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1

Anillo, A., M. L. Rodrı́guez, R. Llavona, et al. "Vanadium oxide loaded tin–titanium phosphates." International Journal of Inorganic Materials 2, no. 2-3 (2000): 177–85. http://dx.doi.org/10.1016/s1466-6049(00)00021-0.

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2

Janusz, Władysław, Svetlana Khalameida, Volodymyr Sydorchuk, et al. "Some properties of milled vanadium phosphates." Adsorption 16, no. 4-5 (2010): 333–41. http://dx.doi.org/10.1007/s10450-010-9238-x.

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3

PIETRZAK, TOMASZ K., IRENA GORZKOWSKA, JAN L. NOWIŃSKI, JERZY E. GARBARCZYK, and MAREK WASIUCIONEK. "PREPARATION OF TRIPHYLITE-LIKE GLASSES AND NANOMATERIALS IN THE LiFePO4-V2O5 SYSTEM AND STUDY ON THEIR ELECTRICAL CONDUCTIVITY." Functional Materials Letters 04, no. 02 (2011): 143–45. http://dx.doi.org/10.1142/s1793604711001750.

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Research on lithium iron phosphates is stimulated by their application as cathodes in Li -ion rechargeable batteries. The aim of this study was to enhance its initially poor electronic conductivity. A thermal nanocrystallization is applied to lithium-iron-phosphate and lithium-vanadium-iron-phosphates materials resulting in a significant increase of the electronic conductivity of the latter (almost 10-6 S/cm). The obtained nanomaterial exhibits very good thermal stability (up to 625°C), the activation energy 0.51 eV and moderate electronic conductivity at the room temperature, which is, however, a good starting point for further enhancement.
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4

Ennaciri, A., and P. Barboux. "Solution Synthesis of Vanadium and Titanium Phosphates." Materials Science Forum 152-153 (March 1994): 331–34. http://dx.doi.org/10.4028/www.scientific.net/msf.152-153.331.

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5

Živkov Baloš, Milica, Dragana Ljubojević, Sandra Jakšić, et al. "VANADIUM IN POULTRY NUTRITION." Archives of Veterinary Medicine 10, no. 1 (2019): 85–92. http://dx.doi.org/10.46784/e-avm.v10i1.84.

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Vanadium (V) is essential element for poultry nutrition. Relatively low level of V (< 10 μg/kg of feed) is known to reduce both growth in chicks and Haugh unit value of eggs. The National Research Council (NRC) recommends the presence of very low levels of V in poultry diets, with the maximum tolerance level (MTL) being 10 mg/kg. Excessive vanadium in poultry diets has been shown to be detrimental to egg production, interior quality of eggs (albumen height), body weight and feed consumption. There is little information on the content of V in feedstuffs. Phosphates are known to be the cause of excessive V in various types of poultry diets. The objective of this study was to obtain information about the content of vanadium in phosphates and poultry feed. The samples were prepared by microwave wet digestion. Content of V was determined by the method of coupled plasma with mass spectrometry on the Agilent ICP-MS 7700. The concentrations of vanadium determined in the examined samples were above the minimum recommended levels for poultry feed, still not exceeding the maximum tolerable values.
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6

Kalousová, Jaroslava, Jiří Votinský, Ludvík Beneš, Klára Melánová, and Vítězslav Zima. "Vanadyl Phosphate and Its Intercalation Reactions. A Review." Collection of Czechoslovak Chemical Communications 63, no. 1 (1998): 1–19. http://dx.doi.org/10.1135/cccc19980001.

