Academic literature on the topic 'Palladium, rhodium'

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Journal articles on the topic "Palladium, rhodium"

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Zagula-Yavorska, Maryana. "Oxidation Behavior of Non-Modified and Rhodium- or Palladium-Modified Aluminide Coatings Deposited on CMSX-4 Superalloy." Metals 8, no. 8 (2018): 613. http://dx.doi.org/10.3390/met8080613.

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Rhodium-modified as well as palladium-modified and non-modified aluminide coatings on CMSX-4 Ni-based superalloy were oxidized in air atmosphere at 1100 °C. Uncoated substrate of CMSX-4 superalloy was also oxidized. The microstructure of coatings before oxidation consists of two layers: an additive and an interdiffusion one. The NiAl intermetallic phase was found in the microstructure of non-modified coatings, while the (Ni,Rh)Al intermetallic phase was observed in the microstructure of rhodium-modified aluminide coatings before oxidation. The (Ni,Pd)Al phase of palladium-modified aluminide co
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Hartwig, J. F. "Development of catalysts for the hydroamination of olefins." Pure and Applied Chemistry 76, no. 3 (2004): 507–16. http://dx.doi.org/10.1351/pac200476030507.

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Studies on the development of palladium, nickel, and rhodium catalysts for the hydroamination of dienes and vinylarenes are described. Enantioselective catalysts based on palladium have been developed for the addition of arylamines to dienes and for Markovnikov addition of arylamines to vinylarenes. In addition, nickel catalysts for the addition of aliphatic amines to dienes have been developed, and rhodium catalysts for the first transition metal-catalyzed aminations of vinylarenes that generate terminal amines as the major product are described. Mechanistic data on the hydroamination of viny
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Ren, Li, Austin C. Chen, Andreas Decken, and Cathleen M. Crudden. "Chiral bidentate N-heterocyclic carbene complexes of Rh and Pd." Canadian Journal of Chemistry 82, no. 12 (2004): 1781–87. http://dx.doi.org/10.1139/v04-165.

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The synthesis of a new chiral, bidentate oxazoline/imidazolidene carbene precursor is described. This species is reacted with various metal salts in the presence of a base to generate rhodium and palladium complexes, which are characterized spectroscopically and crystallographically.Key words: chiral N-heterocyclic carbene, rhodium, palladium, oxazolidine, asymmetric catalysis.
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Weber, W. H., R. J. Baird, and G. W. Graham. "Raman investigation of palladium oxide, rhodium sesquioxide and palladium rhodium dioxide." Journal of Raman Spectroscopy 19, no. 4 (1988): 239–44. http://dx.doi.org/10.1002/jrs.1250190404.

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Akkarasamiyo, Sunisa, Somsak Ruchirawat, Poonsaksi Ploypradith та Joseph S. M. Samec. "Transition-Metal-Catalyzed Suzuki–Miyaura-Type Cross-Coupling Reactions of π-Activated Alcohols". Synthesis 52, № 05 (2020): 645–59. http://dx.doi.org/10.1055/s-0039-1690740.

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The Suzuki–Miyaura reaction is one of the most powerful tools for the formation of carbon–carbon bonds in organic synthesis. The utilization of alcohols in this powerful reaction is a challenging task. This short review covers progress in the transition-metal-catalyzed Suzuki­–Miyaura-type cross-coupling reaction of π-activated alcohol, such as aryl, benzylic, allylic, propargylic and allenic alcohols, between 2000 and June 2019.1 Introduction2 Suzuki–Miyaura Cross-Coupling Reactions of Aryl Alcohols2.1 One-Pot Reactions with Pre-activation of the C–O Bond2.1.1 Palladium Catalysis2.1.2 Nickel
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Teter, D. F., R. D. Field, and D. J. Thoma. "Hydrogen-Induced Phase Separation of Palladium-Rhodium Alloys Using an Environmental Cell TEM." Microscopy and Microanalysis 3, S2 (1997): 591–92. http://dx.doi.org/10.1017/s1431927600009843.

