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Journal articles on the topic 'Perylene bisimide (PBI)'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Schmidt, Rüdiger, Peter Osswald, Martin Könemann, and Frank Würthner. "Synthetic Routes to Core-fluorinated Perylene Bisimide Dyes and their Properties." Zeitschrift für Naturforschung B 64, no. 6 (2009): 735–46. http://dx.doi.org/10.1515/znb-2009-0621.

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Numerous core-fluorinated perylene bisimide (PBI) dyes with various substituents at the imide positions have been synthesized by different methods. Core-difluorinated PBIs 4a-f are obtained by imidization of difluoro-substituted perylene bisanhydride 1 with appropriate primary amines or, alternatively, by nucleophilic halogen exchange reactions (Halex process) of the corresponding dibromosubstituted PBIs 2a-d,f with potassium fluoride. Core-tetrafluorinated PBIs 5a-c could also be synthesized by halogen exchange reactions of the respective tetrachlorinated PBIs 3a-c. In particular, core-fluori

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2

Ling, Cheng, Miao, Zhang, Zhang, and Zhu. "Synthesis and Photocontrolled Supramolecular Self-Assembly of Azobenzene-Functionalized Perylene Bisimide Derivatives." Polymers 11, no. 7 (2019): 1143. http://dx.doi.org/10.3390/polym11071143.

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Azobenzene (Azo) units were successfully introduced into perylene bisimide (PBI) structures in order to realize the photocontrolling of the morphology of the supramolecular assembly of PBI by a photoisomerization process. A total of three Azo-functionalized perylene bisimide derivatives (PBI1, PBI2, and PBI3) with different alkyl chain lengths were designed and synthesized by imidization of 3,4,9,10-perylene tetracarboxylic dianhydride with the corresponding amines. The structures of these compounds were characterized by proton nuclear magnetic resonance (1H NMR) and matrix-assisted laser deso

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3

Xu, Xu, Yuqi Li, Zhongqiang Xiong, et al. "Preparation and model of high-performance shape-memory polyurethane with hydroxylated perylene bisimide." RSC Advances 6, no. 111 (2016): 110329–36. http://dx.doi.org/10.1039/c6ra24393b.

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4

He, Xu, Bing Hu, Yan Yang, et al. "Synthesis, self-aggregation and cryopreservation effects of perylene bisimide–glycopeptide conjugates." Chemical Communications 57, no. 90 (2021): 12000–12003. http://dx.doi.org/10.1039/d1cc03835d.

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5

Ouyang, Guanghui, David Bialas, and Frank Würthner. "Reversible fluorescence modulation through the photoisomerization of an azobenzene-bridged perylene bisimide cyclophane." Organic Chemistry Frontiers 8, no. 7 (2021): 1424–30. http://dx.doi.org/10.1039/d0qo01635g.

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An azobenzene-bridged perylene bisimide cyclophane was designed and synthesized, which showed reversible fluorescence intensity switching under light-irradiation due to cooperative adjustments of PBI–PBI and PBI–Azo interactions.

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6

Lee, Ji-Eun, Ye Ri Han, Sujin Ham, Chul-Ho Jun, and Dongho Kim. "A solution-based single-molecule study of surface-bound PBIs: solvent-mediated environmental effects on molecular flexibility." Physical Chemistry Chemical Physics 19, no. 43 (2017): 29255–62. http://dx.doi.org/10.1039/c7cp04756h.

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7

Nastasi, Francesco, Giuseppina La Ganga, Sebastiano Campagna, et al. "Multichromophoric hybrid species made of perylene bisimide derivatives and Ru(ii) and Os(ii) polypyridine subunits." Physical Chemistry Chemical Physics 19, no. 21 (2017): 14055–65. http://dx.doi.org/10.1039/c7cp01597f.

