Academic literature on the topic 'Phenolic molding compound'

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Journal articles on the topic "Phenolic molding compound"

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Srebrenkoska, Vineta, Gordana Bogoeva-Gaceva, and Dimko Dimeski. "Composite material based on an ablative phenolic resin and carbon fibers." Journal of the Serbian Chemical Society 74, no. 4 (2009): 441–53. http://dx.doi.org/10.2298/jsc0904441s.

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In this study, a technological procedure for the production of a molding compound based on short carbon fibers and an ablative phenol-formaldehyde resin for high temperature application was optimized. The starting raw materials were characterized and molding compounds with different fiber/ /matrix ratios and different fiber lengths were obtained. From the different laboratory samples, molded parts were made by thermo-compression. The basic mechanical and thermal properties of the composites were determined. From the obtained results, the optimal fiber/matrix ratio was determined for a production of molding compound for high temperature application. The molding process of the composite material was optimized and all the parameters for good mechanical properties and high thermal stability of the composite were obtained. Optimization of the composite molding process was performed by the application of a numerical method for a planned experiment, i.e., a full three-factorial experimental design with variance of all three parameters (fiber length, temperature and time of the press cycle) on two levels. The obtained mechanical properties (flexural strength: 247 MPa, modulus: 27.6 GPa, impact resistance: 110 (for test moldings 10 mm?10 mm) and 91 kJ/m2 (for test moldings 15 mm?15 mm)) justified the application of this composite material in the automotive, leisure, military and other industries where high temperature resistance and high mechanical strength is required.
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Qi-lin, Mei, Yan Shi-lin, and Huang Zhi-xiong. "Numerical simulation of phenolic sheet molding compound in compression molding." Journal of Wuhan University of Technology-Mater. Sci. Ed. 18, no. 2 (June 2003): 79–81. http://dx.doi.org/10.1007/bf02838810.

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Guo, Jie, Jia Li, Qunli Rao, and Zhenming Xu. "Phenolic Molding Compound Filled with Nonmetals of Waste PCBs." Environmental Science & Technology 42, no. 2 (January 2008): 624–28. http://dx.doi.org/10.1021/es0712930.

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Horie, Masayoshi, Eiji Funatsu, Masahiro Mitsui, and Etsuji Ohno. "High Cycle Injection Molding of Phenolic Compound by Newly Designed Screw." Seikei-Kakou 9, no. 8 (1997): 612–15. http://dx.doi.org/10.4325/seikeikakou.9.612.

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Bernardeau, Fabien, Didier Perrin, Anne-Sophie Caro, Jean-Charles Benezet, and Patrick Ienny. "Valorization of waste thermoset material as a filler in thermoplastic: Mechanical properties of phenolic molding compound waste-filled PP composites." Journal of Applied Polymer Science 135, no. 12 (November 27, 2017): 45849. http://dx.doi.org/10.1002/app.45849.

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Guo, Jie, Qunli Rao, and Zhenming Xu. "Effects of particle size of fiberglass–resin powder from PCBs on the properties and volatile behavior of phenolic molding compound." Journal of Hazardous Materials 175, no. 1-3 (March 2010): 165–71. http://dx.doi.org/10.1016/j.jhazmat.2009.09.144.

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Haberstroh, E., J. Berthold, and T. Jüntgen. "Injection-Compression Molding of Glass-Fiber Filled Phenolic Molding Compounds." Advanced Engineering Materials 2, no. 11 (November 2000): 752–56. http://dx.doi.org/10.1002/1527-2648(200011)2:11<752::aid-adem752>3.0.co;2-m.

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Zhou, Wen Fu, Yan Qian He, and Ye Yong Yan. "Study of Mechanical Properties of High Quality Phenolic Molding Compounds." Advanced Materials Research 512-515 (May 2012): 1716–25. http://dx.doi.org/10.4028/www.scientific.net/amr.512-515.1716.

