. "Catalysts for Suzuki–Miyaura Coupling Reaction." Catalysts 10, no. 1 (2020): 50. http://dx.doi.org/10.3390/catal10010050.

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12

Nakada, Masahisa, Yosuke Hosoya, Kota Mizoguchi, and Honoka Yasukochi. "Palladium-Catalyzed Thiocarbonylations with Triisopropylsilyl Thioethers." Synlett 33, no. 05 (2022): 495–501. http://dx.doi.org/10.1055/a-1733-6073.

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AbstractWe have developed a palladium-catalyzed thiocarbonylation through the reaction of a σ-alkyl palladium intermediate with carbon monoxide and a triisopropylsilyl (TIPS) thioether. The use of CsF, (IPr)Pd(allyl)Cl [IPr =1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene], CO, and a TIPS thioether in THF are key to obtaining alkyl and aryl thioesters in high yields. The yield of the palladium-catalyzed thiocarbonylation depended on the structure of the substrate; indoline-2-one derivatives were formed faster than indoline derivatives. The reactions of benzoyl and hydrocinnamoyl fluorides wit

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13

Wang, Liangguang, Xiaoyu Zhou, Juan Ma, and Xia Chen. "Synthesis of Enaminones by a Palladium-Catalyzed Four-Component Carbonylative Addition Reaction." Synlett 28, no. 19 (2017): 2680–84. http://dx.doi.org/10.1055/s-0036-1590976.

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A palladium-catalyzed carbonylative addition reaction of aryl bromides, amines, and alkynes has been developed. The reaction occurs readily in N,N-dimethylformamide with PdCl2(PPh3)2 as a catalyst to give the corresponding enaminones in medium to excellent yields. Furthermore, a mechanism for the palladium-catalyzed four-component carbonylative addition reaction is proposed.

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14

Li, Xuefeng, Zhenhua Zhang, Jiyao Feng, and Zhen Zhang. "Palladium-Catalyzed Carbonylation of Azides and Mechanistic Studies." Synlett 31, no. 11 (2020): 1040–49. http://dx.doi.org/10.1055/s-0039-1690859.

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Isocyanates are widely applied in the fields of materials science, drug discovery and chemical industry processes. Palladium-catalyzed carbonylation of azides with carbon monoxide (CO) is reported as a powerful method for simple and efficient access to isocyanates, which are important precursors for preparing structurally meaningful urea, carbamate and amidine derivatives. In this account, we provide an overview on the synthesis of isocyanates and their subsequent reactions to obtain diverse nucleophilic addition products. In addition, with particular emphasis on our mechanistic studies of the

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15

Akkarasamiyo, Sunisa, Somsak Ruchirawat, Poonsaksi Ploypradith та Joseph S. M. Samec. "Transition-Metal-Catalyzed Suzuki–Miyaura-Type Cross-Coupling Reactions of π-Activated Alcohols". Synthesis 52, № 05 (2020): 645–59. http://dx.doi.org/10.1055/s-0039-1690740.

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The Suzuki–Miyaura reaction is one of the most powerful tools for the formation of carbon–carbon bonds in organic synthesis. The utilization of alcohols in this powerful reaction is a challenging task. This short review covers progress in the transition-metal-catalyzed Suzuki–Miyaura-type cross-coupling reaction of π-activated alcohol, such as aryl, benzylic, allylic, propargylic and allenic alcohols, between 2000 and June 2019.1 Introduction2 Suzuki–Miyaura Cross-Coupling Reactions of Aryl Alcohols2.1 One-Pot Reactions with Pre-activation of the C–O Bond2.1.1 Palladium Catalysis2.1.2 Nickel

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16

Reymond, Sébastien, Laurent Ferrié, Amandine Guérinot, Patrice Capdevielle, and Janine Cossy. "Chemoselective reactions: Toward the synthesis of biologically active natural products with anticancer activities." Pure and Applied Chemistry 80, no. 8 (2008): 1683–91. http://dx.doi.org/10.1351/pac200880081683.