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8

Mutoh, Katsuya, Michel Sliwa, Eduard Fron, Johan Hofkens, and Jiro Abe. "Fluorescence modulation by fast photochromism of a [2.2]paracyclophane-bridged imidazole dimer possessing a perylene bisimide moiety." Journal of Materials Chemistry C 6, no. 35 (2018): 9523–31. http://dx.doi.org/10.1039/c8tc02713g.

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9

Weißenstein, Annike, and Frank Würthner. "Metal ion templated self-assembly of crown ether functionalized perylene bisimide dyes." Chemical Communications 51, no. 16 (2015): 3415–18. http://dx.doi.org/10.1039/c4cc09443c.

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10

Al-Galiby, Qusiy, Iain Grace, Hatef Sadeghi та Colin J. Lambert. "Exploiting the extended π-system of perylene bisimide for label-free single-molecule sensing". Journal of Materials Chemistry C 3, № 9 (2015): 2101–6. http://dx.doi.org/10.1039/c4tc02897j.

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We demonstrate the potential of perylene bisimide (PBI) for label-free sensing of organic molecules by investigating the change in electronic properties of five symmetric and asymmetric PBI derivatives, which share a common backbone, but are functionalised with various bay-area substituents.

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11

Zheng, Jie, Jiawei Peng, Yu Xie, Yunze Long, Xin Ning, and Zhenggang Lan. "Study of the exciton dynamics in perylene bisimide (PBI) aggregates with symmetrical quasiclassical dynamics based on the Meyer–Miller mapping Hamiltonian." Physical Chemistry Chemical Physics 22, no. 32 (2020): 18192–204. http://dx.doi.org/10.1039/d0cp00648c.

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The exciton dynamics in one-dimensional stacked PBI (Perylene Bisimide) aggregates was studied with SQC-MM dynamics (Symmetrical Quasiclassical Dynamics based on the Meyer–Miller mapping Hamiltonian).

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12

Zhu, Mingguang, Yunxiang Chen, Xiaoyi Zhang, Meihui Chen, Hongyu Guo, and Fafu Yang. "Perylene bisimide with diphenylacrylonitrile on side-chain: strongly fluorescent liquid crystal with large pseudo Stokes shift based on AIE and FRET effect." Soft Matter 14, no. 32 (2018): 6737–44. http://dx.doi.org/10.1039/c8sm01183d.

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13

Aigner, D., R. I. Dmitriev, S. M. Borisov, D. B. Papkovsky, and I. Klimant. "pH-sensitive perylene bisimide probes for live cell fluorescence lifetime imaging." J. Mater. Chem. B 2, no. 39 (2014): 6792–801. http://dx.doi.org/10.1039/c4tb01006j.

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Several new perylene bisimide (PBI) probes comprising oligo-guanidine conjugates and cationic hydrogel nanoparticle structures were designed for sensing intracellular pH in live cell fluorescence lifetime imaging microscopy (FLIM).

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14

Solymosi, Iris, Swathi Krishna, Edurne Nuin, et al. "Diastereoselective formation of homochiral flexible perylene bisimide cyclophanes and their hybrids with fullerenes." Chemical Science 12, no. 47 (2021): 15491–502. http://dx.doi.org/10.1039/d1sc04242d.

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Perylene bisimide (PBI) cyclophanes linked by flexible malonates were functionalized with fullerenes. Modulation of the chemical environment enhances the chiral self-sorting, leading exclusively to the homochiral diastereomeric pair (M,M)/(P,P).

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15

Cao, Dapeng, Qifang Li, Manxi Zhou, Lei Zhu, Zhimin Sun, and Zhenqing Yang. "Tri-Petal Lilac-Like Perylene: Asymmetrical Substituted Platform for Regioselective Ether-Exchange Reaction." Synlett 28, no. 16 (2017): 2121–25. http://dx.doi.org/10.1055/s-0036-1590808.

