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Journal articles on the topic 'Phenoxyl-radicals'

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1

Manderville, Richard A. "Ambident reactivity of phenoxyl radicals in DNA adduction." Canadian Journal of Chemistry 83, no. 9 (2005): 1261–67. http://dx.doi.org/10.1139/v05-121.

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Phenols are a class of compounds that can create beneficial effects in vivo owing to their antioxidant properties (through radical scavenging), or they can display hazardous effects owing to their pro-oxidant properties. The mechanism by which phenols act as pro-oxidants stems from their one-electron oxidation into reactive phenoxyl radicals by peroxidase enzymes or redox-active transition metals. In the presence of thiols and molecular oxygen, these reactive phenoxyl radicals stimulate an oxidative stress and cause oxidative damage to biomolecules, which is proposed to contribute to the occur
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2

Shukla, D., N. P. Schepp, N. Mathivanan, and L. J. Johnston. "Generation and spectroscopic and kinetic characterization of methoxy-substituted phenoxyl radicals in solution and on paper." Canadian Journal of Chemistry 75, no. 12 (1997): 1820–29. http://dx.doi.org/10.1139/v97-615.

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A number of methoxy-substituted phenoxyl radicals have been generated and characterized by laser flash photolysis techniques in solution and on paper. The radicals have been produced by three routes in solution: hydrogen abstraction from phenols by tert-butoxyl radical, photolysis of α-aryloxyacetophenones, and direct excitation of phenols. Most of the phenoxyl radicals studied have a characteristic absorption near 400 nm; the ortho-substituted radicals have an additional broad absorption in the visible in non-hydroxylic solvents (e.g., 650 nm for 2-methoxyphenoxyl radical). The relative inten
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3

Aotake, Tatsuya, Mitsuharu Suzuki, Naoki Aratani, et al. "Correction: 9,9′-Anthryl-anthroxyl radicals: strategic stabilization of highly reactive phenoxyl radicals." Chemical Communications 51, no. 24 (2015): 5124. http://dx.doi.org/10.1039/c5cc90112j.

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4

de Jonge, Cornelis R. H. I. "Reactions with Stable Phenoxyl Radicals." Liebigs Annalen der Chemie 1986, no. 2 (1986): 299–304. http://dx.doi.org/10.1002/jlac.198619860210.

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5

Teng, Zhuochao, Xianwei Zhao, Hetong Wang, et al. "Mechanism and kinetic properties for the complete series reactions of chloro(thio)phenols with O(3P) under high temperature conditions." RSC Advances 11, no. 29 (2021): 17683–93. http://dx.doi.org/10.1039/d1ra02407h.

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Under pyrolysis or combustion conditions, chlorophenols (CPs) and chlorothiophenols (CTPs) can readily form chlorophenoxy radicals (CPRs) and chlorotriophenoxy radicals (CTPRs) by abandoning the phenoxyl-H and sulfydryl-H, respectively.
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6

Wojnárovits, L., A. Kovács, and G. Földiák. "Spectral characteristics of monosubstituted phenoxyl radicals." Radiation Physics and Chemistry 50, no. 4 (1997): 377–79. http://dx.doi.org/10.1016/s0969-806x(97)00053-4.

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7

Thomas, Fabrice. "ChemInform Abstract: Metal-Coordinated Phenoxyl Radicals." ChemInform 42, no. 41 (2011): no. http://dx.doi.org/10.1002/chin.201141217.

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8

Dol, Cyrielle, Guillaume Gerbaud, Bruno Guigliarelli, Emily Bloch, Stéphane Gastaldi, and Eric Besson. "Modulating lifetimes and relaxation times of phenoxyl radicals through their incorporation into different hybrid nanostructures." Physical Chemistry Chemical Physics 21, no. 29 (2019): 16337–44. http://dx.doi.org/10.1039/c9cp03052b.