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Leucascandrolide A and migrastatin were synthesized efficiently by using chemoselective reactions such as olefin metatheses. The use of an iron-catalyzed cross-coupling reaction overcame difficulties encountered with palladium-catalyzed processes in our synthetic approach toward spirangien A.

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17

Hu, Fangdong, Ying Xia, Zhenxing Liu, Chen Ma, Yan Zhang, and Jianbo Wang. "Palladium-catalyzed three-component reaction of N-tosylhydrazone, norbornene and aryl halide." Org. Biomol. Chem. 12, no. 22 (2014): 3590–93. http://dx.doi.org/10.1039/c4ob00590b.

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18

Messina, Andrea, Filippo Monticelli, Tiziano Miroglio, et al. "Photoexcited Palladium Complex-Catalyzed Isocyanide Insertion into Inactivated Alkyl Iodides." Molecules 30, no. 12 (2025): 2584. https://doi.org/10.3390/molecules30122584.

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Isocyanides insertions represent an important transformation in the palladium-catalyzed reactions landscape. However, one of their most significant limitations is in the use of inactivated alkyl electrophiles. Palladium photocatalysis has been proven as a solid tool for the generation of alkyl radicals from alkyl halides, which may engage in subsequent transformations with a variety of reaction partners, closing the catalytic cycle. Herein, we report the mild three-component isocyanide insertions into inactivated alkyl iodides mediated by the catalytic activity of a photoexcited palladium comp

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19

Venkata Krishna Reddy, Motakatla, Peddiahgari Vasu Govardhana Reddy, and Cirandur Suresh Reddy. "PEPPSI-SONO-SP2: a new highly efficient ligand-free catalyst system for the synthesis of tri-substituted triazine derivatives via Suzuki–Miyaura and Sonogashira coupling reactions under a green approach." New Journal of Chemistry 40, no. 6 (2016): 5135–42. http://dx.doi.org/10.1039/c5nj03299g.

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20

Su, Yijin, and Ning Jiao. "Palladium-Catalyzed Oxidative Heck Reaction." Current Organic Chemistry 15, no. 18 (2011): 3362–88. http://dx.doi.org/10.2174/138527211797248030.

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21

Trost, Barry M., and Yian Shi. "A palladium-catalyzed zipper reaction." Journal of the American Chemical Society 113, no. 2 (1991): 701–3. http://dx.doi.org/10.1021/ja00002a064.

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22

Punk, Molly, Charlotte Merkley, Katlyn Kennedy, and Jeremy B. Morgan. "Palladium-Catalyzed, Enantioselective Heine Reaction." ACS Catalysis 6, no. 7 (2016): 4694–98. http://dx.doi.org/10.1021/acscatal.6b01400.

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23

Morteza, Shiri, Notash Behrouz, Zamanian Fatemeh, Yasaei Zahra, and Ranjbar Maryam. "Palladium-catalyzed tandem reaction of 2-chloroquinoline-3-carbaldehydes and isocyanides." Organic and Biomolecular Chemistry 15, no. 47 (2017): 10073–81. https://doi.org/10.1039/c7ob02043k.

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A facile domino reaction of 2-chloroquinoline-3-carbaldehydes in one and two equivalents of isocyanide has been investigated. Three-component reactions of 2chloroquinoline-3-carbaldehydes, isocyanides and amines are also described. In this Pdcatalyzed reaction under controlled conditions, three novel types of quinoline derivatives were formed via amidation, lactamization or carbamate formation along with the formation of C–C, C–N, and C–O bonds in a one-pot procedure.

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24

Wang, Lei, Jianwei Zhang, Ming Lang, and Jian Wang. "Palladium-catalyzed ring contraction reaction of naphthoquinones upon reaction with alkynes." Organic Chemistry Frontiers 3, no. 5 (2016): 603–8. http://dx.doi.org/10.1039/c6qo00045b.

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25

Serban, Georgeta, та Faïza Diaba. "Palladium-Catalyzed α-Arylation of Esters: Synthesis of the Tetrahydroisoquinoline Ring". Reactions 6, № 1 (2025): 17. https://doi.org/10.3390/reactions6010017.