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An asymmetrical tri-petal lilac-like platform based on perylene bisimide (PBI) was designed and synthesized to further perform the ether-exchange reaction, while common tetraphenoxy PBI analogue cannot do it. We found that the tri-petal lilac-like platform strategy not only avoids the regioisomers of difunctionalized PBI, but also is a precise and facile way to achieve regioselective introduction of alkyloxy, alkylthio and C=C double bond ended substituents onto the 1-position of perylene bay without the use and removal of the protecting groups. Due to the tunable photoelectrical properties an

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16

Karakostas, Nikolaos, Antonia Kaloudi-Chantzea, Elisabeth Martinou, et al. "Energy transfer within self-assembled cyclic multichromophoric arrays based on orthogonally arranged donor–acceptor building blocks." Faraday Discussions 185 (2015): 433–54. http://dx.doi.org/10.1039/c5fd00083a.

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We herein present the coordination-driven supramolecular synthesis and photophysics of a [4+4] and a [2+2] assembly, built up by alternately collocated donor–acceptor chromophoric building blocks based, respectively, on the boron dipyrromethane (Bodipy) and perylene bisimide dye (PBI). In these multichromophoric scaffolds, the intensely absorbing/emitting dipoles of the Bodipy subunit are, by construction, cyclically arranged at the corners and aligned perpendicular to the plane formed by the closed polygonal chain comprising the PBI units. Steady-state and fs time-resolved spectroscopy reveal

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17

Kaur, Sandeep, Manoj Kumar, and Vandana Bhalla. "Supramolecular ensemble of PBI derivative and copper nanoparticles: a light harvesting antenna for photocatalytic C(sp2)–H functionalization." Green Chemistry 18, no. 21 (2016): 5870–83. http://dx.doi.org/10.1039/c6gc01728b.

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A supramolecular ensemble of triazole-appended perylene bisimide (PBI) derivative 4 and in situ generated copper nanoparticles (CuNPs) serves as a light-harvesting antenna in photocatalytic C(sp<sup>2</sup>)–H alkynylation and amination reactions of arenes under mild and eco-friendly conditions.

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18

Ma, Weitao, Leiqiang Qin, Yu Gao, et al. "A perylene bisimide network for high-performance n-type electrochromism." Chemical Communications 52, no. 93 (2016): 13600–13603. http://dx.doi.org/10.1039/c6cc07962h.

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A micro-porous network thin film of core-tetrachlorinated perylene bisimide (PBI) was deposited by electrochemical polymerization, which showed reversible n-doping/dedoping processes at rather low potentials, accompanied by color changes from an orange red (neutral) state to a transparent (radical anion) state and further to an aquamarine (dianion) state.

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19

Sarbu, Alexandru, Laure Biniek, Jean-Michel Guenet, Philippe J. Mésini, and Martin Brinkmann. "Reversible J- to H-aggregate transformation in thin films of a perylenebisimide organogelator." Journal of Materials Chemistry C 3, no. 6 (2015): 1235–42. http://dx.doi.org/10.1039/c4tc02444c.

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A perylene bisimide organogelator is shown to behave as a reversible stimuli responsive material: thermal annealing and contact with organic non solvents allow to switch back and forth between a green J-type (Form I) and a red H-type (Form II) aggregate in thin films and powders of a N,N′-substituted H-bonding perylenebisimide (PBI-C10).

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20

Zhang, Wenqiang, Shu Zhong, Li Nian, et al. "Perylene bisimide as the cathode modifier in organic photovoltaics: the role of aggregation morphology on the interlayer performance." RSC Advances 5, no. 50 (2015): 39973–77. http://dx.doi.org/10.1039/c5ra03988f.

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Nanorods and nanoparticles of perylene bisimides (PBI-1) were prepared and applied as cathode interlayer in organic photovoltaic devices. The device performance showed important relation with the morphology of the interlayer.

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21

Wang, Ying, Xinguo Yang, Siyu Li, Tao Long, and Wei Li. "Organic Acid Regulated Self-Assembly and Photophysical Properties of Perylene Bisimide Derivatives." Materials 13, no. 7 (2020): 1656. http://dx.doi.org/10.3390/ma13071656.