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9

Kasumov, Veli T., Bünyamin Karabulut, Ibrahim Kartal, and Fevzi Köksal. "Synthesis And Spectroscopic Studies Of New Bis(N-1-hydroxy-2,6-Di-Fe/Tf-Butylphenyl- Salicylideneaminato)Cobalt(Ii) Complexes And Their Oxidation With PbO2." Zeitschrift für Naturforschung B 56, no. 8 (2001): 778–86. http://dx.doi.org/10.1515/znb-2001-0811.

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A series of new bis[N-(1-OH-2,6-di-tert-butylphenyl)salicylaldiminato]cobalt(II) complexes possessing one or two HO- and CH3O - substituents on the salicylaldehyde moiety were prepared, and their spectroscopic properties as well as their oxidation with PbO2 were examined. ESR data indicate that oxidation of the complexes produces stable phenoxyl radicals. All phenoxyl radicals have similar g-values and hyperfine coupling constants, which are influenced very little by the substituents and by coordination. The experimental observations indicate that the Co(L·x)2 radicals are ligand-localized and
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10

Molloy, J. K., O. Jarjayes, C. Philouze, L. Fedele, D. Imbert, and F. Thomas. "A redox active switch for lanthanide luminescence in phenolate complexes." Chemical Communications 53, no. 3 (2017): 605–8. http://dx.doi.org/10.1039/c6cc07942c.

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11

d’Alessandro, Nicola, Giorgio Bianchi, Xingwang Fang, Famin Jin, Heinz-Peter Schuchmann, and Clemens von Sonntag. "Reaction of superoxide with phenoxyl-type radicals." Journal of the Chemical Society, Perkin Transactions 2, no. 9 (2000): 1862–67. http://dx.doi.org/10.1039/b003346o.

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12

Foti, M., K. U. Ingold, and J. Lusztyk. "The Surprisingly High Reactivity of Phenoxyl Radicals." Journal of the American Chemical Society 116, no. 21 (1994): 9440–47. http://dx.doi.org/10.1021/ja00100a005.

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13

Ye, Mingyu, and Robert H. Schuler. "Second-order combination reactions of phenoxyl radicals." Journal of Physical Chemistry 93, no. 5 (1989): 1898–902. http://dx.doi.org/10.1021/j100342a040.

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14

Jonsson, M., J. Lind, T. Reitberger, T. E. Eriksen, and G. Merenyi. "Free radical combination reactions involving phenoxyl radicals." Journal of Physical Chemistry 97, no. 31 (1993): 8229–33. http://dx.doi.org/10.1021/j100133a018.

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15

Bolton, J. "Quinoids, quinoid radicals, and phenoxyl radicals formed from estrogens and antiestrogens." Toxicology 177, no. 1 (2002): 55–65. http://dx.doi.org/10.1016/s0300-483x(02)00195-6.

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16

Aotake, Tatsuya, Mitsuharu Suzuki, Naoki Aratani, et al. "9,9′-Anthryl-anthroxyl radicals: strategic stabilization of highly reactive phenoxyl radicals." Chemical Communications 51, no. 31 (2015): 6734–37. http://dx.doi.org/10.1039/c4cc10104a.

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17

Tomilin, O. B., O. V. Boyarkina, and B. S. Tanaseichuk. "One-Electron Transfer during Dimerization of Phenoxyl Radicals." Russian Journal of Organic Chemistry 58, no. 5 (2022): 637–47. http://dx.doi.org/10.1134/s1070428022050013.

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18

Nishide, Hiroyuki, Makoto Miyasaka, Ryuji Doi, and Takashi Araki. "Poly(1,2-phenylenevinylene) Ferromagnetically 3,5-Bearing Phenoxyl Radicals." Macromolecules 35, no. 3 (2002): 690–98. http://dx.doi.org/10.1021/ma011209f.

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19

Xie, Chunping, and Paul M. Lahti. "Highly stabilized phenoxyl radicals with hydrogen-bonding capability." Tetrahedron Letters 40, no. 23 (1999): 4305–8. http://dx.doi.org/10.1016/s0040-4039(99)00784-4.

