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Journal articles on the topic 'Pd-catalysed reaction'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Silva, Vera L. M., and Artur M. S. Silva. "Palladium-Catalysed Synthesis and Transformation of Quinolones." Molecules 24, no. 2 (2019): 228. http://dx.doi.org/10.3390/molecules24020228.

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Palladium-catalysed reactions have had a large impact on synthetic organic chemistry and have found many applications in target-oriented synthesis. Their widespread use in organic synthesis is due to the mild conditions associated with the reactions together with their tolerance of a wide range of functional groups. Moreover, these types of reactions allow the rapid construction of complex molecules through multiple bond-forming reactions in a single step, the so-called tandem processes. Pd-catalysed reactions have been applied to the synthesis of a large number of natural products and bioacti

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2

Martos-Redruejo, Alicia, Ruth López-Durán, Elena Buñuel, and Diego J. Cárdenas. "Ligand-controlled divergent formation of alkenyl- or allylboronates catalyzed by Pd, and synthetic applications." Chem. Commun. 50, no. 70 (2014): 10094–97. http://dx.doi.org/10.1039/c4cc04092a.

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Pd-catalysed reactions of allyl carbonates containing alkynes with B2(pin)2 afford either alkenylboronates by cascade borylative cyclisation, or allylboronates. The reaction outcome is controlled by a suitable choice of ligands. Boronates have been applied to a number of synthetic applications.

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3

Červený, Libor, Nguyen Thi Du, and Ivo Paseka. "Model reactions for the study of hydrogenation and acidic activity of palladium catalysts." Collection of Czechoslovak Chemical Communications 52, no. 8 (1987): 2019–27. http://dx.doi.org/10.1135/cccc19872019.

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Palladium catalysts have been used to study the hydrogenation of 1-phenyl-2-butene-1-ol which is accompanied by several side reactions considered to be acid-catalysed. Another model reaction studied was dehydration and subsequent hydrogenation or hydrogenolysis of 1-phenyl-1,3-propanediol to 3-phenyl-1-propanol, accompanied by formation of propylbenzene. The dehydration and propylbenzene formation can be again classified as acid-catalysed reactions. Another one is methanolysis of styrene oxide taking place under conditions of liquid phase hydrogenation due to the acid properties of Pd-H system

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4

Osakada, Kohtaro, and Yasushi Nishihara. "Transmetalation of boronic acids and their derivatives: mechanistic elucidation and relevance to catalysis." Dalton Transactions 51, no. 3 (2022): 777–96. http://dx.doi.org/10.1039/d1dt02986j.

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The Suzuki–Miyaura reaction (the cross-coupling reaction of boronic acids with organic halides catalysed by Pd complexes) has been recognised as a useful synthetic organic reaction that forms a C(sp2)–C(sp2) bond.

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5

Li, Yang, and Zhenyang Lin. "Understanding the reaction mechanisms of Pd-catalysed oxidation of alcohols and domino oxidation–arylation reactions using phenyl chloride as an oxidant." Org. Chem. Front. 1, no. 10 (2014): 1188–96. http://dx.doi.org/10.1039/c4qo00214h.

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6

Mahato, Shreya, Parveen Rawal, Ajitrao Kisan Devadkar, et al. "Hydroboration and reductive amination of ketones and aldehydes with HBpin by a bench stable Pd(ii)-catalyst." Organic & Biomolecular Chemistry 20, no. 5 (2022): 1103–11. http://dx.doi.org/10.1039/d1ob02339j.

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A Pd(ii) complex catalysed hydroboration and reductive amination reaction of several aldehydes and ketones are reported. DFT-based computational study of the reaction mechanism unravels the dual role of HBpin in accomplishing the hydroboration reaction.

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7

Ferlin, Francesco, Stefano Santoro, Lutz Ackermann, and Luigi Vaccaro. "Heterogeneous C–H alkenylations in continuous-flow: oxidative palladium-catalysis in a biomass-derived reaction medium." Green Chemistry 19, no. 11 (2017): 2510–14. http://dx.doi.org/10.1039/c7gc01103b.