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In this work, perylene bisimide derivatives (PBI-1 and PBI-2) with tertiary amine groups were designed and synthesized. To control the final morphologies and properties of their aggregates, seven kinds of organic acids were used to alter the self-assembly environment. The influence of organic acids on the morphology of the aggregates was investigated. Photophysical properties of the aggregates were markedly affected by the kind and concentration of the organic acid. The thermal and gas sensitivities of the PBI-1 aggregates were studied with the use of UV–visible spectroscopy and digital imagin

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22

Zhang, Xiaoxiao, Tingyuan Gong, Hong Chi, and Tianduo Li. "Nanostructured polyurethane perylene bisimide ester assemblies with tuneable morphology and enhanced stability." Royal Society Open Science 5, no. 3 (2018): 171686. http://dx.doi.org/10.1098/rsos.171686.

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Size control has been successfully achieved in inorganic materials, but it remains a challenge in polymer nanomaterials due to their polydispersity. Here, we report a facile approach to tailor the diameters of polyurethane (PU) nanoparticles (490 nm, 820 nm and 2.1 µm) via perylene bisimide (PBI) assisted self-assembly. The formed morphologies such as spindle, spherical and core–shell structures depend on the ratio of PBI and polymer concentrations. It is shown that the formation of PU nanoparticles is directed by π–π stacking of PBI and the morphology transition is not only affected by the am

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23

Marcia, Mario, Prabhpreet Singh, Frank Hauke, Michele Maggini, and Andreas Hirsch. "Novel EDTA-ligands containing an integral perylene bisimide (PBI) core as an optical reporter unit." Org. Biomol. Chem. 12, no. 36 (2014): 7045–58. http://dx.doi.org/10.1039/c4ob01007h.

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24

Tsutsumi, Naoto, Takafumi Sassa, Tam Van Nguyen, et al. "Photoconductive Dynamics of Photorefractive Poly((4-Diphenylamino)benzyl Acrylate)-Based Composites Sensitized by Perylene Bisimide." Polymers 17, no. 1 (2025): 96. https://doi.org/10.3390/polym17010096.

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The transient dynamics of photocurrents for poly((4-diphenylamino)benzyl acrylate) (PDAA)-based photorefractive (PR) polymers sensitized with perylene bisimide derivative N,N′-diisopropylphenyl-1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxyl bisimide (PBI) at various composition ratios were studied. The PR polymer included (4-(diphenylamino)phenyl)methanol (TPAOH) photoconductive plasticizer and (4-(azepan-1-yl)-benzylidene) malononitrile nonlinear optical dye as well, which are needed for inducing PR effects. All the photocurrents measured at 640 nm were well simulated by a two-trapping s

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25

Wei, Kang, Haitao Zhang, Jianbo Qu, Jianyong Wang, Yang Bai, and Futao Sai. "Recyclable Shape-Memory Waterborne Polyurethane Films Based on Perylene Bisimide Modified Polycaprolactone Diol." Polymers 13, no. 11 (2021): 1755. http://dx.doi.org/10.3390/polym13111755.

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Currently, much attention is given to the functionality and recyclability of waterborne polyurethane (WPU). Herein, ε-caprolactone was used as a chain extender for grafting onto perylene bisimide (PBI) and 1,4-butanediol (BDO) via ring-opening reactions to obtain PBI-PCL and BDO- PCL. Then, two kinds of WPU, namely PBI-WPU (PWPU) and BDO-WPU (BWPU), were fabricated using PBI-PCL/polytetrahydrofuran ether glycol (PTMG) and BDO-PCL/PTMG, respectively, as mixed soft segments. The properties and appearance of PWPU and BWPU emulsions were analyzed in terms of particle size, zeta potential and TEM i

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26

Maier, Johannes, Martti Pärs, Tina Weller, Mukundan Thelakkat, and Jürgen Köhler. "Switching or blinking? – The switching behaviour of single photochromic triads." EPJ Web of Conferences 190 (2018): 04014. http://dx.doi.org/10.1051/epjconf/201819004014.

