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Dissertations / Theses on the topic 'Palladium compounds'

Author: Grafiati

Published: 4 June 2021

Last updated: 21 February 2023

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1

Farhad, Mohammad. "Studies on new trinuclear palladium compounds." Connect to full text, 2007. http://hdl.handle.net/2123/2477.

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Doctor of Philosophy(PhD)<br>The present study deals with the synthesis and characterization of six tri-palladium complexes code named MH3, MH4, MH5, MH6, MH7 and MH8 that contained two planaramine ligands bound to the central or each of the terminal metal ions. The activity of the compounds against human cancer cell lines: A2780, A2780cisR and A2780ZD0473R, cell uptake, levels of DNA-binding and nature of interaction with salmon sperm and pBR322 plasmid DNA have also been determined. Whereas cisplatin binds with DNA forming mainly intrastrand GG adduct that causes local bending of a DNA stran

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2

Burrows, Andrew David. "Cluster compounds of palladium and platinum." Thesis, University of Oxford, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.302903.

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3

Hoogervorst, Wilhelmus Johannes. "Isophthalaldimine compounds of palladium, platinum and rhodium." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2003. http://dare.uva.nl/document/69284.

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4

Ezomo, O. J. "Studies on palladium and platinum cluster compounds." Thesis, University of Oxford, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.234990.

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5

Chiffey, Andrew Francis. "Bimetallic compounds of palladium, platinum and gold." Thesis, University of Southampton, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.294602.

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6

Kelly, P. F. "Sulphur-nitrogen compounds of platinum and palladium." Thesis, Imperial College London, 1987. http://hdl.handle.net/10044/1/46826.

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7

Phillips, David J. "Palladium-catalysed synthesis of highly functionalised compounds." Thesis, University of Glasgow, 2018. http://theses.gla.ac.uk/9011/.

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Palladium-catalysis is extremely important in fine chemical synthesis. This thesis looks at the development of new palladium-catalysed carbon–carbon bond formation reactions, with particular attention to forming new bonds to sp3 carbons. The opening chapter of this thesis gives an overview of current methods for palladium-catalysed heterocyclisation, and the methods for incorporating further functionalisation into this process, then focuses on the optimisation and expansion of a new palladium-catalysed carboallylation reaction. The reaction mechanism was demonstrated via a deuterium-labelling

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8

Cloete, Jezreel. "Synthesis and applications of functionalized pyridinyl imine complexes of palladium." Thesis, University of the Western Cape, 2005. http://etd.uwc.ac.za/index.php?module=etd&amp.

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The synthesis and characterization of pyridinyl &alpha<br>-diimine Pd(II) complexes having a functionalized hydrocarbon attached to the imino nitrogen was performed. The catalytic activity of these complexes were then evaluated in the polymerization of ethylene and in the Heck coupling reaction of methyl acrylate with iodobenzene.<br /> <br /> Unconjugated &beta<br>-diimine complexes of palladium were also synthesized and their activities towards ethylene polymerization and the Heck coupling of methyl acrylate and iodobenzene also evaluated and compared to that of the &alpha<br>-diimine comple

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9

Wallner, Olov. "Palladium-Catalyzed Synthesis and Transformations of Organometallic Compounds." Doctoral thesis, Stockholm : Dept. of Organic Chemistry, Stockholm University, 2006. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-804.

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10

Tarlton, Stephen Vijay. "Low oxidation state compounds of palladium and platinum." Thesis, Imperial College London, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.300855.

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11

Zinser, Caroline Magdalene. "Palladium and gold N-heterocyclic carbene complexes : synthesis and catalytic applications." Thesis, University of St Andrews, 2019. http://hdl.handle.net/10023/17066.

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12

陳雁菁 and Suzanna Chan. "The chemistry of osmium-palladium carbonyl clusters." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1995. http://hub.hku.hk/bib/B31234628.

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13

Chan, Suzanna. "The chemistry of osmium-palladium carbonyl clusters /." Hong Kong : University of Hong Kong, 1995. http://sunzi.lib.hku.hk/hkuto/record.jsp?B18061576.

