Relevant bibliographies by topics / Phosphorus atomic ions

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  1. Journal articles
  2. Dissertations / Theses
  3. Book chapters
  4. Conference papers

Academic literature on the topic 'Phosphorus atomic ions'

Author: Grafiati
Published: 4 June 2021
Last updated: 6 February 2022

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Journal articles on the topic "Phosphorus atomic ions"

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Harbol, M. R., J. R. Appling, and A. C. Goren. "State selective production of phosphorus ions via multiphoton ionization of atomic phosphorus." Journal of Chemical Physics 101, no. 4 (August 15, 1994): 2659–64. http://dx.doi.org/10.1063/1.467645.

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HARBOL, M. R., J. R. APPLING, and A. C. GOREN. "ChemInform Abstract: State Selective Production of Phosphorus Ions via Multiphoton Ionization of Atomic Phosphorus." ChemInform 25, no. 49 (August 18, 2010): no. http://dx.doi.org/10.1002/chin.199449029.

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Bacchus-Montabonel, M. C., and Y. S. Tergiman. "Charge transfer processes induced by collision of phosphorus P2+ ions with atomic hydrogen." Chemical Physics Letters 422, no. 1-3 (April 2006): 122–26. http://dx.doi.org/10.1016/j.cplett.2006.02.019.

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Liu, Zhao-yang, Rong-bin Huang, and Lan-sun Zheng. "Bare phosphorus and binary phosphide cluster ions generated by laser ablation." Zeitschrift f�r Physik D Atoms, Molecules and Clusters 38, no. 2 (September 3, 1996): 171–77. http://dx.doi.org/10.1007/s004600050079.

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Furuyama, Taniyuki, Ryosuke Harako, and Nagao Kobayashi. "Structural changes in non-planar octaaryl substituted phthalocyanine phosphorus complexes." Journal of Porphyrins and Phthalocyanines 19, no. 01-03 (January 2015): 500–509. http://dx.doi.org/10.1142/s1088424615500364.

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Phosphorus complexes of non-planar α-octaaryl phthalocyanine derivatives ((α- Ar )8 Pc ), 3a and 3b have been synthesized by introduction of phosphorus(V) ions into free-base Pcs 2a and 2b. 3a and 3b were characterized by MS, 1 H and 31 P NMR spectra. The solid state structure of 3a indicated a ruffled Pc structure due to the small atomic radius of phosphorus, although the corresponding free-base Pc 2a has a saddled Pc structure. The phosphorus complexes showed intense absorption bands (Q-bands) in the near-IR region, while the introduction of electron-donating groups at the peripheral phenyl groups was efficient for additional red-shifting of the Q-band. Electrochemical data revealed that the red-shift of the Q-band is attributable to a decrease in the HOMO–LUMO gap due to significant and moderate stabilization of the LUMO and HOMO, respectively. MO calculations suggested that the phosphorus(V) ion intensified the electronic interaction between the peripheral aryl moieties and the Pc macrocyclic core.
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Luo, Shi-Zhong, Yan-Mei Li, Yan-Ling Niu, Yi Chen, Yu-Yang Jiang, Jing Chen, and Yu-Fen Zhao. "Characterization of Electrospray Ionization Mass Spectrometry for N-Diisopropyloxyphosphoryl Dipeptide Methyl Esters." European Journal of Mass Spectrometry 11, no. 1 (February 2005): 107–17. http://dx.doi.org/10.1255/ejms.733.