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The structure of the layered αI-VOPO4, VOPO4·2H2O, and their intercalation reactions are discussed. These reactions are divided into two groups. The first includes intercalation reactions of molecular guests which proceed as acid-base processes between the host layered lattice (Lewis acid) and a donor atom of the guest (base). Interaction of water molecules, alcohols, amines, carboxylic acids and their derivatives, heterocyclic N- and S-donors, and complex compounds with vanadyl phosphates is discussed. Vanadyl phosphate, in particular vanadyl phosphate dihydrate can also undergo the second type of the reactions which involves the reduction of a fraction of vanadium(V) atoms to vanadium(IV) with concomitant intercalation of alkylammonium, hydronium or mono- and divalent metal cations to counterbalance the induced negative layer charge. A review with 76 references.
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7

Garcia-Ponce, A. L., L. Moreno-Real, and A. Jimenez-Lopez. "Synthesis and characterization of mixed niobium-vanadium phosphates." Inorganic Chemistry 27, no. 19 (1988): 3372–76. http://dx.doi.org/10.1021/ic00292a022.

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8

Mokry, Ladd M., Jeffrey Thompson, Marcus R. Bond, Tom Otieno, Madan Mohan, and Carl J. Carrano. "Stereochemical Control of Cluster Size in Vanadium Phosphates." Inorganic Chemistry 33, no. 13 (1994): 2705–6. http://dx.doi.org/10.1021/ic00091a003.

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9

Sidorchuk, V. V., S. V. Khalameida, and V. A. Zazhigalov. "Hydrothermal deposition of vanadium phosphates onto carbon materials." Russian Journal of Applied Chemistry 82, no. 3 (2009): 343–51. http://dx.doi.org/10.1134/s107042720903001x.

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10

Alhumaimess, Mosaed, Zhongjie Lin, Nicholas F. Dummer, Stuart H. Taylor, Graham J. Hutchings, and Jonathan K. Bartley. "Highly crystalline vanadium phosphate catalysts synthesized using poly(acrylic acid-co-maleic acid) as a structure directing agent." Catalysis Science & Technology 6, no. 9 (2016): 2910–17. http://dx.doi.org/10.1039/c5cy01260k.

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11

ENNACIRI, SIDI ABDERAZAK, and CHAIUB R'KHA. "COPRECIPITATION OF MIXED VANADIUM AND TITANIUM PHOSPHATES FROM ALKOXIDES." Phosphorus Research Bulletin 12 (2001): 181–89. http://dx.doi.org/10.3363/prb1992.12.0_181.

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12

Jiménez-López, A., and AL García-Ponce. "Synthèse et réactivité des phosphates mixtes de niobium – vanadium." Journal de Chimie Physique 88 (1991): 1957–62. http://dx.doi.org/10.1051/jcp/1991881957.

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13

Datta, Arunabha, Monika Agarwal, Soumen Dasgupta, and Ravindra Y. Kelkar. "Novel platinum incorporated vanadium phosphates and their catalytic activity." Journal of Molecular Catalysis A: Chemical 198, no. 1-2 (2003): 205–14. http://dx.doi.org/10.1016/s1381-1169(02)00689-1.

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14

Robert, V., S. A. Borshch, and B. Bigot. "Role of mixed-valence state in vanadium phosphates catalysts." Journal of Molecular Catalysis A: Chemical 119, no. 1-3 (1997): 327–33. http://dx.doi.org/10.1016/s1381-1169(96)00495-5.

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15

ENNACIRI, S. A., C. R'KHA, P. BARDOUX, and J. LIVAGE. "ChemInform Abstract: Synthesis of Vanadium Phosphates from Molecular Precursors." ChemInform 24, no. 21 (2010): no. http://dx.doi.org/10.1002/chin.199321032.

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16

Asunskis, Daniel J., and Peter M. A. Sherwood. "Valence-band x-ray photoelectron spectroscopic studies of vanadium phosphates and the formation of oxide-free phosphate films on metallic vanadium." Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films 21, no. 4 (2003): 1133–38. http://dx.doi.org/10.1116/1.1575223.

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17

Datta, A. "Characterization and catalytic activity of novel palladium-incorporated vanadium phosphates." Journal of Molecular Catalysis A: Chemical 181, no. 1-2 (2002): 119–27. http://dx.doi.org/10.1016/s1381-1169(01)00354-5.

