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Journal articles on the topic 'Perfluorophenyl derivatives'

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1

Kwiczak-Yiğitbaşı, Joanna, Jean-Luc Pirat, David Virieux, et al. "Synthesis, structural studies and biological properties of some phosphono-perfluorophenylalanine derivatives formed by SNAr reactions." RSC Advances 9, no. 42 (2019): 24117–33. http://dx.doi.org/10.1039/c9ra03982a.

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Several novel phosphono-perfluorophenylalanine derivatives, as mimetics of phenylalanine, were synthesized by subjecting diethyl (2-(perfluorophenyl)-1-(phenylamino)ethyl)-phosphonate to S<sub>N</sub>Ar reactions with thiols, amines and phenols.
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2

Syutkina, O. P., L. F. Rybakova, E. S. Petrov, and I. P. Beletskaya. "Thienyl and perfluorophenyl derivatives of divalent lanthanides." Journal of Organometallic Chemistry 280, no. 3 (1985): c67—c69. http://dx.doi.org/10.1016/0022-328x(85)88124-9.

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3

Askerova, Ulviyya F. "Prediction of Acute Toxicity of (Z) -N, N-Dimethyl-2- (perfluorophenyl) -2- (2-phenylhydrazinylidine)acetamide for Rats using the GUSAR Program." Pharmaceutical and Chemical Journal 8, no. 5 (2021): 63–66. https://doi.org/10.5281/zenodo.13963658.

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It is known that the determination of the values of half-lethal doses (LD<sub>50</sub>) for rodents is a necessary stage of preclinical experimental studies for putative physiologically active substances. To calculate (<em>in silico</em>) the LD<sub>50</sub> value for 4 methods of substance administration (oral, intraperitoneal, intravenous, subcutaneous), we used the GUSAR (General Unrestricted Structure-Activity Relationships) computer program as a web service. When making a forecast of the LD<sub>50</sub> value for the analyzed compound, it is assessed that it falls within the range of appl
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4

Petrova, T. D., and V. E. Platonov. "Reactions of N-(Perfluorophenyl)carbonimidoyl Dichloride with Aromatic Acids and Their Derivatives in the Presence of AlCl3. Formation of 2-(Perfluorophenyl)isoindoline-1,3-dione and Its Derivatives." Russian Journal of Organic Chemistry 41, no. 2 (2005): 218–26. http://dx.doi.org/10.1007/s11178-005-0147-5.

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5

Wyrębek, Przemysław, Anna Osuch-Kwiatkowska, Zbigniew Pakulski, Sławomir Jarosz, and Stanisław Ostrowski. "The synthesis of sugar-decorated hydrophilic porphyrins." Journal of Porphyrins and Phthalocyanines 17, no. 05 (2013): 384–91. http://dx.doi.org/10.1142/s1088424613500703.

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The synthesis of porphyrins conjugated with sugar moieties is described. meso-Aminophenyl-substituted and β-amino-substituted porphyrin derivatives reacted with benzyl protected glucuronic acid leading to gluco-conjugated hybrids, which after reductive deprotection of OH groups ( H2, 10% Pd/C ) gave the desired target products of increased hydrophilicity. Alternatively, this type of similar conjugates were obtained through SNAr reaction of meso-tetrakis(pentafluorophenyl)porphyrin with aminomethyl sacharides. The substitution took place selectively in para-position of meso-perfluorophenyl ring
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6

Chen, Yang, Jiao He, Hang Lin, et al. "Efficient synthesis of fluorinated triphenylenes with enhanced arene–perfluoroarene interactions in columnar mesophases." Beilstein Journal of Organic Chemistry 20 (December 16, 2024): 3263–73. https://doi.org/10.3762/bjoc.20.270.