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Photochromic molecules can be interconverted between two bistable conformations by light [1–3]. Irie and coworkers described a strategy to achieve superior fluorescence characteristics and outstanding switching characteristics of a photochromic unit by linking strong fluorophores covalently to photochromic building blocks [3,4]. Accordingly, we synthesised molecular triads that consist of two perylene bisimide (PBI) fluorophores covalently linked to a dithienylcyclopentene (DCP) photochromic switch, see fig. 1. Such kinds of triads are promising candidates for super-resolution microscopy like

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27

Seifert, Sabine, David Schmidt, and Frank Würthner. "An ambient stable core-substituted perylene bisimide dianion: isolation and single crystal structure analysis." Chemical Science 6, no. 3 (2015): 1663–67. http://dx.doi.org/10.1039/c4sc03671a.

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28

Rühe, Jessica, David Bialas, Peter Spenst, Ana-Maria Krause, and Frank Würthner. "Perylene Bisimide Cyclophanes: Structure–Property Relationships upon Variation of the Cavity Size." Organic Materials 02, no. 02 (2020): 149–58. http://dx.doi.org/10.1055/s-0040-1709998.

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Five cyclophanes composed of two perylene bisimide (PBI) dyes and various CH2–arylene–CH2 linker units were synthesized. PM6-D3H4 geometry-optimized structures and a single crystal for one of these cyclophanes reveal well-defined distances between the two coplanar PBI units in these cyclophanes, spanning the range from 5.0 to 12.5 Å. UV/vis absorption spectra reveal a redistribution of oscillator strength of the vibronic bands due to a H-type exciton coupling even for the cyclophane with the largest interchromophoric distance. A quantitative evaluation according to the Kasha–Spano theory affor

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29

Wang, Gang, Xingmao Chang, Junxia Peng, et al. "Towards a new FRET system via combination of pyrene and perylene bisimide: synthesis, self-assembly and fluorescence behavior." Physical Chemistry Chemical Physics 17, no. 7 (2015): 5441–49. http://dx.doi.org/10.1039/c4cp04860a.

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30

Alloa, Elisa, Vincenzo Grande, Rishat Dilmurat, David Beljonne, Frank Würthner, and Sophia C. Hayes. "Resonance Raman study of the J-type aggregation process of a water soluble perylene bisimide." Physical Chemistry Chemical Physics 21, no. 33 (2019): 18300–18309. http://dx.doi.org/10.1039/c9cp01874c.

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31

Zhang, Jinling, Ke Liu, Gang Wang, et al. "Detection of gaseous amines with a fluorescent film based on a perylene bisimide-functionalized copolymer." New Journal of Chemistry 42, no. 15 (2018): 12737–44. http://dx.doi.org/10.1039/c8nj02540a.

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32

Tilmann, Rita, Corinna Weiß, Conor P. Cullen, et al. "Highly Selective Non-Covalent On-Chip Functionalization of Layered Materials." Advanced Electronics Materials 7 (January 15, 2021): 2000564. https://doi.org/10.1002/aelm.202000564.

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Non-covalent functionalization of layered 2D materials is an essential tool to modify and fully harness their optical, electrical, and chemical properties. Herein, a facile method enabling the selective formation of self-assembled monolayers (SAMs) of perylene bisimide (PBI) on transition metal dichal- cogenides (TMDs), directly on the growth substrate (on-chip), is presented. Laterally-resolved infrared atomic force microscopy (AFM-IR) and time-of- flight secondary ion mass spectrometry (TOF-SIMS) are applied as superior techniques to gain detailed information beyond traditional surface analy

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33

Cui, Lingyun, Yang Jiao, Anhe Wang, et al. "Regulating morphologies and near-infrared photothermal conversion of perylene bisimide via sequence-dependent peptide self-assembly." Chemical Communications 54, no. 18 (2018): 2208–11. http://dx.doi.org/10.1039/c8cc00177d.

