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Journal articles on the topic 'Peroxoborate'

Author: Grafiati

Published: 4 June 2025

Last updated: 1 August 2025

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1

Grootveld, Martin, Edward Lynch, Georgina Page, et al. "Potential Advantages of Peroxoborates and Their Ester Adducts Over Hydrogen Peroxide as Therapeutic Agents in Oral Healthcare Products: Chemical/Biochemical Reactivity Considerations In Vitro, Ex Vivo And In Vivo." Dentistry Journal 8, no. 3 (2020): 89. http://dx.doi.org/10.3390/dj8030089.

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Peroxides present in oral healthcare products generally exert favourable protective activities against the development and progression of tooth decay, plaque, gingivitis, and halitosis, etc. However, despite the high level of research focus on hydrogen and carbamide peroxides as therapeutically active (and tooth-whitening) agents, to date the use of alternative chemical forms of peroxides such as peroxoborates for these purposes has received only scant attention. Intriguingly, peroxoborate and its esters with polyols, such as glycerol, have a very diverse chemistry/biochemistry in aqueous solu

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2

Kunkely, Horst, and Amd Vogler. "Optical Outer-Sphere Charge Transfer in Ion Pairs with Peroxoborate as Donor." Zeitschrift für Naturforschung B 55, no. 12 (2000): 1121–23. http://dx.doi.org/10.1515/znb-2000-1203.

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Peroxoborate and the oxidizing cations [Co(NH3)6]3+, [Ru(NH3)6]3+ and N,N′-dimethyl-4,4′- bipyridinium2+ (paraquat2+) form ion pairs in aqueous solutions which display outer-sphere charge transfer (OSCT) bands in their absorption spectra. This CT involves an electronic transition from the peroxo substituents of peroxoborate to the cations. When 10,10′-dimethyl- 9,9′-biacridinium2+ (lucigenin2+, LG2+) is used as an electron acceptor an OSCT absorption is not observed owing to the instability of the ion pair LG2+ peroxoborate which undergoes a chemiluminescent conversion to N-methylacridone.

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3

Liubymova, А. K., V. L. Lobachev, and T. V. Bezbozhnaya. "Diethyl Sulfide Oxidation with Sodium Peroxoborate in Water–Acetonitrile System. Kinetics and Mechanism." Журнал общей химии 94, no. 1 (2024): 3–9. http://dx.doi.org/10.31857/s0044460x24010016.

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In aqueous solutions of acetonitrile (1 vol%), the rate of oxidation of diethyl sulfide with sodium peroxoborate, Na2[B2(O2)2(OH)4]∙6H2O, in the pH range of 8.5–11 is significantly higher than the oxidation rate in water and exceeds the rate of reaction of Et2S with hydrogen peroxide in the H2O–MeCN system. The reaction order with respect to the substrate, which is close to zero, suggests that the limiting stage of the process is the reaction of peroxoborate anions with MeCN, leading to the formation of active boron peroxyimidates, which then react in a rapid stage with Et2S.

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4

Nagaishi, T., M. Inoue, M. Matsumoto, and S. Yoshinaga. "Thermal decomposition of magnesium peroxoborate." Journal of Thermal Analysis 31, no. 3 (1986): 523–29. http://dx.doi.org/10.1007/bf01914227.

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5

Brovkina, O. V., E. D. Shkorina, L. A. Zemnukhova, N. A. Didenko, and L. E. Kryukova. "Bleaching of buckwheat straw and peel with potassium peroxoborate." Russian Journal of Applied Chemistry 79, no. 3 (2006): 480–83. http://dx.doi.org/10.1134/s107042720603030x.

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6

Mikhailov, Mikhail M., and Aleksey N. Sokolovskii. "Photostability of Coatings Based on TiO2 (Rutile) Doped with Potassium Peroxoborate." Journal of Spacecraft and Rockets 43, no. 2 (2006): 451–55. http://dx.doi.org/10.2514/1.14363.

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7

Vakhitova, L. N., N. V. Lakhtarenko, and A. F. Popov. "Kinetics of the Oxidation of Methyl Phenyl Sulfide by Peroxoborate Anions." Theoretical and Experimental Chemistry 51, no. 5 (2015): 307–13. http://dx.doi.org/10.1007/s11237-015-9430-x.

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8

Zemnukhova, L. A., O. V. Brovkina, N. A. Didenko, L. E. Kryukova, V. V. Bespalova, and E. D. Shkorina. "Kinetics of bleaching of rice straw and husk with potassium peroxoborate." Russian Journal of Applied Chemistry 79, no. 10 (2006): 1690–95. http://dx.doi.org/10.1134/s1070427206100272.

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9

Alayadi, Haya, Arwa Talakey, Hajer Aldulaijan, and Marwa Y. Shaheen. "The Impact of a Topical Oxygen-Releasing Gel (blue®m) on Deep Periodontal Pockets: A Case Report." Medicina 60, no. 9 (2024): 1527. http://dx.doi.org/10.3390/medicina60091527.

