Academic literature on the topic 'Phase Transfer Catalysis (PTC)'

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Journal articles on the topic "Phase Transfer Catalysis (PTC)"

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Wang, Chuan-Hui, Chen-Fu Liu, and Guo-Wu Rao. "Green Application of Phase-Transfer Catalysis in Oxidation: A Comprehensive Review." Mini-Reviews in Organic Chemistry 17, no. 4 (2020): 405–11. http://dx.doi.org/10.2174/1570193x16666190617154733.

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Oxidation reactions have emerged as one of the most versatile tools in organic chemistry. Various onium salts such as ammonium, phosphonium, arsonium, bismuthonium, tellurium have been used as phase transfer catalysts in many oxidation reactions. Certainly, considerable catalysts have been widely used in Phase-Transfer Catalysis (PTC). This review focuses on the application of PTC in various oxidation reaction. Furthermore, PTC also conforms to the concept of “Green Chemistry”. <p></p> • Oxidation has become one of the most widely used tools in organic chemistry and phase transfer
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Zhao, Qianqiang, Xiao Zhao, Hui Peng, et al. "Static phase transfer catalysis for Williamson reactions: Pickering interfacial catalysis." Catalysis Science & Technology 9, no. 13 (2019): 3445–53. http://dx.doi.org/10.1039/c9cy00620f.

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Nur, Hadi. "A Perspective on Catalysis in the Immiscible Liquid-Liquid System." Journal of the Indonesian Chemical Society 2, no. 2 (2019): 66. http://dx.doi.org/10.34311/jics.2019.02.2.66.

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This manuscript provides a perspective on research work related to the catalysis in the immiscible liquid-liquid system. Three catalytic concepts, i.e., phase-transfer catalysis (PTC), triphase catalysis (TPC), and phase-boundary catalysis (PBC), are presented as well as their use for the design of a better catalytic system. This perspective emphasizes based on the SWO (Strengths, Weaknesses, and Opportunities) analysis of PTC, TPC, and PBC and advances concept uses for future directions of research in this area.
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Della Sala, Giorgio, Rosaria Schettini, Marina Sicignano, Francesco De Riccardis, and Irene Izzo. "Macrocyclic Hosts in Asymmetric Phase-Transfer Catalyzed Reactions." Synthesis 50, no. 24 (2018): 4777–95. http://dx.doi.org/10.1055/s-0037-1610311.

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The introduction and development of neutral macrocyclic hosts capable of complexing ions within their pre-organized cavity, has been of utmost importance in supramolecular chemistry. Their ability to form stable organic-soluble metal–macrocycle complexes opened up the way to their application in phase-transfer catalysis (PTC) as a viable alternative to quaternary onium salts. In particular, their conformationally rigid preorganized backbone, accommodating organic substrates in defined orientations, promotes highly efficient stereoselective reactions. This short review summarizes the applicatio
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Wu, Jia-Hong, Jianke Pan, and Tianli Wang. "Dipeptide-Based Phosphonium Salt Catalysis: Application to Enantioselective Synthesis of Fused Tri- and Tetrasubstituted Aziridines." Synlett 30, no. 19 (2019): 2101–6. http://dx.doi.org/10.1055/s-0039-1690192.

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Over the past decades, phase-transfer catalysis (PTC), generally based on numerous chiral quaternary ammonium salts, has been recognized as a powerful and versatile tool for organic synthesis in both industry and academia. In sharp contrast, PTC involving chiral phosphonium salts as the catalysts is insufficiently developed. Recently, our group realized the first enantioselective aza-Darzens reaction for preparing tri- and tetrasubstituted aziridine derivatives under bifunctional phosphonium salt catalysis. This article briefly discusses the recent development in asymmetric reactions (mainly i
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El-Sayed, Ahmed M., Omyma A. Abd Allah, Ahmed M. M. El-Saghier, and Shaaban K. Mohamed. "Synthesis and Reactions of Five-Membered Heterocycles Using Phase Transfer Catalyst (PTC) Techniques." Journal of Chemistry 2014 (2014): 1–47. http://dx.doi.org/10.1155/2014/163074.