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A systematic study of the fragmentation pattern of N-diisopropyloxyphosphoryl (DIPP) dipeptide methyl esters in an electrospray ionization (ESI) tandem mass spectrometry (MS/MS) was presented. A combination of accurate mass measurement and tandem mass spectrometry had been used to characterize the major fragment ions observed in the ESI mass spectrum. It was found that the alkali metal ions acted as a fixed charge site and expelled the DIPP group after transferring a proton to the amide nitrogen. For all the N-phosphoryl dipeptide methyl esters, under the activation of a metal ion, the rearrangement product ion at m/z 163 was observed and confirmed to be the sodium adduct of phosphoric acid mono-isopropyl esters (PAIE), via a specific five-membered penta-coordinated phosphorus intermediate. However, no rearrangement ion was observed when a β-amino acid was at the N-terminal. This could be used to develop a novel method for differentiating isomeric compounds when either α- or β-amino acid are at the N-terminus of peptides. From the [M + Na]+ ESI-MS/MS spectra of N-phosphoryl dipeptide methyl esters (DIPP – Xaa1 – Xaa2 – OMe), the peaks corresponding to the [M + Na – Xaa1 – C3H6]+ were observed and explained. The [M + Na]+ ESI-MS/MS spectra of N-phosphoryl dipeptide methyl esters with Phe located in the C-terminal, such as DIPP–Val–Phe–OMe, DIPP–Leu–Phe–OMe, DIPP–Ile–Phe–OMe, DIPP–Ala–Phe–OMe and DIPP–Phe–Phe–OMe, had characteristic fragmentation. Two unusual gas-phase intramolecular rearrangement mechanisms were first proposed for this fragmentation. These rearrangements were not observed in dipeptide methyl ester analogs which did not contain the DIPP at the N-terminal, suggesting that this moiety was critical for the rearrangement.
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Nakabayashi, N., H. Ohyama, E. Simoen, M. Ikegami, C. Claeys, K. Kobayashi, M. Yoneoka, and K. Miyahara. "Mechanical stress of the electrical performance of polycrystalline-silicon resistors." Journal of Materials Research 16, no. 9 (September 2001): 2579–82. http://dx.doi.org/10.1557/jmr.2001.0354.

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Results are presented of a study on the mechanical stress dependence of the resistance of polycrystalline silicon (Poly-Si) films doped with different atomic species. Two types of Poly-Si film implanted with boron and phosphorus ions were studied, namely, B-doped films of 400 nm and P-doped films of 250 nm thickness, which were deposited by low-pressure chemical vapor deposition at 620 °C on thermally oxidized silicon wafers. The film doping was done by ion implantation at 50 keV, with a dose of boron and phosphorus of 2 × 1014 and 5.3 × 1014 cm−2, respectively. The Poly-Si films were annealed in a N2 ambient at 1000 °C for 20 min to activate the implanted atoms. A controlled amount of external stress was applied to the silicon wafers to study the impact on the electrical performance of the implanted Poly-Si resistors. The resistance of the B-doped Poly-Si films is shown to increase by the mechanical stress, while the resistance of the P-implanted Poly-Si films remained unchanged. It is concluded that this difference is related to the structural differences between Poly-Si films implanted with boron and phosphorus, respectively.
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Djosic, Marija, Miodrag Mitric, and Vesna Miskovic-Stankovic. "The porosity and roughness of electrodeposited calcium phosphate coatings in simulated body fluid." Journal of the Serbian Chemical Society 80, no. 2 (2015): 237–51. http://dx.doi.org/10.2298/jsc140626098d.

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Calcium phosphate coatings were electrochemically deposited on titanium from the aqueous solution of Ca(NO3)2 and NH4H2PO4 with the current density of 10 mA cm-2 for deposition time of 15 min. The obtained brushite coatings, (CaHPO4?2H2O), were converted to hydroxyapatite (HA) by soaking in simulated body fluid (SBF) for 2, 7 and 14 days. The brushite and hydroxyapatite coatings were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM). It was shown that the increase in soaking time increases the porosity, roughness and crystallite domain size of HA coatings and decreases the unit cell parameters and unit cell volume, while does not affect the HA mean pore area. The calcium and phosphorus ions concentrations in SBF were determined by atomic absorption spectroscopy (AAS) and UV-Vis spectroscopy, respectively and the mechanism of HA growth based on dissolution-precipitation was proposed.
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Vilkas, Marius J., and Yasuyuki Ishikawa. "Relativistic multireference many-body perturbation theory calculations on ions of the phosphorus isoelectronic sequence." Journal of Physics B: Atomic, Molecular and Optical Physics 37, no. 24 (December 7, 2004): 4763–78. http://dx.doi.org/10.1088/0953-4075/37/24/004.

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Yin, Yu, Shi Li, Shunbin Wang, Shijie Jia, Jing Ren, Gerald Farrell, Elfed Lewis, and Pengfei Wang. "Ultra-high-resolution detection of Pb2+ ions using a black phosphorus functionalized microfiber coil resonator." Photonics Research 7, no. 6 (May 3, 2019): 622. http://dx.doi.org/10.1364/prj.7.000622.