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The palladium-rhodium system has been extensively studied for its hydrogen absorption characteristics. However, the phase diagram of the palladium-rhodium system has not been conclusively determined below 800 K. Shield and Williams have experimentally determined the incoherent miscibility gap in Pd-Rh alloys using electrical resistivity studies, however the coherent miscibility gap and spinodal have not been determined. Recently work by Noh and Flanagan has suggested that hydrogen enhances metal atom mobility and may increase the kinetics of phase separation in Pd-Rh alloys. Field and Thoma fo
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Fedoseev, I. V., V. V. Vasekin, and N. V. Rovinskaya. "Hydrocarbonyl Processes for Conversion of Platinum-Rhodium-Palladium Alloys : Technological possibilities of a new process for pgms extraction." Johnson Matthey Technology Review 64, no. 1 (2020): 42–47. http://dx.doi.org/10.1595/205651320x15700992885660.

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A novel process for the recovery of platinum group metals (pgms) from ternary alloys using a hydrocarbonyl process is proposed. The hydrocarbonyl process involves treatment of a chloride solution of the pgms with carbon monoxide at ambient pressure. The results demonstrate that the process can provide high purity pgms from a ternary platinum-rhodium-palladium alloy such as that obtained from palladium-nickel catchment alloys used with platinum-rhodium gauzes during high temperature ammonia oxidation.
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Kleykamp, Heiko, and Sung-Goon Kang. "The Constitution of the Uranium-Palladium and Uranium-Rhodium-Palladium Systems / Der Aufbau der Systeme Uran-Palladium und Uran-Rhodium-Palladium." International Journal of Materials Research 82, no. 7 (1991): 544–52. http://dx.doi.org/10.1515/ijmr-1991-820707.

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Bálint, Erika, Ádám Tajti, Anna Tripolszky та György Keglevich. "Synthesis of platinum, palladium and rhodium complexes of α-aminophosphine ligands". Dalton Transactions 47, № 14 (2018): 4755–78. http://dx.doi.org/10.1039/c8dt00178b.

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McMinn, A., R. Viswanathan, and C. L. Knauf. "Field Evaluation of Gas Turbine Protective Coatings." Journal of Engineering for Gas Turbines and Power 110, no. 1 (1988): 142–49. http://dx.doi.org/10.1115/1.3240077.

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The hot corrosion resistance of several protective coatings that had been applied to MAR-M-509 nozzle guide vanes and exposed in a utility gas turbine has been evaluated. The coatings included basic aluminide, rhodium-aluminide, platinum-rhodium-aluminide, and palladium-aluminide diffusion coatings, and cobalt-chromium-aluminum-yttrium (CoCrAlY) and ceramic overlay coatings. A combination of metallographic examination of vane cross sections and energy dispersive X-ray analysis (EDS) was employed in the evaluation. The results showed that none of the coatings was totally resistant to corrosive
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Dissertations / Theses on the topic "Palladium, rhodium"

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Haaren, Richard Johannes van. "Palladium and rhodium allyl complexes in catalysis." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2002. http://dare.uva.nl/document/64738.

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Hoogervorst, Wilhelmus Johannes. "Isophthalaldimine compounds of palladium, platinum and rhodium." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2003. http://dare.uva.nl/document/69284.

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Baiden, Joseph Eshun. "The structure of uranium-palladium-rhodium alloys." Thesis, University of Surrey, 1985. http://epubs.surrey.ac.uk/847229/.

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The structure and phases of alloys of uranium and two of the light platinum metals, Pd and Rh have been studied. Using X-ray diffraction, metallography and electron microscopy, the phase diagram of the noble metal-rich end of the ternary system, U-Pd-Rh has been established. Portions of the binary systems, U-Pd and U-Rh have also been studied and the Pd-Rh phase diagram re-established. The structure of the solid phases which are stable at 1050°C, 1150°C and 1250°C have been determined. A thermodynamic calculation of the isothermal sections of the ternary U-Pd-Rh system at 1350°
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Palucci, Benedetta. "Rhodium and Palladium Catalysed Unusual Regioselective Hydroformylation and Rhodium Catalysed Reductive Carbonylation." Doctoral thesis, Universitat Rovira i Virgili, 2020. http://hdl.handle.net/10803/670491.