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Phase transfer catalysts (PTCs) have been widely used for the synthesis of organic compounds particularly in both liquid-liquid and solid-liquid heterogeneous reaction mixtures. They are known to accelerate reaction rates by facilitating formation of interphase transfer of species and making reactions between reagents in two immiscible phases possible. Application of PTC instead of traditional technologies for industrial processes of organic synthesis provides substantial benefits for the environment. On the basis of numerous reports it is evident that phase-transfer catalysis is the most effi
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Hegde, Narayan G. "Phase Transfer Catalysis: New Technology to Boost Organic Farming." Asian Journal of Research in Crop Science 9, no. 3 (2024): 86–94. http://dx.doi.org/10.9734/ajrcs/2024/v9i3292.

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Introduction of Phase Transfer Catalysis (PTC) technology, which was developed in the 1970s has revolutionised the dyes and pharmaceutical industries in many ways. PTC is a process that facilitates the organic compounds to move from one phase to another phase, without any change in the chemical qualities. Application of this technology was explored in the 1980s for agriculture, by using different plant extracts as PT catalysts. The objective was to facilitate increased absorption of nutrients by plants, by stimulating plant growth and easy availability of nutrients in the soil. Introduction of
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Lewandowski, Grzegorz. "Comparison of the methods of the phase transfer catalysis and hydroperoxide in the epoxidation of 1,5,9-cyclododecatriene." Polish Journal of Chemical Technology 9, no. 3 (2007): 101–4. http://dx.doi.org/10.2478/v10026-007-0065-0.

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Comparison of the methods of the phase transfer catalysis and hydroperoxide in the epoxidation of 1,5,9-cyclododecatriene The process of the epoxidation of cis, trans, trans-1,5,9-cyclododecatriene (CDT) to 1,2-epoxy-5,9-cyclododecadiene (ECDD) with the 30% aqueous hydrogen peroxide under the phase transfer conditions and with tert-butyl hydroperoxide under the homogeneous conditions was investigated. Onium salts such as Aliquat® 336, Arquad® 2HT, methyltrioctylammonium bromide and the Na2WO4/H3PO4 catalyst system are very active under the phase transfer catalysis (PTC) conditions for the sele
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Iribarren, Iñigo, and Cristina Trujillo. "Improving phase-transfer catalysis by enhancing non-covalent interactions." Physical Chemistry Chemical Physics 22, no. 37 (2020): 21015–21. http://dx.doi.org/10.1039/d0cp02012e.

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A theoretical study of the interactions established between an alkaloid quinine-derived PTC and different anions of interest was performed. Ion pairing competes with an intermolecular hydrogen bond between the PT counteranion and potential HB donors.
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Makosza, Mieczyslaw. "Phase-transfer catalysis. A general green methodology in organic synthesis." Pure and Applied Chemistry 72, no. 7 (2000): 1399–403. http://dx.doi.org/10.1351/pac200072071399.

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Basic concept of phase-transfer catalysis (PTC), its field of applications and specific features as the most general, efficient, and environment-friendly green methodology of organic synthesis, particularly for industrial processes, is discussed.
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Dissertations / Theses on the topic "Phase Transfer Catalysis (PTC)"

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Zhang, Jiuqing. "Palladium-Imidazolium Carbene Catalyzed Heck Coupling Reactions and Synthesis of a Novel Class of Fluoroanthracenylmethyl PTC Catalysts." Diss., CLICK HERE for online access, 2005. http://contentdm.lib.byu.edu/ETD/image/etd1075.pdf.

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Hicken, Erik J. "Total Syntheses of (+)-Geldanamycin, (-)-Ragaglitazar, and (+)-Kurasoin A and Phase-Transfer-Catalyzed Asymmetric Alkylation." BYU ScholarsArchive, 2005. https://scholarsarchive.byu.edu/etd/801.

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Geldanamycin possesses various biological activities as seen in the NCI 60 cell line panel (13 nM avg., 70 nM SKBr-3 cells). The predominant mode of action providing these unique results arises from the ability of geldanamycin (GA) to bind to the chaperone heat shock protein 90 (Hsp90). Despite its complicated functionality, the first total synthesis of GA was accomplished, which included two new reactions developed specifically to address the stereochemical features. The final step in the synthesis of GA was a demethylation-oxidation sequence to generate the desired para-quinone. This step co
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Berkner, Joachim Ernst. "Synthesis and characterization of new organic electrically conducting polymers : part II: Direct carboxylation of sulfolene : part III: Effect of water on PTC systems : part IV: Mechanism of Phase transfer catalytic N-alkylation reactions." Diss., Georgia Institute of Technology, 1996. http://hdl.handle.net/1853/30715.