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Periodontitis represents a prevalent oral pathological condition. Various supplementary local therapies are utilized in clinical practice. Recently introduced, topical oxygen therapy exhibits the potential to effectively hinder the growth of plaque (bacterial biofilm). Delivered in the form of an oral gel, this formulation contains cellulose, glycerol, and sodium peroxoborate, releasing topical oxygen in a regulated manner. Additionally, it discharges topical oxygen and lactoferrin in a controlled manner, with the former showcasing antibacterial properties and the latter stimulating bone cell

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10

Erkaeva, N., A. Kaipbergenov, A. Erkaev, and B. Kucharov. "Study on the process of producing sodium percarbonate." IOP Conference Series: Earth and Environmental Science 1142, no. 1 (2023): 012106. http://dx.doi.org/10.1088/1755-1315/1142/1/012106.

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Abstract To increase the washing efficiency and more completely remove stained impurities, chemical bleaches are introduced into the composition of SD (synthetic detergents), the most common of which are peroxide salts - sodium peroxocarbonate (percarbonate) and sodium peroxoborate (perborate).The theoretical substantiation of the process of interaction of sodium carbonate and hydrogen peroxide in the three-component reciprocal system Na2CO3-H2O2-H2O by the visual-polythermal and isothermal method at 10 and 30°C is carried out. The formation of new compounds of the compositions: Na2CO3•1,5H2O2

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11

Mikhailov, M. M., and A. N. Sokolovskii. "Stability to irradiation of coatings fabricated from ZRO2 powder doped by potassium peroxoborate." Russian Physics Journal 48, no. 12 (2005): 1311–13. http://dx.doi.org/10.1007/s11182-006-0063-3.

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12

Lobachev, V. L., L. M. Dyatlenko, and M. Yu Zubritskii. "Kinetics and mechanism of diethyl sulfide oxidation by sodium peroxoborate in aqueous solutions." Kinetics and Catalysis 57, no. 6 (2016): 742–49. http://dx.doi.org/10.1134/s0023158416060094.

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13

Dyatlenko, L. M., V. L. Lobachev, and T. V. Bezbozhnaya. "Kinetics of the Bicarbonate-Assisted Oxidation of Diethyl Sulfide by Hydrogen Peroxide and Sodium Peroxoborate." Russian Journal of Physical Chemistry A 92, no. 7 (2018): 1248–53. http://dx.doi.org/10.1134/s0036024418070099.

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14

Karunakaran, C., and R. Kamalam. "Peroxoborate Anion as Active Oxidant in Perborate Oxidation: Kinetics of the Oxidation of Morpholine and N-Methylmorpholine." Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry 29, no. 8 (1999): 1463–74. http://dx.doi.org/10.1080/00945719909351711.

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15

Basudan, Amani M., Irfan Abas, Marwa Y. Shaheen, and Hamdan S. Alghamdi. "Effectiveness of Topical Oxygen Therapy in Gingivitis and Periodontitis: Clinical Case Reports and Review of the Literature." Journal of Clinical Medicine 13, no. 5 (2024): 1451. http://dx.doi.org/10.3390/jcm13051451.

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Gingivitis and periodontitis are common oral pathological conditions. Several optional adjunctive local therapies are used clinically. While antibiotics and chlorhexidine are the most common agents of choice, their long-term use is associated with several adverse effects. Some of these include staining of teeth and restorations, cellular cytotoxicity and hypersensitivity. Topical oxygen therapy has been recently introduced and could be clinically capable of inhibiting plaque bacterial biofilm growth. Available as a mouthwash, toothpaste and oral gel, this formulation comprises cellulose, glyce

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16

LYNCH, E., M. GROOTVELD, C. SILWOOD, and A. CLAXSON. "Proton (1H) NMR Investigations of the Oxidising Actions and Status of a Peroxoborate-Containing Dentrifice in Human Saliva." Biochemical Society Transactions 28, no. 1 (2000): A46. http://dx.doi.org/10.1042/bst028a046.

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17

Flanagan, John, William P. Griffith, Richard D. Powell, and Anthony P. West. "Nature of peroxoborate species in aqueous solution: a study by boron-11 nuclear magnetic resonance and Raman spectroscopy." Journal of the Chemical Society, Dalton Transactions, no. 9 (1989): 1651. http://dx.doi.org/10.1039/dt9890001651.

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18

Kataoka, M., S. Tahara, and K. Ohzeki. "Catalymetric trace determination of molybdenum(VI) based on a Landolt type peroxoborate-iodide reaction using an ion-selective electrode." Fresenius' Zeitschrift f�r Analytische Chemie 321, no. 2 (1985): 146–49. http://dx.doi.org/10.1007/bf01117753.

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19

Lynch, Edward, Angela Sheerin, Christopher J. Silwood, and Martin Grootveld. "Multicomponent evaluations of the oxidising actions and status of a peroxoborate-containing tooth-whitening system in whole human saliva using high resolution proton NMR spectroscopy." Journal of Inorganic Biochemistry 73, no. 1-2 (1999): 65–84. http://dx.doi.org/10.1016/s0162-0134(98)10092-2.