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Dissertations / Theses on the topic "Phosphorus atomic ions"

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Pastol, Yvon. "Etude de la cristallisation en phase solide de couches minces de silicium implantees." Paris 7, 1987. http://www.theses.fr/1987PA077142.

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Etude des effets de dopage par implantation de bore et de phosphore. Etude du role des defauts d'irradiation dans des couches implantees au silicium. Les couches implantees et non implantees sont cristallisees en phase solide par recuit thermique a basse temperature. Etude de la taille des grains, de la texture, de la morphologie de surface et de la conductivite electriques des couches en fonction de la concentration d'ions implantes
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Zhang, Leifeng. "Ségrégation intergranulaire du phosphore dans les aciers des cuves des REP." Thesis, Normandie, 2018. http://www.theses.fr/2018NORMR166.

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En perspective de la prolongation de la durée de vie en service des REPs, il est de plus en plus important d’obtenir une évaluation fiable de l’évolution de la microstructure des aciers constituant la cuve des REPs et de leurs propriétés correspondantes. Un mécanisme de fragilisation non-durcissante, dû à la ségrégation intergranulaire du P qui affaiblirait la cohésion des joints de grains, pourrait contribuer à la fragilisation et doit donc être étudié. Les présents travaux ont pour objectifs d’étudier la ségrégation intergranulaire du P dans un acier de cuve de réacteur afin (i) de connaître l’influence du type de joint de grain sur la ségrégation du P, (ii) de clarifier l’influence des conditions de vieillissement (vieillissement thermique et irradiation ionique) sur la ségrégation du P et (iii) de faire une comparaison avec les modèles disponibles et proposés ici.Pour cela, une méthodologie corrélative -Diffraction des Électrons Rétrodiffusés (EBSD), Diffraction de Kikuchi en Transmission (TKD) et Sonde Atomique Tomographique (APT) -a été adoptée pour étudier la ségrégation intergranulaire. Les informations cristallographiques (5 paramètres) et la composition chimique ont été collectées et systématiquement corrélées. Les aciers ont une microstructure complexe de ferrite aciculaire et de carbures intergranulaires. La ségrégation des solutés aux joints des grains (joints des grains faiblement désorientés (LAGB), joints des grains fortement désorientés généraux (HAGB) et Σ3HAGBs) et aux interfaces (interfaces carbure-ferrite M2.0-3.2C et interfaces cémentite-ferrite) a été quantifiée. Il existe une ségrégation évidente d'un élément ou de plusieurs espèces chimiques (C, P, Mn, Mo, Cr, Si et Ni) pour tous ces types de défauts plans. Tenant compte de la nature des éléments ségrégants et de la cristallographie du joint de grain, les ségrégations interstitielles et substitutionnelles ont été quantifiées et discutées. Sur la base d’un grand nombre de données, il apparaît que les niveaux moyens des segrégations en P sont plus élevés dans les HAGBs généraux ou les LAGBs que les autres types d'interfaces quel que soit le vieillissement envisagé. Par ailleurs, les résultats expérimentaux ont été comparés avec les résultats prévus par des modèles analytiques pour des systèmes binaires, ternaires et multi-composants. Bien qu'ayant un niveau de ségrégation du P prédit plus élevé, le modèle ternaire Fe-P-C se rapproche le plus des résultats expérimentaux
With expectations for extending the service lifespans of PWRs, it is of great importance to get a reliable evaluation of the microstructural evolution and the corresponding property changes of RPV steels. A non-hardening mechanism, due to intergranular P segregation that impairs the grain boundary (GB) cohesion, may contribute to the embrittlement and thus needs to be studied. The present work aims to investigate the intergranular P segregation behavior in a RPV steel in order to (i) determine the influence of GB type on P segregation behavior, (ii) clarify the influence of ageing conditions (thermal ageing and ion irradiation) on P segregation behavior and (iii) make a comparison with the existing analytical models. To reach these objectives, a correlative - Electron Backscatter Diffraction (EBSD), Transmission Kikuchi Diffraction (TKD) and Atom Probe Tomography (APT) - methodology was adopted to study the GB segregation behavior. The crystallographic information (5 parameters) and chemical composition were collected simultaneously. The steels have a complex microstructure of acicular ferrite and intergranular carbides. The solute segregation at GBs (Low Angle Grain Boundaries (LAGBs), general High Angle Grain Boundaries (HAGBs) and Σ3 HAGBs) and interfaces (M2.0-3.2C carbide-ferrite interfaces and cementite-ferrite interfaces) were quantified. There is an obvious segregation of one element or several chemical species (C, P, Mn, Mo, Cr, Si and Ni) at all boundary types. Taking into account the nature of segregants and the five-parameter GB crystallography, both interstitial and substitutional segregation behaviors were discussed. Based on a large dataset, it appears that the average P segregation levels are higher in general HAGBs or LAGBs than in other boundary types. Besides, the experimental results were compared to the predicted ones from analytical models for binary, ternary and multicomponent systems. Though with a higher predicted P segregation level, the Fe-P-C ternary model seems to better fit the experimental results in all ageing conditions
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Wu, Jing-Yun, and 吳景雲. "A Study on Chelation Modes of Hemilabile Ligands Containing Phosphorus, Nitrogen, and Sulfur Atoms toward Late Transition Metal Ions." Thesis, 2003. http://ndltd.ncl.edu.tw/handle/61537677576524487901.

