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Dissertations / Theses on the topic 'Palladium'

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1

Bangun, Nimpan. "NMR study of palladium methoxide and palladium carbomethoxide complexes." Thesis, This resource online, 1993. http://scholar.lib.vt.edu/theses/available/etd-12052009-020137/.

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2

El, Allam Driss. "Les enthalpies de formation des alliages liquides : palladium-nickel, palladium-gallium, palladium-indium, nickel-gallium, nickel-indium, palladium-nickel-gallium et paladium-nickel-indium." Aix-Marseille 1, 1989. http://www.theses.fr/1989AIX11239.

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A l'aide d'un calorimetre tres haute temperature (1000c<t<1500c) completement automatise, les enthalpies de formation des alliages liquides binaires et tertiaires suivants: nickel - palladium, nickel - gallium, nickel - indium, palladium - gallium, palladium - indium, palladium - nickel - gallium, palladium - nickel - indium ont ete determinees a diverses temperatures et sur l'ensemble du domaine de composition. Ces determinations experimentales et, pour les systemes ternaires l'utilisation de quelques modeles phenomenologiques, nous ont permis de donner la loi de variation de la fonction enth
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3

Oh, Seung-Hoon. "Low-temperature catalytic oxidation of carbon monoxide over palladium metal, hydrous palladium oxides, and anhydrous palladium oxides." [Gainesville, Fla.] : University of Florida, 2005. http://purl.fcla.edu/fcla/etd/UFE0013045.

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4

McNicholl, Ruth-Anne. "A study of hydrogen interactions with palladium and palladium alloys." Thesis, Queen's University Belfast, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.334511.

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5

Frey, Karin Marita Grossen Johannes Michael. "Untersuchung der Korrosion von Silber, Palladium und Silber-Palladium-Legierungen /." [S.l : s.n.], 1987. http://www.ub.unibe.ch/content/bibliotheken_sammlungen/sondersammlungen/dissen_bestellformular/index_ger.html.

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6

Kim, Jeha. "Structural and elastic properties of silver-palladium and copper-palladium superlattices." Diss., The University of Arizona, 1993. http://hdl.handle.net/10150/186275.

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I prepared Ag/Pd and Cu/Pd superlattices using both sputtering and molecular beam epitaxy. For the Ag/Pd (t(Ag):t(Pd) = 1:1) superlattices, I observed two distinctive behaviors in the structural coherence length ξ as a function of modulation wavelength Λ. Using Brillouin light scattering (BLS) I observed a 50% enhancement of the shear elastic constant c₅₅ and a 16% increase of c₁₁ with decreasing Λ. Annealing study showed that a high structural order of the films in the growth direction was strongly correlated to the increase of c₅₅. For the 3:1 and 1:3 Ag/Pd samples, I also observed a monoton
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7

Zuideveld, Martin Alexander. "Solvolysis of palladium-carbon bonds in palladium(II) complexes containing diphosphine ligands." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2001. http://dare.uva.nl/document/60731.

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8

Todorova, Mira. "Oxidation of Palladium surfaces." [S.l.] : [s.n.], 2004. http://deposit.ddb.de/cgi-bin/dokserv?idn=971639868.

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9

Williamson, Anna Maria. "Studies on novel palladium." Thesis, Imperial College London, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.252246.

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10

Sparkes, Robert P. "Carbocations in palladium crystals." Thesis, University of Oxford, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.249213.

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11

Sukirthalingam, Sukanthini. "Palladium catalysed cyclisation processes." Thesis, Queen's University Belfast, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.335444.

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12

Morris, James Alan. "Palladium-ruthenium bimetallic cascades." Thesis, University of Leeds, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.405707.

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13

Ostovar, Peyman. "Palladium-catalysed neuroleptic synthesis." Thesis, Imperial College London, 1989. http://hdl.handle.net/10044/1/47601.

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14

Rojas, Anthony J. (Anthony Jose). "Palladium reagents for bioconjugation." Thesis, Massachusetts Institute of Technology, 2018. http://hdl.handle.net/1721.1/120905.

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Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemistry, 2018.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references.<br>physicochemical properties in comparison to their linear counterparts. Here we detail a method for a divergent macrocyclization of unprotected peptides by crosslinking two cysteine residues with bis-palladium organometallic reagents. These synthetic intermediates are prepared in a single step from commercially available aryl bis-halides. Two bioactive linear peptides with cysteine residues at i, i + 4 and i, i + 7 positions, r
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15

Li, Meiling. "Palladium catalysed allene carbocyclisation." Thesis, University of Oxford, 2010. http://ora.ox.ac.uk/objects/uuid:747420b6-c11f-451c-83c7-fa9fca5f7752.

