Academic literature on the topic 'Pd-catalysed reaction'

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Journal articles on the topic "Pd-catalysed reaction"

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Silva, Vera L. M., and Artur M. S. Silva. "Palladium-Catalysed Synthesis and Transformation of Quinolones." Molecules 24, no. 2 (2019): 228. http://dx.doi.org/10.3390/molecules24020228.

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Palladium-catalysed reactions have had a large impact on synthetic organic chemistry and have found many applications in target-oriented synthesis. Their widespread use in organic synthesis is due to the mild conditions associated with the reactions together with their tolerance of a wide range of functional groups. Moreover, these types of reactions allow the rapid construction of complex molecules through multiple bond-forming reactions in a single step, the so-called tandem processes. Pd-catalysed reactions have been applied to the synthesis of a large number of natural products and bioacti
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Martos-Redruejo, Alicia, Ruth López-Durán, Elena Buñuel, and Diego J. Cárdenas. "Ligand-controlled divergent formation of alkenyl- or allylboronates catalyzed by Pd, and synthetic applications." Chem. Commun. 50, no. 70 (2014): 10094–97. http://dx.doi.org/10.1039/c4cc04092a.

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Pd-catalysed reactions of allyl carbonates containing alkynes with B2(pin)2 afford either alkenylboronates by cascade borylative cyclisation, or allylboronates. The reaction outcome is controlled by a suitable choice of ligands. Boronates have been applied to a number of synthetic applications.
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Červený, Libor, Nguyen Thi Du, and Ivo Paseka. "Model reactions for the study of hydrogenation and acidic activity of palladium catalysts." Collection of Czechoslovak Chemical Communications 52, no. 8 (1987): 2019–27. http://dx.doi.org/10.1135/cccc19872019.

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Palladium catalysts have been used to study the hydrogenation of 1-phenyl-2-butene-1-ol which is accompanied by several side reactions considered to be acid-catalysed. Another model reaction studied was dehydration and subsequent hydrogenation or hydrogenolysis of 1-phenyl-1,3-propanediol to 3-phenyl-1-propanol, accompanied by formation of propylbenzene. The dehydration and propylbenzene formation can be again classified as acid-catalysed reactions. Another one is methanolysis of styrene oxide taking place under conditions of liquid phase hydrogenation due to the acid properties of Pd-H system
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Osakada, Kohtaro, and Yasushi Nishihara. "Transmetalation of boronic acids and their derivatives: mechanistic elucidation and relevance to catalysis." Dalton Transactions 51, no. 3 (2022): 777–96. http://dx.doi.org/10.1039/d1dt02986j.

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The Suzuki–Miyaura reaction (the cross-coupling reaction of boronic acids with organic halides catalysed by Pd complexes) has been recognised as a useful synthetic organic reaction that forms a C(sp2)–C(sp2) bond.
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Li, Yang, and Zhenyang Lin. "Understanding the reaction mechanisms of Pd-catalysed oxidation of alcohols and domino oxidation–arylation reactions using phenyl chloride as an oxidant." Org. Chem. Front. 1, no. 10 (2014): 1188–96. http://dx.doi.org/10.1039/c4qo00214h.

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Mahato, Shreya, Parveen Rawal, Ajitrao Kisan Devadkar, et al. "Hydroboration and reductive amination of ketones and aldehydes with HBpin by a bench stable Pd(ii)-catalyst." Organic & Biomolecular Chemistry 20, no. 5 (2022): 1103–11. http://dx.doi.org/10.1039/d1ob02339j.

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A Pd(ii) complex catalysed hydroboration and reductive amination reaction of several aldehydes and ketones are reported. DFT-based computational study of the reaction mechanism unravels the dual role of HBpin in accomplishing the hydroboration reaction.
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Ferlin, Francesco, Stefano Santoro, Lutz Ackermann, and Luigi Vaccaro. "Heterogeneous C–H alkenylations in continuous-flow: oxidative palladium-catalysis in a biomass-derived reaction medium." Green Chemistry 19, no. 11 (2017): 2510–14. http://dx.doi.org/10.1039/c7gc01103b.

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Yang, Bo, Chang Lian, Guanglu Yue, et al. "Synthesis of N-arylsulfonamides through a Pd-catalyzed reduction coupling reaction of nitroarenes with sodium arylsulfinates." Organic & Biomolecular Chemistry 16, no. 43 (2018): 8150–54. http://dx.doi.org/10.1039/c8ob02226g.

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Le Bras, Jean, and Jacques Muzart. "Palladium-catalysed inter- and intramolecular formation of C–O bonds from allenes." Chem. Soc. Rev. 43, no. 9 (2014): 3003–40. http://dx.doi.org/10.1039/c3cs60379b.

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Jadhav, Sanjay N., and Chandrashekhar V. Rode. "An efficient palladium catalyzed Mizoroki–Heck cross-coupling in water." Green Chemistry 19, no. 24 (2017): 5958–70. http://dx.doi.org/10.1039/c7gc02869e.

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Dissertations / Theses on the topic "Pd-catalysed reaction"

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Platt, George. "Mechanistic investigation into the Pd-catalysed C–H bond functionalisation of fluoroarenes : reaction kinetics and intermediate characterisation." Thesis, University of York, 2016. http://etheses.whiterose.ac.uk/17253/.

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The project aimed to reveal mechanistic details of the Pd-catalysed direct arylation reaction involving fluoroarenes. Direct arylation methodologies have rapidly developed over the last decade as cost-effective, eco-friendly and sustainable alternatives to cross-coupling reactions. Fluoroarenes are attractive substrates due to the fluorine-substitution effect as well as the ability to control the regioselectivity of C–H bond activation by the ortho-fluorine effect. Understanding the reaction mechanisms are crucial for making improvements to the C–H bond functionalisation field and provides acc
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Sarnpitak, Pakornwit. "Scaffold-oriented Synthesis for Drug Discovery." Thesis, Griffith University, 2017. http://hdl.handle.net/10072/366103.