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博士
國立中山大學
化學系研究所
91
Hemilabile ligands attracted much attention in past thirty years because they were effectively utilized in the field of coordination chemistry and homogenous catalysis. We have synthesized four tridentate iminophosphine ligands (o-Ph2P(C6H4)-C(H)=N-(CH2)n-R, n = 2, R = SnBu, LPNS1; n = 3, R = SMe, LPNS2; n = 3, R = OMe, LPNO3; and n = 3, R = NMe2, LPNN4) and one tridentate aminophosphine ligand (o-Ph2P(C6H4)CH2N(H)(CH2)3NMe2, LPNHN5) in this work. The structures of the iminophosphine copper(I) complexes were determined by the carbon-chain length between imino-nitrogen and third donor atom, the coordination ability of the third donor atom, and the nature of the anions (i.e. its donor ability and atomic radius). An unexpected tetranuclear copper(I) iodide complex [(CuI)2(LPNN4)]2 (16) was obtained due to the larger atomic radius of iodide ion. The ligand LPNN4 displayed versatile coordination behavior after complexing with some late transition metals such as Pd(II), Ag(I), Zn(II), Cd(II). These tridentate ligands may act as PN-chelator or PNE-chelator (E = S, N’). Both chelating and bridging modes were observed at the same time in Cu(I) and Ag(I) complexes. In Zn(II) complex, however, chelating by LPNN4 chelated only occurred through its N donor atoms. In term of the reactivity study of these complexes, we found that the complex [Cu(LPNN4)(CH3CN)0.2](BF4) (17) would successful react with Na(SCN), NaN3, and PhCCH/KOH to generate corresponding substitution products. However when reacted with PhCCC(O)OH/KOH, copper complexes bearing LPNN4 could not give the corresponding substituted carboxylate copper(I) product and gave the complex [Cu(CCPh)(LPNN4)]2 (18) via auto-decarboxylation instead.
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Book chapters on the topic "Phosphorus atomic ions"

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Davies, A. G. "17.9.9 Heteroaromatic compounds containing 1 or 2 nitrogen atoms." In Phosphorus-Centered Radicals, Radicals Centered on Other Heteroatoms, Organic Radical Ions. Part 2, 468–84. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-87641-0_48.

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Davies, A. G. "17.9.10 Heteroaromatic compounds containing 3 or 4 nitrogen atoms." In Phosphorus-Centered Radicals, Radicals Centered on Other Heteroatoms, Organic Radical Ions. Part 2, 485–90. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-87641-0_49.

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Atkins, Peter. "Carbon Footprints: The Wittig Reaction." In Reactions. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199695126.003.0026.