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In this thesis, firstly, a Pd-catalysed diastereoselective carbocyclisation of allenes with aryl halides or vinyl iodides was designed and developed to form arylative or vinylative spirolactam compounds. High yields and diastereoselectivities were obtained in the presence of Pd<sub>2</sub>(dba)<sub>3</sub>/dppe and K<sub>2</sub>CO<sub>3</sub> in DMSO at 70 &deg;C, particularly when spiropiperidin-2-ones were formed. The method is simple to perform and broad in scope. Having established the diastereoselective methodology for the arylative or vinylative allene carbocyclisation, a Pd-catalysed en
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16

Sadig, Jessie E. R. "Palladium-catalysed heterocycle synthesis." Thesis, University of Oxford, 2012. http://ora.ox.ac.uk/objects/uuid:c9608957-d215-4a15-87e3-5871c1391946.

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Chapter 1 is a literature review of selected palladium-catalysed aryl C-N and C-S bond forming reactions. The application of these reactions to the synthesis of heterocycles is also discussed. Chapter 2 highlights the importance of the benzimidazole motif and gives a brief discussion of the existing routes to this scaffold. The utility of N-(o-halophenyl)imidoyl chlorides and imidates as precursors to heterocycles is demonstrated in a palladium-catalysed reaction with N-nucleophiles to afford benzimidazole products. Chapter 3 provides a brief introduction to the synthesis of benzothiazoles and
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17

Hollingworth, Charlotte. "Palladium mediated allylic fluorination." Thesis, University of Oxford, 2013. http://ora.ox.ac.uk/objects/uuid:8c61b9e9-b143-4c5e-b151-7e62bf4ecc03.

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In this thesis, the construction of the allylic fluorides under palladium catalysis was investigated. Chapter 1 provides a general introduction to organofluorine compounds and the use of palladium for the formation of both Csp<sup>2</sup>- and Csp<sup>3</sup>-F bonds. The aims of the thesis are presented. In Chapter 2 the identification that a p-nitrobenzoate is the optimum leaving group under Pd-catalysis to give allyl fluorides is described. A range of allylic fluorides was synthesized in 35->95% yield using the nucleophilic fluorinating reagent, TBAF(tBuOH)<sub>4</sub>. To further develop t
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18

Setayandeh, Samaneh S. "Hydrogen Properties in Palladium." Thesis, Griffith University, 2021. http://hdl.handle.net/10072/404154.

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In this project the palladium-hydrogen system was investigated, using computational and experimental approaches. Computational modelling, employing ab initio calculations based on density functional theory (DFT), were done with the Quantum Espresso package, to investigate the electronic and phonon properties of PdH and its superabundant vacancy phase (Pd3VacH4), assuming that octahedral or tetrahedral lattice interstices are occupied by hydrogen, and to relate these to important physical properties, in particular the atomic volume of hydrogen in Pd and the superconducting transition temperatur
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19

Powell, Luke Haydn William. "Palladium-catalysed enantioselective desymmetrisations." Thesis, University of Bath, 2005. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.425803.

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20

Tong, Xiu Qiang. "Lattice strain induced (Gorsky effect) diffusion of hydrogen in palladium and palladium alloys." Thesis, Queen's University Belfast, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.334683.

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21

Rayee, Quentin. "Dépôts électrochimiques d’argent, de palladium et d’alliages argent-palladium en solvants eutectiques profonds." Doctoral thesis, Universite Libre de Bruxelles, 2020. http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/303218.

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Le recours aux solvants eutectiques profonds se présente comme une alternative potentielle aux limitations rencontrées en milieux aqueux pour la réalisation de dépôts électrochimiques. La transposition des procédés électrochimiques des milieux conventionnels vers ces nouveaux milieux n’est pas immédiate et nécessite d’entreprendre des études fondamentales visant à comprendre l’impact de la nature des solvants eutectiques profonds sur différents processus survenant à l’interface électrochimique. Dans cette optique, le présent travail examine les mécanismes impliqués dans la formation de dépôts
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22

Yang, Zhiqiang. "Preparation of palladium, palladium sulfide, cadmium selenide nanoparticles and magnesium oxychloride, magnesium hydroxide nanorods." Diss., Manhattan, Kan. : Kansas State University, 2008. http://hdl.handle.net/2097/891.