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Currently, there are many unresolved issues to produce high quality phenolic molding compounds (PMC), which are widely used in many industry sectors. In this paper, we design a new approach to resolve some issues, and produce high quality PMC from phenolic resins, fillers, curing agents, and modified fiberglass by silane coupling agents. The preparation processes and the mechanical properties of the newly prepared PMC are studied extensively, and typical composite properties are: volume resistivity of 2.4×1013Ω.cm, surface resistivity of 3.9×1013Ω.cm, impact strength of 2.65KJ/m2, bending strength of 95.9MPa, electric strength of 12.28mv, heat deflection temperature of 240°C, fluidity of 0.26mm, electric strength of 12.28mv, specific gravity of 1.661g/mL. Compared with currently used approaches, our approach can produce PMC with better overall performance and lower costs. This paper has two contributions, one is to propose and test a new approach for producing high quality PMC, and another is that we made a high quality PMC material with low costs.
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Chaiwan, Pattarakamon, and Jantrawan Pumchusak. "The Synergistic Effects of Multi-Filler Addition on the Mechanical and Thermo-Mechanical Properties of Phenolic Resins." Materials Science Forum 940 (December 2018): 23–27. http://dx.doi.org/10.4028/www.scientific.net/msf.940.23.

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The effects of the carbon fiber (CF), carbon black (CB) and nanosilica (SiO2) on the mechanical properties of the phenolic resin (PF) were studied and the optimum composition was selected for the preparation of quaternary composites (CF/CB/SiO2 phenolic composites). The incorporation of poly (acrylonitrile-co-butadiene) rubber (NBR) to strengthen the quaternary composites were also studied. The morphological, mechanical and thermo-mechanical properties of unmodified and NBR modified-quaternary phenolic composites were investigated. The phenolic compounds were mixed by ball milling and the phenolic composites were fabricated by hot compression molding. Scanning electron microscopy images of NBR modified-quaternary phenolic composites show the high fracture surface roughness. The results show that the addition of 5 wt% NBR in the quaternary composites offer the highest tensile strength and Young’s modulus which are significantly improved by 176% and 235%, respectively, and they also offer the high flexural strength, impact strength and flexural modulus which are improved by 79%, 29% and 12%, respectively, compared to neat PF. The glass transition temperature (Tg) of unmodified and NBR modified-quaternary phenolic composites are higher than that of neat PF (107.3 °C). The increase of NBR content does not deteriorate Tg of the quaternary phenolic composites. This study provides a new pathway for making advanced phenolic composites.
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Caro, A. S., F. Bernardeau, D. Perrin, R. Leger, J. C. Benezet, and P. Ienny. "Computational modelling of void growth in Phenolic Molding Compounds filled PolyPropylene from optical measurements." Polymer Testing 71 (October 2018): 209–16. http://dx.doi.org/10.1016/j.polymertesting.2018.09.008.

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Dissertations / Theses on the topic "Phenolic molding compound"

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Englich, Sascha. "Strukturbildung bei der Verarbeitung von glasfasergefüllten Phenolformaldehydharzformmassen." Doctoral thesis, Universitätsbibliothek Chemnitz, 2015. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-176155.