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8

Yang, Bo, Chang Lian, Guanglu Yue, et al. "Synthesis of N-arylsulfonamides through a Pd-catalyzed reduction coupling reaction of nitroarenes with sodium arylsulfinates." Organic & Biomolecular Chemistry 16, no. 43 (2018): 8150–54. http://dx.doi.org/10.1039/c8ob02226g.

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9

Le Bras, Jean, and Jacques Muzart. "Palladium-catalysed inter- and intramolecular formation of C–O bonds from allenes." Chem. Soc. Rev. 43, no. 9 (2014): 3003–40. http://dx.doi.org/10.1039/c3cs60379b.

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10

Jadhav, Sanjay N., and Chandrashekhar V. Rode. "An efficient palladium catalyzed Mizoroki–Heck cross-coupling in water." Green Chemistry 19, no. 24 (2017): 5958–70. http://dx.doi.org/10.1039/c7gc02869e.

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11

Tulichala, R. N. Prasad, та K. C. Kumara Swamy. "Reactivity of alkynylindole-2-carboxamides in [Pd]-catalysed C–H activation and phase transfer catalysis: formation of pyrrolo-diindolones vs. β-carbolinones". Organic & Biomolecular Chemistry 14, № 19 (2016): 4519–33. http://dx.doi.org/10.1039/c6ob00583g.

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12

Bheeter, Charles Beromeo, Lu Chen, Jean-François Soulé, and Henri Doucet. "Regioselectivity in palladium-catalysed direct arylation of 5-membered ring heteroaromatics." Catalysis Science & Technology 6, no. 7 (2016): 2005–49. http://dx.doi.org/10.1039/c5cy02095f.

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13

Palagin, Dennis, and Jonathan P. K. Doye. "CO oxidation catalysed by Pd-based bimetallic nanoalloys." Physical Chemistry Chemical Physics 17, no. 42 (2015): 28010–21. http://dx.doi.org/10.1039/c5cp00889a.

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Density functional theory based global geometry optimization has been used to demonstrate the crucial influence of the geometry of the catalytic cluster on the energy barriers for the CO oxidation reaction over Pd-based bimetallic nanoalloys.

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14

Gabriele, Bartolo, Raffaella Mancuso, Giuseppe Salerno, and Lucia Veltri. "Sequential homobimetallic catalysis: an unprecedented tandem Pd(0)-catalysed deprotection ? Pd(ii)-catalysed heterocyclisation reaction leading to benzofurans." Chemical Communications, no. 2 (2005): 271. http://dx.doi.org/10.1039/b413240h.

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15

Yoshimura, Aya, Michiyo Yoshinaga, Hiroshi Yamashita, Masayasu Igarashi, Shigeru Shimada, and Kazuhiko Sato. "A convenient and clean synthetic method for borasiloxanes by Pd-catalysed reaction of silanols with diborons." Chemical Communications 53, no. 43 (2017): 5822–25. http://dx.doi.org/10.1039/c7cc02420g.

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16

Davuluri, Yogeswara Rao, and Anoop Anakuthil. "Density Functional Theory study on the formation of the active catalysts in palladium catalysed reaction." Journal of Indian Chemical Society Vol. 96, Jul 2019 (2019): 909–19. https://doi.org/10.5281/zenodo.5644712.

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Department of Chemistry, Indian Institute of Technology Kharagpur, Kharagpur-721 302, West Bengal, India <em>E-mail</em>: anoop@chem.iitkgp.ac.in <em>Manuscript received online 03 May 2019, revised and accepted 22 May 2019</em> The formation of active catalyst species in the Pd-catalyzed reactions is studied using Density Functional Theory calculations. Taking palladium acetate and simple phosphine as the models, we estimated the energetics for the addition of phosphines, release of acetates, and associative exchange or ligands which convert the unreactive PdOAc<sub>2</sub> to reactive species

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17

Kayet, Anirban, and Vinod K. Singh. "A one-pot synthesis of 2,2′-disubstituted diindolylmethanes (DIMs) via a sequential Sonogashira coupling and cycloisomerization/C3-functionalization of 2-iodoanilines." Organic & Biomolecular Chemistry 15, no. 33 (2017): 6997–7007. http://dx.doi.org/10.1039/c7ob01701d.