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The palladium-catalyzed cross-coupling reaction used for carbon–carbon bond formation is one of the most commonly applied reactions in modern organic synthesis. In this work, a concise strategy was developed for constructing the tetrahydroisoquinoline core, a key structural motif found in many biologically active compounds. This method involves the palladium-catalyzed intramolecular coupling of aryl iodides with ester enolates generated in the presence of K3PO4 as a base, resulting in the formation of the tetrahydroisoquinoline ring with an exceptionally high yield of 84%.

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26

Lautens, Mark, Dino Alberico, Cyril Bressy, Yuan-Qing Fang, Brian Mariampillai, and Thorsten Wilhelm. "Palladium-catalyzed ring-forming reactions: Methods and applications." Pure and Applied Chemistry 78, no. 2 (2006): 351–61. http://dx.doi.org/10.1351/pac200678020351.

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Several Pd-catalyzed cyclization methods were developed, including norbornene-mediated Catellani-type reactions, a Pd-catalyzed coupling reaction of aryl iodides and allyl moieties, and a tandem C-N/C-C coupling of gem-dihalovinyl systems. These ring-forming methods were applied to the synthesis of highly functionalized carbocyclic and heterocyclic compounds. Intermolecular Pd-catalyzed methods for synthesis of highly substituted arene compounds were also developed.

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27

Vasapollo, Giuseppe, and Giuseppe Mele. "Palladium-catalyzed asymmetric cyclocarbonylation of allyl naphthols." Canadian Journal of Chemistry 83, no. 6-7 (2005): 674–80. http://dx.doi.org/10.1139/v05-075.

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The asymmetric cyclocarbonylation reaction of allyl naphthol catalyzed by palladium complexes and chiral phosphine is reported. The reaction was performed under syn-gas conditions at relatively mild experimental conditions (80100 °C, 300600 psi (1 psi = 6.895 kPa)) in CH2Cl2 as the solvent.Key words: enantioselective, carbonylation, cyclocarbonylation, lactones, palladium acetate.

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28

Jiang, Xinpeng, Yong Liu, Lei Zhang, Jinkang Chen, Kang Cheng, and Chuanming Yu. "Palladium-Catalyzed Allylation of Polyfluoroarenes with Allylic Pivalates." Synlett 29, no. 02 (2017): 251–55. http://dx.doi.org/10.1055/s-0036-1590914.

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An efficient 1,5-cyclooctadiene–PdCl2/dicyclohexyl(2′,4′,6′-triisopropylbiphenyl-2-yl)phosphine (XPhos) catalytic system was developed for C–H allylation of polyfluoroarenes with allylic pivalates. The reactions showed excellent functional-group tolerance, good yields, and high regioselectivities. Mechanistic investigations supported a (π-allyl)palladium complex pathway through a directed oxidative addition of the allylic pivalate to palladium, followed by sequential nucleophilic attack by the polyfluorobenzene and reductive elimination. In a gram-scale reaction, a palladium loading of 0.5 mol

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29

Dodonova, Jelena, and Sigitas Tumkevicius. "Fused Pyrrolo[2,3-d]pyrimidines (7-Deazapurines) by Palladium-Catalyzed Direct N–H and C–H Arylation Reactions." Synthesis 49, no. 11 (2017): 2523–34. http://dx.doi.org/10.1055/s-0036-1588734.

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Palladium-catalyzed intramolecular direct C–H arylations for the synthesis of hitherto unknown fused hetero systems containing an incorporated pyrrolo[2,3-d]pyrimidine scaffold are described. Pyrimido[5′,4′:4,5]pyrrolo[2,1-a]isoindoles were synthesized from 2,4-diarylpyrrolo[2,3-d]pyrimidines and o-bromobenzyl bromides by using a cascade N-benzylation/C–H arylation reaction sequence. A series of pyrimido[5′,4′:4,5]pyrrolo[1,2-f]phenanthridines were successfully assembled via a domino process involving the palladium-catalyzed direct double C–H arylation reactions of 2,4,7-triarylpyrrolo[2,3-d]

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30

Doi, T., and K. Yamamoto. "Palladium(O)-Catalyzed Cyclization of 2,7-0ctadienyl Acetates and Analogst." Current Organic Chemistry 1, no. 3 (1997): 219–34. http://dx.doi.org/10.2174/1385272801666220124191458.

