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Journal articles on the topic 'Pentanetriol'

Author: Grafiati

Published: 2 June 2025

Last updated: 31 July 2025

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1

Zhu, Chun, Travis B. Meador, Wolf Dummann, and Kai-Uwe Hinrichs. "Identification of unusual butanetriol dialkyl glycerol tetraether and pentanetriol dialkyl glycerol tetraether lipids in marine sediments." Rapid Communications in Mass Spectrometry 28 (December 27, 2013): 332–38. https://doi.org/10.1002/rcm.6792.

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RATIONALE: Glycerol serves as the principal backbone moiety bound to various acyl/alkyl chains for membrane lipids of <em>Eukarya</em>, <em>Bacteria</em>, and <em>Archaea</em>. In this study, we report a suite of unusual tetraether lipids in which one of the two conventional glycerol backbones is substituted by butanetriol or pentanetriol. METHODS: Identification of these lipids was achieved via diagnostic fragments and their expected acetylation products using liquid chromatography/mass spectrometry (LC/MS), and their diagnostic ether cleavage products using gas chromatography/mass spectromet

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2

Coffinet, Sarah, Travis B. Meador, Lukas Mühlena, et al. "Structural elucidation and environmental distributions of butanetriol and pentanetriol dialkyl glycerol tetraethers (BDGTs and PDGTs)." Biogeosciences 17, no. 2 (2020): 317–30. http://dx.doi.org/10.5194/bg-17-317-2020.

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Abstract. Butanetriol and pentanetriol dialkyl glycerol tetraethers (BDGTs and PDGTs) are membrane lipids, recently discovered in sedimentary environments and in the methanogenic archaeon Methanomassiliicoccus luminyensis. They possess an unusual structure, which challenges fundamental assumptions in lipid biochemistry. Indeed, they bear a butanetriol or a pentanetriol backbone instead of a glycerol at one end of their core structure. In this study, we unambiguously located the additional methyl group of the BDGT compound on the C3 carbon of the lipid backbone via high-field nuclear magnetic r

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3

Chênevert, Robert, and Gabriel Courchesne. "Enzymatic desymmetrization of meso(anti-anti)-2,4-dimethyl-1,3,5-pentanetriol." Tetrahedron: Asymmetry 6, no. 9 (1995): 2093–96. http://dx.doi.org/10.1016/0957-4166(95)00272-q.

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4

FEDORTSOVA, E. V., G. S. IDLIS, E. M. SHVARTS, and A. Z. KAMARS. "ChemInform Abstract: Reaction of Boric Acid with 3-Methyl-1,3,5-pentanetriol." ChemInform 26, no. 21 (2010): no. http://dx.doi.org/10.1002/chin.199521177.

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5

Santaniello, Enzo, Rosangela Casati, Lucio Ceriani, Patrizia Ferraboschi, and Paride Grisenti. "Synthesis of 3-methyl-1,3,5-pentanetriol and its mono- and diesters." Chemistry and Physics of Lipids 49, no. 1-2 (1988): 97–100. http://dx.doi.org/10.1016/0009-3084(88)90069-2.

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6

CHENEVERT, R., and G. COURCHESNE. "ChemInform Abstract: Enzymatic Desymmetrization of meso(anti-anti)-2,4-Dimethyl-1,3,5- pentanetriol." ChemInform 27, no. 6 (2010): no. http://dx.doi.org/10.1002/chin.199606069.

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7

Becker, Kevin W., Felix J. Elling, Marcos Y. Yoshinaga, Andrea Söllinger, Tim Urich, and Kai-Uwe Hinrichs. "Unusual Butane- and Pentanetriol-Based Tetraether Lipids in Methanomassiliicoccus luminyensis, a Representative of the Seventh Order of Methanogens." Applied and Environmental Microbiology 82, no. 15 (2016): 4505–16. http://dx.doi.org/10.1128/aem.00772-16.