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Pd(ii)–Ag(i) catalysed, highly efficient synthesis of diindolylmethanes under mild reaction conditions, with six new bonds being formed in a one-pot fashion, and the products being transformed into synthetically useful compounds.

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18

Matias, Inês A. S., Ana P. C. Ribeiro, and Luísa M. D. R. S. Martins. "Microwave-Assisted Solvent- and Cu(I)-Free Sonogashira C-C Cross-Coupling Catalysed by Pd Ionanofluids." Processes 12, no. 7 (2024): 1351. http://dx.doi.org/10.3390/pr12071351.

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The microwave-assisted Sonogashira C-C cross-coupling reaction catalysed by Pd ionanofluids based on bis(trifluoromethane-sulfonyl)imide (NTf2) ionic liquids, [Cnmim][NTf2] (n = 4, 6 or 8), is described here. An organic solvent- and Cu(I)-free methodology running under very mild conditions was established by creating in situ catalysts from Pd(II) salts and [Cnmim][NTf2]. The microwave-irradiated catalytic systems quickly yielded almost quantitative conversions of 4-bromoanisole and phenylacetylene (model reaction) into the desired 1-methoxy-4-(phenylethynyl)benzene as a single product, and a g

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19

Xiong, Xue, Yang-Jie Mao, Hong-Yan Hao, et al. "Nitrate promoted mild and versatile Pd-catalysed C(sp2)–H oxidation with carboxylic acids." Organic & Biomolecular Chemistry 18, no. 34 (2020): 6732–37. http://dx.doi.org/10.1039/d0ob01124j.

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A nitrate-promoted Pd-catalysed cross-dehydrogenative C(sp<sup>2</sup>)–H oxidation of oximes or azobenzenes with diverse aromatic and aliphatic acids was developed, allowing the versatile formation of O-aryl esters under mild reaction conditions.

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20

Kuuloja, Noora, Tuula Kylmälä, Youjun Xu, and Robert Franzén. "Synthesis of Xenbucin using Suzuki reaction catalyzed by Pd/C in water." Open Chemistry 6, no. 3 (2008): 390–92. http://dx.doi.org/10.2478/s11532-008-0044-1.

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AbstractXenbucin 1, an analgesic drug, was synthesized in 4 steps using two different routes. The biaryl fragment could successfully be produced via a Pd/C catalysed Suzuki coupling in water using sodium tetraphenylborate as a phenylation reagent. Overall yields of the routes were 36% and 59%, respectively.

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21

Pradhan, Subhashis, Subhadip Dutta, and Rohith P. John. "A coordination driven self-assembled Pd6L8 nanoball catalyses copper and phosphine-free Sonogashira coupling reaction in both homogeneous and heterogeneous formats." New Journal of Chemistry 40, no. 8 (2016): 7140–47. http://dx.doi.org/10.1039/c5nj03658e.

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A self-assembled Pd<sub>6</sub>L<sub>8</sub> nanocage catalysed copper free Sonogashira reaction under mild and aerobic conditions, at 100 ppm catalyst loading in aqueous medium in the homogeneous phase, and at 500 ppm in the heterogeneous phase.

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22

Ishitsuka, Takuya, Yasuhiro Okuda, Robert K. Szilagyi, Seiji Mori, and Yasushi Nishihara. "The molecular mechanism of palladium-catalysed cyanoesterification of methyl cyanoformate onto norbornene." Dalton Transactions 45, no. 18 (2016): 7786–93. http://dx.doi.org/10.1039/c6dt00341a.

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Density functional theory-based potential energy surface investigation revealed that the reaction mechanism of palladium-catalysed cyanoesterification onto norbornene (NBE) proceeds through exclusive exo-coordination, regioselective olefin insertion first into the Pd–COOR bond, and reduction elimination to form the subsituted NBE.

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23

Trzeciak, Anna, Przemyslaw Wojcik, Radoslaw Lisiecki, Yuriy Gerasymchuk, Wieslaw Strek, and Janina Legendziewicz. "Palladium Nanoparticles Supported on Graphene Oxide as Catalysts for the Synthesis of Diarylketones." Catalysts 9, no. 4 (2019): 319. http://dx.doi.org/10.3390/catal9040319.