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23

Vicente, Aurélie. "Hydrogénation du citral sur catalyseurs bimétalliques supportés rhodium-germanium, palladium-germanium et palladium-étain." Poitiers, 2008. http://www.theses.fr/2008POIT2338.

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Ce travail est consacré à la préparation de catalyseurs bimétalliques supportés Rh-Ge, Pd-Ge et Pd-Sn pour l’hydrogénation sélective du citral en alcools a,b-insaturés. Pour les catalyseurs à base de Rh, l’étude porte sur l’influence de la nature des sels précurseurs utilisés. L’existence d’interactions entre les deux métaux des différents systèmes bimétalliques est mise en évidence par diverses techniques de caractérisation (EDX, réaction modèle de déshydrogénation du cyclohexane, RTP sous H2, IRTF de CO adsorbé). La réaction d’hydrogénation sélective du citral a montré qu’il est possible de
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24

Beyer, Andreas. "Reaktivmembranen aus Polyacrylsäure-Palladium-Verbundsystemen." [S.l.] : [s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=963799169.

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25

Markmann, Jürgen. "Mikrostrukturuntersuchungen an kaltgewalztem nanokristallinem Palladium." Karlsruhe : FZKA, 2005. http://bibliothek.fzk.de/zb/berichte/FZKA7126.pdf.

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26

Lindh, Jonas. "Palladium(II)-Catalyzed Coupling Reactions." Doctoral thesis, Uppsala universitet, Avdelningen för organisk farmaceutisk kemi, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-130031.

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Sustainable chemical processes are becoming increasingly important in all fields of synthetic chemistry. Catalysis can play an important role in developing environmentally benign chemical processes, and transition metals have an important role to play in the area of green chemistry. In particular, palladium(II) catalysis includes many key features for successful green chemistry methods, as demonstrated by a number of eco-friendly oxidation reactions catalyzed by palladium(II). The aim of the work presented in this thesis was to develop novel and greener palladium(II)-catalyzed coupling reactio
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27

Zargarian, Davit. "Palladium-catalyzed carbonylation of alkynes." Thesis, University of Ottawa (Canada), 1992. http://hdl.handle.net/10393/7555.

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This thesis describes the palladium-catalyzed carbonylation of alkynes with formic acid. Terminal alkynes react with formic acid in the presence of catalytic amounts of Pd(OAc)$\sb2$ and suitable phosphine ligands (120 psi of CO gas pressure, 100-110$\sp\circ$C) to produce the unsaturated carboxylic acids CR(COOH)=CH$\sb2,$ 1, and (E)-CHR=CH(COOH), 2. The combined yields of 1 and 2 for various R's range from 60 to 90%. The regioselectivity is approximately 90:10 in favour of 1 when R is a phenyl or a straight chain alkyl group; 2 is the favoured product when R is t-Bu and the exclusive one whe
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28

Zhao, Jian. "Palladium migrations and aryne annulations." [Ames, Iowa : Iowa State University], 2007.

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29

Flegeau, Emmanuel Ferrer. "Palladium cross-couplings of oxazoles." Thesis, University of Edinburgh, 2008. http://hdl.handle.net/1842/3171.

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A review covering the literature until April 2008 concerning organometallic reactions to funcionalise oxazoles is described. A protocol for the functionalisation of the oxazole 2- and 4-positions using the Suzuki coupling reaction is described. 2- Aryl-4-trifloyloxazoles undergo rapid, microwave-assisted coupling with a range of aryl and heteroaryl boronic acids in good to excellent yields. The methodology is similarly effective using 4-aryl-2-chlorooxazoles as the coupling partner and has been extended to the synthesis of a novel class of homo- and heterodimeric 4,4- linked dioxazoles. In add
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30

Yusop, Rahimi Muhammad. "Palladium chemistry in chemical biology." Thesis, University of Edinburgh, 2011. http://hdl.handle.net/1842/5734.

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A range of fluorescein derivatives were synthesised via Pd0-mediated cross-coupling chemistry of the mono triflate of fluorescein with a variety of boronic acids and the optical properties of each dye was studied. Among these derivatives, a new multicolour pH–dependant anthofluorescein which was highly sensitive to pH changes and viscosity changes was identified. Work was carried out to explore intracellular catalysis based on the immobilisation of Pd0 nanoparticles on microspheres. The entrapped Pd0 nanoparticles were rapidly taken up by cells, stay harmlessly within the cytoplasm for days an
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31

Dumrongchai, Nuethip. "Palladium Catalyzed Multicomponent Cascade Reactions." Thesis, University of Leeds, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.487516.