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Brooks, Lancelot L. "Synthesis of bromochloromethane using phase transfer catalysis." Thesis, Nelson Mandela Metropolitan University, 2011. http://hdl.handle.net/10948/d1008162.

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The synthesis of bromochloromethane (BCM) in a batch reactor, using phase transfer catalysis, was investigated. During the synthetic procedure, sodium bromide (100.0g, 0.97mol) along with an excess amount of dichloromethane (265.0g, 3.12 mol) was charged to a reactor containing benzyl triethylammonium chloride (13 mmol), dissolved in 50 ml of water. The bench scale reactions were all carried out in a Parr 4520 bench top pressure reactor coupled to a Parr 4841 temperature controller. The method produced a 50.0 percent yield of the product BCM after a reaction time of 12 to 13 hours. The main ob
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Wheeler, Theresa Christy. "Phase-transfer catalysis in supercritical fluid solvents." Diss., Georgia Institute of Technology, 2001. http://hdl.handle.net/1853/9371.

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Milani, Michael. "Devulcanization of automobile tires via phase transfer catalysis." Thesis, Georgia Institute of Technology, 1997. http://hdl.handle.net/1853/11700.

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Schettini, Rosaria. "Novel macrocyclic systems in asymmetric phase-transfer catalysis." Doctoral thesis, Universita degli studi di Salerno, 2017. http://hdl.handle.net/10556/2422.

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2014 - 2015<br>In the great realm of organic synthesis, phase-transfer catalysis (PTC) is a well recognized methodology which plays a key role both in industry and academia research. This process involves reactions that take place between reagents which are located in different phases, for example an inorganic water-soluble reagent and a substrate soluble in the organic phase. Considering the well-defined advantages of asymmetric phase-transfer catalysis as a powerful method for organic synthesis, the aim of this research project is to introduce novel macrocycle systems as new and efficient ca
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Fair, Barbara E. "An investigation of omega-phase catalysis." Diss., Georgia Institute of Technology, 1985. http://hdl.handle.net/1853/30308.

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Racz, Robert. "Use of phase transfer catalysts in emulsion polymerization." Thesis, Georgia Institute of Technology, 1996. http://hdl.handle.net/1853/11128.

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Maxey, Natalie Brimer. "Transport and Phase-Transfer Catalysis in Gas-Expanded Liquids." Diss., Georgia Institute of Technology, 2006. http://hdl.handle.net/1853/10411.

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Gas-expanded liquids (GXL) are a new and benign class of liquid solvents that are intermediate in physical properties between normal liquids and supercritical fluids and therefore may offer advantages in separations, reactions, and advanced materials. Phase-transfer catalysis (PTC) is a powerful tool in chemistry that facilitates interaction and reaction between two or more species present in immiscible phases and offers the ability to eliminate the use of frequently expensive, environmentally undesirable, and difficult to remove polar, aprotic solvents. The work presented here seeks to furt
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Books on the topic "Phase Transfer Catalysis (PTC)"

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Starks, Charles M., ed. Phase-Transfer Catalysis. American Chemical Society, 1987. http://dx.doi.org/10.1021/bk-1987-0326.

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Halpern, Marc E., ed. Phase-Transfer Catalysis. American Chemical Society, 1997. http://dx.doi.org/10.1021/bk-1997-0659.

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Starks, Charles M., Charles L. Liotta, and Marc E. Halpern. Phase-Transfer Catalysis. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-0687-0.

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Dehmlow, Eckehard V. Phase transfer catalysis. 3rd ed. VCH, 1993.

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Maruoka, Keiji. Asymmetric phase transfer catalysis. Wiley-VCH, 2008.

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Sasson, Y., and R. Neumann, eds. Handbook of Phase Transfer Catalysis. Springer Netherlands, 1997. http://dx.doi.org/10.1007/978-94-009-0023-3.

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R, Neumann, and Sasson Y, eds. Handbook of phase transfer catalysis. Blackie Academic & Professional, 1997.

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Starks, Charles M. Phase-transfer catalysis: Fundamentals, applications, and industrial perspectives. Chapman & Hall, 1994.