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14

Graves-Brook, Melissa Kaye. "Synthesis and characterization methods of palladium-doped ceria-zirconia compounds." Master's thesis, Mississippi State : Mississippi State University, 2005. http://sun.library.msstate.edu/ETD-db/ETD-browse/browse.

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15

Hill, Christopher M. "The synthesis of novel cluster compounds of palladium and platinum." Thesis, University of Oxford, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.334864.

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16

Worakun, Tanachat. "Palladium and rhodium catalysed construction of carbocyclic and heterocyclic compounds." Thesis, Queen's University Belfast, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.317069.

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17

Suginome, Michinori. "Bis-silylation of Unsaturated Compounds Catalyzed by Palladium-Isocyanide Complex." Kyoto University, 1993. http://hdl.handle.net/2433/74624.

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18

Masuda, Kohei. "New Synthetic Strategy of Organosilicon Compounds Utilizing Palladium-Silylene Species." 京都大学 (Kyoto University), 2011. http://hdl.handle.net/2433/142246.

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19

Moyo, Cyprian Bertrand. "Development of Palladium selective reagents and materials." Thesis, Nelson Mandela Metropolitan University, 2016. http://hdl.handle.net/10948/12231.

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The adsorption and separation of Pd(II) from Pt(IV), Ir(IV) and Rh(III) by silica microparticles functionalized with triethylenetetramine (TETA), 2-(2-aminoethylthio)ethanamine (NSN) and 2-(2-(2-aminoethyl)ethylthio)ethanamine (NSSN) in 1 M hydrochloric acid medium was investigated by continuous column studies. The functionalized sorbent materials were characterized by microanalysis, SEM-EDS and FT-IR. Palladium selectivity of the sorbent materials was achieved by stripping of rhodium, iridium and platinum chlorido species with 0.5 M of NaClO4 in 1 M HCl while [PdCl4]2 was eluted with 3% w/v t

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20

Marelli, Enrico. "Nickel- and palladium-catalysed deprotonative cross-couplings." Thesis, University of St Andrews, 2017. http://hdl.handle.net/10023/15603.

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Transition metal-catalysed cross coupling chemistry is a valuable tool for synthetic organic chemistry, enabling the preparation of compounds of great interest. The catalytic metal of choice is usually palladium, which generally offer better performances in term of catalytic activity and easy handling. On the other hand, the use of nickel in this class of reactions is gaining attention, as it would provide more economically and environmentally sustainable processes. Deprotonative cross couplings are a subgroup of these reactions, in which the nucleophile is generated in situ by direct deproton

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21

許穎思 and Wing-sze Janesse Hui. "The chemistry of mixed-metal clusters of osmium and palladium." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1998. http://hub.hku.hk/bib/B31237095.

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22

Hui, Wing-sze Janesse. "The chemistry of mixed-metal clusters of osmium and palladium /." Hong Kong : University of Hong Kong, 1998. http://sunzi.lib.hku.hk/hkuto/record.jsp?B19737749.

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23

Yue, Congyong. "Palladium complexes of aromatic amide-derived phosphines and application for synthesis of biaryls, nitrogen heterocycles, and benzo[b]furans /." View abstract or full-text, 2009. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202009%20YUE.

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24

Louw, Marissa. "New platinum and palladium complexes: their anticancer application." Thesis, Nelson Mandela Metropolitan University, 2010. http://hdl.handle.net/10948/d1016218.

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Novel non-leaving groups were employed in this dissertation to synthesize platinum complexes which can assist in the understanding or improvement of anticancer action. Emphasis was placed on (NS)-chelate and (NN)-chelate platinum complexes. Bidentate (NS)-donor ligands were used as non-leaving ligands in the synthesis of platinum(II) complexes with iodo, chloro, bromo and oxalato groups as leaving groups. These complexes were synthesized and studied since many questions regarding the interaction of sulfur-donors and platinum still exist. These relate to thermodynamic and kinetic factors and th

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25

Lo, Kai-yip, and 羅啟業. "Synthesis of aza-bicyclic compounds via palladium-catalyzed cascade cyclization reactions." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2012. http://hub.hku.hk/bib/B47849691.