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This Thesis is divided into three parts: Introduction (Chapter 1), Result and Discussion (Chapter 2) and Experimental (Chapter 3). The Introduction (Chapter 1) provides a review of the recent literature relating to the 1,3dipolar cycloaddition reactions. It· covers nitrones, azomethine ylides and azomethine imines. The Result and Discussion. section (Chapter 2) deals with the author's work which is . concerned with developing four novel multicomponent cascade reactions. These are (i) a 3- component cascade involving bifunctional aryl halide! Michael acceptors, allene and arriine or sulphona
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32

Cooper, Ian Ronald. "Palladium-indium bimetallic cascade processes." Thesis, University of Leeds, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.401087.

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33

Marchbank, John David. "Palladium-catalysed cascade ring syntheses." Thesis, University of Leeds, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.405708.

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34

Sheridan, Kelly Jane. "Palladium catalysed co/alkyne reactions." Thesis, University of Liverpool, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.428220.

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35

Cleghorn, Simon John Charles. "Electrocatalytic hydrogenation at palladium electrodes." Thesis, University of Southampton, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.332771.

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36

Henderson, William Howell. "Palladium-Mediated C-H Activations." The Ohio State University, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=osu1318003095.

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37

Broderick, Meghann. "Characterization of Stabilized Palladium Nanocatalysts." VCU Scholars Compass, 2010. http://scholarscompass.vcu.edu/etd/2201.

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Metal nanoparticles have received much interest for their application in catalysis due to high surface-to-volume ratios resulting in more available active sites. Ideally these catalysts are heterogeneous and allow for facile separation from the catalytic reaction mixture making them ideal for industrial application. Dispersed metal nanoparticles are explored due to their high reactivity in solution and are stabilized by surfactants and polymers. However, it is difficult to determine whether or not a catalyst is truly heterogeneous as a certain degree of leaching from the metal nanoparticle
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38

Švejd, Michal. "Typologie zákazníka nákupního centra Palladium." Master's thesis, Vysoká škola ekonomická v Praze, 2008. http://www.nusl.cz/ntk/nusl-4704.

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Stěžejní částí diplomové práce je vlastní marketingové šetření, které proběhlo v nákupním centru Palladium za asistence společnosti Property Value Solutions, s.r.o., která na výzkum dohlížela a má velký zájem na vyhodnocení výsledků, které budou prezentovány managementu Palladia.
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39

Boysen, Ryan Bradley. "Development of palladium L-edge X-Ray absorption spectroscopy and its application on chloro palladium complexes." Thesis, Montana State University, 2006. http://etd.lib.montana.edu/etd/2005/boysen/BoysenR0506.pdf.

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X-ray Absorption Spectroscopy (XAS) is a synchrotron-based experimental technique that can provide information about geometric and electronic structures of transition metal complexes with unoccupied d orbitals. Combination of metal L-edge and ligand K-edge XAS has the potential to define the experimental ground state electronic structure. We developed a quantitative treatment for Pd L-edge spectroscopy based on the already established Cl K-edge XAS for a series of chloro palladium complexes, which are precatalysts in numerous organic transformations. We found that Pd-Cl bonds are highly covale
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40

Brits, Johannes Hendrik Wilhelmus Machiel. "Study on the thermodynamics and kinetics of the stripping of palladium from a typical palladium organic." Master's thesis, University of Cape Town, 2005. http://hdl.handle.net/11427/11784.

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Includes bibliographical references.<br>The aim of this thesis was to investigate the thermodynamics and the kinetics of the stripping of palladium from a typical palladium organic. The thesis firstly characterizes the thermodynamic effects of temperature and strip acid normality on the stripping of palladium and secondly investigates the kinetics of the palladium stripping reaction by exploring the effect of impeller speed and type on the overall volumetric mass transfer coefficient. which was the major focus of this thesis.
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41

Ji, Jianhua. "Regioselective Coupling Reactions of Diiodophenol Derivatives." Thesis, University of North Texas, 1994. https://digital.library.unt.edu/ark:/67531/metadc277926/.

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Palladium catalyzed reactions of derivatives of 2,4-diiodophenol are explored. Coupling reactions with a series of terminal alkynes and formylation are found to be efficient and regioselective. Coupling with stananne reagents and alkenes do not work. The nature of the oxygen protecting group is critical. The phytotoxic natural product, Eutypine, is synthesized by using regioselective formylation and alkyne coupling. An approach to the plant antimicrobial compound Plicatin B is examined.
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42

Püntener, Kurt Andreas. "Chirale Palladium-Komplexe mit dreizähnigen Stickstoffliganden /." [S.l.] : [s.n.], 1994. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=10888.