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20

Sakihama, Yasuko, Jun'ichi Mano, Satoshi Sano, Kozi Asada, and Hideo Yamasaki. "Reduction of Phenoxyl Radicals Mediated by Monodehydroascorbate Reductase." Biochemical and Biophysical Research Communications 279, no. 3 (2000): 949–54. http://dx.doi.org/10.1006/bbrc.2000.4053.

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21

Forni, L. G., and R. L. Willson. "Thiyl and phenoxyl free radicals and NADH Direct observation of one-electron oxidation." Biochemical Journal 240, no. 3 (1986): 897–903. http://dx.doi.org/10.1042/bj2400897.

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Absolute rate constants for the reaction of NADH with thiyl free radicals derived from various sulphur-containing compounds of biological significance were measured by using the technique of pulse radiolysis. These and related reactions with phenoxyl free radicals are believed to occur through one-electron-transfer processes. Further evidence comes from studies with deuterated NADH. The results support the possibility that, in biochemical systems, thiols may act as catalysts linking hydrogen-atom and electron-transfer reactions.
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22

Adounkpe, Julien, Martin Aina, Daouda Mama, and Brice Sinsin. "Gas Chromatography Mass Spectrometry Identification of Labile Radicals Formed during Pyrolysis of Catechool, Hydroquinone, and Phenol through Neutral Pyrolysis Product Mass Analysis." ISRN Environmental Chemistry 2013 (December 29, 2013): 1–8. http://dx.doi.org/10.1155/2013/930573.

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Catechol, hydroquinone, and phenol are known to be environmental pollutants due to their ability to generate environmentally free radicals, which cause millions of deaths worldwide. Recently, efforts have been done to precisely identify the origin and the nature of those free radicals employing EPR-LTMI technique. All the three precursors generate cyclopentadienyl radical as major pyrolysis products and phenoxyl radical as both pyrolysis and photolysis products which were obtained from phenol; ortho-semiquinone and para-semiquinone were seen, respectively, from the pyrolysis of catechol and hy
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23

Bordwell, Frederick G., and Jinpei Cheng. "Substituent effects on the stabilities of phenoxyl radicals and the acidities of phenoxyl radical cations." Journal of the American Chemical Society 113, no. 5 (1991): 1736–43. http://dx.doi.org/10.1021/ja00005a042.

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24

Lahti, Paul M., Burak Esat, Jacqueline R. Ferrer, et al. "Polymeric, H-Bonded, and Chelatable Phenoxyl and Nitroxide Radicals." Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 334, no. 1 (1999): 285–94. http://dx.doi.org/10.1080/10587259908023326.

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25

Xu, Jing, Xinguo Wu, Wei Yan, Ruxiu Cai, and Zhixin Lin. "A new kinetic method for quantification phenoxyl free radicals." Talanta 70, no. 2 (2006): 323–29. http://dx.doi.org/10.1016/j.talanta.2006.02.055.

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26

Neta, Pedatsur, and Jan Grodkowski. "Rate Constants for Reactions of Phenoxyl Radicals in Solution." Journal of Physical and Chemical Reference Data 34, no. 1 (2005): 109–99. http://dx.doi.org/10.1063/1.1797812.

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27

Xie, Chunping, Paul M. Lahti, and Clifford George. "Modulating Spin Delocalization in Phenoxyl Radicals Conjugated with Heterocycles." Organic Letters 2, no. 22 (2000): 3417–20. http://dx.doi.org/10.1021/ol0063407.

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28

Chekalov, A. K., A. I. Prokof'ev, N. N. Bubnov, S. P. Solodovnikov, and M. I. Kabachnik. "EPR spectra of some substituted 2-(?-hydroxyethoxy)phenoxyl radicals." Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 36, no. 6 (1987): 1155–59. http://dx.doi.org/10.1007/bf00956652.

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29

Grampp, Günter, Stephan Landgraf, and Claudia Mureşanu. "Redox properties and bond dissociations energies of phenoxyl radicals." Electrochimica Acta 49, no. 4 (2004): 537–44. http://dx.doi.org/10.1016/j.electacta.2003.09.007.

