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Journal articles on the topic 'Phenanthroline-1,10(diphenyl-2,9)'

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Published: 4 June 2021

Last updated: 7 February 2022

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1

Wang, Jia, Jun-Wei Ye, and Yue Wang. "2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline." Acta Crystallographica Section E Structure Reports Online 63, no. 4 (2007): o2007—o2008. http://dx.doi.org/10.1107/s1600536807012974.

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2

Xie, Min-Hao, Ya-Ling Liu, Pei Zou, Yong-Jun He, and Biao Huang. "4,7-Diphenyl-2,9-bis(trichloromethyl)-1,10-phenanthroline." Acta Crystallographica Section E Structure Reports Online 66, no. 1 (2009): o5. http://dx.doi.org/10.1107/s1600536809051071.

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3

Qiu, Yu-E. "Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) 0.35-hydrate." Acta Crystallographica Section E Structure Reports Online 63, no. 11 (2007): m2835. http://dx.doi.org/10.1107/s1600536807052580.

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The title compound, [ZnCl2(C26H20N2)]·0.35H2O, consists of one mononuclear dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)zinc(II) molecule and a partial-occupancy water molecule. The ZnII atom is coordinated by two N atoms of one phenanthroline molecule and two chloride ions in a tetrahedral geometry. In the structure there exist O—H...Cl hydrogen bonds and π–π interactions [centroid–centroid = 4.035 (4) Å and vertical distance = 3.883 (4) Å], which lead to the formation of one-dimensional supramolecular chains. This compound is isostructural with the CuCl2, NiI2, NiBr2 and PtI2 add

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4

ARMAROLI, N., L. DE COLA, V. BALZANI, J. P. SAUVAGE, C. O. DIETRICH-BUCHECKER, and J. M. KERN. "ChemInform Abstract: Absorption and Luminescence Properties of 1,10-Phenanthroline, 2,9- Diphenyl-1,10-phenanthroline, 2,9-Dianisyl-1,10-phenanthroline and Their Protonated Forms in Dichloromethane Solution." ChemInform 23, no. 27 (2010): no. http://dx.doi.org/10.1002/chin.199227034.

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5

Saitoh, Yutaka, Take-aki Koizumi, Kohtaro Osakada, and Takakazu Yamamoto. "Preparation of symmetric dibromides of 1,10-phenanthroline." Canadian Journal of Chemistry 75, no. 10 (1997): 1336–39. http://dx.doi.org/10.1139/v97-160.

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Bromation of 1,10-phenanthroline with Br2 proceeds smoothly in the presence of S2Cl2 and pyridine to give 3,8-dibromo-1,10-phenanthroline in good yield. Bromation of 2,9-dibutoxy-1,10-phenanthroline with Br2, in an aqueous medium gives 5,6-dibromo-2,9-dibutoxy-1,10-phenanthroline selectively. Similar bromination of 4,7-dibutoxy-1,10-phenanthroline with Br2 gives 3,8-dibromo-4,7-dibutoxy-1,10-phenanthroline, which forms a 1:1 adduct with Cu(NO3)2. Molecular structure of the 1:1 adduct has been determined by X-ray crystallography. Keywords: bromination, 1,10-phenanthroline, 3,8-dibromo-1,10-phen

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6

Sun, Shih-Sheng, Peter Y. Zavalij, and Alistair J. Lees. "Acetonitriletricarbonyl(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)rhenium(I) hexafluorophosphate." Acta Crystallographica Section E Structure Reports Online 57, no. 3 (2001): m119—m121. http://dx.doi.org/10.1107/s1600536801003440.

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7

Nadeem, Said, Muhammad Raza Shah, and Seik Weng Ng. "2,9-Dichloro-1,10-phenanthroline." Acta Crystallographica Section E Structure Reports Online 65, no. 4 (2009): o922. http://dx.doi.org/10.1107/s1600536809011180.

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8

Stange, Andreas F., Eberhard Waldhör, Michael Moscherosch, and Wolfgang Kaim. "Variable Structure of the Cu2S2 Core in Doubly Thiolate-Bridged Dicopper(I) Complexes. An X-Ray Crystallographic, Electrochemical and EPR Study of (dmp)2(o-CH3C6H4S)2Cu2, dmp = 2,9-Dimethyl-1,10-phenanthroline, and a Comment on the Nature of Phenanthroline-Containing “Cu(0)” Complexes." Zeitschrift für Naturforschung B 50, no. 1 (1995): 115–22. http://dx.doi.org/10.1515/znb-1995-0122.