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18

Korthuis, V. C., R. D. Hoffmann, Jinfan Huang, and A. W. Sleight. "Synthesis and crystal structure of potassium and sodium vanadium phosphates." Chemistry of Materials 5, no. 2 (1993): 206–9. http://dx.doi.org/10.1021/cm00026a009.

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19

Zhang, Zhibin, Jiuyu Guo, Jie Fu, et al. "Hydrothermal Syntheses and Crystal Structures of Two New Vanadium Phosphates." Journal of Cluster Science 23, no. 2 (2011): 177–87. http://dx.doi.org/10.1007/s10876-011-0385-3.

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20

Boivin, Edouard, Jean-Noël Chotard, Christian Masquelier, and Laurence Croguennec. "Towards Reversible High-Voltage Multi-Electron Reactions in Alkali-Ion Batteries Using Vanadium Phosphate Positive Electrode Materials." Molecules 26, no. 5 (2021): 1428. http://dx.doi.org/10.3390/molecules26051428.

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Vanadium phosphate positive electrode materials attract great interest in the field of Alkali-ion (Li, Na and K-ion) batteries due to their ability to store several electrons per transition metal. These multi-electron reactions (from V2+ to V5+) combined with the high voltage of corresponding redox couples (e.g., 4.0 V vs. for V3+/V4+ in Na3V2(PO4)2F3) could allow the achievement the 1 kWh/kg milestone at the positive electrode level in Alkali-ion batteries. However, a massive divergence in the voltage reported for the V3+/V4+ and V4+/V5+ redox couples as a function of crystal structure is noticed. Moreover, vanadium phosphates that operate at high V3+/V4+ voltages are usually unable to reversibly exchange several electrons in a narrow enough voltage range. Here, through the review of redox mechanisms and structural evolutions upon electrochemical operation of selected widely studied materials, we identify the crystallographic origin of this trend: the distribution of PO4 groups around vanadium octahedra, that allows or prevents the formation of the vanadyl distortion (O…V4+=O or O…V5+=O). While the vanadyl entity massively lowers the voltage of the V3+/V4+ and V4+/V5+ couples, it considerably improves the reversibility of these redox reactions. Therefore, anionic substitutions, mainly O2− by F−, have been identified as a strategy allowing for combining the beneficial effect of the vanadyl distortion on the reversibility with the high voltage of vanadium redox couples in fluorine rich environments.
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21

Lim, S. "Redox transformations of simple vanadium phosphates: the synthesis of ε-VOPO4". Solid State Ionics 84, № 3-4 (1996): 219–26. http://dx.doi.org/10.1016/0167-2738(96)00007-0.

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22

Ennaciri, S. A., K. Malka, C. Louis, P. Barboux, C. R'kha, and J. Livage. "SOL-GEL SYNTHESIS AND CATALYTIC PROPERTIES OF VANADIUM PHOSPHATES BULK MATERIALS." Phosphorus Research Bulletin 11 (2000): 87–93. http://dx.doi.org/10.3363/prb1992.11.0_87.

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23

Lee, Young-Sook, Jon Zjbieta, Robert Haushalter, and Charles J. Oconnor. "Ferromagnetism, Antiferromagnetism and Paramagnetism in Vanadium Phosphates Prepared From Hydrothermal Conditions." Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 274, no. 1 (1995): 79–88. http://dx.doi.org/10.1080/10587259508031868.

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24

Dong, Wen-Sheng, Jonathan K. Bartley, Nicholas F. Dummer, et al. "Reaction of vanadium phosphates with alcohols at elevated temperature and pressure." Journal of Materials Chemistry 15, no. 31 (2005): 3214. http://dx.doi.org/10.1039/b505586p.

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25

Whittingham, M. Stanley, Yanning Song, Samuel Lutta, Peter Y. Zavalij, and Natasha A. Chernova. "Some transition metal (oxy)phosphates and vanadium oxides for lithium batteries." Journal of Materials Chemistry 15, no. 33 (2005): 3362. http://dx.doi.org/10.1039/b501961c.