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The behavior of PBI self-assembly can be precisely organised by the conjugation of sequence dependent dipeptides in aqueous media resulting in different assembled nanostructures with improved radical anions yield and enhanced photothermal conversion efficiency.

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34

Kaur, Sandeep, Manoj Kumar, and Vandana Bhalla. "Aggregates of perylene bisimide stabilized superparamagnetic Fe3O4nanoparticles: an efficient catalyst for the preparation of propargylamines and quinolines via C–H activation." Chemical Communications 51, no. 91 (2015): 16327–30. http://dx.doi.org/10.1039/c5cc05752c.

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Supramolecular aggregates of the PBI derivative3serve as reactors and stabilizers for the preparation of Fe<sub>3</sub>O<sub>4</sub>nanoparticles, which exhibit high catalytic efficiency for the preparation of propargylamines and quinolines derivativesviaC–H activation.

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35

Sarbu, Alexandru, Patrick Hermet, David Maurin, et al. "Supramolecular organization of a H-bonded perylene bisimide organogelator determined by transmission electron microscopy, grazing incidence X-ray diffraction and polarized infra-red spectroscopy." Physical Chemistry Chemical Physics 19, no. 48 (2017): 32514–25. http://dx.doi.org/10.1039/c7cp06761e.

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36

Martínez, Manuel A., Elisa E. Greciano, Jorge Cuéllar, José M. Valpuesta, and Luis Sánchez. "Globular Aggregates Stemming from the Self-Assembly of an Amphiphilic N-Annulated Perylene Bisimide in Aqueous Media." Nanomaterials 11, no. 6 (2021): 1457. http://dx.doi.org/10.3390/nano11061457.

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Herein, we describe the synthesis of highly emissive amphiphilic N-annulated PBI 1 decorated with oligo ethylene glycol (OEG) side chains. These polar side chains allow the straightforward solubility of 1 in solvents of different polarity such as water, iPrOH, dioxane, or chloroform. Compound 1 self-assembles in aqueous media by π-stacking of the aromatic units and van der Waals interactions, favored by the hydrophobic effect. The hypo- and hypsochromic effect observed in the UV-Vis spectra of 1 in water in comparison to chloroform is diagnostic of H-type aggregation. Solvent denaturation expe

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37

Yang, Gui-Xia, Hai-Lin Fan, Xiao-Di Niu, and Zong-Hao Huang. "A theoretical study of bipolar organic transport material: Disilanyl double-pillared bisanthracene (SiDPBA)." Canadian Journal of Chemistry 89, no. 10 (2011): 1257–63. http://dx.doi.org/10.1139/v11-085.

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A novel anthracene derivative, disilanyl double-pillared bisanthracene (SiDPBA), has been recently synthesized, which effectively functions as a bipolar carrier transport material in OLEDs. Its charge transport properties have been systemically investigated by band model and hopping model. Band structure calculations of SiDPBA show that the dispersions of the larger valence band and conduction band are comparable, which demonstrates that both electron and hole are favoured for transport, and that SiDPBA has the potential to be used as bipolar transport material from the viewpoint of band model

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38

Nowak-Król, Agnieszka, Benjamin Fimmel, Minjung Son, Dongho Kim, and Frank Würthner. "Photoinduced electron transfer (PET) versus excimer formation in supramolecular p/n-heterojunctions of perylene bisimide dyes and implications for organic photovoltaics." Faraday Discussions 185 (2015): 507–27. http://dx.doi.org/10.1039/c5fd00052a.