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A palladium-catalyzed oxidative cascade cyclization reaction has been developed to prepare pyrrolizidine and indolizidine derivatives from simple aliphatic alkenyl amides 2.1ak in one step in moderate to good yields, using Pd(TFA)2 as the catalyst and molecular oxygen (1 atm) as a green oxidant. This cascade cyclization can also proceed for ring-containing unsaturated amides 2.1ln to afford azatricyclic systems. Palladium(II)-catalyzed dehydrohalogenation cascade cyclization reactions have been developed to synthesize polycyclic pyrrolizidine derivatives from iodoalkenylanilides 4.1ai

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26

Chen, Nan. "Kinetics of the hydrodechlorination reaction of chlorinated compounds on palladium catalysts." Link to electronic thesis, 2003. http://www.wpi.edu/Pubs/ETD/Available/etd-0823103-161859.

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27

Du, Wei, and 杜玮. "Palladium-catalyzed oxidative cascade cyclizations via C-N/C-C formation for synthesis of nitrogen heterocycles." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/206320.

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28

Yung, Ka-fu, and 容家富. "The chemistry of osmium-palladium mixed-metal nanoclusters and nanoparticles." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2003. http://hub.hku.hk/bib/B31245067.

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29

Champkin, Paul Anthony. "A structural and electronic study of novel palladium bis-phosphate complexes." Thesis, University of Newcastle Upon Tyne, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.391274.

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30

Tao, Chi-hang, and 陶志恆. "Synthesis and luminescence studies of branched carbonrich platinum(II)and palladium(II) alkynyl complexes: versatile building blocks for multinuclear assemblies." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2004. http://hub.hku.hk/bib/B31246011.

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31

Shaffer, Andrew Ronald. "Synthesis, reactivity, and catalysis of 3-iminophosphine palladium complexes /." Connect to full text in OhioLINK ETD Center, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=toledo1248288981.

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Thesis (Ph. D.)--University of Toledo, 2009.<br>Typescript. "Submitted as partial fulfillment of the requirements for the Doctor of Philosophy in Chemistry." Includes bibliographical references (leaves 183-217).

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32

Damian, Karen Serena. "Pd catalysed synthesis of phosphines for homogeneous catalysis." Thesis, St Andrews, 2009. http://hdl.handle.net/10023/907.

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33

Stürzer, Christine [Verfasser], and Dirk [Akademischer Betreuer] Johrendt. "Calcium Iron Palladium Arsenides and related compounds / Christine Stürzer. Betreuer: Dirk Johrendt." München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2015. http://d-nb.info/107698102X/34.

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34

Aparece, Mark Docto. "Synthesis of Organoboron Compounds via a Palladium-Induced 1,2-Metallate Shift Mechanism:." Thesis, Boston College, 2020. http://hdl.handle.net/2345/bc-ir:108927.

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Thesis advisor: James P. Morken<br>This dissertation describes the development of various palladium-catalyzed syntheses of organoboron compounds with the 1,2-metallate shift of organoboron “ate” complexes as a common mechanistic feature. Chapter one discusses the history of the 1,2-metallate shift with a focus on reactions promoted by transition metals, followed by my work on the palladium-catalyzed, enantioselective, halide-tolerant conjunctive cross-coupling reaction to enable the use of Grignard reagents and arylbromides. Chapter two discusses the attempt to engage allylic electrophiles in

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35

Son, Eun-Cheol. "Exploitation of some palladium-catalyzed coupling reactions of aryltriazenes or arylsilicon compounds." 京都大学 (Kyoto University), 2006. http://hdl.handle.net/2433/144020.