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<p>The palladium(O)-catalyzed cyclization of 2,7-octadienyl acetates and analogs proceeds in acetic acid solvent and generally consists of an intramolecular insertion of an alkene counterpart into a 7t-allylpalladium(ll) unit to give a 2-vinylcyclopentylmethylpalladium as the key intermediate. The process is referred to as a &#039;pallada-ene&#039; reaction after Oppolzer. Depending on the structure of the substrate, the key intermediate undergoes -hydride elimination, carbonylation and/or further intramolecular Heck reaction. In the last two cases, the stereochemical outcome of

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31

Weng, Jian-Quan, Ling-Ling Xing, Wen-Ren Hou, Ren-Xiao Liang, and Yi-Xia Jia. "Palladium-catalyzed dearomative arylphosphorylation of indoles." Organic Chemistry Frontiers 6, no. 10 (2019): 1577–80. http://dx.doi.org/10.1039/c9qo00246d.

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32

Chen, Shanshan, Xihao Chang, Yu Tao, Haoming Chen, and Yong Xia. "Palladium(ii)-catalyzed direct alkenylation of dihydropyranones." Organic & Biomolecular Chemistry 13, no. 43 (2015): 10675–80. http://dx.doi.org/10.1039/c5ob00432b.

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33

Xu, Zhaotao, Bin Huang, Zebiao Zhou, and Mingzhong Cai. "Recyclable Heterogeneous Palladium-Catalyzed Carbonylative Cyclization of 2-Iodoanilines with Aryl Iodides Leading to 2-Arylbenzoxazinones." Synthesis 52, no. 04 (2019): 581–90. http://dx.doi.org/10.1055/s-0039-1690265.

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A highly efficient and practical heterogeneous palladium-catalyzed carbonylative coupling of 2-iodoanilines with aryl iodides has been developed. The reaction occurs smoothly in toluene at 110 °C with N,N-diisopropylethylamine as base under carbon monoxide (5 bar) and offers a general and powerful tool for the construction of various valuable 2-arylbenzoxazinones with excellent atom-economy, high functional group tolerance, good to high yields, and easy recyclability of the palladium catalyst. The reaction is the first example of heterogeneous palladium-catalyzed carbonylative coupling for the

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Naka, Akinobu, Jun Sakata, Junnai Ikadai, et al. "Stereochemistry of Disilanylene-containing Cyclic Compounds – Synthesis and Palladium-catalyzed Reactions of cis- and trans-3,4- Benzo-1,2-diisopropyl-1,2-dimethyl-1,2-disilacyclobut-3-ene." Zeitschrift für Naturforschung B 64, no. 11-12 (2009): 1580–90. http://dx.doi.org/10.1515/znb-2009-11-1243.

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The synthesis and palladium-catalyzed reactions of cis- and trans-3,4-benzo-1,2-diisopropyl- 1,2-dimethyl-1,2-disilacyclobut-3-ene (1a and 1b) are reported. Their reactions with diphenylacetylene in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0) proceeded with high stereospecificity to give cis- and trans-5,6-benzo-1,4-diisopropyl-1,4-dimethyl- 2,3-diphenyl-1,4-disilacyclohexa-2,5-diene, 2a and 2b, in 95% and 93% yield, respectively. Similar palladium-catalyzed reactions of 1a and 1b with monosubstituted acetylenes, such as 1-hexyne, tert-butylacetylene, phenyla

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35

Yuasa, Akihiro, Kazunori Nagao та Hirohisa Ohmiya. "Allylic cross-coupling using aromatic aldehydes as α-alkoxyalkyl anions". Beilstein Journal of Organic Chemistry 16 (7 лютого 2020): 185–89. http://dx.doi.org/10.3762/bjoc.16.21.

