Academic literature on the topic 'Phenyl thioureas'

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Journal articles on the topic "Phenyl thioureas"

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Ngaini, Zainab, Wan Sharifatun Handayani Wan Zulkiplee, and Ainaa Nadiah Abd Halim. "One-Pot Multicomponent Synthesis of Thiourea Derivatives in Cyclotriphosphazenes Moieties." Journal of Chemistry 2017 (2017): 1–7. http://dx.doi.org/10.1155/2017/1509129.

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In this study, hexasubstituted thiourea was carried out via reaction of isothiocyanato cyclophosphazene intermediates with a series of aromatics amines and amino acids in a one-pot reaction system. The reaction was not as straightforward as typical thiourea synthesis. Six unexpected thiourea derivatives3a–fwere formed in the presence of cyclotriphosphazene moieties in good yields (53–82%). The structures of3a–fwere characterized by elemental analysis and FTIR,1H,13C, and31P NMR spectroscopies. The occurrence of reverse thioureas formation in a one-pot reaction system is discussed. The possible
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Konrad, Nele, Matvey Horetski, Mariliis Sihtmäe, et al. "Thiourea Organocatalysts as Emerging Chiral Pollutants: En Route to Porphyrin-Based (Chir)Optical Sensing." Chemosensors 9, no. 10 (2021): 278. http://dx.doi.org/10.3390/chemosensors9100278.

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Environmental pollution with chiral organic compounds is an emerging problem requiring innovative sensing methods. Amino-functionalized thioureas, such as 2-(dimethylamino)cyclohexyl-(3,5-bis(trifluoromethyl)phenyl)thiourea (Takemoto’s catalyst), are widely used organocatalysts with virtually unknown environmental safety data. Ecotoxicity studies based on the Vibrio fischeri luminescence inhibition test reveal significant toxicity of Takemoto’s catalyst (EC50 = 7.9 mg/L) and its NH2-substituted analog (EC50 = 7.2–7.4 mg/L). The observed toxic effect was pronounced by the influence of the trifl
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Dzurilla, Milan, Peter Kutschy, and Dušan Koščík. "A new method for preparation of 1-(4-substituted phenyl)-6-phenyl-2-thiouracils via cyclization of N-(4-substituted phenyl)-N'-3-phenylpropenoylthioureas and Dimroth rearrangement of 2-(4-substituted phenylimino)-6-phenyl-5,6-dihydro-4H-1,3-thiazin-4-ones." Collection of Czechoslovak Chemical Communications 52, no. 9 (1987): 2260–65. http://dx.doi.org/10.1135/cccc19872260.

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N-(4-Substituted phenyl)-N'-3-phenylpropenoylthioureas treated with lithium hydride afforded 1-(4-substituted phenyl)-6-phenyl-2-thiouracils; these could also be obtained by Dimroth rearrangement of 2-(4-substituted phenylimino)-6-phenyl-5,6-dihydro-4H-1,3-thiazin-4-ones under the same reaction conditions. 2-(4-Substituted phenylimino)-6-phenyl-5,6-dihydro-4H-1,3-thiazin-4-ones were synthesized from the corresponding thioureas under catalysis of boron trifluoride in chloroform.
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V., Madhura, Hrishikesh M. Revankar, and Manohar V. Kulkarni. "A new route for the synthesis of 4-arylacetamido-2-aminothiazoles and their biological evaluation." Zeitschrift für Naturforschung B 70, no. 7 (2015): 483–89. http://dx.doi.org/10.1515/znb-2015-0013.

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AbstractA series of 4-arylacetamido-2-amino- and 2-arylamino-1,3-thiazoles (4a–o) were synthesized in a single step in high yields from ω-bromoacetoacetanilides and thiourea/phenyl thioureas and were characterized by spectral and analytical methods. The compounds were evaluated for their in vitro antibacterial antifungal and antioxidant activities. In vitro antimicrobial evaluation of these compounds indicated their specificity towards Gram-positive species. p-Tolyl and m-chlorophenyl substituents on the arylamino moiety (compounds 4b and 4g) exhibited the lowest minimum inhibitory concentrati
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Janovec, Ladislav, Stanislav Böhm, Ivan Danihel, Ján Imrich, Pavol Kristian, and Karel D. Klika. "Theoretical Confirmation of the Reaction Mechanism Leading to Regioselective Formation of Thiazolidin-4-one from Bromoacetic Acid Derivatives." Collection of Czechoslovak Chemical Communications 72, no. 10 (2007): 1435–45. http://dx.doi.org/10.1135/cccc20071435.

