Academic literature on the topic 'Phenylsydnone'

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Journal articles on the topic "Phenylsydnone"

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Schmidt, Andreas, Ana-Luiza Lücke, Sascha Wiechmann, and Tyll Freese. "Suzuki–Miyaura Cross-Coupling Reactions in Acetic Acid Employing Sydnone-Derived Catalyst Systems." Synlett 28, no. 15 (2017): 1990–93. http://dx.doi.org/10.1055/s-0036-1589059.

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The catalyst system consisting of lithium N-phenylsydnone-4-carboxylate/Pd(PPh3)4 has proven to be an effective catalyst for the Suzuki–Miyaura reaction of 2,4-dinitrochlorobenzene with boronic acids in acetic acid at pH 5.7, whereas the N-phenylsydnone carbene palladium complex [sydPd(PPh3)2Br] required pH 8.0.
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Lücke, Ana-Luiza, Sascha Wiechmann, Tyll Freese, Zong Guan, and Andreas Schmidt. "Palladium complexes of anionic N-heterocyclic carbenes derived from sydnones in catalysis." Zeitschrift für Naturforschung B 71, no. 6 (2016): 643–50. http://dx.doi.org/10.1515/znb-2016-0006.

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AbstractThe anion of N-phenylsydnone, which can be generated on treatment of N-phenylsydnone with cyanomethyllithium without decomposition, can be represented as tripolar zwitterionic and as anionic N-heterocyclic carbene resonance forms. Its palladium complex was prepared from 4-bromo-3-phenylsydnone and tetrakis(triphenylphosphine)palladium and proved to be active as catalyst in Suzuki-Miyaura reactions. Thus, 2,5-dibromo-3,4-dinitrothiophene was effectively converted into 2,5-diaryl-3,4-dinitrothiophenes with 1-naphthyl, (4-trifluoromethoxy)phenyl, [4-(methylsulfanyl)phenyl], and biphenyl-4
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Fun, Hoong-Kun, Tze Shyang Chia, Nithinchandra, Balakrishna Kalluraya, and Shobhitha Shetty. "4-Bromoacetyl-3-phenylsydnone." Acta Crystallographica Section E Structure Reports Online 68, no. 7 (2012): o2103. http://dx.doi.org/10.1107/s1600536812026049.

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Tullis, S. A., and K. Turnbull. "Acylation and Aroylation of 3-Phenylsydnone." Synthetic Communications 20, no. 20 (1990): 3137–44. http://dx.doi.org/10.1080/00397919008051537.

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Jogul, Johnson J., Mohammedshafi A. Phaniband, S. R. Pattan, and B. V. Badami†. "Synthesis and biological evaluation of 3-[p-(heterocyclocarbonyl)]phenylsydnones from the versatile precursor, 3-[p-(hydrazinocarbonyl)]phenylsydnone." Main Group Chemistry 8, no. 4 (2009): 337–47. http://dx.doi.org/10.1080/10241220903377523.

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Abdul Ajees, A., S. Karthikeyan, C. V. Yelamaggad, and B. V. Badami. "4-(2-Benzoylhydrazinothiazol-4-yl)-3-phenylsydnone." Acta Crystallographica Section E Structure Reports Online 58, no. 7 (2002): o784—o786. http://dx.doi.org/10.1107/s1600536802010668.

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Pruschinski, Lucas, Ana-Luiza Lücke, Tyll Freese, Sean-Ray Kahnert, Sebastian Mummel, and Andreas Schmidt. "Suzuki–Miyaura Cross-Couplings under Acidic Conditions." Synthesis 52, no. 06 (2019): 882–92. http://dx.doi.org/10.1055/s-0039-1691487.

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Suzuki–Miyaura reactions with Pd(PPh3)4 have been carried out using lithium N-phenylsydnone-4-carboxylate as additive, which gave best yields at pH 5.7 in a mixture of acetic acid, water, and sodium carbonate. Reaction parameters such as the Pd source, the solvent, reaction time and temperature, acid, base and carboxylate have been varied and some representative examples of the Suzuki–Miyaura reaction have been examined.
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Grossie, D., L. Harrison, and K. Turnbull. "Crystal structure of 4-(2-bromopropionyl)-3-phenylsydnone." Acta Crystallographica Section E Structure Reports Online 70, no. 11 (2014): o1165—o1166. http://dx.doi.org/10.1107/s1600536814022260.

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Sydnones are a class of mesoionic compounds containing a five-membered heterocyclic ring. In general, sydnone compounds are synthesized with an aromatic substutuent at the N3position. This feature, adds to the stability of the heterocyclic ring. In the title compound {systematic name: 4-(2-bromopropanoyl)-3-phenyl-1,2,3λ5-oxadiazol-3-ylium-5-olate}, C11H9BrN2O3, the aromatic substitutent is an unsubstituted phenyl ring. The sydnone ring is almost planar, with a maximum deviation from the mean plane of 0.023 (1) Å, but is not coplanar with the phenyl ring, having a dihedral angle of 40.93 (8)°.
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TULLIS, S. A., and K. TURNBULL. "ChemInform Abstract: Acylation and Aroylation of 3-Phenylsydnone." ChemInform 22, no. 15 (2010): no. http://dx.doi.org/10.1002/chin.199115172.

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Kawase, Masami, Ryosuke Saijo, Shigeki Mori, and Hidemitsu Uno. "Synthesis and Crystal Structure of 4-Trifluoroacetyl-3-phenylsydnone." HETEROCYCLES 94, no. 11 (2017): 2103. http://dx.doi.org/10.3987/com-17-13802.

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Dissertations / Theses on the topic "Phenylsydnone"

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Chen, Ying-Nan, and 陳盈男. "Study on dual properties of sydnone via nitration of 3-aryl-4-phenylsydnones." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/94106918894338692866.

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碩士<br>靜宜大學<br>應用化學系<br>99<br>Sydnone is a typical mesoionic compound. Their unique dual properties have drawn some attention from a number of organic chemists. In this work, 3-aryl-4-phenlsydnones were prepared for nitration to demonstrate their dual properties. In general, the nitro group preferential substituted at C(4) position. However, with presence of an electron-donor on the benzene ring on N(3), the nitration will take place at both phenyl rings. The activation of benzene ring by methoxyl group is able to compensate the electro-withdrawing ability of the sydnone ring. In general,
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Book chapters on the topic "Phenylsydnone"

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Bhosale, Sachin K., Shreenivas R. Deshpande, Rajendra D. Wagh, and Nirmala Vikram Shinde. "Green Synthesis and Antimicrobial/Antioxidant Screening of 4-[1-oxo-3-(substituted phenyl)-2-propenyl]-3-substituted Phenylsydnones." In Advanced Concepts in Pharmaceutical Research Vol. 8. B P International, 2024. http://dx.doi.org/10.9734/bpi/acpr/v8/5018a.

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