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26

Gautier, Romain, Yoann Fourré, Eric Furet, Régis Gautier, and Eric Le Fur. "Analysis and Prediction of Stacking Sequences in Intercalated Lamellar Vanadium Phosphates." European Journal of Inorganic Chemistry 2015, no. 11 (2015): 1941–45. http://dx.doi.org/10.1002/ejic.201403210.

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27

Shugurov, S. M., and S. I. Lopatin. "Thermodynamic study of gaseous vanadium phosphates by high-temperature mass spectrometry." Rapid Communications in Mass Spectrometry 25, no. 23 (2011): 3464–68. http://dx.doi.org/10.1002/rcm.5254.

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28

Wadewitz, C., and Hk Müller-Buschbaum. "Synthese und Struktureines Strontium-Vanadyl-Phosphats: Sr2(VO)(PO4)2 / Synthesis and Structure of a Strontium Vanadyl Phosphate: Sr2(VO)(PO4)2." Zeitschrift für Naturforschung B 51, no. 7 (1996): 929–33. http://dx.doi.org/10.1515/znb-1996-0705.

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Dark green single crystals of Sr2(VO)P2O8 have been prepared by solid state reactions in closed quartz tubes. X-ray investigations led to monoclinic symmetry, space group C2h6-I2/a, a = 6.744(4), b = 15.866(4), c = 7.032(2) Å, β = 115.41(2), Z = 4. Sr2(VO)P2O8 is isotypic to Sr2(VO)V2O8 and shows V4+ in split positions. The split positions are in non-centric octahedral coordination forming a short vanadium to oxygen distance typical for the vanadyl group. The crystal chemistry of the monovanadyl orthophate Sr2(VO)P2O8 is discussed considering related divanadyl phosphates.
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29

Lisi, L., G. Ruoppolo, M. P. Casaletto, et al. "Vanadium-metal(IV)phosphates as catalysts for the oxidative dehydrogenation of ethane." Journal of Molecular Catalysis A: Chemical 232, no. 1-2 (2005): 127–34. http://dx.doi.org/10.1016/j.molcata.2005.01.035.

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30

Yin, Shih-Chieh, Hiltrud Grondey, Pierre Strobel, Huan Huang, and Linda F. Nazar. "Charge Ordering in Lithium Vanadium Phosphates: Electrode Materials for Lithium-Ion Batteries." Journal of the American Chemical Society 125, no. 2 (2003): 326–27. http://dx.doi.org/10.1021/ja028973h.

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31

KORTHUIS, V. C., R. D. HOFFMANN, J. HUANG, and A. W. SLEIGHT. "ChemInform Abstract: Synthesis and Crystal Structure of Potassium and Sodium Vanadium Phosphates." ChemInform 24, no. 20 (2010): no. http://dx.doi.org/10.1002/chin.199320032.

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32

Chen, Bin, and Eric J. Munson. "Evidence for Two Competing Mechanisms forn-Butane Oxidation Catalyzed by Vanadium Phosphates." Journal of the American Chemical Society 121, no. 47 (1999): 11024–25. http://dx.doi.org/10.1021/ja9929180.

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33

Martin, Andreas, Ursula Steinike, Klára Melánová, and Vítezslav Zima. "Solid‐state reactions of vanadium(v) phosphates in the presence of ammonia." Journal of Materials Chemistry 9, no. 10 (1999): 2523–27. http://dx.doi.org/10.1039/a903491i.

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34

Brutovský, Milan, Lucia Ferdinandyová, Štefan Gerej, and Ján Novák. "Effect of the Method of Synthesis, Forming, and Activation on the Catalytic Activity of Vanadium-Phosphorus Catalysts." Collection of Czechoslovak Chemical Communications 58, no. 5 (1993): 1007–12. http://dx.doi.org/10.1135/cccc19931007.