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20

Volodymyr, Bessarabov, Vasylenko Volodymyr, Vakhitova Lubov, et al. "Development of a decontamination system for decomposing N-(phosphonomethyl)glycine." Eastern-European Journal of Enterprise Technologies 3, no. 6(99) (2019): 6–13. https://doi.org/10.15587/1729-4061.2019.168391.

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The study has specified the influence of activators on the decomposition of N-(phosphonomethyl) glycine under the effect of hydrogen peroxide and potassium hydroxide. As decontamination systems, potassium hydroxide, hydrogen peroxide, boric acid, cetylpyridinium chloride, and monoethanolamine borate were considered. It has been shown that boric acid is an effective activator of hydrogen peroxide as α-nucleophile in the micellar decontamination system of N-(phosphonomethyl) glycine. It has been found that N-(phosphonomethyl) glycine does not enter the splitting reaction at high pH wi

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21

Flanagan, John, William P. Griffith, Richard D. Powell, and Anthony P. West. "Vibrational spectra of alkali metal peroxoborates." Spectrochimica Acta Part A: Molecular Spectroscopy 45, no. 9 (1989): 951–55. http://dx.doi.org/10.1016/0584-8539(89)80153-9.

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22

Lubov, Vakhitova, Bessarabov Volodymyr, Taran Nadezhda, et al. "DEVELOPMENT OF CHEMICAL METHODS FOR INDIVIDUAL DECONTAMINATION OF ORGANOPHOSPHORUS COMPOUNDS." Eastern-European Journal of Enterprise Technologies 2, no. 6 (98) (2019): 6–14. https://doi.org/10.15587/1729-4061.2019.161208.

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The methods of individual decontamination of organophosphorus esters of paralytic action were studied using the decontamination of paraoxon (O, O-diethyl-O-4-nitrophenylphosphate) and methyl parathion (O, O-dimethyl-O-4-nitrophenylthiophosphate) from solid surfaces (metal, fabric, plastic) as an example. The mixtures of urea hydrogen peroxide, boric acid, cetylpyridinium chloride and montmorillonite nanoclay as decontamination systems were studied. The study showed that application of the micellar system together with nanoclays significantly increases a degree of adsorption of substrates from

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23

Pizer, Richard, and Cherryl Tihal. "Peroxoborates. Interaction of boric acid and hydrogen peroxide in aqueous solution." Inorganic Chemistry 26, no. 21 (1987): 3639–42. http://dx.doi.org/10.1021/ic00268a046.

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24

Rey, Sébastien, and D. Martin Davies. "Photochemistry of Peroxoborates: Borate Inhibition of the Photodecomposition of Hydrogen Peroxide." Chemistry - A European Journal 12, no. 36 (2006): 9284–88. http://dx.doi.org/10.1002/chem.200600437.

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25

Litvinenko, S. L., V. L. Lobachev, L. M. Dyatlenko, and N. A. Turovskii. "Quantum-chemical investigation of the mechanisms of oxidation of dimethyl sulfide by hydrogen peroxide and peroxoborates." Theoretical and Experimental Chemistry 47, no. 1 (2011): 2–8. http://dx.doi.org/10.1007/s11237-011-9176-z.

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26

Davies, D. Martin, Michael E. Deary, Kieran Quill, and Robert A. Smith. "Borate-Catalyzed Reactions of Hydrogen Peroxide: Kinetics and Mechanism of the Oxidation of Organic Sulfides by Peroxoborates." Chemistry - A European Journal 11, no. 12 (2005): 3552–58. http://dx.doi.org/10.1002/chem.200401209.

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27

"Peroxoborate." Tenside Surfactants Detergents 23, no. 2 (1986): 73–75. http://dx.doi.org/10.1515/tsd-1986-230208.

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28

Zhou, Jiajie, Yan Tian, Chen Yan, et al. "0Potassium Peroxoborate: A sustained-released reactive oxygen carrier with enhanced PAHs contaminated soil remediation performance." Journal of Hazardous Materials, April 2024, 134259. http://dx.doi.org/10.1016/j.jhazmat.2024.134259.

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29

FLANAGAN, J., W. P. GRIFFITH, R. D. POWELL, and A. P. WEST. "ChemInform Abstract: Nature of Peroxoborate Species in Aqueous Solution: A Study by 11B NMR and Raman Spectroscopy." ChemInform 20, no. 48 (1989). http://dx.doi.org/10.1002/chin.198948004.

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30

MARTYNYUK, YU L., S. A. ZAKHAROVA, B. N. CHERNYSHOV, V. YA KAVUN, and YU V. GORIN. "ChemInform Abstract: Formation and Characteristics of the Structure of Alkali Metal Peroxoborates." ChemInform 19, no. 31 (1988). http://dx.doi.org/10.1002/chin.198831025.

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31

PIZER, R., and C. TIHAL. "ChemInform Abstract: Peroxoborates. Interaction of Boric Acid and Hydrogen Peroxide in Aqueous Solution." ChemInform 19, no. 5 (1988). http://dx.doi.org/10.1002/chin.198805011.

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