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Werkstoffe auf Basis duroplastischer Harze besitzen exzellente Gebrauchseigenschaften für viele Bereiche des industriellen Einsatzes. Vor allem durch die Spritzgießverarbeitung rieselfähiger duroplastischer Formmassen entsteht ein hohes Substitutionspotential gegenüber Bauteilen aus Metallen oder Hochleistungsthermoplasten. Jedoch führen bestehende Erkenntnisdefizite im Prozessverständnis zu Ressentiments hinsichtlich des Einsatzes duroplastischer Werkstoffe. Ziel der Untersuchungen dieser Arbeit war die Ermittlung und Analyse der prozessinduzierten Werkstoffstruktur von spritzgegossenen technischen Phenolharzformteilen. Dabei wurden zum einen das Füllen der Werkzeugkavität und die sich ausbildende Faserorientierung untersucht und zum anderen die sich während des Temperns verändernde chemische Struktur. Anhand von Platten- sowie Zugprüfkörpern wurden sowohl beim Spritzgießen als auch beim Tempern Parametervariationen durchgeführt und die jeweils resultierende Werkstoffstruktur sowie deren Einfluss auf die Formteileigenschaften analysiert. Die Ergebnisse zeigen, dass die Strömungsverhältnisse während der Werkzeugfüllung stark von den Prozessparametern und der Werkstoffzusammensetzung abhängig sind. Dadurch wird auch die Faserorientierung beeinflusst, sodass im Formteil lokal und richtungsabhängig stark unterschiedliche Eigenschaften entstehen können. Darüber hinaus konnte anhand einer alternativen Tempermethode geklärt werden, warum es beim Tempern zu einem Abfall der mechanischen Eigenschaften kommt und eine Möglichkeit zur Vermeidung gegeben werden
Because of their excellent properties, thermosets can be applied in a bright range of industrial applications. Especially thermoset molding compounds can be processed highly effective by injection molding, which enables them to substitute metals or high performance thermoplastics. But there is a deficit in process understanding, which limits the industrial application. The objective of this work is the investigation and analysis of the process induced material structure of injection molded technical phenolic components. Therefor the filling of the cavity with the resulting fiber orientation and the chemical processes during post-curing were examined. A parameter variation with injection molded plate and tensile specimens were done and the resulting material structure and the effect on the component properties were analyzed. The results show a big influence of the process parameter and the material on the flow condition during the filling of the cavity. Thereby also the fiber orientation is affected. This leads to process-depending local and direction-depending properties. In addition, this work shows an alternative method for post-curing to avoid the decrease of mechanical properties
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Scheffler, Thomas, Sascha Englich, and Michael Gehde. "Specific mold filling characteristics of highly filled phenolic injection molding compounds." Universitätsbibliothek Chemnitz, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-198644.

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Thermosets show excellent mechanical properties and chemical resistance (for most automotive fluids) even at high temperatures up to 300 °C. Furthermore they can be highly efficient processed by injection molding. So they should be particularly suited for e.g. under the bonnet applications. However, the reality shows that thermosets are, except fiber reinforced composites, heavily underrepresented in technical applications. E.g. thermosetting components only account 0,2 % to a vehicle’s weight. Therefore reasons can be found in limited knowledge, e.g. relating mold filling behavior. The objective of the study is to analyze the influence of the mold filling behavior during injection molding of highly filled phenolic compounds on mechanical properties. Injection molding filling studies, mechanical testing and optical microscopy were done while varying mold geometry (injection gate and cavity height), mold temperature and injection rate during injection molding a highly filled phenolic compound. It was found that the mold filling behavior varies with altered injection molding parameters as well as the mold geometry. In consequence of this the mechanical properties change according to the resulting reinforcement orientation. The results can help to improve part and mold design for optimal load transmission.
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Scheffler, Thomas, Sascha Englich, and Michael Gehde. "Specific mold filling characteristics of highly filled phenolic injection molding compounds." Technische Universität Chemnitz, 2013. https://monarch.qucosa.de/id/qucosa%3A20416.

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Thermosets show excellent mechanical properties and chemical resistance (for most automotive fluids) even at high temperatures up to 300 °C. Furthermore they can be highly efficient processed by injection molding. So they should be particularly suited for e.g. under the bonnet applications. However, the reality shows that thermosets are, except fiber reinforced composites, heavily underrepresented in technical applications. E.g. thermosetting components only account 0,2 % to a vehicle’s weight. Therefore reasons can be found in limited knowledge, e.g. relating mold filling behavior. The objective of the study is to analyze the influence of the mold filling behavior during injection molding of highly filled phenolic compounds on mechanical properties. Injection molding filling studies, mechanical testing and optical microscopy were done while varying mold geometry (injection gate and cavity height), mold temperature and injection rate during injection molding a highly filled phenolic compound. It was found that the mold filling behavior varies with altered injection molding parameters as well as the mold geometry. In consequence of this the mechanical properties change according to the resulting reinforcement orientation. The results can help to improve part and mold design for optimal load transmission.
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Maenz, Torsten. "Spritzgießtechnische Herstellung duroplastgebundener Dauermagnete." Universitätsverlag der Technischen Universität Chemnitz, 2017. https://monarch.qucosa.de/id/qucosa%3A23550.