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Starks, Charles M. Phase-Transfer Catalysis: Fundamentals, Applications, and Industrial Perspectives. Springer Netherlands, 1994.

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L, Liotta Charles, Starks Charles M, and Halpern Marc, eds. Phase-Transfer Catalysis: Fundamentals, Applications and Industrial Perspectives. Chapman & Hall, 1993.

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Book chapters on the topic "Phase Transfer Catalysis (PTC)"

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Ooi, Takashi, and Keiji Maruoka. "Phase-Transfer Catalysis." In Quaternary Stereocenters. Wiley-VCH Verlag GmbH & Co. KGaA, 2006. http://dx.doi.org/10.1002/3527606858.ch10.

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Tavener, S. J., and J. H. Clark. "Phase transfer catalysis." In Chemistry of Waste Minimization. Springer Netherlands, 1995. http://dx.doi.org/10.1007/978-94-011-0623-8_5.

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Vanýsek, P. "Phase Transfer Catalysis." In Lecture Notes in Chemistry. Springer Berlin Heidelberg, 1985. http://dx.doi.org/10.1007/978-3-642-48910-5_8.

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Gates, B. C. "Phase Transfer Catalysis." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145319.ch20.

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Starks, Charles M., Charles L. Liotta, and Marc E. Halpern. "Phase-Transfer Catalysts." In Phase-Transfer Catalysis. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-0687-0_4.

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Starks, Charles M., Charles L. Liotta, and Marc E. Halpern. "Basic Concepts in Phase-Transfer Catalysis." In Phase-Transfer Catalysis. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-0687-0_1.

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Starks, Charles M., Charles L. Liotta, and Marc E. Halpern. "Phase-Transfer-Catalyzed Oxidations." In Phase-Transfer Catalysis. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-0687-0_10.

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Starks, Charles M., Charles L. Liotta, and Marc E. Halpern. "Phase-Transfer-Catalyzed Reductions." In Phase-Transfer Catalysis. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-0687-0_11.

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Starks, Charles M., Charles L. Liotta, and Marc E. Halpern. "Phase-Transfer Catalysis: Chiral Phase-Transfer-Catalyzed Formation of Carbon-Carbon Bonds." In Phase-Transfer Catalysis. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-0687-0_12.

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Starks, Charles M., Charles L. Liotta, and Marc E. Halpern. "Phase-Transfer Catalysis-Transition Metal Cocatalyzed Reactions." In Phase-Transfer Catalysis. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-0687-0_13.

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Conference papers on the topic "Phase Transfer Catalysis (PTC)"

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Yang, Hung-Ming, and Wei-Ming Chu. "Ultrasound-Assisted Phase-Transfer Catalysis: Green Synthesis of Substituted Benzoate with Novel Dual-Site Phase-Transfer Catalyst in Solid-Liquid System." In 14th Asia Pacific Confederation of Chemical Engineering Congress. Research Publishing Services, 2012. http://dx.doi.org/10.3850/978-981-07-1445-1_210.

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Guo, Hang, Chong Fang Ma, Mao Hai Wang, et al. "Heat and Mass Transfer and Two Phase Flow in Hydrogen Proton Exchange Membrane Fuel Cells and Direct Methanol Fuel Cells." In ASME 2003 1st International Conference on Fuel Cell Science, Engineering and Technology. ASMEDC, 2003. http://dx.doi.org/10.1115/fuelcell2003-1755.

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Fuel cells are related to a number of scientific and engineering disciplines, which include electrochemistry, catalysis, membrane science and engineering, heat and mass transfer, thermodynamics and so on. Several thermophysical phenomena such as heat transfer, multicomponent transport and two phase flow play significant roles in hydrogen proton exchange membrane fuel cells and direct methanol fuel cells based on solid polymer electrolyte membrane. Some coupled thermophysical issues are bottleneck in process of scale-up of direct methanol fuel cells and hydrogen proton exchange membrane fuel ce
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Aimei, Yu, and Li Qiang. "Study on Thermal Control Behavior by Using BaTiO3-Based PTC Materials With Room Temperature Curie Point." In ASME 2019 6th International Conference on Micro/Nanoscale Heat and Mass Transfer. American Society of Mechanical Engineers, 2019. http://dx.doi.org/10.1115/mnhmt2019-4014.