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Foldamer systems comprised of two perylene bisimide (PBI) dyes attached to the conjugated backbones of 1,2-bis(phenylethynyl)benzene and phenylethynyl-bis(phenylene)indane, respectively, were synthesized and investigated with regard to their solvent-dependent properties. UV/Vis absorption and steady-state fluorescence spectra show that both foldamers exist predominantly in a folded H-aggregated state consisting of π–π-stacked PBIs in THF and in more random conformations with weaker excitonic coupling between the PBIs in chloroform. Time-resolved fluorescence spectroscopy and transient absorpti

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39

Sharma, G. D., M. S. Roy, J. A. Mikroyannidis, and K. R. Justin Thomas. "Synthesis and characterization of a new perylene bisimide (PBI) derivative and its application as electron acceptor for bulk heterojunction polymer solar cells." Organic Electronics 13, no. 12 (2012): 3118–29. http://dx.doi.org/10.1016/j.orgel.2012.07.002.

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40

Hiroto, Satoru, та Mana Wakita. "Supramolecular Assembly of Nitrogen-Containing Curved π-Conjugated Molecules to Polar Crystal". ECS Meeting Abstracts MA2024-01, № 14 (2024): 1145. http://dx.doi.org/10.1149/ma2024-01141145mtgabs.

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The chemistry of curved π-conjugated molecules has been extensively studied because of the development of their synthetic approach. Among the numerous studies, we have been engaged in nitrogen-containing curved π-conjugated molecules. These molecules have extended optical properties, redox-active behaviors, and electron-donating ability due to the electron-rich nature of nitrogen atoms. Recently, we have focused on the supramolecular assembling behavior of these compounds. For example, we have reported buckycatcher consisted of two azabuckybowls, providing two-photon absorbing host-guest compl

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41

Meenal, Kataria, Kumar Manoj, and Bhalla Vandana. "Smart fluorescent supramolecular assemblies: Self-assembly in the presence of metal ions and anions in mixed aqueous media." Journal of India Chemical Society Vol. 95, Dec 2018 (2018): 1559–77. https://doi.org/10.5281/zenodo.5644786.

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Department of Chemistry, UGC Sponsored Centre for Advanced Studies-II, Guru Nanak Dev University, Amritsar-143 005, Punjab, India <em>E-mail</em>: vanmanan@yahoo.co.in <em>Manuscript received online 25 November 2018, accepted 29 November 2018</em> Recently, aggregation induced emission (AIE) phenomena has been extensively explored for preparation of fluorescent assemblies which find wide spread applications in diverse fields such as molecular recognition, catalysis, sensing and fabrication of optoelectronic devices. The fluorescent assemblies having specific binding sites act as selective sens

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42

Lundy, Ross, Emily R. Draper, and James J. Walsh. "Amino acid appended perylene bisimides: self-assembly, immobilization on nanocrystalline TiO2, and electrochromic properties." New Journal of Chemistry 42, no. 23 (2018): 19020–25. http://dx.doi.org/10.1039/c8nj04214d.

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Titanium dioxide (TiO<sub>2</sub>) nanoparticle films have been used as a conducting support for the immobilisation of alanine-appended perylene bisimides (PBI-A) via dip-coating and carboxylate chemisorption.

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43

Wang, Yi Jia, Zeyu Li, Jiaqi Tong, et al. "The fluorescence properties and aggregation behavior of tetraphenylethene–perylenebisimide dyads." Journal of Materials Chemistry C 3, no. 15 (2015): 3559–68. http://dx.doi.org/10.1039/c4tc02550d.

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Perylene-bisimides (PBIs) modified with tetraphenylethene (TPE) at N-terms show unique X-aggregation and are non-fluorescent in solution, aggregate and solid film due to the photoinduced charge transfer between TPE and PBI subunits.

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44

Qi, Rui, Xiaotian Huang, Ting Yang, et al. "Morphology Control and Spectral Study of the 2D and Hierarchical Nanostructures Self-Assembled by the Chiral Alanine-Decorated Perylene Bisimides." Molecules 29, no. 19 (2024): 4610. http://dx.doi.org/10.3390/molecules29194610.

