Academic literature on the topic 'Palladium-mediated cross-coupling'

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Journal articles on the topic "Palladium-mediated cross-coupling"

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Burt, Liam K., Richard L. Cordiner, Anthony F. Hill, Richard A. Manzano, and Jörg Wagler. "The significance of phosphoniocarbynes in halocarbyne cross-coupling reactions." Chemical Communications 56, no. 42 (2020): 5673–76. http://dx.doi.org/10.1039/d0cc02070b.

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Competent intermediates as well as productive and non-productive tangents have been identified in the catalytic cycle for palladium(0)–copper(i) mediated synthesis of propargylidynes via cross coupling reactions of bromocarbyne complexes with alkynes.
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Camp, Jason, Thomas Bousfield, Jay Dunsford, et al. "Dehydrative Cross-Coupling of 1-Phenylethanol Catalysed by Palladium Nanoparticles Formed in situ Under Acidic Conditions." Synthesis 50, no. 19 (2018): 3862–74. http://dx.doi.org/10.1055/s-0037-1610246.

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A dehydrative cross-coupling of 1-phenylethanol catalysed by sugar derived, in situ formed palladium(0) nanoparticles under acidic conditions is realised. The acidic conditions allow for use of alcohols as a feedstock in metal-mediated coupling reactions via their in situ dehydration and subsequent cross-coupling. Extensive analysis of the size and morphology of the palladium nanoparticles formed in situ showed that the zero-valent metal was surrounded by hydrophilic hydroxyl groups. EDX-TEM imaging studies using a prototype silicon drift detector provided insight into the problematic role of
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Sakata, Komei, Daisuke Urabe та Masayuki Inoue. "Preparation and palladium-mediated cross-coupling of α-benzoyloxyalkylzinc bromides". Tetrahedron Letters 54, № 32 (2013): 4189–92. http://dx.doi.org/10.1016/j.tetlet.2013.05.114.

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Hillier, Anna C., Gabriela A. Grasa, Mihai S. Viciu, Hon Man Lee, Chuluo Yang, and Steven P. Nolan. "Catalytic cross-coupling reactions mediated by palladium/nucleophilic carbene systems." Journal of Organometallic Chemistry 653, no. 1-2 (2002): 69–82. http://dx.doi.org/10.1016/s0022-328x(02)01154-3.

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Grasa, Gabriela A., Mihai S. Viciu, Jinkun Huang, Chunming Zhang, Mark L. Trudell, and Steven P. Nolan. "Suzuki−Miyaura Cross-Coupling Reactions Mediated by Palladium/Imidazolium Salt Systems." Organometallics 21, no. 14 (2002): 2866–73. http://dx.doi.org/10.1021/om020178p.

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Indrigo, Eugenio, Jessica Clavadetscher, Sunay V. Chankeshwara, Annamaria Lilienkampf, and Mark Bradley. "Palladium-mediated in situ synthesis of an anticancer agent." Chemical Communications 52, no. 99 (2016): 14212–14. http://dx.doi.org/10.1039/c6cc08666g.

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Farina, Vittorio, and Gregory P. Roth. "Catalyst tailoring for palladium-mediated cross coupling of arylstannanes with vinyl triflates." Tetrahedron Letters 32, no. 34 (1991): 4243–46. http://dx.doi.org/10.1016/s0040-4039(00)92138-5.

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Hillier, Anna C., Gabriela A. Grasa, Mihai S. Viciu, Hon Man Lee, Chuluo Yang, and Steven P. Nolan. "ChemInform Abstract: Catalytic Cross-Coupling Reactions Mediated by Palladium/Nucleophilic Carbene Systems." ChemInform 33, no. 39 (2010): no. http://dx.doi.org/10.1002/chin.200239248.

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Böck, Katharina, Julia E. Feil, Konstantin Karaghiosoff, and Konrad Koszinowski. "Catalyst Activation, Deactivation, and Degradation in Palladium-Mediated Negishi Cross-Coupling Reactions." Chemistry - A European Journal 21, no. 14 (2015): 5548–60. http://dx.doi.org/10.1002/chem.201406408.

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Zhao, Zijian, Qiao Zhu, Shiying Che, Zhenghong Luo, and Yan Lian. "Palladium/nickel-mediated cross coupling reaction between phosphorylamides and alkenes toward enephosphorylamides." Synthetic Communications 50, no. 15 (2020): 2338–46. http://dx.doi.org/10.1080/00397911.2020.1774903.

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Dissertations / Theses on the topic "Palladium-mediated cross-coupling"

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Singh, Rohit. "Development of N-Heterocyclic Carbenes as Organic Catalysts and Efficient Ligands in Palladium Mediated Transformations." ScholarWorks@UNO, 2007. http://scholarworks.uno.edu/td/576.

