Academic literature on the topic 'Phosphonomethyl'

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Journal articles on the topic "Phosphonomethyl"

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Ying, Shao-Ming, Jun-Yue Lin, Guang-Pei Zhou, Qiu-Yan Luo, and Jian-Hong Wu. "[N-(Phosphonomethyl)ethylammonio]methylphosphonate." Acta Crystallographica Section E Structure Reports Online 63, no. 3 (February 7, 2007): o1153—o1154. http://dx.doi.org/10.1107/s1600536807004461.

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The title compound, C5H15NO6P2, exists as a zwitterion. The N atom of the amino group is protonated and one of the phosphonic acid groups is deprotonated. The molecules form hydrogen-bonded (202) layers.
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Krečmerová, Marcela, Hubert Hřebabecký, and Antonín Holý. "Synthesis of 5'-O-phosphonomethyl derivatives of pyrimidine 2'-deoxynucleosides." Collection of Czechoslovak Chemical Communications 55, no. 10 (1990): 2521–36. http://dx.doi.org/10.1135/cccc19902521.

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Reaction of sodium salt of 3-N,3'-O-bis(benzyloxymethyl)-2'-deoxyuridine (X) and 3-N,3'-O-bis(benzyloxymethyl)-2'-deoxythymidine (XI) with diethyl p-toluenesulfonyloxymethanephosphonate in dimethylformamide afforded diesters of the respective 5'-O-phosphonomethyl derivatives XII and XVII. Diethyl esters of 5'-O-phosphonomethyl-2'-deoxynucleosides XV and XIX, obtained after hydrogenolytic removal of the benzyloxymethyl groups, were converted into free 2'-deoxy-5'-O-phosphonomethyluridine (XVI) and a mixture of anomeric 1-(2-deoxy-5-O-phosphonomethyl-β-D-erythro-pentofuranosyl)thymines (XXIIIa, XXIIIb), respectively. Analogously, 2'-deoxy-5'-O-phosphonomethylcytidine (XXXIV) was prepared from 4-N-benzoyl-2'-deoxy-3'-O-(tetrahydro-2H-pyran-2-yl) cytidine (XXX) via diethyl ester of 2'-deoxy-5'-O-phosphonomethylcytidine (XXXIII). This compound reacted with bromotrimethylsilane to give compound XXXIV without anomerization and nucleoside bond cleavage. Condensation of the protected nucleosides X and XI with dibenzyl p-toluenesulfonyloxymethanephosphonate afforded dibenzyl esters of the corresponding 5'-O-phosphonomethyl derivatives XIII and XVIII. The free 5'-O-phosphonomethyl derivatives XVI and XXIIIa were obtained from XIII and XVIII by catalytic hydrogenation.
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Solyev, Pavel N., Maxim V. Jasko, Alla A. Kleymenova, Marina K. Kukhanova, and Sergey N. Kochetkov. "Versatile synthesis of oxime-containing acyclic nucleoside phosphonates – synthetic solutions and antiviral activity." Organic & Biomolecular Chemistry 13, no. 44 (2015): 10946–56. http://dx.doi.org/10.1039/c5ob01571e.

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New oxime-containing acyclic nucleoside phosphonates 9-{2-[(phosphonomethyl)oximino]ethyl}adenine (1), -guanine (2) and 9-{2-[(phosphonomethyl)oximino]propyl}adenine (3) with wide spectrum activity against different types of viruses were synthesized.
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Gavagan, John E., Susan K. Fager, John E. Seip, Dawn S. Clark, Mark S. Payne, David L. Anton, and Robert DiCosimo. "Chemoenzymic Synthesis ofN-(Phosphonomethyl)glycine." Journal of Organic Chemistry 62, no. 16 (August 1997): 5419–27. http://dx.doi.org/10.1021/jo970455f.

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Weichsel, A., and T. Lis. "2-(Phosphonomethyl)acrylic Acid Hemihydrate and Ammonium 2-(Phosphonomethyl)acrylate: Analogues of Phosphoenolpyruvate (PEP)." Acta Crystallographica Section C Crystal Structure Communications 52, no. 1 (January 15, 1996): 97–101. http://dx.doi.org/10.1107/s0108270195009802.

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Sawka-Dobrowolska, W., and J. Barycki. "Structure of N-phosphonomethyl-L-proline." Acta Crystallographica Section C Crystal Structure Communications 45, no. 4 (April 15, 1989): 606–9. http://dx.doi.org/10.1107/s0108270188010236.

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Gaied, Lilia Ben, Soufiane Touil, and Hedi Zantour. "Synthese de 2-Amino-5-(phosphonomethyl) Thiophenes." Phosphorus, Sulfur, and Silicon and the Related Elements 181, no. 3 (March 1, 2006): 601–8. http://dx.doi.org/10.1080/10426500500269844.