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The high potential of non-covalent arene–fluoroarene intermolecular interactions in the design of liquid crystals lies in their ability to strongly promote self-assembly, improve the order and stability of the supramolecular mesophases, and enable tuneability of the optical and electronic properties, which can potentially be exploited for advanced applications in display technologies, photonic devices, sensors, and organic electronics. We recently successfully reported the straightforward synthesis of several mesogens containing four lateral aliphatic chains and derived from the classical trip
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7

Aivali, Stefania, Sofia Kakogianni, Charalampos Anastasopoulos, Aikaterini Andreopoulou, and Joannis Kallitsis. "Copolymers and Hybrids Based on Carbazole Derivatives and Their Nanomorphology Investigation." Nanomaterials 9, no. 2 (2019): 133. http://dx.doi.org/10.3390/nano9020133.

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Oligomers of the low-band-gap PCDTBT polymer, based on either 3,6 or 2,7 carbazole units, were modified with vinyl ω-chain end functionalities. The vinyl-functionalized oligomers were used as comonomers in free radical polymerizations with quinoline-based monomers such as 6-vinylphenyl-(2-pyridinyl)-4-phenyl-quinoline (vinyl-QPy), and 6-vinylphenyl-(2-perfluorophenyl)-4-phenyl quinoline (vinyl-5FQ). The co-polymeric materials bearing the vinyl-QPy moiety were developed as potential compatibilizers in polymer electron donor–fullerene acceptor blends for non-covalent interactions with the fuller
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8

Sivý, Július, Dušan Bortňák, Daniel Végh, and Erik Rakovský. "Two novel potent perfluorophenylhydrazone derivatives, 1-((4-bromothiophen-2-yl)methylene)-2-(perfluorophenyl) hydrazine, and 1-((4-bromo-5-methylthiophen-2-yl)methylene)-2-(perfluorophenyl)hydrazine as multi-target compounds to combat Alzheimer disease and their crystal, molecular, and electronic properties." Acta Chimica Slovaca 16, no. 1 (2023): 81–91. http://dx.doi.org/10.2478/acs-2023-0008.

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Abstract Two potent novel perfluorophenylhydrazone derivatives are presented as multi-target compounds to combat Alzheimer disease C11H4BrF5N2S, 1-((4-bromothiophen-2-yl)methylene)-2-(perfluorophenyl) hydrazine, (I) and C12H6BrF5N2S, 1-((4-bromo-5-methylthiophen-2-yl)methylene)-2-(perfluorophenyl) hydrazine, (II), which can potentially be improved by further design. Their multi-target structures and features have been combined as potential AD therapeutics. Crystals (I), and (II), are molecules with two rings and a hydrazone part as a centre of the molecule. The compounds have been synthesised
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9

Ileri, Merve, Serife O. Hacioglu, Ali Cirpan, and Levent Toppare. "Syntheses and Optical Properties of Perfluorophenyl Containing Benzimidazole Derivatives: The Effect of Donor Units." Journal of Macromolecular Science, Part A 52, no. 7 (2015): 510–16. http://dx.doi.org/10.1080/10601325.2015.1039321.

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10

Khan, Momin, Ghulam Ahad, Abdul Manaf, et al. "Synthesis, in vitro urease inhibitory activity, and molecular docking studies of (perfluorophenyl)hydrazone derivatives." Medicinal Chemistry Research 28, no. 6 (2019): 873–83. http://dx.doi.org/10.1007/s00044-019-02341-5.

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11

Menjón, Babil, Sonia Martínez-Salvador, Miguel A Gómez-Saso, et al. "Oxidative Addition of Halogens to Homoleptic Perfluoromethyl or Perfluorophenyl Derivatives of Platinum(II): A Comparative Study." Chemistry - A European Journal 15, no. 26 (2009): 6371–82. http://dx.doi.org/10.1002/chem.200900323.

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12

Xiong Cai, Sui, and John F. W. Keana. "4-azido-2-iodo-3,5,6-trifluorophenylcarbonyl derivatives. A new class of functionalized and iodinated perfluorophenyl azide photolabels." Tetrahedron Letters 30, no. 40 (1989): 5409–12. http://dx.doi.org/10.1016/s0040-4039(01)80580-3.