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Kunststoffgebundene Dauermagnete kommen bereits seit einem dreiviertel Jahrhundert in diversen Anwendungen zum Einsatz. Dabei werden die gängigen Kunststoffverarbeitungsverfahren wie beispielsweise Spritzgießen, Extrudieren, Pressen und Kalandrieren angewandt. Ähnlich zu der Aufteilung in der Verarbeitung von herkömmlichen Kunststoffen, werden auch für die kunststoffgebundenen Dauermagnete nur selten duroplastische Matrixmaterialien im Spritzgießverfahren eingesetzt. Dabei bringt gerade diese Werkstoffklasse hervorragende Eigenschaften mit sich, die eine Verbesserung der Eigenschaften von kunststoffgebundenen Dauermagneten zur Folge haben können. Neben der Medien- und Temperaturbeständigkeit dieser Werkstoffklasse spielt dabei auch deren Viskosität eine bedeutende Rolle für diese Anwendung. Im Rahmen der vorliegenden Arbeit soll geprüft werden, ob der Einsatz duroplastischer Matrixmaterialien zu einer Verbesserung der Eigenschaften kunststoffgebundener Dauermagnete führen kann. Hierfür werden anisotrope Magnetpartikel in den Kunststoff eincompoundiert und während der Verarbeitung im Spritzgießverfahren orientiert. Dies geschieht durch ein integriertes Magnetfeld im Spritzgießwerkzeug. Insbesondere sollen der Einfluss des Matrixmaterials, der Partikelgeometrie, der Fließrichtung sowie des Richtfeldes auf die Partikelorientierung untersucht werden. Zusammen mit grundlegenden analytischen Untersuchungen der Ausgangsmaterialien sollen abschließend Richtlinien für eine Bauteilauslegung definiert und erste Ansätze für eine Simulation der magnetischen Bauteileigenschaften erarbeitet werden.
Polymer bonded magnets are used for different applications for over 70 years yet. These materials are produced within known polymer processing procedures as injection molding, extruding, compression molding and calendaring. However, as for standard plastics thermoset materials are seldom used in injection molding even though they show great potential regarding temperature and media resistance as well as in terms of a low viscosity. These properties could be of use in case of polymer bonded magnets. Within this work the use of thermoset matrix materials for polymer bonded magnets should be evaluated and thus their properties shall be improved. Therefore anistotropic magnetic particles will be incorporated in the thermoset matrix and they will be oriented during the injection molding process which requires a magnetic field in the cavity during processing. Especially the influences of the matrix material, the particle geometry, the flow direction and the aligning field on the particle orientation should be investigated and together with fundamental analytical procedures guidelines for engineering of parts should be generated as well as first approaches for a simulation of the part properties shall be given.
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Scheffler, Thomas. "Werkstoffeinflüsse auf den Spritzgussprozess von hochgefüllten Phenol-Formaldehydharz­-Formmassen." Universitätsverlag Chemnitz, 2018. https://monarch.qucosa.de/id/qucosa%3A32200.