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Methods where vanadium in the precursor is reduced to V4+ in solution are well suited to the synthesis of vanadium-phosphorus catalyst because the high temperatures (500 to 800 °C) required to transform the precursor to the active catalyst are thus avoid, which is desirable from the chemical as well as structuro-physical aspects. The way of forming and activating the catalyst, i.e. the temperature regime of the treatment and the kind of the gas atmosphere, were found to affect appreciably the catalyst activity in the partial oxidation of butane to maleic anhydride.. Forming procedures resulting in sufficiently fine crystals and optimized lattice defects are suitable. The application of synthesis, forming and activation procedures exhibiting a low tendency to form, in the catalyst phase composition, condensed phosphates such as VO(PO3)2 or even V(PO3)3 is also beneficial to the catalyst activity. The catalytic properties of the vanadium-phosphorus catalyst which was prepared in concentrated HCl were improved considerably by doping the lattice with modifying metal cations.
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35

Sydorchuk, V., V. Zazhigalov, S. Khalameida, et al. "Solvothermal synthesis of vanadium phosphates in the form of xerogels, aerogels and mesostructures." Materials Research Bulletin 45, no. 9 (2010): 1096–105. http://dx.doi.org/10.1016/j.materresbull.2010.06.010.

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36

Turco, M., G. Bagnasco, G. Russo, et al. "NH3 TPD study and thermal behaviour of vanadium-exchanged titanium phosphates as catalysts." Journal of Thermal Analysis 47, no. 1 (1996): 215–25. http://dx.doi.org/10.1007/bf01982700.

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37

Coulston, G. W. "The Kinetic Significance of V5+ in n-Butane Oxidation Catalyzed by Vanadium Phosphates." Science 275, no. 5297 (1997): 191–93. http://dx.doi.org/10.1126/science.275.5297.191.

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38

Ben Abdelouahab, F., M. Ziyad, C. Leclercq, JM Millet, R. Olier, and JC Volta. "Étude physicochimique de phases phosphates de vanadium dopées par le cobalt et le fer." Journal de Chimie Physique 92 (1995): 1320–32. http://dx.doi.org/10.1051/jcp/1995921320.

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39

Hu, Linfeng, Zeyi Wu, Chengjie Lu, Fei Ye, Qiang Liu, and Zhengming Sun. "Principles of interlayer-spacing regulation of layered vanadium phosphates for superior zinc-ion batteries." Energy & Environmental Science 14, no. 7 (2021): 4095–106. http://dx.doi.org/10.1039/d1ee01158h.

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Phenylamine molecules can be controllably introduced into the interlayer spacing of layered VOPO<sub>4</sub> to regulate the interlayer spacing. An approximate linear dependence between Zn<sup>2+</sup> storage specific capacity and interlayer spacing is revealed.
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40

Bock, David C., Amy C. Marschilok, Kenneth J. Takeuchi, and Esther S. Takeuchi. "A kinetics and equilibrium study of vanadium dissolution from vanadium oxides and phosphates in battery electrolytes: Possible impacts on ICD battery performance." Journal of Power Sources 231 (June 2013): 219–25. http://dx.doi.org/10.1016/j.jpowsour.2013.01.012.

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41

Brutovský, Milan, Štefan Gerej, Ján Novák, and Lucia Ferdinandyová. "A Contribution to the Structure Characteristics and Phase Composition of Vanadium-Phosphorus Catalysts Prepared from the VOPO4.xH2O.yH3PO4 Precursor." Collection of Czechoslovak Chemical Communications 57, no. 12 (1992): 2475–80. http://dx.doi.org/10.1135/cccc19922475.