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Three palladium catalysts supported on graphene oxide (GO) and on its composite with TiO2 (GO-TiO2) were prepared and characterized. The presence of Pd NPs of different diameters (4–89 nm) and size distributions was evidenced by TEM measurements. GO-supported palladium efficiently catalysed the carbonylative coupling of iodobenzenes with aryl boronic acids forming relevant diarylketones at 1 atm CO. The highest activity and recyclability were obtained for Pd/GO-TiO2. The emission behaviour of Pd/GO and Pd/GO-TiO2 catalysts indicated structural changes occurring during the catalytic reaction.

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24

Das, Sajal, and Prasanjit Ghosh. "Creation of 4-Quinolone Thioether and Selenoether Derivatives via Pd-NHC Catalysed Cross-Coupling Reaction." SynOpen 04, no. 02 (2020): 33–37. http://dx.doi.org/10.1055/s-0039-1690897.

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Pd-NHC catalysed direct sulfenylation and selenylation of 3-iodo-4-quinolones has been developed. This protocol provides an alternative route for the construction of ipso-C–S and C–Se bond formation in 4-quinolones under aerobic conditions.

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25

Nagy, Enikő, Attila Máriás, Margit Kovács, and Rita Skoda-Földes. "Synthesis of 6- or 8-Carboxamido Derivatives of Imidazo[1,2-a]pyridines via a Heterogeneous Catalytic Aminocarbonylation Reaction." Molecules 29, no. 21 (2024): 5048. http://dx.doi.org/10.3390/molecules29215048.

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Imidazo[1,2-a]pyridines and especially their amide derivatives exhibit a wide range of favourable pharmacological properties. In this work, Pd-catalysed carbonylation was used for the first time for the introduction of the carboxamide moiety into positions 6 or 8. A recyclable Pd catalyst, with palladium immobilised on a supported ionic liquid phase decorated with pyridinium ions, was used efficiently for the conversion of 6- or 8-iodo derivatives to the products. In the case of 6-iodo derivatives, a competing mono- and double carbonylation could be observed in the reactions of aliphatic amine

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26

Zhang, Kan, Yanxiu Yao, Wenjin Sun, et al. "Triazine-wingtips accelerated NHC-Pd catalysed carbonylative Sonogashira cross-coupling reaction." Chemical Communications 57, no. 96 (2021): 13020–23. http://dx.doi.org/10.1039/d1cc05280b.

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27

Nikoshvili, Linda Zh, Kristina N. Shkerina, Alexey V. Bykov, et al. "Mono- and Bimetallic Nanoparticles Stabilized by an Aromatic Polymeric Network for a Suzuki Cross-Coupling Reaction." Nanomaterials 12, no. 1 (2021): 94. http://dx.doi.org/10.3390/nano12010094.

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This work addresses the Suzuki cross-coupling between 4-bromoanisole (BrAn) and phenylboronic acid (PBA) in an environmentally benign ethanol–water solvent catalysed by mono- (Pd) and bimetallic (PdAu, PdCu, PdZn) nanoparticles (NPs) stabilised within hyper-cross-linked polystyrene (HPS) bearing tertiary amino groups. Small Pd NPs of about 2 nm in diameters were formed and stabilized by HPS independently in the presence of other metals. High catalytic activity and complete conversion of BrAn was attained at low Pd loading. Introduction of Zn to the catalyst composition resulted in the formatio

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28

Landge, Vinod G., Manoj K. Sahoo, Siba P. Midya, Garima Jaiswal, and Ekambaram Balaraman. "Well-defined palladium(ii) complexes for ligand-enabled C(sp3)-alkynylation." Dalton Transactions 44, no. 35 (2015): 15382–86. http://dx.doi.org/10.1039/c5dt02772a.

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The first example of ligand-enabled C(sp<sup>3</sup>)-alkynylation of 8-methylquinoline is reported. The reaction is catalysed by well-defined Pd(ii) complexes. The present C(sp<sup>3</sup>)-alkynylation has a broad substrate scope as well as functional group tolerance and proceeds under mild conditions.