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ABSTRACTA new clade of archaea has recently been proposed to constitute the seventh methanogenic order, theMethanomassiliicoccales, which is related to theThermoplasmatalesand the uncultivated archaeal clades deep-sea hydrothermal ventEuryarchaeotagroup 2 and marine group IIEuryarchaeotabut only distantly related to other methanogens. In this study, we investigated the membrane lipid composition ofMethanomassiliicoccus luminyensis, the sole cultured representative of this seventh order. The lipid inventory ofM. luminyensiscomprises a unique assemblage of novel lipids as well as lipids otherwis

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8

Yusufo??lu, Ayşe, Stefan Antons, and Hans-Dieter Scharf. "Syntheses of pure enantiomers oferythro-1,2,3-pentanetriol and their 1-Bromo- and 1-Tosyloxy Derivatives." Liebigs Annalen der Chemie 1986, no. 6 (1986): 1119–23. http://dx.doi.org/10.1002/jlac.198619860616.

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9

MacQueen, Blake, Michael Royko, Bradie S. Crandall, Andreas Heyden, Yomaira J. Pagán-Torres, and Jochen Lauterbach. "Kinetics Study of the Hydrodeoxygenation of Xylitol over a ReOx-Pd/CeO2 Catalyst." Catalysts 11, no. 1 (2021): 108. http://dx.doi.org/10.3390/catal11010108.

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In this study, we elucidate the reaction kinetics for the simultaneous hydrodeoxygenation of xylitol to 1,2-dideoxypentitol and 1,2,5-pentanetriol over a ReOx-Pd/CeO2 (2.0 weight% Re, 0.30 weight% Pd) catalyst. The reaction was determined to be a zero-order reaction with respect to xylitol. The activation energy was elucidated through an Arrhenius relationship as well as non-Arrhenius kinetics. The Arrhenius relationship was investigated at 150–170 °C and a constant H2 pressure of 10 bar resulting in an activation energy of 48.7 ± 10.5 kJ/mol. The investigation of non-Arrhenius kinetics was co

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10

Zhu, Chun, Travis B. Meador, Wolf Dummann, and Kai-Uwe Hinrichs. "Identification of unusual butanetriol dialkyl glycerol tetraether and pentanetriol dialkyl glycerol tetraether lipids in marine sediments." Rapid Communications in Mass Spectrometry 28, no. 4 (2013): 332–38. http://dx.doi.org/10.1002/rcm.6792.

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11

Soriente, Annunziata, Giovanna Laudisio, Maurizio Giordano, and Guido Sodano. "Enzymatic desymmetrization of a prochiral 1,3,5-pentanetriol derivative. Application to the synthesis of a cyanobacterial heterocyst glycolipid." Tetrahedron: Asymmetry 6, no. 4 (1995): 859–62. http://dx.doi.org/10.1016/0957-4166(95)00089-8.

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12

Tapia, O., and J. Andr�s. "Towards an explanation of carboxylation/oxygenation bifunctionality in Rubisco. Transition structure for the carboxylation reaction of 2,3,4-pentanetriol." Molecular Engineering 2, no. 1 (1992): 37–41. http://dx.doi.org/10.1007/bf00999521.

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13

SORIENTE, A., G. LAUDISIO, M. GIORDANO, and G. SODANO. "ChemInform Abstract: Enzymatic Desymmetrization of a Prochiral 1,3,5-Pentanetriol Derivative. Application to the Synthesis of a Cyanobacterial Heterocyst Glycolipid." ChemInform 26, no. 36 (2010): no. http://dx.doi.org/10.1002/chin.199536266.

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14

Miyazawa, Kazutoshi, and Naoyuki Yoshida. "A Convenient Synthesis of (2S,4R)-1-Acetoxy-2,4-O-Isopropylidene-1,2,5-Pentanetriol by Using Lipase Catalyzed Regio- and Enantioselective Reactions." Chemistry Letters 22, no. 9 (1993): 1529–30. http://dx.doi.org/10.1246/cl.1993.1529.