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Kyoto University (京都大学)<br>0048<br>新制・課程博士<br>博士(工学)<br>甲第12334号<br>工博第2663号<br>新制||工||1376(附属図書館)<br>24170<br>UT51-2006-J326<br>京都大学大学院工学研究科物質エネルギー化学専攻<br>(主査)教授小澤文幸, 教授檜山爲次郎, 教授杉野目道紀<br>学位規則第4条第1項該当

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36

曾炳堯 and Biing-chiau Tzeng. "Design, structures, spectroscopic, and photophysical properties of supramoleculsar gold(I), platinum(II), and palladium(II) complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1998. http://hub.hku.hk/bib/B31237782.

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37

Tzeng, Biing-chiau. "Design, structures, spectroscopic, and photophysical properties of supramoleculsar gold(I), platinum(II), and palladium(II) complexes /." Hong Kong : University of Hong Kong, 1998. http://sunzi.lib.hku.hk/hkuto/record.jsp?B19471397.

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38

劉曉霞 and Xiaoxia Liu. "Coordination Chemistry of 1,2-naphthoquinone-mono-oxime withruthenium, rhodium and palladium." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2000. http://hub.hku.hk/bib/B3124063X.

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39

Liu, Xiaoxia. "Coordination Chemistry of 1,2-naphthoquinone-mono-oxime with ruthenium, rhodium and palladium /." Hong Kong : University of Hong Kong, 2000. http://sunzi.lib.hku.hk/hkuto/record.jsp?B2168781X.

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40

Dostert, Karl-Heinz. "Selectivity in hydrogenation of alpha, beta-unsaturated carbonyl compounds on model palladium catalysts." Doctoral thesis, Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät, 2015. http://dx.doi.org/10.18452/17399.

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Die Umsetzung von alpha,beta-ungesättigten Aldehyden und Ketonen mit Wasserstoff über Pd-Modellkatalysatoren wurde anhand von Molekularstrahlmethoden, kombiniert mit Infrarot-Reflexions-Absorptions-Spektroskopie (IRAS), Quadrupol-Massenspektrometrie (QMS) und Röntgen-Nahkanten-Absorptions-Spektroskopie (NEXAFS), unter wohldefinierten Ultrahochvakuumbedingungen untersucht. Das Ziel dieser Arbeit war es, ein atomistisches Verständnis der strukturellen Faktoren zu gewinnen, die die Aktivität und Selektivität eines Pd(111)-Einkristalls und Eisenoxid-geträgerter Pd-Nanopartikel für die Hydrierung d

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41

Akintomide, Temiloluwa Selby Trent Dale. "Synthesis, characterization and properties of rigid macromolecules with extended conjugation, using palladium-catalyzed, alkynylated polyhaloarenes." [Denton, Tex.] : University of North Texas, 2007. http://digital.library.unt.edu/permalink/meta-dc-5206.

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42

Tang, Hau-san. "Design and synthesis of metal phosphine complexes of palladium(II) and gold(I) with various receptor ligands for ion-controlled or photoresponsive host-guest chemistry." Click to view the E-thesis via HKUTO, 2006. http://sunzi.lib.hku.hk/hkuto/record/B37877422.

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43

Smythe, Nicole. "Reactivity studies of platinum(IV) hydroxide and methoxide complexes and the study of pincer palladium(II) complexes as potential catalysts for olefin epoxidation /." Thesis, Connect to this title online; UW restricted, 2004. http://hdl.handle.net/1773/8618.

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44

Hung, Faan-fung, and 孔繁峰. "Luminescent platinum(II), palladium(II) and gold(III) complexes containing isocyanide, alkynyl and N-heterocyclic carbene ligands : synthesis, photophysical properties and material applications." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/206318.

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45

Banini, Serge R. "Palladium-catalyzed syntheses of indoles, pyrroloindoles, quinolines a base-mediated formation of N-alkoxyindoles, and progress toward the first total synthesis of echinosulfone A /." Morgantown, W. Va. : [West Virginia University Libraries], 2008. https://eidr.wvu.edu/etd/documentdata.eTD?documentid=5710.