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29

Linnenberg, Oliver, Lisa Mayerl, and Kirill Yu Monakhov. "The Heck reaction as a tool to expand polyoxovanadates towards thiol-sensitive organic–inorganic hybrid fluorescent switches." Dalton Transactions 47, no. 41 (2018): 14402–7. http://dx.doi.org/10.1039/c8dt02340a.

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Pd-catalysed Heck cross-coupling reactions between organically-tailored polyoxovanadates and a variety of olefins were realised. The synthesised organic–inorganic hybrids pave the way for the redox-driven luminescence switching, opening up great perspectives in tracing smart reducing agents such as e.g. toxic thiols.

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30

Wippich, Julian, Ingo Schnapperelle, and Thorsten Bach. "Regioselective oxidative Pd-catalysed coupling of alkylboronic acids with pyridin-2-yl-substituted heterocycles." Chem. Commun. 51, no. 15 (2015): 3166–68. http://dx.doi.org/10.1039/c4cc10144h.

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A total of 19 alkylated heterocycles (thiophenes, benzo-thiophenes, pyrroles, furans) were prepared (36–99% yield) from the respective pyridin-2-yl-substituted precursors employing alkylboronic acids as the alkylating reagents in an oxidative (Ag<sub>2</sub>CO<sub>3</sub> and 2,6-dimethyl-1,4-benzoquinone as oxidants) Pd-catalysed coupling reaction.

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31

Cao, Liwei, Mikhail Kabeshov, Steven V. Ley, and Alexei A. Lapkin. "In silico rationalisation of selectivity and reactivity in Pd-catalysed C–H activation reactions." Beilstein Journal of Organic Chemistry 16 (June 25, 2020): 1465–75. http://dx.doi.org/10.3762/bjoc.16.122.

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A computational approach has been developed to automatically generate and analyse the structures of the intermediates of palladium-catalysed carbon–hydrogen (C–H) activation reactions as well as to predict the final products. Implemented as a high-performance computing cluster tool, it has been shown to correctly choose the mechanism and rationalise regioselectivity of chosen examples from open literature reports. The developed methodology is capable of predicting reactivity of various substrates by differentiation between two major mechanisms – proton abstraction and electrophilic aromatic su

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32

Zhang, Guolin. "Ligand-free Suzuki-Miyaura reaction catalysed by Pd/C at room temperature." Journal of Chemical Research 2004, no. 9 (2004): 593–95. http://dx.doi.org/10.3184/0308234042430539.

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33

Qiu, Weiming, and Zhiqin Wang. "Pd-catalysed reaction of allylic acetates with carbonyl compounds via electrochemical reduction." Journal of the Chemical Society, Chemical Communications, no. 6 (1989): 356. http://dx.doi.org/10.1039/c39890000356.

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34

Nazmul Alam, Md, Shaheen M. Sarkar, and Md Rezwan Miah. "Heterogeneous Heck reaction catalysed by silica gel-supported 1,2-diaminocyclohexane–Pd complex." Reaction Kinetics and Catalysis Letters 98, no. 2 (2009): 383–89. http://dx.doi.org/10.1007/s11144-009-0085-2.

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35

Siciliano, Sofia, Elena Cini, Maurizio Taddei, and Giorgia Vinciarelli. "Synthesis of 2-Substitued Indoles via Pd-Catalysed Cyclization in an Aqueous Micellar Medium." Molecules 26, no. 13 (2021): 3917. http://dx.doi.org/10.3390/molecules26133917.

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The synthesis of 2-substituted indoles starting from the corresponding unprotected 2-alkynylanilines was made possible in 3% TPGS-750-M water using Pd(OAc)2 alone as the catalyst. The reaction was sensitive to the heating mode respect to the nature of the starting material as, in many cases, convectional heating was better than microwave dielectric heating. The MW (microwave) delivery mode had also an influence in the formation of by-products and, consequently, product yields. A tandem Sonogashira-cyclisation reaction was also accomplished using Pd(OAc)2/Xphos in the nanomicellar water environ

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36

Liu, Hui, Tiesheng Li, Xiaoxia Xue, Wenjian Xu, and Yangjie Wu. "The mechanism of a self-assembled Pd(ferrocenylimine)–Si compound-catalysed Suzuki coupling reaction." Catalysis Science & Technology 6, no. 6 (2016): 1667–76. http://dx.doi.org/10.1039/c5cy01341k.