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A regioselective synthesis of 3-alkyl-2-[(anthracen-9-yl)imino]thiazolidin-4-ones 2a-2e and 2-(alkylimino)-3-(anthracen-9-yl)thiazolidin-4-ones 3a-3e from appropriate thioureas using methyl bromoacetate or bromoacetyl bromide, respectively, has been rationalized by DFT calculations of model thiourea and its phenyl derivative. The proposed mechanism indicates that the regioselective formation of the target thiazolidinones is a consequence of a different reactivity of the reagents and a varying stability of the intermediates, 1-alkyl-3-(anthracen-9-yl)-2-[(methoxycarbonyl)methyl]isothioureas 4a-
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Kutschy, Peter, Ján Imrich, Juraj Bernát, Pavol Kristian, Oľga Hritzová, and Thomas Schöffmann. "Photocyclization of N-(3-chloro-2-benzo[b]thienocarbonyl)-N'-monosubstituted thioureas." Collection of Czechoslovak Chemical Communications 51, no. 12 (1986): 2839–47. http://dx.doi.org/10.1135/cccc19862839.

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N-(3-Chloro-2-benzo[b]thienocarbonyl)-N'-monosubstituted thioureas, when irradiated with a high-pressure mercury discharge lamp through a pyrex or quartz filter, give the corresponding benzothienothiazine derivatives in lower yields than the analogous N',N'-disubstituted thioureas. The reactivity lowering of the N'-monosubstituted thioureas is ascribed to the intramolecular hydrogen bond C=O...H-N due to which these compounds in their ground states exist in the six-membered cyclic conformation unfavourable for the cyclization. The photolysis of N'-phenylthiourea results - due to a stronger hyd
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Zhang, Ze, Hao-Hao Wu, and Ya-Jun Tan. "Correction: A simple and straightforward synthesis of phenyl isothiocyanates, symmetrical and unsymmetrical thioureas under ball milling." RSC Advances 11, no. 38 (2021): 23418. http://dx.doi.org/10.1039/d1ra90128a.

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Correction for ‘A simple and straightforward synthesis of phenyl isothiocyanates, symmetrical and unsymmetrical thioureas under ball milling’ by Ze Zhang et al., RSC Adv., 2013, 3, 16940–16944, DOI: 10.1039/C3RA43252A.
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Jurášek, Adolf, Jarmila Štetinová, Jaroslav Kováč, et al. "Reactions of aromatic amines with 5-nitro-3-furoyl and 5-nitro-2-furoyl isothiocyanates." Collection of Czechoslovak Chemical Communications 54, no. 3 (1989): 699–705. http://dx.doi.org/10.1135/cccc19890699.

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5-Nitro-3-furoyl isothiocyanate reacts with 4-X-anilines (X = H, CH3, OH, N(C2H5)2, NHCOCH3, Cl, Br) to give the corresponding N-(5-nitro-3-furoyl)-N'-(4-X-phenyl)thioureas, in contrast to 4-methoxyaniline and 4-nitroaniline, which afford 5-nitro-3-furancarboxylic acid amides in a rather anomalous way. Formation of these amides is discussed and some properties of 2- and 3-substituted thioureas related to 5-nitrofuran are compared.
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Uma, Pathki, Kamatala Rajanna, Yelike Sriram, Akarapu Premalatha, and Pondichery Saipraksh. "Synthesis of 3-(4-(Benzo[d]thiazol-2-yl)phenyl)-5-aryl-1,3,5-oxadiazinane-4-thiones and 1-(4-(Benzo[d]thiazol-2-yl)phenyl)-5-methyl-3-aryl-1,3,5-triazinane-2-thiones." SynOpen 02, no. 01 (2018): 0030–35. http://dx.doi.org/10.1055/s-0036-1591917.