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15

MIYAZAWA, K., and N. YOSHIDA. "ChemInform Abstract: A Convenient Synthesis of (2S,4R)-1-Acetoxy-2,4-O-isopropylidene-1,2,5- pentanetriol by Using Lipase-Catalyzed Regio- and Enantioselective Reactions." ChemInform 25, no. 25 (2010): no. http://dx.doi.org/10.1002/chin.199425051.

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16

Gong, Qihang, Peikai Luo, Jian Li, Xinluona Su, and Haiyang Cheng. "Chemical Transformation of Biomass-Derived Furan Compounds into Polyols." Chemistry 6, no. 5 (2024): 941–61. http://dx.doi.org/10.3390/chemistry6050055.

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Polyols such as 1,5-pentadiol, 1,6-hexanediol, and 1,2,6-hexanetriol are crucial chemicals, traditionally derived from non-renewable fossil sources. In the pursuit of sustainable development, exploring renewable and environmentally benign routes for their production becomes imperative. Furfural and 5-hydroxymethylfurfural are C5 and C6 biomass-derived platform molecules, which have potential in the synthesis of various polyols through hydrogenation and hydrogenolysis reactions. Currently, there is an extensive body of literature exploring the transformation of biomass-derived furan compounds.

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17

Onyegbule, F. A., N. E. Egba, C. C. Abba, S. O. Bruce, B. O. Umeokoli, and O. O. Anyanwu. "Pharmacognostic and in vitro antimicrobial evaluation of the sub-fractions of the ethyl acetate fraction of the methanol leaf extract of Anthocleista djalonensis." Journal of Scientific and Innovative Research 12, no. 1 (2023): 13–19. http://dx.doi.org/10.31254/jsir.2023.12103.

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Anthocleista djalonensis has many ethnomedicinal claims, one of which is the treatment of infections. The study evaluated the phytochemical, physicochemical profile and antimicrobial properties of the vacuum liquid chromatographic (VLC) sub-fractions of A. Djalonensis leaves. The plant was collected from Umuoji, Idemili North, Anambra State. The plant leaves were identified, authenticated and the herbarium specimen was deposited, with herbarium number PCG/474/A/057. The leaves were dried, pulverized and extracted using cold maceration with methanol, and fractionated successively into n-Hexane,

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18

Chike, Luke Orjiekwe, Adegoke Adeniyi Samuel, and Uluego Orjiekwe Immaculata. "Synthesis and fungicidal properties of 2,4-diaza-1,3,5-pentanetrione compounds." African Journal of Biotechnology 12, no. 27 (2013): 4368–73. http://dx.doi.org/10.5897/ajb09.942.

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19

Cacho, J., M. A. Lacoma, and C. Nerín. "Gravimetric and spectrophotometric determination of palladium with 2,3,4-pentanetrione trioxime." Talanta 32, no. 1 (1985): 11–14. http://dx.doi.org/10.1016/0039-9140(85)80005-9.

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20

Harada, Toshiro, Isao Wada, Jun-ji Uchimura, Atsushi Inoue, Sachi Tanaka, and Akira Oku. "Enantiodifferentiating transformation of prochiral 1,3,5-pentanetriols controlled by intramolecular van der Waals attractions." Tetrahedron Letters 32, no. 9 (1991): 1219–22. http://dx.doi.org/10.1016/s0040-4039(00)92049-5.

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21

Andersen, Kristine B., Shiming Li, Knut Lundquist, et al. "Infrared Linear Dichroism on 1,5-Diphenyl-1,3,5-pentanetrione Aligned in Stretched Polyethylene." Acta Chemica Scandinavica 52 (1998): 1171–76. http://dx.doi.org/10.3891/acta.chem.scand.52-1171.

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22

HARADA, T., I. WADA, J. UCHIMURA, A. INOUE, S. TANAKA, and A. OKU. "ChemInform Abstract: Enantiodifferentiating Transformation of Prochiral 1,3,5-Pentanetriols Controlled by Intramolecular van der Waals Attractions." ChemInform 22, no. 51 (2010): no. http://dx.doi.org/10.1002/chin.199151207.