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La present tesi doctoral té com a objectiu el desenvolupament de sistemes per aconseguir una regioselectivitat no convencional en l’hidroformilació d'alquens terminals. Degut a que nombroses substàncies naturals perfumades contenen un grup aldehid. Els processos d’hidroformilació, on es fan reaccionar monòxid de carboni i hidrogen amb olefines, han esdevenit mètodes inestimables per a les empreses de fragàncies per a la producció d’aquests derivats. La regioselectividad del procés, per a l’obtenció del producte lineal o ramificat, és extremadament dependent del substrat. Com a tendència genera
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Vicente, Aurélie. "Hydrogénation du citral sur catalyseurs bimétalliques supportés rhodium-germanium, palladium-germanium et palladium-étain." Poitiers, 2008. http://www.theses.fr/2008POIT2338.

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Ce travail est consacré à la préparation de catalyseurs bimétalliques supportés Rh-Ge, Pd-Ge et Pd-Sn pour l’hydrogénation sélective du citral en alcools a,b-insaturés. Pour les catalyseurs à base de Rh, l’étude porte sur l’influence de la nature des sels précurseurs utilisés. L’existence d’interactions entre les deux métaux des différents systèmes bimétalliques est mise en évidence par diverses techniques de caractérisation (EDX, réaction modèle de déshydrogénation du cyclohexane, RTP sous H2, IRTF de CO adsorbé). La réaction d’hydrogénation sélective du citral a montré qu’il est possible de
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Barletta, Julien. "[11C]Carbon Monoxide in Rhodium-/Palladium-Mediated Carbonylation Reactions." Doctoral thesis, Uppsala universitet, Institutionen för biokemi och organisk kemi, 2006. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-6654.

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Methods for the 11C-labeling of carbonyl compounds applicable in the preparation of radiotracers for Positron Emission Tomography (PET) are described. To this end [11C]carbon monoxide at low concentration was used in transition metal- mediated reactions. Stille couplings were employed in the synthesis of [carbonyl-11C]ketones from methyl and aryl halides with [11C]carbon monoxide. The synthesized [carbonyl-11C]ketones were obtained from the corresponding organostannanes with analytical radiochemical yields up to 98%. A number of synthetic routes were designed using [11C]carbon monoxide and rho
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Rudkin, Christopher Julian. "Surface organometallic chemistry of rhodium and palladium on titania." Thesis, University of Southampton, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.242666.

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Stahlhut, Rainer. "Synthese von ligandstabilisierten bimetallischen Palladium-Rhodium- und Platin-Rhodium-Nanoteilchen und deren Verwendung als Katalysatoren zur Wechselwirkung der Metalle bei bimetallischen, schalenförmigen Kolloiden /." [S.l.] : [s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=96494409X.

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Hilpert, Lukas [Verfasser]. "Rhodium- & Palladium-Katalysierte Hydrofunktionalisierungen von Internen Allenen / Lukas Hilpert." München : Verlag Dr. Hut, 2019. http://d-nb.info/1200754921/34.

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Worakun, Tanachat. "Palladium and rhodium catalysed construction of carbocyclic and heterocyclic compounds." Thesis, Queen's University Belfast, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.317069.

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Books on the topic "Palladium, rhodium"

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Tuwati, Abdulwahab. The determination of platinum, palladium and rhodium in autocatalysts using a gold bead collection method with final analysis by ICP. s.n.], 1993.

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Richardson, Troy. A semi-quantitative method for the rapid determination of gold, platinum, palladium and rhodium in geological materials using a small sample mass. Laurentian University, School of Graduate Studies, 2004.

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Payette, Mark. The determination platinum, palladium and rhodium in autocatalyst. An exploration of sample preparation techniques for the rapid sequential multi-elemental ICP-MS analysis. Laurentian University, Chemistry and Biochemistry Department, 1997.

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Azikiwe, Nnamdi. Melanin Is Worth More Than Gold: Is This The Era of the Blessed Generation? The Mhotep Corporation, 2020.

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Worakun, Tanachat. Palladium and rhodium catalysed construction of carbocyclic and heterocyclic compounds. 1987.

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Howe, Jas Lewis, and H. C. Holtz. Bibliography of the Metals of the Platinum Group - Platinum, Palladium, Iridium, Rhodium, Osmium, Ruthenium. Wexford College Press, 2006.

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Feasibility of Separation and Utilization of Ruthenium, Rhodium and Palladium from High Level Wastes (Technical Report Series). International Atomic Energy Agency (IAEA), 1989.