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In this investigation 4-(benzo[d]thiazol-2-yl)benzenamine was reacted with aryl isothiocyanates to give 1-(4-(benzo[d]thiazol-2-yl)phenyl)-3-aryl thioureas 2, which were cyclized with acid to afford 3-(4-(benzo[d]thiazol-2-yl)phenyl)-5-aryl-1,3,5-oxadiazinane-4-thiones 3. On the other hand, 1-(4-(benzo[d]thiazol-2-yl)phenyl)-5-methyl-3-aryl-1,3,5-triazinane-2-thiones 4 were obtained when compounds 2 were treated with amines.
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Kovalskaya, A. V., A. N. Lobov, V. V. Zarubaev, and I. P. Tsypysheva. "Derivatives of (–)-Cytisine with Thiourea Fragment. Synthesis and Antiviral Activity." Žurnal obŝej himii 94, no. 6 (2024): 712–21. http://dx.doi.org/10.31857/s0044460x24060054.

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New derivatives of the quinolizidine alkaloid, (–)-cytisine, with a substituted 2-pyridone ring and a thiourea moiety in the bispidin fragment of the molecule were synthesized. The ability of the synthesized cytisine-containing thioureas to inhibit the reproduction of human parainfluenza virus type 3 was assessed. It was found that the derivatives obtained by the reaction of benzoyl or phenyl isothiocyanate with (–)-cytisine, as well as its 9-bromo or 9,11-derivative, effectively suppress the reproduction of human parainfluenza virus type 3 (their selectivity indices are 56, 58 and 95, respect
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Dissertations / Theses on the topic "Phenyl thioureas"

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Walchshofer, Nadia. "Mise au point de nouveaux anthelminthiques à partir de données biochimiques synthèse de thiazolyl et de thiadiazolyl urées de phényl thiourées et de phényl-3 propénones : essai de relations structure-activité /." Grenoble 2 : ANRT, 1988. http://catalogue.bnf.fr/ark:/12148/cb37619195j.

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Fernandes, Sónia Rafaela Beleza. "Detection and characterization of phenoloxidasse in Chironomus riparius." Master's thesis, Universidade de Aveiro, 2018. http://hdl.handle.net/10773/22027.

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Mestrado em Biologia Molecular e Celular<br>Insects are frequently exposed to a large variety of microbes, microorganisms and parasites which requires an effective immune system of defence against infections. However, insects lack an adaptive immune system, so they have developed other highly effective systems of host defence, such as innate immune reactions. These innate immune reactions refer to the first-line of defence of hosts against bacterial, fungal, and viral pathogens. Research on invertebrate model systems have been increasing and becoming very important in ecological immunology res
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Book chapters on the topic "Phenyl thioureas"

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Cui, Shengchao, Guangzheng Wang, Shu Liu, Xintong Yan, and Ming Fan. "Synthesis and Property Analysis of a Novel Epoxy Composite Curing Agent Based on Soft Soil Curing." In Lecture Notes in Civil Engineering. Springer Nature Singapore, 2024. https://doi.org/10.1007/978-981-97-6238-5_46.

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AbstractTo meet the demand for shore-based engineering, engineering rescue and traffic emergency support in different complex conditions, a new low-temperature fast solidifier for epoxy resin was synthesized by Mannich reaction using thiourea, polyamine, formaldehyde, phenol and benzyl alcohol. The performance of the curing agent was investigated based on raw material ratio, reaction temperature and reaction time. Moreover, the curing time, amine value, viscosity and infrared spectrum were tested. It was compounded with other highly active curing agents and resins. The compressive strength of
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Conference papers on the topic "Phenyl thioureas"

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Shank, R. A., and T. R. McCartney. "The Search for a Green Alternative in Organic Acid Corrosion Inhibition." In CORROSION 2015. NACE International, 2015. https://doi.org/10.5006/c2015-05991.

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Abstract The application of acid corrosion inhibitors is an absolute necessity to prevent damage to process equipment during acid cleaning operations. The use of organic acids and mineral acids that are not HCl has expanded because of environmental concerns and issues of compatibility with alloys such as stainless or duplex steel. Inhibitors which are used to protect the metals from corrosion by organic acids often contain a number of highly toxic compounds based on amine technology such as quaternary amines, amine ethoxylates, imidazolines and polyamides as well as sulfur compounds such as th
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