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The molecular and crystal structure of the dicopper(I) complex (dmp)2(μ-o-CH3C6H4S)2Cu2 (1), dmp = 2,9-dimethyl-1,10-phenanthroline, has been determined. With Cu/S/Cu and S/Cu/S bond angles between 80 and 100°, the planar structure of the central CuSCuS four-membered ring is much more symmetric for 1 as compared to the analogous complex 2 of unsubstituted 1,10-phenanthroline which has a folded Cu2S2 core with bond angles between 67 and 108°. This result illustrates a considerable structural flexibility of the LCu(μ-SR)2CuL entity which is being discussed as a possible model for CuA centers of

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9

Chabdon-Noblat, Sylvie, and Jean-Pierre Sauvage. "Synthesis of bis-porphyrins containing a 2,9-diphenyl-1,10-phenanthroline spacer." Tetrahedron 47, no. 28 (1991): 5123–32. http://dx.doi.org/10.1016/s0040-4020(01)87125-8.

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10

Wang, Zhong-Ming, Hua-Kuan Lin, Zhi-Fen Zhou, Shou-Rong Zhu, Tian-Fu Liu та Yun-Ti Chen. "Synthesis of novel 1,10-phenanthroline-2,9-bis-α-amino acid conjugates". Journal of Chemical Research 2000, № 4 (2000): 170–71. http://dx.doi.org/10.3184/030823400103167020.

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Starting from 2,9-dimethyl-1,10-phenanthroline, the syntheses of eight novel 1,10-phenanthroline-2,9-bis-α-aminoacid conjugates (α-amino acids: DL-Ala, L-Val, L-Phe, L-His, L-Ile, L-Met, L-Glu, L-Asp) are described in detail.

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11

Baggio, S., R. Baggio, and A. W. Mombrú. "2,9-Dimethyl-1,10-phenanthroline Dihydrate." Acta Crystallographica Section C Crystal Structure Communications 54, no. 12 (1998): 1900–1902. http://dx.doi.org/10.1107/s0108270198009743.

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12

Fun, Hoong-Kun, Suchada Chantrapromma, Annada C. Maity, and Shyamaprosad Goswami. "2,9-Bis(trichloromethyl)-1,10-phenanthroline." Acta Crystallographica Section E Structure Reports Online 66, no. 2 (2010): o424. http://dx.doi.org/10.1107/s1600536810002035.

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13

Nohara, Isaak, Aramis Keller, Nikolai Tarassenko, Alessandro Prescimone, Edwin C. Constable, and Catherine E. Housecroft. "Heteroleptic [Cu(P^P)(N^N)][PF6] Compounds with Isomeric Dibromo-1,10-Phenanthroline Ligands." Inorganics 8, no. 1 (2020): 4. http://dx.doi.org/10.3390/inorganics8010004.

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A series of [Cu(P^P)(N^N)][PF6] compounds are reported in which N^N is 2,9-dibromo-1,10-phenanthroline (2,9-Br2phen), 3,8-dibromo-1,10-phenanthroline (3,8-Br2phen) or 4,7-dibromo-1,10-phenanthroline (4,7-Br2phen) and P^P is bis(2-(diphenylphosphano)phenyl)ether (POP) or 4,5-bis(diphenylphosphano)-9,9-dimethylxanthene (xantphos). The compounds were characterized by solution multinuclear NMR spectroscopy, mass spectrometry and a single-crystal X-ray analysis. Each compound underwent a partially reversible or irreversible copper-centred oxidation, the highest potential being for 2,9-Br2phen-conta

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14

Steinkamp, Tanja, Heiko Hayen, Jurriaan Huskens, and Uwe Karst. "Lanthanide-induced hydrolysis of 4,7-diphenyl-1,10-phenanthroline-2,9-dicarboxylic acid esters." Inorganica Chimica Acta 362, no. 2 (2009): 421–25. http://dx.doi.org/10.1016/j.ica.2008.04.027.

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15

Yang, Weixi, та Tamaki Nakano. "Synthesis of poly(1,10-phenanthroline-5,6-diyl)s having a π-stacked, helical conformation". Chemical Communications 51, № 97 (2015): 17269–72. http://dx.doi.org/10.1039/c5cc07005h.

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5,6-Dibromo-1,10-phenanthroline and 2,9-di-n-butyl-5,6-dibromo-1,10-phenanthroline were polymerized using a Ni catalyst to afford helical polymers in which the phenanthroline moieties are densely stacked on top of each other.