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43

Unterhalt, Holger. "Summenfrequenzerzeugungsspektroskopie an Platin- und Palladium-Modellkatalysatoren." [S.l.] : [s.n.], 2002. http://www.diss.fu-berlin.de/2002/123/index.html.

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44

Sävmarker, Jonas. "Palladium-Catalyzed Carbonylation and Arylation Reactions." Doctoral thesis, Uppsala universitet, Avdelningen för organisk farmaceutisk kemi, 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-167720.

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Palladium-catalyzed reactions have found widespread use in contemporary organic chemistry due to their impressive range of functional group tolerance and high chemo- and regioselectivity. The pioneering contributions to the development of the Pd-catalyzed C-C bond forming cross-coupling reaction were rewarded with the Nobel Prize in Chemistry in 2010. Today, this is a rapidly growing field, and the development of novel methods, as well as the theoretical understanding of the various processes involved are of immense importance for continued progress in this field. The aim of the work presented
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45

Sullivan, Brian Thomas. "Spectroscopic ellipsometry of Palladium thin films." Thesis, University of British Columbia, 1987. http://hdl.handle.net/2429/27546.

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Spectroscopic ellipsometry is a nondestructive, ambient surface analysis technique for studying surfaces, interfaces and thin films. To take advantage of this method an automatic spectroscopic ellipsometer was designed and constructed for the microstructural characterization of thin films. This high precision instrument is capable of measuring in real-time the optical properties of bulk or thin film materials over the visible-UV region (1.5 - 6.0 eV). The microstructure of thin films can be determined from an effective medium theory analysis of the spectroellipsometric data to investigate how
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46

Clentsmith, Guy Kenneth Bruce. "Dinuclear palladium complexes with bridging hydrides." Thesis, University of British Columbia, 1991. http://hdl.handle.net/2429/29800.

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The palladium hydride dimer, [(dippp)Pd]₂(µ--H)₂, (2) (dippp = 1,3-bis(diisopropylphosphino)propane), was synthesized, and its interaction with lithium tetraethylborate examined. When the two compounds were mixed in stoichiometric amounts high yields of the adduct, [(dippp)Pd]₂(µ-H) ₂•LiBEt₄ (1) — previously isolated adventitiously by a co-worker — were obtained. Variable temperature ³¹P{¹H} NMR spectroscopy showed a condition of chemical equilibrium between 2 and 1, but the value of the equilibrium constant, Keq, could not be determined owing to its large magnitude. Extension of this chemistr
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47

Robinson, I. K. "Computational studies of hydrogen in palladium." Thesis, University of Salford, 2015. http://usir.salford.ac.uk/45237/.

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A series of Monte-Carlo investigations on the Palladium Hydrogen system are presented. It is demonstrated that a simple long-range concentration-dependent attractive force reproduces the form of the pressure-composition isotherms well. Short range pairwise repulsive forces reproduce much of the hydrogen ordering seen within the lattice. A suitable scaling between the long and short range forces has been found which appears to reproduce both the isotherms and the short-range ordering to a reasonable degree. Programs have been written to generate virtual diffractograms in 1d and 2d in order to o
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48

Farhad, Mohammad. "Studies on new trinuclear palladium compounds." Connect to full text, 2007. http://hdl.handle.net/2123/2477.

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Doctor of Philosophy(PhD)<br>The present study deals with the synthesis and characterization of six tri-palladium complexes code named MH3, MH4, MH5, MH6, MH7 and MH8 that contained two planaramine ligands bound to the central or each of the terminal metal ions. The activity of the compounds against human cancer cell lines: A2780, A2780cisR and A2780ZD0473R, cell uptake, levels of DNA-binding and nature of interaction with salmon sperm and pBR322 plasmid DNA have also been determined. Whereas cisplatin binds with DNA forming mainly intrastrand GG adduct that causes local bending of a DNA stran
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49

Amandusson, Helena. "Hydrogen extraction with palladium based membranes /." Linköping : Univ, 2000. http://www.bibl.liu.se/liupubl/disp/disp2000/tek651s.htm.

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50

Du, Toit Zita. "Simulation of a palladium extraction circuit." Thesis, Stellenbosch : University of Stellenbosch, 2006. http://hdl.handle.net/10019/536.

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