Academic literature on the topic 'Palladium hydride'

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Journal articles on the topic "Palladium hydride"

1

Zhirov, Gregory I., and Mariya V. Goltsova. "Hydrogen-phase naklep as a result of single isothermal hydride transformations." Journal of the Belarusian State University. Physics, no. 1 (January 27, 2022): 65–74. http://dx.doi.org/10.33581/2520-2243-2022-1-65-74.

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Hydrogen treatment of metallic materials is a promising area of controlled hydrogen action on metals and alloys in order to impart special properties to them. In this work, the changes in the mechanical properties of palladium during single hydride transformations, which are initiated in the initially non-nakleped palladium hydride, have been experimentally studied. Were investigated wire palladium samples with a purity of 99.98 %, a diameter of 0.5 mm and a length of 165 mm. Samples for research were preliminarily subjected to hydrogen treatment, and then mechanical tests were carried out. Th
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2

Kimber, Marc, Yassir Al-Jawaheri, and Matthew Turner. "Enabling the Rearrangement of Unactivated Allenes to 1,3-Dienes by Use of a Palladium (0)/Boric Acid System." Synthesis 50, no. 12 (2018): 2329–36. http://dx.doi.org/10.1055/s-0036-1591580.

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A redox neutral rearrangement of an allene to a 1,3-diene by means of a unique palladium hydride complex is reported. The palladium hydride complex is generated from a simple Pd0 source and boric acid [B(OH)3], which is typically identified as a waste by-product of the Suzuki–Miyaura reaction. A mechanism for this transformation using this novel palladium hydride complex is presented; using a direct sample loop and flow injection ESI-HRMS analysis we have detected and identified key π-allylpalladium complexes that support the addition of the palladium hydride complex to the allene.
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3

Kirichkov, Mikhail V., Aram L. Bugaev, Alina A. Skorynina та ін. "In Situ Time-Resolved Decomposition of β-Hydride Phase in Palladium Nanoparticles Coated with Metal-Organic Framework". Metals 10, № 6 (2020): 810. http://dx.doi.org/10.3390/met10060810.

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The formation of palladium hydrides is a well-known phenomenon, observed for both bulk and nanosized samples. The kinetics of hydrogen adsorption/desorption strongly depends on the particle size and shape, as well as the type of support and/or coating of the particles. In addition, the structural properties of hydride phases and their distribution also depend on the particle size. In this work, we report on the in situ characterization of palladium nanocubes coated with HKUST-1 metal-organic framework (Pd@HKUST-1) during desorption of hydrogen by means of synchrotron-based time-resolved X-ray
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4

DeLuca, Ryan J., Benjamin J. Stokes, and Matthew S. Sigman. "The strategic generation and interception of palladium-hydrides for use in alkene functionalization reactions." Pure and Applied Chemistry 86, no. 3 (2014): 395–408. http://dx.doi.org/10.1515/pac-2014-5041.

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Abstract We review methods that our lab has developed for the generation of Pd-hydrides and the manipulation of these useful intermediates via β-hydride elimination and migratory insertion steps. For a given alkene functionalization reaction, careful understanding of the dynamics of β-hydride elimination, migratory insertion, and transmetallation have allowed for the selective functionalization of Pd-alkyl intermediates. This has afforded us a means by which to transpose palladium to a desired position on a substrate for subsequent functionalization, empowering a number of useful C–H, C–O, and
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5

Stolyarov, I. P., T. A. Stromonova, V. P. Zagorodnikov, et al. "Palladium carbonyl hydride complexes." Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 35, no. 4 (1986): 860–62. http://dx.doi.org/10.1007/bf00954251.

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6

Goods, S. H., and S. E. Guthrie. "Mechanical properties of palladium and palladium hydride." Scripta Metallurgica et Materialia 26, no. 4 (1992): 561–65. http://dx.doi.org/10.1016/0956-716x(92)90284-l.

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7

Nakata, Norio, Noriko Sekizawa, and Akihiko Ishii. "Cationic dinuclear platinum and palladium complexes with bridging hydrogermylene and hydrido ligands." Chemical Communications 51, no. 50 (2015): 10111–14. http://dx.doi.org/10.1039/c5cc03062e.

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New cationic (μ-hydrido)(μ-germyl) diplatinum and dipalladium complexes, [{M(dcpe)}<sub>2</sub>(μ-H)(μ-GeHTrip)]<sup>+</sup> (M = Pt, Pd), were prepared by hydride-abstraction reactions of [MH(GeH<sub>2</sub>Trip)(dcpe)] with B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>.
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8

Kawae, Tatsuya, Yuji Inagaki, Si Wen, Souhei Hirota, Daiki Itou, and Takashi Kimura. "Superconductivity in Palladium Hydride Systems." Journal of the Physical Society of Japan 89, no. 5 (2020): 051004. http://dx.doi.org/10.7566/jpsj.89.051004.

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9

Lisowski, W. "Oxygen interaction with palladium hydride and titanium hydride surfaces." Surface Science 322, no. 1-3 (1995): 285–92. http://dx.doi.org/10.1016/0039-6028(94)00598-2.

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10

Duś, R., W. Lisowski, E. Nowicka, and Z. Wolfram. "Oxygen interaction with palladium hydride and titanium hydride surfaces." Surface Science 322, no. 1-3 (1995): 285–92. http://dx.doi.org/10.1016/0039-6028(95)90037-3.

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