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8

L, Meier Allen, Carlson Robert R, and Geological Survey (U.S.), eds. Analytical results for platinum, palladium, rhodium, ruthenium, and iridium in rock samples from selected mines and prospect areas, Delta 1p0s x 2p0s quadrangle, Utah. U.S. Dept. of the Interior, U.S. Geological Survey, 1992.

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Analytical results for platinum, palladium, rhodium, ruthenium, and iridium in rock samples from selected mines and prospect areas, Delta 1⁰ x 2⁰ quadrangle, Utah. U.S. Dept. of the Interior, U.S. Geological Survey, 1992.

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Analytical results for platinum, palladium, rhodium, ruthenium, and iridium in rock samples from selected mines and prospect areas, Delta 1 x 2 quadrangle, Utah. U.S. Dept. of the Interior, U.S. Geological Survey, 1992.

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Book chapters on the topic "Palladium, rhodium"

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Franke, P., and D. Neuschütz. "Pd-Rh (Palladium - Rhodium)." In Binary Systems. Part 5: Binary Systems Supplement 1. Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-45280-5_99.

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Storms, E. K. "Carbides of Rhodium, Palladium, Iridium, and Platinum." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145265.ch130.

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Rauch, Sebastien, and Gregory M. Morrison. "Speciation of Platinum, Palladium, Gold and Rhodium." In Handbook of Elemental Speciation II - Species in the Environment, Food, Medicine and Occupational Health. John Wiley & Sons, Ltd, 2005. http://dx.doi.org/10.1002/0470856009.ch2o(i).

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Berthon, Guillaume, and Tamio Hayashi. "Rhodium- and Palladium-Catalyzed Asymmetric Conjugate Additions." In Catalytic Asymmetric Conjugate Reactions. Wiley-VCH Verlag GmbH & Co. KGaA, 2010. http://dx.doi.org/10.1002/9783527630578.ch1.

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Predel, F. "Thermodynamic properties of Pd-Rh (palladium-rhodium) system." In Phase Equilibria, Crystallographic and Thermodynamic Data of Binary Alloys. Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-642-24977-8_99.

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Gebel, T. "Toxicology of platinum, palladium, rhodium, and their compounds." In Anthropogenic Platinum-Group Element Emissions. Springer Berlin Heidelberg, 2000. http://dx.doi.org/10.1007/978-3-642-59678-0_25.

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Gebel, T. "Toxikologisches Gefährdungspotential der Platingruppenelemente Platin, Palladium und Rhodium." In Emissionen von Platinmetallen. Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/978-3-642-58611-8_24.

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Hangen, Edzard, and Thomas Dörr. "Platinum, Palladium and Rhodium in a Bavarian Roadside Soil." In Environmental Science and Engineering. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-662-44559-4_10.

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Buckley, Robert G. "Rhodium, iridium and palladium compounds as experimental anticancer drugs." In Metal Compounds in Cancer Therapy. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-1252-9_5.

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Lebeau, Alex. "Platinum Group Elements: Palladium, Iridium, Osmium, Rhodium, and Ruthenium." In Hamilton & Hardy's Industrial Toxicology. John Wiley & Sons, Inc., 2015. http://dx.doi.org/10.1002/9781118834015.ch27.

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Conference papers on the topic "Palladium, rhodium"

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Brisiey, R. J., N. R. Collins, A. C. French, D. Morris, R. D. O'Sullivan, and M. V. Twigg. "Advanced Platinum-Rhodium Exhaust Catalysts - An Economic Alternative To Palladium-Rhodium." In SAE 2000 India Mobility Conference. SAE International, 2000. http://dx.doi.org/10.4271/2000-01-1418.

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Williamson, W. B., G. W. Denison, G. L. Starin, and H. J. Robota. "Palladium-Rhodium Catalyst Strategies for LEV Emission Applications." In International Fuels & Lubricants Meeting & Exposition. SAE International, 1997. http://dx.doi.org/10.4271/972844.

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Brisley, R. J., R. D. O'Sullivan, and A. J. J. Wilkins. "The Effect of High Temperature Ageing on Platinum-Rhodium and Palladium-Rhodium Three Way Catalysts." In International Congress & Exposition. SAE International, 1991. http://dx.doi.org/10.4271/910175.