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37

Zhang, Wei. "Copper-Free Palladium-Catalysed Desulfinative Homocoupling of Sodium Arylsulfinates under Mild and Aerobic Conditions." Journal of Chemical Research 41, no. 1 (2017): 1–3. http://dx.doi.org/10.3184/174751916x14798135087600.

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A Pd(II)-catalysed homocoupling of sodium arylsulfinates has been successfully achieved under mild conditions. This transformation is a new method for the homocoupling reaction of sodium arylsulfinates, thus providing an alternative synthesis of symmetric biaryls. The reported homocoupling reaction is tolerant to many common functional groups, such as ester, halo, cyano and nitro and works well in the presence of electron-donating and electron-withdrawing substituents. Notably, the reported desulfinative homocoupling does not require Cu salts, ligands and bases, making this newly developed tra

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38

Hu, Ronghua, Yan Yu та Mingzhong Cai. "Stereoselective Synthesis of Vinyl Sulfones by the Stille Coupling of (E)-α-Stannylvinyl Sulfones with Aryl Halides". Journal of Chemical Research 2008, № 10 (2008): 592–94. http://dx.doi.org/10.3184/030823408x360319.

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Palladium-catalysed hydrostannylation of acetylenic sulfones (R–C≡C–SO2Ar) in benzene at room temperature gives stereoselectively (E)-α-stannylvinyl sulfones in good to high yields. (E)-α-Stannylvinyl sulfones are difunctional group reagents which undergo Stille coupling reaction with aryl halides in the presence of Pd(PPh3)4 and CuI co-catalyst to afford stereoselectively (Z)-1,2-disubstituted vinyl sulfones in good yields.

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39

Khodja, Walid, Alexandre Leclair, Jordi Rull-Barrull, et al. "The promoting effect of pyridine ligands in the Pd-catalysed Heck–Matsuda reaction." New Journal of Chemistry 40, no. 10 (2016): 8855–62. http://dx.doi.org/10.1039/c6nj01717g.

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40

Singh, Keisham. "Recent Advances in C–H Bond Functionalization with Ruthenium-Based Catalysts." Catalysts 9, no. 2 (2019): 173. http://dx.doi.org/10.3390/catal9020173.

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The past decades have witnessed rapid development in organic synthesis via catalysis, particularly the reactions through C–H bond functionalization. Transition metals such as Pd, Rh and Ru constitute a crucial catalyst in these C–H bond functionalization reactions. This process is highly attractive not only because it saves reaction time and reduces waste,but also, more importantly, it allows the reaction to be performed in a highly region specific manner. Indeed, several organic compounds could be readily accessed via C–H bond functionalization with transition metals. In the recent past, trem

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41

Damas, Liliana, Rui M. B. Carrilho, Sandra C. C. Nunes, et al. "A novel Pd-catalysed sequential carbonylation/cyclization approach toward bis- N -heterocycles: rationalization by electronic structure calculations." Royal Society Open Science 5, no. 9 (2018): 181140. http://dx.doi.org/10.1098/rsos.181140.

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An unprecedented palladium-catalysed sequential aminocarbonylation/cyclization synthetic strategy, using carbon monoxide and structurally different aliphatic diamines as N -nucleophiles, gives access, in one pot, to a new family of indole-based N -heterocyclic derivatives (hydropyrazinones, benzodiazepinones and hydroquinoxalines). Optimization of the reaction conditions towards double carbonylation ( P CO = 30 bar, T = 80°C, iodoindole/diamine ratio = 1 : 1.5, toluene as solvent) allowed the target cyclic products, which are formed in situ via intramolecular cyclization of the ketocarboxamide

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42

Voronov, Aleksandr, Vinayak Botla, Luca Montanari та ін. "Pd-Catalysed oxidative carbonylation of α-amino amides to hydantoins under mild conditions". Chemical Communications 58, № 2 (2022): 294–97. http://dx.doi.org/10.1039/d1cc04154a.