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Thesis (Ph. D.)--West Virginia University, 2008.<br>Title from document title page. Document formatted into pages; contains xv, 275 p. : ill. Includes abstract. Includes bibliographical references (p. 107-113).

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46

Açıkel, Müge Artok Levent. "Silica Supported N-Heterocyclic Carbenes:Active and Reusable Heterogeneous Catalysts for Mizoroki-Heck Reactions/." [s.l.]: [s.n.], 2004. http://library.iyte.edu.tr/tezler/master/kimya/T000496.pdf.

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47

Dohanosova, Jana. "Domino reactions. Asymmetric palladium(II)-catalyzed cyclizations-carbonylations in the synthesis of natural compounds." Thesis, Paris 11, 2012. http://www.theses.fr/2012PA112082/document.

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La réaction de cyclisation de type Wacker, de composés polyols et aminopolyols insaturés constitue un outil puissant et efficace pour la synthèse d’hétérocycles oxygénés ou azotés.Dans ce travail de thèse, nous proposons l’étude d’une réaction catalysée par un complexe de palladium(II) de type domino-cyclisation, mettant en jeu une réaction de couplage. Cette séquence catalytique revient à une fonctionnalisation d’un hétérocycle par une chaîne latérale, tout en créant deux centres stéréogènes en une seule étape. L’influence de la nature des réactifs mis en jeu, ainsi que des conditions expérim

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48

Otsuka, Shinya. "Studies on Catalytic Transformations of Organosulfur Compounds via C-S Bond Cleavage." Kyoto University, 2019. http://hdl.handle.net/2433/242625.

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49

Daghriri, Hassan. "Studies on Tumour Active Compounds with Multiple Metal Centres." University of Sydney. Biomedical Sciences, 2004. http://hdl.handle.net/2123/595.

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Four tumour active trinuclear complexes: DH4Cl: [{trans-PtCl(NH3)2}2m-{trans-Pd( NH3)2(H2N(CH2)4NH2)2]Cl4, DH5Cl: [{trans-PtCl(NH3)2}2m-{trans-Pd( NH3)2(H2N(CH2)5NH2)2]Cl4, DH6Cl: [{trans-PtCl(NH3)2}2m-{trans-Pd( NH3)2(H2N(CH2)6NH2)2]Cl4, DH7Cl: [{trans-PtCl(NH3)2}2m-{trans-Pd(NH3)2-( H2N(CH2)7NH2)2]Cl4 and one dinuclear complex DHD: [{trans-PtCl(NH3)2}�-{ H2N(CH2)6NH2}{trans-PdCl(NH3)2]Cl(NO3), have been prepared and characterised based on elemental analyses, IR, Raman, mass and 1 H NMR spectral measurements. For the trinuclear complexes, the synthesis has been carried out using a step

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50

Daghriri, Hassan. "Studies on Tumour Active Compounds with Multiple Metal Centres." Thesis, The University of Sydney, 2003. http://hdl.handle.net/2123/595.

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Four tumour active trinuclear complexes: DH4Cl: [{trans-PtCl(NH3)2}2m-{trans-Pd( NH3)2(H2N(CH2)4NH2)2]Cl4, DH5Cl: [{trans-PtCl(NH3)2}2m-{trans-Pd( NH3)2(H2N(CH2)5NH2)2]Cl4, DH6Cl: [{trans-PtCl(NH3)2}2m-{trans-Pd( NH3)2(H2N(CH2)6NH2)2]Cl4, DH7Cl: [{trans-PtCl(NH3)2}2m-{trans-Pd(NH3)2-( H2N(CH2)7NH2)2]Cl4 and one dinuclear complex DHD: [{trans-PtCl(NH3)2}�-{ H2N(CH2)6NH2}{trans-PdCl(NH3)2]Cl(NO3), have been prepared and characterised based on elemental analyses, IR, Raman, mass and 1 H NMR spectral measurements. For the trinuclear complexes, the synthesis has been carried out using a step

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