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Im Rahmen der vorliegenden Arbeit wurden verschiedene duroplastische Formmassen laboranalytisch hinsichtlich der rheologischen und thermischen Eigenschaften untersucht. Es wurde u.a. gezielt die absolute Materialfeuchte gesteigert, um den Einfluss dieser auf das Fließ­ Härtungsverhalten zu charakterisieren. Anschließend wurden die Materialien auf einer hochinstrumentierten Spritzgussmaschine mit einem Fließspiralenwerkzeug untersucht. Dabei konnte ein direkter Zusammenhang zwischen dem Rückfluss und dem Plastifizierdrehmoment in Abhängigkeit der Materialfeuchte und der Prozessparameter detektiert werden . Des Weiteren wurden über die Differenzdruckmessung im Fließspiralenwerkzeug die scheinbaren Viskositäten über den Fließweg ermittelt. Hierbei konnten unterschiedliche Aufschmelzeffekte über die Fließweglänge in Abhängigke it der duroplastischen Formmasse, der absoluten Materialfeuchte und der Prozessparameter detektiert werden . Durch Schererwärmung konnte die Formmassentemperatur teilweise die Werkzeugtemperatur übersteigen. Hinsichtlich der mechanischen Eigenschaften (Schlagzähigkeit, Biegefestigkeit) konnten keine signifikanten Einflussgrößen detektiert werden. Hinsichtlich des Tg konnten systematischen Unterschiede detektiert und begründet werden. Die beste Möglichkeit zur Ermittlung des Tg lieferte die TMA. Die thermischen Glasübergänge korrelieren mit den in der DSC ermittelten Aushärtegraden , wobei mit steigender Materialfeuchte ein geringer Aushärtegrad detektiert wird.
Within this paper, the rheologieal and thermie eharaeteristies of different thermosetting molding eompounds were investigated using lab analysis methods. Among others, the absolute moisture eontent was inereased purposefully to investigate its influenee on the flow-euring behavior. Subsequently, the materials were analyzed using a highly instrumented injeetion-molding maehine and a flow spiral tool. A direet link between the baekflow and the plastifieation torque dependent on the moisture eontent and proeess parameters was deteeted . Furthermore, a measurement of the differential pressure was eondueted within the flow spiral to deteet the apparent viseosity over the flow path. Within this proeess, different melting effeets over the flow eurve length depending on the molding eompound, the absolute moisture eontent and proeess parameters were deteeted. The shear heating lead to a material temperature inerease of the molding eompound, whieh was partly higher than the tool temperature . Coneerning the meehanieal eharaeteristies (impaet strength, flexural strength), no signifieant influeneing faetors eould be deteeted. In eontrast, systematie differenees of the glass transition temperature were deteeted and their eause eould be explained. The best way to determine the glass transition is the TMA. The glass transition temperatures eorrelate with the degree of eure determined with the DSC, whereas an inereasing moisture eontent is assoeiated with a lower degree of eure.
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Bernardeau, Fabien. "Stratégies et scénarii de valorisation de déchets phénoplastes au sein de matrices thermoplastiques." Thesis, Montpellier, 2017. http://www.theses.fr/2017MONTS033/document.