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16

Dehghani, Ali, Mostafa M. Amini, Ezzatollah Najafi, Azadeh Tadjarodi та Behrouz Notash. "Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2 N,N′)zinc". Acta Crystallographica Section E Structure Reports Online 68, № 6 (2012): m811. http://dx.doi.org/10.1107/s1600536812022738.

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The reaction of equimolar amounts of zinc bromide and 2,9-dimethyl-1,10-phenanthroline in dry methanol provided the title compound, [ZnBr2(C14H12N2)], in good yield. The ZnII ion is coordinated in a distorted tetrahedral environment by two N atoms from the chelating 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions. There is intermolecular π–π stacking between adjacent phenanthroline units, with centroid–centroid distances of 3.594 (3) and 3.652 (3) Å.

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17

Zhang, Shi Guo, Long Miao Xie, and Hong Li. "2,9-Bis(4-pyridylmethoxy)-1,10-phenanthroline." Acta Crystallographica Section E Structure Reports Online 65, no. 10 (2009): o2549. http://dx.doi.org/10.1107/s1600536809038318.

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18

Cai, Yuhua, Libin Tang, Jinzhong Xiang, et al. "Exceptional ultraviolet photovoltaic response of 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline based detector." Journal of Applied Physics 118, no. 12 (2015): 124503. http://dx.doi.org/10.1063/1.4931430.

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19

Alizadeh, Robabeh. "(2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline-κ2N,N′)bis(thiocyanato-κS)mercury(II)". Acta Crystallographica Section E Structure Reports Online 65, № 7 (2009): m817—m818. http://dx.doi.org/10.1107/s1600536809023228.

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20

Ahmadi, Roya, Khadijeh Kalateh, Robabeh Alizadeh, Zeinab Khoshtarkib та Vahid Amani. "Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ2N,N′)mercury(II) acetonitrile hemisolvate". Acta Crystallographica Section E Structure Reports Online 65, № 8 (2009): m848—m849. http://dx.doi.org/10.1107/s1600536809024180.

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21

Collin, Jean-Paul, Pierre Mobian, Jean-Pierre Sauvage, Angélique Sour, Yi-Ming Yan, and Itamar Willner. "Copper-Complexed Pirouetting [2]pseudorotaxanes with Sulfur-Containing End-Groups Attached to the Thread: Synthesis, Electrochemical Studies, and Deposition on Gold Electrodes." Australian Journal of Chemistry 62, no. 10 (2009): 1231. http://dx.doi.org/10.1071/ch09334.

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Two copper [2]pseudorotaxanes incorporating a macrocycle with two chelating sites (2,9-diphenyl-1,10-phenanthroline and 2,2′,6′,2″-terpyridine) and a thread based on crescent-shaped 2,2′-bipyridine derivatives have been synthesized and characterized. One of the threads was a hindering 2,2′-bipyridine functionalized by two thioctic-ended arms. The second thread was an 8,8′-diphenyl-3,3′-biisoquinoline functionalized by two thioether-ended arms. The electrochemical studies of the two copper [2]pseudorotaxanes, both in solution and anchored on a gold surface, showed only fast-moving systems in so

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22

Shan, Fa-Shuo, Jia-Ping Lai, Hui Sun, et al. "A facile, fast responsive and highly selective mercury(ii) probe characterized by the fluorescence quenching of 2,9-dimethyl-1,10-phenanthroline and two new metal–organic frameworks." RSC Advances 6, no. 70 (2016): 66215–23. http://dx.doi.org/10.1039/c6ra13514e.

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23

Jin, Shuang, Mei-Feng Wen, Lu-Fang Liu, Ming-Juan Gao та Jian-Zhong Wu. "Synthesis and supramolecular networks of 5,6-dioxo-1,10-phenanthroline-2,9-dicarboxylic acid dihydrate and its first coordination compoundcis-diaquachlorido(5,6-dioxo-1,10-phenanthroline-2,9-dicarboxylic acid-κ4O2,N,N′,O9)manganese(II) chloride dihydrate". Acta Crystallographica Section C Crystal Structure Communications 68, № 5 (2012): m135—m138. http://dx.doi.org/10.1107/s0108270112017763.