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The design and synthesis of three different scaffolds of nitrogen heterocycles have been achieved by using either methods described in the literature or newly developed synthetic methodologies/routes. The three synthesised libraries in this thesis were based on Pd-catalysed N-arylations, Castagnoli-Cushman multicomponent reaction, and Rh(II)-catalysed intramolecular C-H insertions. The compounds were successfully synthesised in moderate to excellent yields. Firstly, one of the synthesised diaryl imidazolines was found to be a selective COX-2 inhibitor due to its comparable activity to the appr
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Smith, Alexander. "Exploring new asymmetric reactions catalysed by dicationic Pd(II) complexes." Thesis, Imperial College London, 2010. http://hdl.handle.net/10044/1/6324.

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Dicationic palladium(II) complexes have been shown to catalyse a number of important asymmetric transformations including Michael, Mannich and aldol reactions. This PhD thesis describes work undertaken to discover and develop novel applications of dicationic palladium(II) complexes in asymmetric catalysis. The introductory chapter outlines the advances in catalytic asymmetric α-functionlisation of β-ketoesters. This includes both metal-catalysed and organocatalytic processes with reference to C-C, C-X (X = F, Cl, Br), C-N, C-O and C-S bond forming reactions. Chapter 2 discusses the work toward
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Bailey, Christopher David. "New Pd(II) Catalysed C-H Insertion Reactions of Aryl Ureas." Thesis, University of Bristol, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.520217.

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Walker, Sarah Elizabeth. "The development of Pd(II)-catalysed oxidative Heck reactions and C-H functionalisations." Thesis, Heriot-Watt University, 2015. http://hdl.handle.net/10399/3138.

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This thesis outlines the work undertaken on three projects focusing on the development of Pd(II)-catalysed oxidative Heck reactions and C-H functionalisations. Chapter one reviews literature related to palladium catalysis, specifically the oxidative Heck reaction, its development and the most recent advances in this area. Chapter two describes methodology developed to switch the outcome of the ligand- and base-free Pd(II)-catalysed reaction between cyclic enones and boronic acids from conjugate addition to oxidative Heck product, by simply changing the solvent. Additionally, factors which favo
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Hövelmann, Claas. "Oxidative intramolecular diamination of alkenes with ureas as nitrogen sources : Mechanistic investigations of Pd catalysed and halogen mediated reactions." Université Louis Pasteur (Strasbourg) (1971-2008), 2008. http://www.theses.fr/2008STR13107.

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FIORANI, GIULIA. "Synthesis and application of innovative solvents in carbon-carbon bond formation reactions." Doctoral thesis, Università degli Studi di Roma "Tor Vergata", 2010. http://hdl.handle.net/2108/1210.

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In questo lavoro sperimentale sono stati sintetizzati e caratterizzati diversi Liquidi Ionici. I Liquidi Ionici sintetizzati sono stati successivamente impiegati come solventi in reazioni di formazione di legame carbonio-carbonio. I Liquidi Ionici sono stati preparati e caratterizzati ottimizzando procedure riportate in letteratura. In alcuni casi i Liquidi Ionici sono stati preparati mediante reazioni che prevedevano riscaldamento con le microonde. La sintesi di Liquidi Ionici microonde assistita è stata perfezionata con l’aiuto di un programma di calcolo delle rese (CROW), a partire da dat
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"Pd-catalysed methoxycarbonylation reactions of alkynes." Thesis, 2013. http://hdl.handle.net/10210/8602.

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Hughes, Tanya. "DoM chemistry in the preparation of phosphine ligands for Pd-catalysed reactions." Thesis, 2010. http://hdl.handle.net/10210/3149.

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M.Sc.<br>The objective of the project described in this dissertation was the preparation of a range of bulky electron-rich phosphine ligands making use of the directed ortho metallation (DoM) methodology developed in our labs. These ligands would then be employed in the Suzuki and Heck reactions of aryl bromides and aryl chlorides. A range of phosphinic amides were synthesised with various structural differences. These phosphinic amides all showed high activity in the DoM reaction when using TMSCl and MeI as electrophiles, by successfully incorporating TMS and Me groups in the ortho-positions
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Santos, Ana Sofia Branco dos. "Sustainable synthesis of heterocyclic compounds on a soluble polymer support." Master's thesis, 2017. http://hdl.handle.net/10362/25625.

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Book chapters on the topic "Pd-catalysed reaction"

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Campbell, I. B. "The Sonogashira Cu-Pd-catalysed alkyne coupling reaction." In Organocopper Reagents: A Practical Approach. Oxford University PressOxford, 1995. http://dx.doi.org/10.1093/oso/9780198557579.003.0010.

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Abstract Carbon–carbon bond-forming reactions are of crucial importance to the practising organic chemist. In particular, those which are technically simple, efficient, high-yielding, and which tolerate a wide variety of functional groups are of special use. One such reaction is the Sonogashira copper–palladium-catalysed coupling of terminal alkynes with aromatic and vinyl halides. The general forms of the reaction are given in eqns (1) and (2).
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Conference papers on the topic "Pd-catalysed reaction"

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Thiemann, Thies, and Kyoko Yamamoto. "Suzuki-Miyaura cross-coupling and Heck reactions catalysed by Pd on carbon nanofibres." In The 13th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2009. http://dx.doi.org/10.3390/ecsoc-13-00173.

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