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Gholivand, Khodayar, and Ali Reza Farrokhi. "Poly[{μ10-[(phosphonomethyl)iminodimethylene]diphosphonato}dithallium(I)]." Acta Crystallographica Section E Structure Reports Online 66, no. 8 (July 3, 2010): m873. http://dx.doi.org/10.1107/s1600536809031006.

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Dupont, Nathalie, Pascal Retailleau, Evelyne Migianu-Griffoni, and Carole Barbey. "Methyl [hydroxy(phenyl)phosphonomethyl]phosphonate methanol solvate." Acta Crystallographica Section E Structure Reports Online 64, no. 10 (September 6, 2008): o1874—o1875. http://dx.doi.org/10.1107/s160053680802285x.

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Ferguson, G., J. F. Gallagher, W. Vogt, J. Phillips, and G. J. B. Williams. "4-Methyl-2,6-bis(phosphonomethyl)phenol dihydrate." Acta Crystallographica Section C Crystal Structure Communications 49, no. 5 (May 15, 1993): 1024–26. http://dx.doi.org/10.1107/s0108270192011685.

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Dissertations / Theses on the topic "Phosphonomethyl"

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Piunova, Victoria A. "Photopolymerizable “Roundup” Synthesis, Herbicidal Activity and Coating Formulation." Bowling Green State University / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1151340117.

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Ramstedt, Madeleine. "Chemical Processes at the Water-Manganite (γ-MnOOH) Interface." Doctoral thesis, Umeå universitet, Kemi, 2004. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-253.

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The chemistry of mineral surfaces is of great importance in many different areas including natural processes occurring in oceans, rivers, lakes and soils. Manganese (hydr)oxides are one important group to these natural processes, and the thermodynamically most stable trivalent manganese (hydr)oxide, manganit (γ-MnOOH), is studied in this thesis. This thesis summarises six papers in which the surface chemistry of synthetic manganite has been investigated with respect to surface acid-base properties, dissolution, and adsorption of Cd(II) and the herbicide N-(phosphonomethyl)glycine (glyphosate, PMG). In these papers, a wide range of analysis techniques were used, including X-ray photoelectron spectroscopy (XPS), extended X-ray absorption fine structure (EXAFS) spectroscopy, Fourier transform infra-red (FTIR) spectroscopy, atomic force microscopy (AFM), scanning electron microscopy (SEM), X-ray diffraction (XRD), potentiometry, electrophoretic mobility measurements and wet chemical techniques, in order to obtain a more complete understanding of the different processes occurring at the manganite-water interface. From the combined use of these techniques, a 1-pKa acid-base model was established that is valid at pH>6. The model includes a Na+ interaction with the surface: =MnOH2+½ --> =MnOH-½ + H+ log β0 (intr.) = -8.20 = -pHiep =MnOH2+½ + Na+ --> =MnOHNa+½ + H+ log β0 (intr.) = -9.64 At pH<6 the manganite crystals dissolve and disproportionate into pyrolusite (β-MnO2) and Mn(II)-ions in solution according to: 2 γ-MnOOH + 2H+ --> β-MnO2 + Mn2+ + 2H2O log K0 = 7.61 ± 0.10 The adsorption and co-adsorption of Cd(II) and glyphosate at the manganite surface was studied at pH>6. Cd(II) adsorption displays an adsorption edge at pH~8.5. Glyphosate adsorbs over the entire pH range, but the adsorption decreases with increasing pH. When the two substances are co-adsorbed, the adsorption of Cd(II) is increased at low pH but decreased at high pH. The adsorption of glyphosate is increased in the entire pH range in the presence of Cd(II). From XPS, FTIR and EXAFS it was found that glyphosate and Cd(II) form inner sphere complexes. The binary Cd(II)-surface complex is bonded by edge sharing of Mn and Cd octahedra on the (010) plane of manganite. Glyphosate forms inner-sphere complexes through an interaction between the phosphonate group and the manganite surface. The largest fraction of this binary glyphosate complex is protonated throughout the pH range. A ternary surface complex is also present, and its structure is explained as type B ternary surface complex (surface-glyphosate-Cd(II)). The chelating rings between the Cd(II) and glyphosate, found in aqueous complexes, are maintained at the surface, and the ternary complex is bound to the surface through the phosphonate group of the ligand.
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Book chapters on the topic "Phosphonomethyl"

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Larsson, E., and B. Lüning. "Synthesis of integrin intracellular domains containing phosphonomethyl phenylalanine." In Peptides 1994, 739–40. Dordrecht: Springer Netherlands, 1995. http://dx.doi.org/10.1007/978-94-011-1468-4_340.