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N-Heterocyclic carbenes (NHCs) have emerged as appropriate replacements for phosphines in transition metal catalyzed cross-coupling chemistry. The advantages of NHCs over phosphines include ease of handling, minimal toxicity, stability and powerful electron donating properties. Improvement of catalytic processes has become increasingly relevant in light of prospective applications of organic transformations in industry as well as in synthetic laboratories. To that end, NHCs represent an important class of catalysts and catalyst modifiers which mandate continued research efforts. Prospect
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Clavadetscher, Jessica Veronica. "Transition metal catalysis : a new paradigm in bioorthogonal drug activation." Thesis, University of Edinburgh, 2017. http://hdl.handle.net/1842/29580.

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Powerful tools have emerged in the past few years to allow the sensing, imaging and modulation of biological processes in living systems. Bioorthogonal organometallic reactions are transformations catalysed by transition metals, which are compatible within a biological environment. Palladium-mediated cross-coupling and decaging reactions, for example, have been successfully applied to catalyse non-natural chemical transformations within a biological milieu. Up until now, copper-catalysed cycloaddition reactions have been used extensively for the conjugation, immobilisation, and purification of
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Eriksson, Ludvig. "Transition Metal Mediated Transformations of Carboranes." Doctoral thesis, Uppsala University, Organic Chemistry, 2003. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-3324.

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<p>This thesis describes the use of copper and palladium to mediate transformations of carboranes, especially <i>p</i>-carborane.</p><p>1-(1-<i>p</i>-carboranyl)-<i>N</i>-methyl-<i>N</i>-(2-butyl)-3-isoquinolinecarboxamide, a carborane containing analogue of the peripheral benzodiazepine receptor (PBR) ligand PK11195, has been synthesised. A key step in the reaction is the copper (I) mediated coupling of p-carborane with ethyl 1-bromo-isoquinoline-3-carboxylate. </p><p><i>p</i>-Carborane has been arylated on the 2-<i>B</i>-atom in high yields, using the Suzuki–Miyaura reaction. Thus the reacti
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Kang, Jun. "Chromium-Catalyzed Homoaldol Equivalent Reaction, Indium-Mediated Cycloisomerization, and Palladium-Catalyzed Cross-Coupling Reaction." Thesis, 2011. http://hdl.handle.net/1969.1/ETD-TAMU-2011-08-77.

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The homoaldol reaction is one of the most powerful methods for the construction of C–C bonds as well as 1,4-oxygenated compounds yet this reaction remains in challenging tasks due to the instability of homoenolates which spontaneously cyclize to the cyclopropanolate. A regioselective catalytic homoaldol equivalent reaction of 3-bromo vinyl acetate with aldehydes under Cr(III)-Mn(0) redox condition was developed. This homoaldol equivalent reaction allows access to the 1,4-oxygenated compounds that are not possible by a conventional aldol process. Mild hydrolysis of the vinyl acetate and reducti
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Books on the topic "Palladium-mediated cross-coupling"

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Loo, Richard William. The preparation of C-aryl glucals via palladium mediated cross-coupling reactions. National Library of Canada = Bibliothèque nationale du Canada, 1992.

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Book chapters on the topic "Palladium-mediated cross-coupling"

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Whitehead, A., S. R. Sieck, S. Mukherjee, and P. R. Hanson. "Palladium-Mediated Cross-Coupling Reactions." In Three Carbon-Heteroatom Bonds: Esters and Lactones; Peroxy Acids and R(CO)OX Compounds; R(CO)X, X=S, Se, Te. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-021-00955.

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Maestri, G., and A. Serafino. "1.14 Palladium(I)-Mediated Reactions." In Free Radicals: Fundamentals and Applications in Organic Synthesis 1. Georg Thieme Verlag KG, 2021. http://dx.doi.org/10.1055/sos-sd-234-00313.

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AbstractSeveral elegant reactivities can be observed in reactions involving palladium(I) species, allowing access to molecular architectures that are often beyond the capabilities of popular diamagnetic palladium complexes. This review presents three main axes of research in this context, which have mostly emerged in the last decade. Reactions promoted by visible light enable synthetic methods that are unusual in their mild experimental conditions coupled with remarkably broad functional group tolerance. The use of discrete palladium(I) dimers as precatalysts allows one to perform a wide set of cross-coupling protocols, such as Kumada and Negishi reactions, and chalcogenation reactions, with a surgical precision on the carbon—halogen bond that is initially activated. The generation of alkyl radicals and palladium(I) species through a thermal strategy proves useful for the elaboration of substrates with several polyfluorinated fragments, which are otherwise elusive coupling partners for more common two-electron processes.
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Aubert, C., M. Malacria, and C. Ollivier. "Palladium(0)-Mediated [2 + 2 + 2] Carbocyclizations." In Stereoselective Pericyclic Reactions, Cross Coupling, and C—H and C—X Activation. Georg Thieme Verlag KG, 2011. http://dx.doi.org/10.1055/sos-sd-203-00142.

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Wyatt, P. B. "Amides by Palladium-Mediated Cross Coupling of Stannanecarboxamides with Aryl and Alkenyl Halides." In Compounds of Group 14 (Ge, Sn, Pb). Georg Thieme Verlag KG, 2003. http://dx.doi.org/10.1055/sos-sd-005-00393.

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