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As a molecular architect working on an atomic construction site you need to be able to build up the carbon skeleton of your project, not merely decorate it with foreign atoms. There are dozens of different ways of doing that, and in this and the next section I shall introduce you to just two of them to give you a taste of what is available. A secondary point is that throughout chemistry you will find reactions denoted by proper nouns, recognizing the chemists who have invented or developed them. One example is that of the ‘Wittig reaction’, which is named after the German chemist Georg Wittig (1897–1987; Nobel Prize 1979). The reaction is used to replace the oxygen atom of a CO group in a molecule by a carbon atom, so that what starts out as decoration becomes part of a growing network of carbon atoms. You need to know that phosphine, PH3, 1, the phosphorus cousin of ammonia, NH3, is a base (Reaction 2). When it accepts a proton it becomes the ion PH4+. The H atoms in that ion can be replaced with other groups of atoms. A replacement that will be of interest is when three of the H atoms have been replaced by benzene rings and the remaining H atom has been replaced by –CH3. The resulting ion is 2. In the presence of a base, such as the hydroxide ion, OH–, the –CH3 group can be induced to release one of its protons, so the positive ion becomes the neutral molecule, 3. Note that there is a partial positive charge on the P atom and a partial negative charge on the C atom of the CH2 group. The presence of that partial negative charge suggests that the species could act as a nucleophile (Reaction 15), a seeker out of positive charge, with the CH2 group the charge-seeking head of the missile. Let’s watch what happens when 3 attacks a molecule with a CO group, specifically 4: perhaps you want to sprout a carbon chain out from the ring and intend to begin by replacing the O atom with a C atom.
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Schweitzer, George K., and Lester L. Pesterfield. "The Nitrogen Group." In The Aqueous Chemistry of the Elements. Oxford University Press, 2010. http://dx.doi.org/10.1093/oso/9780195393354.003.0011.

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The Nitrogen Group of the Periodic Table contains the elements nitrogen N, phosphorus P, arsenic As, antimony Sb, and bismuth Bi. The outer electron structure ns2np3 characterizes all five of the elements, with n representing principal quantum numbers 2, 3, 4, 5, and 6, respectively. The ns2np3 indicates the possibility of oxidation states V, III, and -III. As one goes down the group, the metallic character increases, with N and P being distinctly non-metals, As a metalloid, and Sb and Bi metals. However, the major bonding in most of the compounds of the group is covalent, aqueous cationic species being formed only by Sb and Bi. A covalency of 5 is exhibited by all the elements except N, this being assignable to the considerable energy required to place 10 electrons around the atom. The pentavalent state is the most stable for P, with its stability falling off down the group, as the trivalent state stability increases. Covalent radii in pm are as follows: N (75), P (110), As(122), and Sb(143). Ionic radii (most hypothetical) in pm are these: Sb+3 (90), Sb+5 (74), Bi+3 (117), and Bi+5 (90). a. E–pH diagram. Figure 9.1 depicts the E–pH diagram for N with the soluble species (except H+) at 10−1.0 M. Equations for the lines that separate the species are displayed in the legend. The colorless strong acid nitric acid HNO3, its colorless anion nitrate NO3−, the colorless weak acid nitrous acid HNO2, its colorless anion NO2−, the colorless ammonium ion NH4+, and the colorless hypothetical compound ammonium hydroxide NH4OH are involved.
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Conference papers on the topic "Phosphorus atomic ions"

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Lu, Y. F., X. K. Shen, and H. Ling. "Laser-Induced Breakdown Spectroscopy Combined With Spatial Confinement of Plasmas and Laser-Induced Fluoresence for Trace-Materials Detection." In ASME 2009 Second International Conference on Micro/Nanoscale Heat and Mass Transfer. ASMEDC, 2009. http://dx.doi.org/10.1115/mnhmt2009-18354.

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Laser-induced breakdown spectroscopy (LIBS) with spatial confinement effects and LIBS combined with laser-induced fluorescence (LIBS-LIF) have been investigated to improve the detection sensitivity and element-selectivity of LIBS. An obvious enhancement in the emission intensity of aluminum (Al) atomic lines was observed when a cylindrical wall was placed to spatially confine the plasma plumes. The maximum enhance factor for the emission intensity of Al atomic lines was measured to be around 10. Assuming local thermodynamic equilibrium conditions, the plasma temperatures are estimated to be in a range from 4,000 to 5,800 K. It shows that the plasma temperature increased by around 1,000 K when the cylindrical confinement was applied. Fast images of the laser-induced Al plasmas show that the plasmas were compressed into a smaller volume with a pipe presented. LIBS-LIF has been investigated to overcome the matrix effects of LIBS for the detection of trace uranium (U) in solids. An optical parametric oscillator wavelength-tunable laser was used to resonantly excite the uranium atoms and ions within the plasma plumes generated by a Q-switched Nd:YAG laser. Both atomic and ionic lines can be selected to detect their fluorescence lines. A U concentration of 462 ppm in a glass sample can be detected using this technique at an excitation wavelength of 385.96 nm for resonant excitation of U II and a fluorescence line wavelength of 409.01 nm from U II. The mechanism of spatial confinement effects and the influence of relevant operational parameters of LIBS-LIF are discussed. In this work, detection in open air of trace phosphorus (P) in steels using LIBS-LIF has also been investigated. The optical parametric oscillator laser was used to resonantly excite the P atoms within plasma plumes generated by the Q-switched Nd:YAG laser. A set of steel samples with P concentrations from 3.9 to 720 ppm were analyzed using LIBS-LIF at wavelengths of 253.40 and 253.56 nm for resonant excitation of P atoms and fluorescence lines at wavelengths of 213.55 and 213.62 nm. The calibration curves were measured to determine the limit of detection for P in steels, which is estimated to be around 0.7 ppm.
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Basu, S., B. J. Lee, and Z. M. Zhang. "Infrared Radiative Properties of Heavily Doped Silicon at Room Temperature." In ASME 2007 International Mechanical Engineering Congress and Exposition. ASMEDC, 2007. http://dx.doi.org/10.1115/imece2007-41266.