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Pokhitonov, Yu, V. Romanovski, and P. Rance. "Distribution of Palladium During Spent Fuel Reprocessing." In ASME 2003 9th International Conference on Radioactive Waste Management and Environmental Remediation. ASMEDC, 2003. http://dx.doi.org/10.1115/icem2003-4766.

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The principal purpose of spent fuel reprocessing consists in the recovery of the uranium and plutonium and the separation of fission products so as to allow re-use of fissile and fertile isotopes and facilitate disposal of waste elements. Amongst the fission products present in spent nuclear fuel of Nuclear Power Plants (NPPs,) there are considerable quantities of platinum group metals (PGMs): ruthenium, rhodium and palladium. Given current predictions for nuclear power generation, it is predicted that the quantities of palladium to be accumulated by the middle of this century will be comparab
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Kim, Young-Deuk, Woo-Seung Kim, and Soo-Jin Jeong. "Analysis of Transient Thermal and Conversion Characteristics of Dual-Monolith Catalytic Converter with Palladium and Palladium/Rhodium Catalysts." In Asia Pacific Automotive Engineering Conference. SAE International, 2007. http://dx.doi.org/10.4271/2007-01-3453.

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Williamson, W. Burton, John G. Nunan, David G. Frownfelter, Richard S. McClaughry, Glenn E. Tripp, and Julia T. Huynh. "Palladium/Rhodium Dual-Catalyst LEV 2 and Bin 4 Close-Coupled Emission Solutions." In SAE World Congress & Exhibition. SAE International, 2007. http://dx.doi.org/10.4271/2007-01-1263.

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Williamson, W. B., R. P. Richmond, J. G. Nunan, A. Bortun, and H. J. Robota. "Palladium and Platinum/Rhodium Dual-Catalyst NLEV and Tier IIa Close-Coupled Emission Solutions." In SAE 2001 World Congress. SAE International, 2001. http://dx.doi.org/10.4271/2001-01-0923.

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Williamson, W. B., M. G. Zammit, H. J. Robota, D. J. Ball, and D. G. Linden. "Palladium and Platinum/Rhodium Dual-Catalyst Emission Solutions for Close-Coupled or Underfloor Applications." In SAE 2000 World Congress. SAE International, 2000. http://dx.doi.org/10.4271/2000-01-0860.

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Jakkaraju, Madhuri, and Vasudha Patri. "S. I. Engine Pollution Control Using Low-Cost Palletized Catalytic Converter." In ASME 7th Biennial Conference on Engineering Systems Design and Analysis. ASMEDC, 2004. http://dx.doi.org/10.1115/esda2004-58248.

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I. C. Engines consume large amounts of fossil fuel emitting harmful pollutants like carbon monoxide (CO), unburnt hydrocarbons (UBHC), and oxides of nitrogen (NOx). By using a catalytic converter (CC), the carbon monoxide, hydrocarbon emissions can be transformed into less harmful carbon dioxide (CO2) & water vapor (H2O). Currently available CC’s are using costly noble metals like platinum (pt), palladium (pd), rhodium (rh) etc., hence making them expensive. This paper deals with the use of low-cost palletized silver coated alumina as the catalyst element in a CC. In this study, alumina an
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Lei, Jih-Fen, Lisa C. Martin, and Herbert A. Will. "Advances in Thin Film Sensor Technologies for Engine Applications." In ASME 1997 International Gas Turbine and Aeroengine Congress and Exhibition. American Society of Mechanical Engineers, 1997. http://dx.doi.org/10.1115/97-gt-458.

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Advanced thin film sensor techniques that can provide accurate surface strain and temperature measurements are being developed at NASA Lewis Research Center. These sensors are needed to provide minimally intrusive characterization of advanced materials (such as ceramics and composites) and structures (such as components for Space Shuttle Main Engine, High Speed Civil Transport, Advanced Subsonic Transports and General Aviation Aircraft) in hostile, high-temperature environments, and for validation of design codes. This paper presents two advanced thin film sensor technologies: strain gauges an
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Reports on the topic "Palladium, rhodium"

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Lavernia, Enrique J., Nancy Y. C. Yang, and Markus D. Ong. Material synthesis and hydrogen storage of palladium-rhodium alloy. Office of Scientific and Technical Information (OSTI), 2011. http://dx.doi.org/10.2172/1030222.

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