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30

Folkes, Lisa K., Madia Trujillo, Silvina Bartesaghi, Rafael Radi, and Peter Wardman. "Kinetics of reduction of tyrosine phenoxyl radicals by glutathione." Archives of Biochemistry and Biophysics 506, no. 2 (2011): 242–49. http://dx.doi.org/10.1016/j.abb.2010.12.006.

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31

JONSSON, M., J. LIND, T. REITBERGER, T. E. ERIKSEN, and G. MERENYI. "ChemInform Abstract: Free Radical Combination Reactions Involving Phenoxyl Radicals." ChemInform 24, no. 47 (2010): no. http://dx.doi.org/10.1002/chin.199347094.

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32

Wanke, Riccardo, Laurent Benisvy, Maxim L. Kuznetsov, M. Fátima C. Guedes da Silva, and Armando J. L. Pombeiro. "Persistent Hydrogen-Bonded and Non-Hydrogen-Bonded Phenoxyl Radicals." Chemistry - A European Journal 17, no. 42 (2011): 11882–92. http://dx.doi.org/10.1002/chem.201101509.

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33

Johnston, Linda J., N. Mathivanan, Fabrizia Negri, Willem Siebrand, and Francesco Zerbetto. "Assignment and vibrational analysis of the 600 nm absorption band in the phenoxyl radical and some of its derivatives." Canadian Journal of Chemistry 71, no. 10 (1993): 1655–62. http://dx.doi.org/10.1139/v93-206.

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An experimental and theoretical study is reported of the 600 nm band system of phenoxyl and several methoxy substituted phenoxyls. These radicals, generated in freon, show a diffuse band in this region with a vibrational structure that is incompletely resolved but consistent with the 500 cm−1 "progression" observed earlier for phenoxyl in the vapour and in a rigid matrix. The low intensity of this band is considerably enhanced by ortho-methoxy substitution. To establish its assignment and analyze its structure, semi-empirical and ab initio quantum chemical calculations have been performed. It
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34

BORDWELL, F. G., and J. P. CHENG. "ChemInform Abstract: Substituent Effects on the Stabilities of Phenoxyl Radicals and the Acidities of Phenoxyl Radical Cations." ChemInform 22, no. 25 (2010): no. http://dx.doi.org/10.1002/chin.199125068.

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35

WINTERBOURN, Christine C., Helena N. PARSONS-MAIR, Silvia GEBICKI, Janusz M. GEBICKI, and Michael J. DAVIES. "Requirements for superoxide-dependent tyrosine hydroperoxide formation in peptides." Biochemical Journal 381, no. 1 (2004): 241–48. http://dx.doi.org/10.1042/bj20040259.

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Superoxide reacts rapidly with other radicals, but these reactions have received little attention in the context of oxidative stress. For tyrosyl radicals, reaction with superoxide is 3-fold faster than dimerization, and forms the addition product tyrosine hydroperoxide. We have explored structural requirements for hydroperoxide formation using tyrosine analogues and di- and tri-peptides. Superoxide and phenoxyl radicals were generated using xanthine oxidase, peroxidase and the respective tyrosine derivative, or by γ-radiation. Peroxides were measured using FeSO4/Xylenol Orange. Tyrosine and t
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36

Porkhun, V. I., Yu V. Aristova, and E. V. Porkhun. "Quantum chemical study of the rearrangement of phenoxyl-hydroxyphenyl radicals." Russian Journal of Physical Chemistry A 91, no. 3 (2017): 472–75. http://dx.doi.org/10.1134/s0036024417030220.

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37

Amorati, Riccardo, and Gian Franco Pedulli. "Hydrogen bond donating ability of meta and parahydroxy phenoxyl radicals." Org. Biomol. Chem. 10, no. 4 (2012): 814–18. http://dx.doi.org/10.1039/c1ob06502e.

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38

Iida, Toshiyuki, Joji Ohshita, Nobuaki Ohta та ін. "Spin–spin interaction between phenoxyl radicals through σ–π system". Journal of Organometallic Chemistry 688, № 1-2 (2003): 192–99. http://dx.doi.org/10.1016/j.jorganchem.2003.09.004.