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The allylic cross-coupling using aromatic aldehydes as α-alkoxyalkyl anions is described. The synergistic palladium/copper-catalyzed reaction of aromatic aldehydes, allylic carbonates, and a silylboronate produces the corresponding homoallylic alcohol derivatives. This process involves the catalytic formation of a nucleophilic α-silyloxybenzylcopper(I) species and the subsequent palladium-catalyzed allylic substitution.

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36

Rocard, Lou, and Piétrick Hudhomme. "Recent Developments in the Suzuki–Miyaura Reaction Using Nitroarenes as Electrophilic Coupling Reagents." Catalysts 9, no. 3 (2019): 213. http://dx.doi.org/10.3390/catal9030213.

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Palladium-catalyzed cross-coupling reactions are nowadays essential in organic synthesis for the construction of C–C, C–N, C–O, and other C-heteroatom bonds. The 2010 Nobel Prize in Chemistry to Richard F. Heck, Ei-ichi Negishi, and Akira Suzuki was awarded for the discovery of these reactions. These great advances for organic chemists stimulated intense research efforts worldwide dedicated to studying these reactions. Among them, the Suzuki–Miyaura coupling (SMC) reaction, which usually involves an organoboron reagent and an organic halide or triflate in the presence of a base and a palladium

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37

Waghmode, Suresh B., Sudhir S. Arbuj, Bina N. Wani, and C. S. Gopinath. "Palladium chloride catalyzed photochemical Heck reaction." Canadian Journal of Chemistry 91, no. 5 (2013): 348–51. http://dx.doi.org/10.1139/cjc-2012-0377.

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PdCl2 catalyzed carbon–carbon bond formation (Heck reaction) between substituted aryl halides and olefins was carried out without a ligand, under irradiation with UV–visible light. The results demonstrated that UV–visible light accelerated the rate of the reaction, leading to an excellent yield of corresponding products. The recovered palladium nanoparticles could be thermally recycled several times. PdCl2 gave excellent conversion up to the fifth addition of substrate.

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38

Salih, Kifah S. M., and Younis Baqi. "Microwave-Assisted Palladium-Catalyzed Cross-Coupling Reactions: Generation of Carbon–Carbon Bond." Catalysts 10, no. 1 (2019): 4. http://dx.doi.org/10.3390/catal10010004.

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Cross-coupling reactions furnishing carbon–carbon (C–C) bond is one of the most challenging tasks in organic syntheses. The early developed reaction protocols by Negishi, Heck, Kumada, Sonogashira, Stille, Suzuki, and Hiyama, utilizing palladium or its salts as catalysis have, for decades, attracted and inspired researchers affiliated with academia and industry. Tremendous efforts have been paid to develop and achieve more sustainable reaction conditions, such as the reduction in energy consumption by applying the microwave irradiation technique. Chemical reactions under controlled microwave c

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Luo, Haiqing, Guojiao Wu, Shuai Xu, et al. "Palladium-catalyzed cross-coupling of aryl fluorides with N-tosylhydrazones via C–F bond activation." Chemical Communications 51, no. 68 (2015): 13321–23. http://dx.doi.org/10.1039/c5cc05035a.

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A palladium-catalyzed cross-coupling reaction of electron-deficient aryl fluorides with aryl N-tosylhydrazones, which involves C–F bond activation and migratory insertion of palladium carbene, has been developed.

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40

Jadhav, Sanjay N., Arjun S. Kumbhar, Chadrashekhar V. Rode, and Rajashri S. Salunkhe. "Ligand-free Pd catalyzed cross-coupling reactions in an aqueous hydrotropic medium." Green Chemistry 18, no. 7 (2016): 1898–911. http://dx.doi.org/10.1039/c5gc02314a.