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5,6-Dioxo-1,10-phenanthroline-2,9-dicarboxylic acid dihydrate (H2pdda·2H2O), C14H6N2O6·2H2O, was obtained by carbonylation of 1,10-phenanthroline-2,9-dicarboxylic acid. Its first coordination compound, [MnCl(C14H6N2O6)(H2O)2]Cl·2H2O, in which the H2pdda ligand remains protonated, was synthesized in aqueous acetic acid. H2pdda chelates one water moleculeviahydrogen bonds in H2pdda·2H2O, whereas in the coordination compound it chelates one heptacoordinate MnIIatomviacoordination bonds. The N atoms in H2pdda·2H2O and the Cl atoms in the coordination compound are also involved in hydrogen bonds. E

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24

Warad, Ismail, Ahmed Boshaala, Saud I. Al-Resayes, Salem S. Al-Deyab та Mohamed Rzaigui. "(2,9-Dimethyl-1,10-phenanthroline-κ2N,N′)diiodidocadmium". Acta Crystallographica Section E Structure Reports Online 67, № 12 (2011): m1650. http://dx.doi.org/10.1107/s1600536811044667.

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25

Britton, D., L. C. Thompson, and R. C. Holz. "Structure of 2,9-dimethyl-1,10-phenanthroline hemihydrate." Acta Crystallographica Section C Crystal Structure Communications 47, no. 5 (1991): 1101–3. http://dx.doi.org/10.1107/s0108270190011295.

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26

Guo, H. C., R. H. Zheng, and H. J. Jiang. "Improved Synthesis of 2,9-Dichloro-1,10-phenanthroline." Organic Preparations and Procedures International 44, no. 4 (2012): 392–96. http://dx.doi.org/10.1080/00304948.2012.697745.

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27

Moncol, Jan, Milan Gembicky, and Philip Coppens. "(2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline)(tetrahydroborato)copper(I): a redetermination at 90 K." Acta Crystallographica Section E Structure Reports Online 62, no. 9 (2006): m2177—m2179. http://dx.doi.org/10.1107/s1600536806031308.

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28

Zhao, Pei-Zheng, Feng-Mei Yan та Jian-Ge Wang. "Aqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)bis(2-hydroxybenzoato-κO)manganese(II) 2,9-dimethyl-1,10-phenanthroline hemisolvate". Acta Crystallographica Section E Structure Reports Online 65, № 2 (2009): m194—m195. http://dx.doi.org/10.1107/s1600536809000981.

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29

Nicholls, Thomas P., Chiara Caporale, Massimiliano Massi, Michael G. Gardiner, and Alex C. Bissember. "Synthesis and characterisation of homoleptic 2,9-diaryl-1,10-phenanthroline copper(i) complexes: influencing selectivity in photoredox-catalysed atom-transfer radical addition reactions." Dalton Transactions 48, no. 21 (2019): 7290–301. http://dx.doi.org/10.1039/c8dt04116d.

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30

Eckenhoff, William T., and Tomislav Pintauer. "Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) tetraphenylborate dichloromethane solvate." Acta Crystallographica Section E Structure Reports Online 63, no. 3 (2007): m800—m802. http://dx.doi.org/10.1107/s1600536807007337.

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In the title compound, [Cu(C14H12N2)2]C24H20B·CH2Cl2, CuI is chelated by two 2,9-dimethyl-1,10-phenanthroline (2,9-Me2phen) ligands, in a distorted tetrahedral coordination geometry. The average Cu—N bond length is 2.032 Å, and the interligand dihedral angle is 77.60 (6)°. The complexes form π–π stacking interactions between 2,9-Me2phen ligands, with a perpendicular interplanar separation of 3.652 (5) Å.

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31

Lemport, Pavel S., Petr I. Matveev, Alexander V. Yatsenko, et al. "The impact of alicyclic substituents on the extraction ability of new family of 1,10-phenanthroline-2,9-diamides." RSC Advances 10, no. 44 (2020): 26022–33. http://dx.doi.org/10.1039/d0ra05182a.

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32

Kohler, Lars, Ryan G. Hadt, Dugan Hayes, Lin X. Chen, and Karen L. Mulfort. "Synthesis, structure, and excited state kinetics of heteroleptic Cu(i) complexes with a new sterically demanding phenanthroline ligand." Dalton Trans. 46, no. 38 (2017): 13088–100. http://dx.doi.org/10.1039/c7dt02476b.

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In this report we describe the synthesis of a new phenanthroline ligand, 2,9-di(2,4,6-tri-isopropyl-phenyl)-1,10-phenanthroline (bL2) and its use as the blocking ligand in the preparation of two new heteroleptic Cu(i)diimine complexes.