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13

Jin, Guifang, Jingwei Zhao, Jianwei Han, Shizheng Zhu, and Jianmin Zhang. "Iodine-promoted imino-Diels–Alder reaction of fluorinated imine with enol ether: synthesis of 2-perfluorophenyl tetrahydroquinoline derivatives." Tetrahedron 66, no. 4 (2010): 913–17. http://dx.doi.org/10.1016/j.tet.2009.11.092.

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14

Jin, Guifang, Jingwei Zhao, Jianwei Han, Shizheng Zhu, and Jianmin Zhang. "ChemInform Abstract: Iodine-Promoted Imino-Diels-Alder Reaction of Fluorinated Imine with Enol Ether: Synthesis of 2-Perfluorophenyl Tetrahydroquinoline Derivatives." ChemInform 41, no. 22 (2010): no. http://dx.doi.org/10.1002/chin.201022137.

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15

Moussallem, Chady, Magali Allain, Charlotte Mallet, Frédéric Gohier та Pierre Frère. "Fluorine–fluorine type II versus πF–π stacking interactions in the supramolecular organizations of extended thiophene derivatives end capped by imino-perfluorophenyl units". Journal of Fluorine Chemistry 178 (жовтень 2015): 34–39. http://dx.doi.org/10.1016/j.jfluchem.2015.06.018.

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16

McGrath, Jack, Rajeev Gautam, and Jianbing "Jimmy" Jiang. "High Energy Density Asymmetric Tetrathiafulvalene Derivative as a Catholyte for Non-Aqueous Redox Flow Batteries." ECS Meeting Abstracts MA2024-01, no. 53 (2024): 2787. http://dx.doi.org/10.1149/ma2024-01532787mtgabs.

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The inherent intermittency challenge associated with renewable energy sources prompts the rapid development of cost-effective, grid-scale energy storage technologies. Redox flow batteries (RFBs) represent a promising solution to this problem owing to their remarkable potential for scalability and the tunability offered by a wide range of available solution-based chemistries. However, to-date, RFB commercialization has been challenged by a lack of long-lived, energy-dense, and earth abundant charge storage materials. Many of these challenges can be addressed with the development of non-aqueous
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17

Alapour, Saba, Anamika Sharma, Beatriz G. de la Torre, Deresh Ramjugernath, Neil A. Koorbanally, and Fernando Albericio. "Perfluorophenyl Derivatives as Unsymmetrical Linkers for Solid Phase Conjugation." Frontiers in Chemistry 6 (November 28, 2018). http://dx.doi.org/10.3389/fchem.2018.00589.

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18

SYUTKINA, O. P., L. F. RYBAKOVA, E. S. PETROV, and I. P. BELETSKAYA. "ChemInform Abstract: THIENYL AND PERFLUOROPHENYL DERIVATIVES OF DIVALENT LANTHANIDES." Chemischer Informationsdienst 16, no. 25 (1985). http://dx.doi.org/10.1002/chin.198525296.

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19

Petrova, T. D., and V. E. Platonov. "Reactions of N-(Perfluorophenyl)carbonimidoyl Dichloride with Aromatic Acids and Their Derivatives in the Presence of AlCl3. Formation of 2-(Perfluorophenyl)isoindoline-1,3-dione and Its Derivatives." ChemInform 36, no. 39 (2005). http://dx.doi.org/10.1002/chin.200539077.

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20

Mary, Y. Sheena, Y. Shyma Mary, K. S. Resmi, and Ali Shokuhi Rad. "Spectroscopic and computational study of chromone derivatives with antitumor activity: detailed DFT, QTAIM and docking investigations." SN Applied Sciences 3, no. 2 (2021). http://dx.doi.org/10.1007/s42452-021-04188-1.