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The common reaction pathway involving unprotected α-amino amides that leads to the formation of symmetrical urea under palladium-catalyzed carbonylative conditions is avoided here. Hydantoins are selectively obtained under mild and safe conditions.

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43

Xiao, Xue-Dong, Jia-Qi Liu, Ya-Li Bai, Rui-Hua Wang, and Jun-Wen Wang. "Pillar[5]arene-based N-heterocyclic carbene ligand for Pd-catalysed Suzuki reaction." Journal of Inclusion Phenomena and Macrocyclic Chemistry 87, no. 1-2 (2016): 29–36. http://dx.doi.org/10.1007/s10847-016-0673-5.

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44

Sajiki, Hironao, Kazuyuki Hattori, Fumiyo Aoki, Kanoko Yasunaga, and Kosaku Hirota. "Pd/C-H2-Catalysed Deuterium Exchange Reaction of the Benzylic Site in D2O." Synlett 2002, no. 07 (2002): 1149–51. http://dx.doi.org/10.1055/s-2002-32605.

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45

Dethe, Dattatraya H., and Raghavender Boda. "A Novel Pd-Catalysed Annulation Reaction for the Syntheses of Pyrroloindoles and Pyrroloquinolines." Chemistry - A European Journal 22, no. 1 (2015): 106–10. http://dx.doi.org/10.1002/chem.201503652.

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46

Law, Cindy Ka Y., Luiza Bonin, Bart De Gusseme, Nico Boon, and Kankana Kundu. "Biogenic synthesis of palladium nanoparticles: New production methods and applications." Nanotechnology Reviews 11, no. 1 (2022): 3104–24. http://dx.doi.org/10.1515/ntrev-2022-0482.

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Abstract The palladium (Pd)-catalysed reaction has attracted much attention, making Pd the most valuable of the four major precious metals. Several different forms of Pd can be used as a catalyst; nanoparticles (NPs) have the advantage of a high surface area:volume ratio. Since the chemical production of Pd NPs is not environmentally friendly, biological synthesis interest has grown. However, the production mechanism remained unknown in several cases and was recently described for the electroactive bacterium Shewanella oneidensis MR-1. The application of these green synthesised NPs was establi

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Yuan, Kedong, Rui Sang, Jean-François Soulé, and Henri Doucet. "Desulfitative Pd-catalysed coupling reaction using benzenesulfonyl chlorides and enones as the coupling partners." Catalysis Science & Technology 5, no. 5 (2015): 2904–12. http://dx.doi.org/10.1039/c5cy00089k.

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Kuwabara, Junpei, Masaru Sakai, Qiao Zhang, and Takaki Kanbara. "Mechanistic studies and optimisation of a Pd-catalysed direct arylation reaction using phosphine-free systems." Organic Chemistry Frontiers 2, no. 5 (2015): 520–25. http://dx.doi.org/10.1039/c4qo00351a.

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Reay, Alan J., Thomas J. Williams, and Ian J. S. Fairlamb. "Unified mild reaction conditions for C2-selective Pd-catalysed tryptophan arylation, including tryptophan-containing peptides." Organic & Biomolecular Chemistry 13, no. 30 (2015): 8298–309. http://dx.doi.org/10.1039/c5ob01174d.

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Polin, Johann, Herwig Schottenberger, and Karl Eberhard Schwarzhans. "Asymmetrie Ethynes. Syntheses of Ethynylferrocene Paradigms." Zeitschrift für Naturforschung B 51, no. 12 (1996): 1683–90. http://dx.doi.org/10.1515/znb-1996-1204.

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Synthetic methods to bifunctional ethynes have been examined. Direct ethynylation, the Stephens-Castro reaction, the Pd-catalysed Hagihara coupling, transmetalation reactions and nucleophilic additions have been evaluated in the preparation of substituted ferrocenylethynes with intended use of these materials in electrochemical and nonlinear optical investigations. Asymmetric ferrocenylethynes are promising candidates for applications in contemporary materials science. Synthetically, 1,4-bis(ferrocenylethynylene)benzene (1), 1,3,5-tris(ferrocenylethynylene) benzene (2), and 9 ,10-bis(ferroceny

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