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23

Harada, Toshiro, Atsushi Inoue, Isao Wada, Junji Uchimura, Sachi Tanaka, and Akira Oku. "Stereoselective acetalization of 1,3-alkanediols controlled by intramolecular van der Waals attractive interactions and its application to an enantiodifferentiating transformation of .sigma.-symmetric 1,3,5-pentanetriols." Journal of the American Chemical Society 115, no. 17 (1993): 7665–74. http://dx.doi.org/10.1021/ja00070a010.

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24

PATEL, H. V., K. A. VYAS, S. P. PANDEY, and P. S. FERNANDES. "ChemInform Abstract: Reaction of 2,3,4-Pentanetrione-3-arylhydrazones (I) with N,N- Dimethylhydrazine (II): Formation of Substituted 1H-Pyrazoles (III) via Demethylation." ChemInform 24, no. 29 (2010): no. http://dx.doi.org/10.1002/chin.199329135.

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25

HARADA, T., A. INOUE, I. WADA, J. UCHIMURA, S. TANAKA та A. OKU. "ChemInform Abstract: Stereoselective Acetalization of 1,3-Alkanediols Controlled by Intramolecular van der Waals Attractive Interactions and Its Application to an Enantiodifferentiating Transformation of σ- Symmetric 1,3,5-Pentanetriols." ChemInform 24, № 51 (2010): no. http://dx.doi.org/10.1002/chin.199351054.

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26

Coffinet, Sarah, Lukas Mühlena, Julius S. Lipp, et al. "Evidence for Enzymatic Backbone Methylation of the Main Membrane Lipids in the Archaeon Methanomassiliicoccus luminyensis." Applied and Environmental Microbiology 88, no. 4 (2022). http://dx.doi.org/10.1128/aem.02154-21.

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Butanetriol and pentanetriol dibiphytanyl glycerol tetraethers are membrane lipids recently discovered in anoxic environments. These lipids differ from typical membrane-spanning tetraether lipids because they possess a nonglycerol backbone.

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27

YUSUFOGLU, A., S. ANTONS, and H. D. SCHARF. "ChemInform Abstract: Syntheses of Pure Enantiomers of erythro-1,2,3-Pentanetriol and Their 1-Bromo- and 1-Tosyloxy Derivatives." Chemischer Informationsdienst 17, no. 43 (1986). http://dx.doi.org/10.1002/chin.198643304.

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28

Setiawati, Setiawati, Eti Nurwening ,. Sholikah, Titik Nuryastuti, Jumina Jumina, Puspita Lisdiyanti, and Mustofa Mustofa. "The potency of Actinomycetes InaCC A758 against dual-species biofilms: Candida albicans and Staphylococcus aureus." Journal of Applied Pharmaceutical Science, 2024. http://dx.doi.org/10.7324/japs.2024.144035.

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Candida albicans and Staphylococcus aureus can coexist to form a biofilm, leading to infections associated with biofilms. Actinomycetes produce secondary metabolites known as antibiotics, antifungals, antibiofilm, anticancer, and antimalarials. This study was aimed to explore the antibiofilm activity of secondary metabolites of Actinomycetes InaCC A758 extracts (InaCC A758) against dual-species biofilms, i.e., C. albicans and S. aureus. Ethyl acetate and chloroform were used as solvents in a maceration extraction technique to isolate the compound designated InaCC A758. The fractionation of the

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29

CLASSEN, A., S. WERSHOFEN, A. YUSUFOGLU, and H. D. SCHARF. "ChemInform Abstract: Preparation of Enantiomeric erythro- and threo-1,2,3-Pentanetriols by an Enzymatic Racemate Resolution." ChemInform 18, no. 43 (1987). http://dx.doi.org/10.1002/chin.198743122.

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30

Obaleye, Joshua A., Chilke L. Orjiekwe, and Dennis A. Edwards. "Cobalt(II) and nickell(II) complexes of 1,5-dicinnamyl1-2,4-diaza-1,3,5-pentanetrione." Bulletin of the Chemical Society of Ethiopia 13, no. 1 (1999). http://dx.doi.org/10.4314/bcse.v13i1.21053.

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