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Vogt, Walter. "Phosphonomethyl Substituted Phenols a New Class of Absorbers and Extractants for Metals." In New Separation Chemistry Techniques for Radioactive Waste and Other Specific Applications, 207–12. Dordrecht: Springer Netherlands, 1991. http://dx.doi.org/10.1007/978-94-011-3654-9_27.

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Guo, Shenghao, Yanni Gu, Jiayin Qu, and Anne Le. "Bridging the Metabolic Parallels Between Neurological Diseases and Cancer." In The Heterogeneity of Cancer Metabolism, 229–48. Cham: Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-65768-0_17.

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AbstractDespite the many recent breakthroughs in cancer research, oncology has traditionally been seen as a distinct field from other diseases. Recently, more attention has been paid to repurposing established therapeutic strategies and targets of other diseases towards cancer treatment, with some of these attempts generating promising outcomes [1, 2]. Recent studies using advanced metabolomics technologies [3] have shown evidence of close metabolic similarities between cancer and neurological diseases. These studies have unveiled several metabolic characteristics shared by these two categories of diseases, including metabolism of glutamine, gamma-aminobutyric acid (GABA), and N-acetyl-aspartyl-glutamate (NAAG) [4–6]. The striking metabolic overlap between cancer and neurological diseases sheds light on novel therapeutic strategies for cancer treatment. For example, 2-(phosphonomethyl) pentanedioic acid (2-PMPA), one of the glutamate carboxypeptidase II (GCP II) inhibitors that prevent the conversion of NAAG to glutamate, has been shown to suppress cancer growth [6, 7]. These promising results have led to an increased interest in integrating this metabolic overlap between cancer and neurological diseases into the study of cancer metabolism. The advantages of studying this metabolic overlap include not only drug repurposing but also translating existing knowledge from neurological diseases to the field of cancer research. This chapter discusses the specific overlapping metabolic features between cancer and neurological diseases, focusing on glutamine, GABA, and NAAG metabolisms. Understanding the interconnections between cancer and neurological diseases will guide researchers and clinicians to find more effective cancer treatments.
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Tzanetou, Evagelia, and Helen Karasali. "Glyphosate Residues in Soil and Air: An Integrated Review." In Pests, Weeds and Diseases in Agricultural Crop and Animal Husbandry Production. IntechOpen, 2020. http://dx.doi.org/10.5772/intechopen.93066.

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Glyphosate [N-(phosphonomethyl) glycine] (GPS) is currently the most commonly applied herbicide worldwide. Given the widespread use of glyphosate, the investigation of the relationship between glyphosate and soil ecosystem is critical and has great significance for its valid application and environmental safety evaluation. However, although the occurrence of glyphosate residues in surface and groundwater is rather well documented, only few information are available for soils and even fewer for air. Due to this, the importance of developing methods that are effective and fast to determine and quantify glyphosate and its major degradation product, aminomethylphosphonic acid (AMPA), is emphasized. Based on its structure, the determination of this pesticide using a simple analytical method remains a challenge, a fact known as the “glyphosate paradox.” In this chapter a critical review of the existing literature and data comparison studies regarding the occurrence and the development of analytical methods for the determination of pesticide glyphosate in soil and air is performed.
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Conference papers on the topic "Phosphonomethyl"

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Rinnová, Markéta, and Ivan Rosenberg. "3'-N-phosphonomethyl derivatives of pyrrolidine nucleosides related to L-nucleotides." In XIth Symposium on Chemistry of Nucleic Acid Components. Prague: Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 1999. http://dx.doi.org/10.1135/css199902060.

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Zakharieva, Julia I., Alexander L. Vereshchagin, and Vladimir N. Khmelev. "Changing of phytotoxicity n-(phosphonomethyl)-glycine under the influence of frequency of an ultrasonic atomizer." In 2012 IEEE 13th International Conference and Seminar of Young Specialists on Micro/Nanotechnologies and Electron Devices (EDM 2012). IEEE, 2012. http://dx.doi.org/10.1109/edm.2012.6310198.

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Verestchagin, Alexander L., Julia I. Zakharieva, and Vladimir N. Khmelev. "Increase in phytotoxicity of N-phosphonomethyl-glycine during ultrasonic atomization with ultralow doses of organic acids." In 2011 12th International Conference and Seminar of Young Specialists on Micro/Nanotechnologies and Electron Devices (EDM 2011). IEEE, 2011. http://dx.doi.org/10.1109/edm.2011.6006963.

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Zachová, Jana, Ivana Císařová, Miloš Buděšínský, Radek Liboska, Zdeněk Točík, and Ivan Rosenberg. "Crystal and solution structure of 5'-O-(guanosine-2'-O-phosphonomethyl)cytidine, an isopolar nonisosteric phosphonate analog of GpC." In XIth Symposium on Chemistry of Nucleic Acid Components. Prague: Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 1999. http://dx.doi.org/10.1135/css199902233.

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