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39

Tripathi, G. N. R. "Proton Reactivity and Electronic Structure of Phenoxyl Radicals in Water†." Journal of Physical Chemistry A 102, no. 13 (1998): 2388–97. http://dx.doi.org/10.1021/jp9808633.

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40

Janzen, Edward G., Allan L. Wilcox, and Vinothane Manoharan. "Reactions of nitric oxide with phenolic antioxidants and phenoxyl radicals." Journal of Organic Chemistry 58, no. 14 (1993): 3597–99. http://dx.doi.org/10.1021/jo00066a001.

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41

Philibert, Aurélie, Fabrice Thomas, Christian Philouze, Sylvain Hamman, Eric Saint-Aman, and Jean-Louis Pierre. "Galactose Oxidase Models: Tuning the Properties of CuII–Phenoxyl Radicals." Chemistry - A European Journal 9, no. 16 (2003): 3803–12. http://dx.doi.org/10.1002/chem.200304880.

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42

Kuznetsova, N. A., A. Y. Krupnova, A. O. Sergeev, and V. I. Porkhun. "KINETICS OF THE REACTION OF PHENOXYL RADICALS WITH METAL IONS." Izvestia Volgograd State Technical University, no. 12 (2022): 73–77. http://dx.doi.org/10.35211/1990-5297-2022-12-271-73-77.

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43

Coronel, Marta E. J., and Agustin J. Colussi. "Entropic and enthalpic effects of 4-methoxy substitution in phenoxyl radicals." Journal of the Chemical Society, Perkin Transactions 2, no. 4 (1994): 785. http://dx.doi.org/10.1039/p29940000785.

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44

O'Malley, Patrick J. "Hybrid Density Functional Studies of Phenoxyl Free Radicals Modeling α-Tocopheroxyl". Journal of Physical Chemistry B 106, № 47 (2002): 12331–35. http://dx.doi.org/10.1021/jp025754+.

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45

Denisova, T. G., and E. T. Denisov. "The reactivity of phenoxyl radicals of bioantioxidants in the abstraction reactions." Russian Chemical Bulletin 58, no. 8 (2009): 1609–15. http://dx.doi.org/10.1007/s11172-009-0221-1.

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46

Sadykov, R. A., G. D. Safina, I. Yu Chukicheva, R. R. Kinzyabulatov, and A. V. Kuchin. "ESR spectra of phenoxyl radicals derived from 2,6-diisobornyl-4-methylphenol." Russian Chemical Bulletin 61, no. 8 (2012): 1667–68. http://dx.doi.org/10.1007/s11172-012-0229-9.

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47

Stolze, Klaus, and Hans Nohl. "Formation of Methemoglobin and Phenoxyl Radicals from P-Hydroxyanisole and Oxyhemoglobin." Free Radical Research Communications 11, no. 6 (1991): 321–28. http://dx.doi.org/10.3109/10715769109088930.

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48

Allard, Marco M., Jason A. Sonk, Mary Jane Heeg, Bruce R. McGarvey, H. Bernhard Schlegel, and Cláudio N. Verani. "Bioinspired Five-Coordinate Iron(III) Complexes for Stabilization of Phenoxyl Radicals." Angewandte Chemie International Edition 51, no. 13 (2011): 3178–82. http://dx.doi.org/10.1002/anie.201103233.

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49

Lahti, Paul M., Burak Esat, Jacqueline R. Ferrer, et al. "ChemInform Abstract: Polymeric, H-Bonded, and Chelatable Phenoxyl and Nitroxide Radicals." ChemInform 31, no. 10 (2010): no. http://dx.doi.org/10.1002/chin.200010270.

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50

Omelka, Ladislav, and Jana Kováčová. "Spin trapping of sterically unhindered phenoxyl radicals with nitrosobenzene and nitrosodurene." Magnetic Resonance in Chemistry 32, no. 9 (1994): 525–31. http://dx.doi.org/10.1002/mrc.1260320905.

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