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Catalysts were prepared from VOPO4.xH2O.yH3PO4 (x = 0.3-2, y = 0.2-0.85) by reduction with SO2 up to a final temperature of 750-800 °C, and activated in a reaction mixture of 1.0-1.4% butane in air up to 500 °C. The structure characteristics and phase composition of the catalysts were found to be affected by the preparation procedure and heat treatment regime. Their diffraction lines and IR spectra revealed that the catalysts from larger and less defective crystals than catalysts which were obtained from the VOHPO4.xH2O.yH3PO4 precursor and activated in the reaction mixture at temperatures up to 500 °C. In the catalysts prepared by the above procedure, the tendency to the formation of phases of higher-condensed phosphates, in particular VO(PO3)2 or even V(PO3)3, increases with increasing n(P):n(V) ratio and is then more pronounced than with vanadium-phosphorus catalysts prepared by other procedures. The tendency to the formation of the catalytically less active condensed phosphates is partly suppressed by the embedding of modifying metal cations (Fe or Cu in this case).
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42

ELBADRAOUI, A., J. PIVAN, M. MAUNAYE, O. PENA, M. LOUER, and D. LOUER. "Order-disorder phenomena in vanadium phosphates. Structures and properties of tetragonal and monoclinic VPO(HO)." Annales de Chimie Science des Mat�riaux 23, no. 1-2 (1998): 97–101. http://dx.doi.org/10.1016/s0151-9107(98)80032-9.

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43

Ai, Mamoru. "Comparison of catalytic properties for partial oxidation between heteropolyacids and phosphates of vanadium and iron." Journal of Molecular Catalysis A: Chemical 114, no. 1-3 (1996): 3–13. http://dx.doi.org/10.1016/s1381-1169(96)00300-7.

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44

Glaum, R., E. Benser, and H. Hibst. "Novell Ternary and Polynary Vanadium(IV) Phosphates as Catalysts for Selective Oxidations of Light Hydrocarbons." Chemie Ingenieur Technik 79, no. 6 (2007): 843–50. http://dx.doi.org/10.1002/cite.200700047.

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45

Martínez, Jorge Alexis Zúñiga, Sara Elena González Náñez, Etienne Le Calvez, et al. "Layered Vanadium Phosphates as Electrodes for Electrochemical Capacitors Part I: The Case of VOPO4·2H2O." Journal of The Electrochemical Society 168, no. 7 (2021): 070531. http://dx.doi.org/10.1149/1945-7111/ac11a3.

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46

Boudin, S., A. Guesdon, A. Leclaire, and M. M. Borel. "Review on vanadium phosphates with mono and divalent metallic cations: syntheses, structural relationships and classification, properties." International Journal of Inorganic Materials 2, no. 6 (2000): 561–79. http://dx.doi.org/10.1016/s1466-6049(00)00074-x.

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47

Batista, Jonathan Carvalhaes, Paulo Cesar de Sousa Filho, and Osvaldo Antonio Serra. "Effect of the vanadium(v) concentration on the spectroscopic properties of nanosized europium-doped yttrium phosphates." Dalton Transactions 41, no. 20 (2012): 6310. http://dx.doi.org/10.1039/c2dt30380a.

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48

Ennaciri, S. A., C. R’kha, P. Barboux, J. Livage, and J. Maquet. "31P and 51V MAS-NMR Characterisation of Mixed Vanadium and Titanium Phosphates Prepared from Molecular Precursors." Journal of Sol-Gel Science and Technology 34, no. 2 (2005): 197–203. http://dx.doi.org/10.1007/s10971-005-1368-3.

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49

Shao, Lianyi, Jie Shu, Yuanhao Tang, et al. "Phase diagram and electrochemical behavior of lithium sodium vanadium phosphates cathode materials for lithium ion batteries." Ceramics International 41, no. 3 (2015): 5164–71. http://dx.doi.org/10.1016/j.ceramint.2014.11.152.

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50

Le Fur, E., O. Peña, and J. Y. Pivan. "Magnetic and thermal properties of vanadium phosphates hydrates MII(VOPO4)2·4H2O (MII=Ca2+, Ba2+ and Cd2+)." Journal of Alloys and Compounds 285, no. 1-2 (1999): 89–97. http://dx.doi.org/10.1016/s0925-8388(99)00013-4.

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