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Cette thèse, réalisée en partenariat avec deux industriels, a pour objectif de mettre au point une voie de valorisation matière des résines phénoplastes (bakélite) issues de gisement de déchets plastiques. En effet, ce type de résine (thermodurcissable) n’est pour l’instant pas valorisé en fin de vie et finit en enfouissement. Pour répondre aux attentes législatives (directive DEEE, mais aussi VHU dans l’automobile), qui imposent un quota de recyclage (réutilisation et valorisation matière) et de valorisation énergétique minimum pour les déchets en fin de vie, il parait important de développer des procédés de régénération de ces plastiques ainsi que de trouver des domaines d’application pour leur utilisation en tant que matière première secondaire.Enedis, dans le cadre du déploiement de ces nouveaux compteurs électriques, collecte les anciens compteurs et équipements installés et cherche une solution de recyclage adaptée. Une partie de ce gisement important de déchets est constituée de plastiques de tous types en mélange, et en particulier de bakélite. Le travail de cette thèse s’est concentré sur le traitement et la régénération de ce gisement.Dans un premier temps, un schéma de démantèlement et de tri de ce gisement varié a été mis en place. Il est basé sur une étude des matières présentes dans le gisement, en particulier plastiques. La présence d’additifs est également évaluée, en particulier celle de substances contrôlées comme les retardateurs de flamme halogénés, le cadmium, etc. L’objectif était d’optimiser le procédé de séparation des matières en vue d’obtenir des gisements de matières régénérées de pureté suffisante pour le réemploi, tout en limitant la présence d’additifs contrôlés pour respecter les concentrations maximales légales.Pour valoriser les résines phénoplastes issues de ce gisement, la voie envisagée consiste à réutiliser cette matière sous forme de charges incorporées au sein de matrices thermoplastiques (éventuellement régénérées). Pour ce faire, une étude de la transformation de la bakélite par broyage pour obtenir un produit de granulométrie très fine (micronisation) a été réalisée. La distribution granulométrique, la morphologie et son état physico-chimique de surface ont été évaluées en fonction des paramètres du procédé. Après incorporation à différents taux de charge dans des matrices thermoplastiques, les propriétés mécaniques en quasi-statique et dynamique des composites ont été évaluées. La fonctionnalisation des charges/matrices et l’incorporation d’agents compatibilisants ont permis d’améliorer la cohésion des interfaces. Une modélisation par homogénéisation a été réalisée pour rendre compte de l’influence des différentes variables sur la tenue mécanique des composites.Le comportement au feu des composites formulés a également été étudié. Du fait de la stabilité thermique élevée de la bakélite et du taux de char important formé lors de sa combustion, il est envisagé d’utiliser les charges phénoplastes comme donneur de carbone dans la formulation d’un système retardateur de flamme intumescent. Des additifs appropriés, comme une source d’acide et un agent gonflant, seront évalués pour la formulation du système
The main goal of this PhD project, born from a partnership between EMA, APR2 and Enedis, was to develop a material recycling solution for phenolic molding compound (PMC, or Bakelite). Indeed, these types of thermoset material are hardly valorized and end up in landfill, mostly because of the lack of technically and economically viable solutions for recycling.Phenolic molding compound material are present in large amount in End of Life (EOL) electrical meter waste stream. Therefore, Enedis committed to find a valorisation scheme for these materials. This PhD work is aimed to develop a recycling process for PMC issued from this waste stream.Firstly, a dismantlement and sorting scheme was designed. It is based on the study of the waste stream material composition – in particular the plastic stream. The presence of regulated substances (such as halogenated flame retardant, etc.) in plastic formulations was assessed. The objective was to optimize the separation process to recover materials with a high degree of purity.The proposed recycling solution consists in using the PMC as a functional filler in a thermoplastic matrix. To do so, a comminution scheme was developed to reduce the size of the PMC part. The particle size distribution, morphology and surface chemistry of the obtained products were characterized. Quasi-static and dynamic mechanical properties of composite materials incorporating micronized PMC were determined. Various coupling schemes were studied in order to increase the adhesion between filler and matrix. The mechanical behaviour of the composite materials was also modelized using finite element methods.The fire behaviour of the composite material incorporating PMC filler was also studied. Because of the high thermal stability and high char yield of phenolic molding compound, its potential use as a carbon donor in intumescent flame retardant formulations was finally assessed
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Methe, Daniel. "Manufacturing of Mechanical Supporting Foamed Sheets by Processing Free Flowing Phenolic Molding Compounds via Foam Extrusion." 2019. https://monarch.qucosa.de/id/qucosa%3A36666.

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Book chapters on the topic "Phenolic molding compound"

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Knop, Andre, and Louis A. Pilato. "Molding Compounds." In Phenolic Resins, 196–212. Berlin, Heidelberg: Springer Berlin Heidelberg, 1985. http://dx.doi.org/10.1007/978-3-662-02429-4_12.

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Koizumi, Koji, Ted Charles, and Hendrik De Keyser. "Phenolic Molding Compounds." In Phenolic Resins: A Century of Progress, 383–437. Berlin, Heidelberg: Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-04714-5_16.

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Conference papers on the topic "Phenolic molding compound"

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Scheffler, Thomas, Michael Gehde, Michael Späth, and Peter Karlinger. "Determination of the flow and curing behavior of highly filled phenolic injection molding compounds by means of spiral mold." In PROCEEDINGS OF THE EUROPE/AFRICA CONFERENCE DRESDEN 2017 – POLYMER PROCESSING SOCIETY PPS. Author(s), 2019. http://dx.doi.org/10.1063/1.5084897.

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