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A simple, efficient and ligand-free protocol for the Suzuki–Miyaura reaction and base-free Heck–Matsuda reactions under mild reaction conditions has been developed over palladium supported on activated carbon (Pd/C) in an aqueous hydrotropic solution.

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41

Solovov, Roman, and Boris Ershov. "Features of Hydrogen Reduction of Fe(CN)63− Ions in Aqueous Solutions: Effect of Hydrogen Dissolved in Palladium Nanoparticles." Nanomaterials 11, no. 10 (2021): 2587. http://dx.doi.org/10.3390/nano11102587.

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Preliminary saturation of 2.6 nm palladium nanoparticles with hydrogen accelerates the reduction of Fe(CN)63− ions in aqueous solution three to four-fold. An analytical equation was derived describing the hydrogen saturation of palladium nanoparticles and the dependence of their catalytic activity on the hydrogen content in the metal. The specific rate constants of reduction do not depend on the content of palladium nanoparticles in the solution. A change in the temperature and pH or stirring of the solution do not affect the rate of catalytic reaction. Approaches to optimization of palladium-

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42

Lin, Jie, Tonghao Zhu, Minqiang Jia, and Shengming Ma. "A Pd-catalyzed ring opening coupling reaction of 2,3-allenylic carbonates with cyclopropanols." Chemical Communications 55, no. 31 (2019): 4523–26. http://dx.doi.org/10.1039/c9cc00979e.

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Ekebergh, Andreas, Christine Lingblom, Peter Sandin, Christine Wennerås, and Jerker Mårtensson. "Exploring a cascade Heck–Suzuki reaction based route to kinase inhibitors using design of experiments." Organic & Biomolecular Chemistry 13, no. 11 (2015): 3382–92. http://dx.doi.org/10.1039/c4ob02694b.

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Liang, Ren‐Xiao, Ling‐Jie Song, Jin‐Bo Lu, Wei‐Yan Xu, Chao Ding, and Yi‐Xia Jia. "Palladium‐Catalyzed Enantioselective Heteroarenyne Cycloisomerization Reaction." Angewandte Chemie International Edition 60, no. 13 (2021): 7412–17. http://dx.doi.org/10.1002/anie.202014796.

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45

Liang, Ren‐Xiao, Ling‐Jie Song, Jin‐Bo Lu, Wei‐Yan Xu, Chao Ding, and Yi‐Xia Jia. "Palladium‐Catalyzed Enantioselective Heteroarenyne Cycloisomerization Reaction." Angewandte Chemie 133, no. 13 (2021): 7488–93. http://dx.doi.org/10.1002/ange.202014796.

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46

Zhao, Ping, and Xinjun Luan. "Palladium-Catalyzed Enantioselective Heteroarenyne Cycloisomerization Reaction." Chinese Journal of Organic Chemistry 41, no. 6 (2021): 2520. http://dx.doi.org/10.6023/cjoc202100043.

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47

Takasu, Kiyosei, Masataka Ihara, and Naoko Nishida. "Palladium-Catalyzed Hydroamidation Reaction of Enones." Synlett, no. 10 (2004): 1844–46. http://dx.doi.org/10.1055/s-2004-830852.

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48

Bee, Cisco, Eric Leclerc, and Marcus A. Tius. "The Palladium(II)-Catalyzed Nazarov Reaction." Organic Letters 5, no. 26 (2003): 4927–30. http://dx.doi.org/10.1021/ol036017e.

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49

Ishida, Naoki, Tatsuo Shinmoto, Shota Sawano, Tomoya Miura, and Masahiro Murakami. "Palladium-Catalyzed Allylation Reaction of Alkynylborates." Bulletin of the Chemical Society of Japan 83, no. 11 (2010): 1380–85. http://dx.doi.org/10.1246/bcsj.20100189.

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Sperger, Theresa, Henry C. Fisher, and Franziska Schoenebeck. "Computationally deciphering palladium-catalyzed reaction mechanisms." Wiley Interdisciplinary Reviews: Computational Molecular Science 6, no. 3 (2016): 226–42. http://dx.doi.org/10.1002/wcms.1244.

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