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Abstract Thermal management has become an important issue to be solved in the miniaturization and weight reduction of electronic equipment, especially in the aerospace field. The doped BaTiO3, as a self-regulating heating material, exhibits an attractive application perspective on the thermal control of electrical devices, resulting from its positive temperature coefficient (PTC) property. However, the Curie temperature of most of the doped BaTiO3 material at present is much higher than the operating temperature of the electrical equipment. On this basis, this paper focuses on the controlling
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Hua, Meng, Liang Zhang, Zi-Qin Zhu, Li-Wu Fan, Zi-Tao Yu, and Ya-Cai Hu. "An Experimental Study of Thermal Performance of a Two-Phase Loop Thermosyphon (TPLT)-Based Steam Generator: Effects of Thermal Boundary Conditions." In ASME 2013 Heat Transfer Summer Conference collocated with the ASME 2013 7th International Conference on Energy Sustainability and the ASME 2013 11th International Conference on Fuel Cell Science, Engineering and Technology. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/ht2013-17104.

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For the Parabolic trough collector (PTC) system, thermal boundary condition of the receiver (or heating section) is important for the thermal optimization. In this work, effects of thermal boundary on thermal performance of the two-phase loop thermosyphon (TPLT) natural circulation PTC system was investigated experimentally. Three kinds of thermal boundary heating conditions (upper and lower half, and whole circular heated) and two filling ratios (FR = 0.6, 1.2) were adopted in this paper. The results show that half heating condition can improve heat transfer performance in receiver and system
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Gharbia, Yousef, Mohamed Fayed, and Mohammed Anany. "Steam Generation for EHOR Using PTC System Modeled in SAM." In ASME 2019 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2019. http://dx.doi.org/10.1115/imece2019-10332.

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Abstract Kuwait’s oil reserves include approximately 13 bn barrels of heavy oil, primarily located in the northern region of the country. The Lower Fars (LF) heavy oil development project aims to extract heavy oil from the Ratqa oil field. The US$7 bn project is being developed in phases, with the first phase expected to start in 2019 with a production rate of 60,000 Barrel of Oil Per Day (BOPD). This amount is planned to ramp up to 270,000 BOPD by 2030. The steam required for the Enhanced Heavy Oil Recovery (EHOR) process can be either generated by using conventional fuels or renewable energy
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Zhang, Shu, Yizhang Yang, Yoed Rabin, Katayun Barmak, and Mehdi Asheghi. "A Novel Experimental Procedure and Technique for Smallscale Calorimetry." In ASME/JSME 2007 Thermal Engineering Heat Transfer Summer Conference collocated with the ASME 2007 InterPACK Conference. ASMEDC, 2007. http://dx.doi.org/10.1115/ht2007-32894.

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By definition, a differential scanning calorimetry (DSC) requires a sample structure and a refrence structure to obtain the latent heat of a speicman. We propose a novel approach, named Phase Transition Calorimetry (PTC), to obtain the specimen’s latent heat by using only the signal from the sample bridge. The new setup and procedure are primarily based on electrical resistance heating and thermometry and the parametric estimation method by solving the heat conduction equation with and without the phase transformation. The new setup has two major advantages over widely used DSC setups: there a
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Sekar, Lokesh Kumar, and Esuru Rita Okoroafor. "Thermohydrochemical Modeling of Hydrogen Generation from Stimulated Ultramafic Rocks." In SPE Reservoir Simulation Conference. SPE, 2025. https://doi.org/10.2118/223864-ms.

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Abstract This study is a preliminary model of hydrogen generation from stimulated ultramafic rocks. A coupled thermohydrochemical model simulates the multifaceted processes of heat transfer, fluid flow, and chemical reactions, accounting for hydrogen generation, phase changes, thermal energy release, and new material formation during induced serpentinization. Some of the model inputs were from experimental data, and others were taken from works in literature. The hydrogen generation from the stimulated ultramafic rock was compared to the base model of unstimulated ultramafic rock. The model wa
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Reports on the topic "Phase Transfer Catalysis (PTC)"

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Thayumanavan, Sankaran. A Novel Dendrimer Design for Phase Transfer Catalysis in the Fluorophase. Defense Technical Information Center, 2005. http://dx.doi.org/10.21236/ada433715.

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