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33

Alyapyshev, M., J. Ashina, D. Dar’in, et al. "1,10-Phenanthroline-2,9-dicarboxamides as ligands for separation and sensing of hazardous metals." RSC Advances 6, no. 73 (2016): 68642–52. http://dx.doi.org/10.1039/c6ra08946a.

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34

Zheng, Changwu, та Shannon S. Stahl. "Regioselective aerobic oxidative Heck reactions with electronically unbiased alkenes: efficient access to α-alkyl vinylarenes". Chemical Communications 51, № 64 (2015): 12771–74. http://dx.doi.org/10.1039/c5cc05312a.

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35

Bidan, G�rard, Bernadette Divisia-Blohorn, Jean-Marc Kern, and Jean-Pierre Sauvage. "Electroactive films of [Cu(dpp)2]+ covalently attached to polypyrrole (dpp = 2,9-diphenyl-1,10-phenanthroline)." Journal of the Chemical Society, Chemical Communications, no. 11 (1988): 723. http://dx.doi.org/10.1039/c39880000723.

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36

Bidan, G., B. Divisia-Blohorn, M. Billon, J. M. Kern, and J. P. Sauvage. "Tangled 3-functionalized polypyrrole derivatives built around Cu(dpp)2+ (dpp = 2,9-diphenyl-1,10-phenanthroline)." Journal of Electroanalytical Chemistry 360, no. 1-2 (1993): 189–98. http://dx.doi.org/10.1016/0022-0728(93)87012-k.

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37

Dehaudt, Jérémy, Neil J. Williams, Ilya A. Shkrob, Huimin Luo, and Sheng Dai. "Selective separation of trivalent f-ions using 1,10-phenanthroline-2,9-dicarboxamide ligands in ionic liquids." Dalton Transactions 45, no. 29 (2016): 11624–27. http://dx.doi.org/10.1039/c6dt01800a.

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38

Zhang, Hongmei, Hujun Cao, Zhiyong Zhang, et al. "Synthesis of 4,7-Diphenyl-1,10-phenanthroline." Chinese Journal of Organic Chemistry 32, no. 03 (2012): 621. http://dx.doi.org/10.6023/cjoc1107061.

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39

Martins, João P., Pablo Martín-Ramos, Abílio J. F. N. Sobral, and Manuela Ramos Silva. "4,7-Diphenyl-1,10-phenanthroline methanol hemisolvate." Acta Crystallographica Section E Structure Reports Online 69, no. 7 (2013): o1018. http://dx.doi.org/10.1107/s1600536813014682.

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40

Wan, Xin-Sheng, Hai-Yan Zhang, Cao-Yuan Niu, Chun-Hong Kou та Cao-Ling Feng. "(2,9-Dimethoxy-1,10-phenanthroline-κ2N,N′)nitratosilver(I)". Acta Crystallographica Section E Structure Reports Online 63, № 12 (2007): m2951. http://dx.doi.org/10.1107/s1600536807055146.

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41

Warad, Ismail, Ahmed Boshaala, Saud I. Al-Resayes, Salem S. Al-Deyab та Mohamed Rzaigui. "Dibromido(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)cadmium". Acta Crystallographica Section E Structure Reports Online 67, № 12 (2011): m1846—m1847. http://dx.doi.org/10.1107/s1600536811050069.

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42

Zhang, Yu, and Weizhou Wang. "Crystal structure of 2,9-dibromo-1,10-phenanthroline, C12H6Br2N2." Zeitschrift für Kristallographie - New Crystal Structures 232, no. 3 (2017): 441–42. http://dx.doi.org/10.1515/ncrs-2016-0306.

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43

Wang, Xinfang. "Dichlorido(2,9-dimethyl-1,10-phenanthroline)manganese(II) hemihydrate." Acta Crystallographica Section E Structure Reports Online 65, no. 12 (2009): m1659. http://dx.doi.org/10.1107/s1600536809049149.

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44

Shi, Zi-Fa, Zhu-Qing Gao, and Jin-Zhong Gu. "Triaqua(1,10-phenanthroline-2,9-dicarboxylato)cobalt(II) dihydrate." Acta Crystallographica Section E Structure Reports Online 66, no. 4 (2010): m372—m373. http://dx.doi.org/10.1107/s1600536810007567.

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45

Cetin, M. Mustafa, Roman T. Hodson, C. Robin Hart, et al. "Characterization and photocatalytic behavior of 2,9-di(aryl)-1,10-phenanthroline copper(i) complexes." Dalton Transactions 46, no. 20 (2017): 6553–69. http://dx.doi.org/10.1039/c7dt00400a.