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AbstractTheoretical investigations of three pharmaceutically active chromone derivatives, (E)-3-((2,3,5,6-tetrafluorophenyl)hydrazono)methyl)-4H-chromen-4-one (TPC), (E)-3-((2-(2,4,6-trifluorophenyl)hydrazono)methyl)-4H-chromen-4-one (FHM) and(E)-3-((2-(perfluorophenyl)hydrazono)methyl)-4H-chromen-4-one (PFH) are reported. Molecular geometries, vibrational spectra, electronic properties and molecular electrostatic potential were investigated using density functional theory. Quantum theory of atoms in molecules (QTAIM) study shows that the maximum of ellipticity parameters in the existing bonds
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21

Wang, Xinping, Tao Wang, Shuxuan Tang, et al. "Rational Design of Crystalline and Enantiomerically Pure Helicenes with Open‐Shell Singlet Ground States." Angewandte Chemie International Edition, September 20, 2024. http://dx.doi.org/10.1002/anie.202415331.

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Helicene diradical derivatives have attracted widespread attentions because of their unique magnetic and chiroptoelectronic properties, however, crystalline and enantiomerically pure forms of helicene diradicals are extremely rare. Herein, we describe the rational design and synthesis of o‐quinone functionalized helicene diradicals with crystalline enantiomerical purity. Diradical dianion salt Rac‐3K and its enantiomers P/M‐3K were obtained by reduction of corresponding precursors Rac‐3 and P/M‐3 with two equivalent potassium graphite in THF in the presence of (di)benzo‐18‐crown‐6. Neutral dio
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22

Wang, Xinping, Tao Wang, Shuxuan Tang, et al. "Rational Design of Crystalline and Enantiomerically Pure Helicenes with Open‐Shell Singlet Ground States." Angewandte Chemie, September 20, 2024. http://dx.doi.org/10.1002/ange.202415331.

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Helicene diradical derivatives have attracted widespread attentions because of their unique magnetic and chiroptoelectronic properties, however, crystalline and enantiomerically pure forms of helicene diradicals are extremely rare. Herein, we describe the rational design and synthesis of o‐quinone functionalized helicene diradicals with crystalline enantiomerical purity. Diradical dianion salt Rac‐3K and its enantiomers P/M‐3K were obtained by reduction of corresponding precursors Rac‐3 and P/M‐3 with two equivalent potassium graphite in THF in the presence of (di)benzo‐18‐crown‐6. Neutral dio
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23

CAI, S. X., and J. F. W. KEANA. "ChemInform Abstract: 4-Azido-2-iodo-3,5,6-trifluorophenylcarbonyl Derivatives. A New Class of Functionalized and Iodinated Perfluorophenyl Azide Photolabels." ChemInform 21, no. 20 (1990). http://dx.doi.org/10.1002/chin.199020149.

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24

Dengale, Sujata G., Hemantkumar N. Akolkar, Bhausaheb K. Karale, et al. "Synthesis of 3‐(trifluoromethyl)‐1‐(perfluorophenyl)‐ 1 H ‐pyrazol‐5( 4 H )‐one derivatives via Knoevenagel condensation and their biological evaluation." Journal of the Chinese Chemical Society, November 26, 2020. http://dx.doi.org/10.1002/jccs.202000357.

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25

Hamurcu, Fatma, Ümmühan Özdemir Özmen, Ozan Sanlı Şentürk, et al. "Biological effects and crystal X‐ray study of novel Schiff base containing pentafluorophenyl hydrazine: In vitro and in silico studies." Chemistry & Biodiversity, September 24, 2023. http://dx.doi.org/10.1002/cbdv.202301132.

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A novel Schiff base namely 3,5‐di‐tert‐butyl‐6‐((2‐(perfluorophenyl) hydrazono) methyl) phenol was successfully synthesized and characterized using FTIR and 1H‐NMR, 13C‐NMR, and 19F‐NMR. The crystal structure analysis of the Schiff base compound was also characterized with single crystal X‐ray diffraction studies and supported the spectroscopic results. The cytotoxicity, anti‐bacterial properties, and enzyme inhibition of the compound were also investigated. The molecular docking studies were performed in order to explain the interactions of the synthesized compound with target enzymes. The ne
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