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This paper describes an experimental investigation on the infrared radiative properties of heavily-doped silicon (Si) at room temperature. Lightly-doped Si wafers were ion implanted with boron and phosphorus atoms to doping concentrations of 1×1020 and 1×1021 cm−3. Rapid thermal annealing was performed to activate the implanted dopants. A Fourier-transform infrared spectrometer was employed to measure the normal transmittance as well as reflectance of the samples in the spectral region from 2 to 20 μm. Accurate carrier mobility and ionization models were identified after carefully reviewing the available literature, and then incorporated into Drude model to predict the dielectric function of doped Si. The radiative properties of doped Si samples were calculated by treating the doped region as multilayer thin films of different doping concentrations on a thick Si substrate. The measured spectral transmittance and reflectance agree well with the model predictions. The results obtained from this study will facilitate the future applications of heavily-doped Si in semiconductor as well as MEMS devices.
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Krewinkel, Robert, Jens Färber, Martin Lauer, Dirk Frank, Ulrich Orth, Alvaro Yañez Gonzalez, Christopher Pilgrim, et al. "Validation of Surface Temperature Measurements on a Combustor Liner Under Full-Load Conditions Using a Novel Thermal History Paint." In ASME Turbo Expo 2016: Turbomachinery Technical Conference and Exposition. American Society of Mechanical Engineers, 2016. http://dx.doi.org/10.1115/gt2016-56669.

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The ever-increasing requirements on gas turbine efficiency, which are at least partially met by increasing firing temperatures, and the simultaneous demand for reduced emissions, necessitate much more accurate calculations of the combustion process and combustor wall temperatures. Thermocouples give locally very accurate measurements of these temperatures, but there is a practical limit to the amount of measurement points. Thermal paints are another established measurement technique, but are toxic and at the same time require dedicated, short-duration tests. Thermal History Paints (THPs) provide an innovative alternative to the aforementioned techniques, but so far only a limited number of tests has been conducted under real engine conditions. THPs are similar in their chemical and physical make-up to conventional thermographic phosphors which have been successfully used in gas turbine applications for on-line temperature detection before. A typical THP comprises of oxide ceramic pigments and a water based binder. The ceramic is synthesized to be amorphous and when heated it crystallizes, permanently changing the microstructure. The ceramic is doped with lanthanide ions to make it phosphorescent. The lanthanide ions act as atomic level sensors and as the structure of the material changes, so do the phosphorescent properties of the material. By measuring the phosphorescence the maximum temperature of exposure can be determined through calibration, enabling post operation measurements at ambient conditions. This paper describes a test in which THP was applied to an impingement-cooled front panel from a combustor of an industrial gas turbine. Since this component sees a wide range of temperatures, it is ideally suited for the testing of the measurement techniques under real engine conditions. The panel was instrumented with a thermocouple and thermal paint was applied to the cold side of the impingement plate. THP was applied to the hot-gas side of this plate for validation against the other measurement techniques and to evaluate its resilience against the reacting hot gas environment. The durability and temperature results of the three different measurement techniques are discussed. The results demonstrate the benefits of THPs as a new temperature profiling technique. It is shown that the THP exhibited greater durability compared to the conventional thermal paint. Furthermore, the new technology provided detailed measurements down to millimeters indicating local temperature variations and global variations over the complete component.
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