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46

Xuan, Xiao-peng, Pei-zheng Zhao та Shu-xia Zhang. "(2,9-Dimethyl-1,10-phenanthroline-κ2 N,N′)bis(3-hydroxybenzoato-κ2 O,O′)manganese(II) 2,9-dimethyl-1,10-phenanthroline dihydrate". Acta Crystallographica Section E Structure Reports Online 63, № 11 (2007): m2813—m2814. http://dx.doi.org/10.1107/s1600536807051628.

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In the title compound, [Mn(C7H5O3)2(C14H12N2)]·C14H12N2·2H2O, the MnII ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two bidentate 3-hydroxybenzoate anions in a distorted octahedral environment. The structure is stabilized by O—H...O and O—H...N hydrogen bonds involving water molecules, the 3-hydroxybenzoate ligands and the uncoordinated dmphen molecules to form a three-dimensional network.

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47

Pal, T. K., M. A. Alam, J. Hossen, S. Paul, H. Ahmad, and M. C. Sheikh. "Spectral and Biological Studies on New Mixed Ligand Complexes." Journal of Scientific Research 10, no. 3 (2018): 291–302. http://dx.doi.org/10.3329/jsr.v10i3.36379.

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In this study, new mixed ligand complexes have been prepared from bis(2,4,4-trimethylpentyl)dithiophosphinic acid (C16H35PS2) and 2,9-dimethyl-1,10-phenanthroline (C14H12N2) with various metal(II) ions. The molecular formula of the metal complexes were [Mn(C16H34PS2)(C14H12N2)]Cl (1), [Fe(C16H34PS2)(C14H12N2)]Cl (2), [Co(C16H34PS2) (C14H12N2)]Cl (3), [Zn(C16H34PS2)(C14H12N2)]Cl (4) and [Cd(C16H34PS2)(C14H12N2)]Cl (5). These complexes have been characterized by various physico-chemical techniques such as melting point, molar conductance, magnetic susceptibility measurements as well as UV-Vis, I

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Huang, Meng-Xia, Cai-Hua Lv, Qing-Da Huang, Jia-Ping Lai, and Hui Sun. "A novel and fast responsive turn-on fluorescent probe for the highly selective detection of Cd2+ based on photo-induced electron transfer." RSC Advances 9, no. 62 (2019): 36011–19. http://dx.doi.org/10.1039/c9ra06356k.

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49

Sun, Hongwei, Zhifen Zhou, Huakuan Lin, et al. "Kinetic and equilibrium studies of the acid dissociation of the cobalt(II) complexes of N,N'-dialkyl- 1,10-phenanthroline-2,9-dimathanamine ligands." Canadian Journal of Chemistry 77, no. 9 (1999): 1471–75. http://dx.doi.org/10.1139/v99-160.

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The complexation property and the acid dissociation kinetics of four N,N'-dialkyl-1,10-phenanthroline-2,9-dimathanamine complexes with cobalt(II) were studied using a pH meter and a stopped-flow spectrophotometer. In 6.6 × 10-3~0.5 mol dm-3 HCl (I = 0.5 mol dm-3 HCl + NaCl), the dissociation rate follows the law kobs = kK2[H+]/(1 + K2[H+]). The acid dissociation can be rationalized in terms of a four-step kinetic process involving two rapid pre-equilibrium protonations and rate-determining cleavage of the Co(II)-N(phenanthroline) bond. The temperature dependence of the rate was determined, and

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Chen, Jincan, Jie Wang, Yuanyuan Deng, et al. "Ru(II) Complexes Bearing O, O-Chelated Ligands Induced Apoptosis in A549 Cells through the Mitochondrial Apoptotic Pathway." Bioinorganic Chemistry and Applications 2020 (August 17, 2020): 1–16. http://dx.doi.org/10.1155/2020/8890950.

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Two new Ru(II) complexes containing O, O-chelated ligands, Ru(dip)2(SA) (Ru-1) and Ru(dmp)2(SA) (Ru-2) (dip = 4,7-diphenyl-1,10-phenanthroline; dmp = 2,9-dimethyl-1,10-phenanthroline; SA = salicylate) were synthesized to evaluate their cytotoxicity in vitro. These complexes were found to exhibit moderate antitumor activity to different types of human cancers, including A549 (human lung carcinoma), MCF-7 (breast cancer), HeLa (human cervical cancer), and HepG2 (human hepatocellular carcinoma) cell lines, but displayed low toxicity to human normal cell lines BEAS-2B (immortalized human bronchial

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