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Tailoring the morphologies and optical properties of the 2D and hierarchical nanostructures self-assembled by the π-conjugated molecules is both interesting and challenging. Herein, a series of 2D ribbon-like nanostructures with single or multiple H-aggregated perylene bisimides (PBI) monolayer and hierarchical nanostructures (including straw-like, dumbbell-shaped, and rod-like nanostructures) are fabricated by solution self-assembly of three chiral alanine-decorated PBI. The influence of the solvent’s dissolving capacity, the chirality of alanine, and the preparation methods on the morphologi

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Maier, Johannes, Martti Pärs, Katja Gräf, Mukundan Thelakkat, and Jürgen Köhler. "Light controls light: single molecules as optical switches." EPJ Web of Conferences 190 (2018): 02006. http://dx.doi.org/10.1051/epjconf/201819002006.

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In recent years much attention has been given to design multistate molecular components with functionalities that cover the range from simple switches to logic gates [1-3]. In this regard photochromic molecules, i.e., molecules that can be interconverted between two bistable forms by light, have played an important role. Promising candidates that fulfill obvious demands such as high photochemical/ photophysical stability and high fatigue resistance are compounds of the family of diarylethenes [2,3]. However, a serious drawback of this class of molecules is a low fluorescence quantum yield. The

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Banerjee, Arindam, Purnadas Ghosh, Soumyajit Hazra, Kousik Gayen, Niladri Hazra, and Arun K. Nandi. "Peptide appended perylene bisimide containing silver nanoparticle-based trihybrid system with GO: improvement of photocatalytic and photo-switching behaviour." New Journal of Chemistry, 2024. http://dx.doi.org/10.1039/d3nj05662g.

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This report demonstrates a facile environmentally friendly synthesis of a trihybrid system (PBI-NP-GO) consisting of perylene bisimide appended peptide (PBI-UW) nanofibers, silver nanoparticles (PBI-AgNP) and graphene oxide (GO) nano-sheet. The...

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Paulino, Victor, Kaixuan Liu, Valentino Cesiliano та ін. "Covalent post-assembly modification of π-conjugated supramolecular polymers delivers structurally robust light-harvesting nanoscale objects". Nanoscale, 2023. http://dx.doi.org/10.1039/d2nr06806k.

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Nagler, Oliver, Kazutaka Shoyama, Olga Anhalt, et al. "Boron-, Carbon-, and Silicon-Bridged 1,12-Dihydroxy-Perylene Bisimides with Tuned Structural and Optical Properties." Organic Chemistry Frontiers, 2023. http://dx.doi.org/10.1039/d3qo01389h.

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Establishing suitable design strategies to tailor the functional properties of perylene bisimide (PBI) dyes are critical for their successful application in various devices. Herein, we report a new synthetic strategy...

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Berruyer, Valentine Le, Aurelie Perrier, and Mayeul Collot. "Photoconvertible and Photoactivatable Perylene BisImide Based on Photocyclization." Advanced Optical Materials, September 24, 2024. http://dx.doi.org/10.1002/adom.202401511.

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AbstractPhotomodulable fluorophores constitute advanced materials as they possess the ability to modify their photophysical properties upon photoirradiation. A new mechanism of photoconversion is recently established, called Directed Photooxidation Induced Conversion based on the coupling of fluorophores with Aromatic Singlet oxygen Reactive Moieties (ASORMs). In this work, The Directed Photooxidation Induced Conversion (DPIC) mechanism is intended to be applied to Perylene BisImide (PBI) due to its appealing photophysical properties. The experimental results showed that coupling two ASORMs to

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Weh, Manuel, Asja A. Kroeger, Olga Anhalt, Amir Karton, and Frank Wuerthner. "Mutual Induced Fit Transition Structure Stabilization of Corannulene’s Bowl-to-Bowl Inversion in a Perylene Bisimide Cyclophane." Chemical Science, 2023. http://dx.doi.org/10.1039/d3sc05341e.

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