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Journal articles on the topic 'Phosphorus functionalization'

Author: Grafiati

Published: 4 June 2025

Last updated: 1 August 2025

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1

Puziy, A. M., O. I. Poddubnaya, B. Gawdzik, M. Sobiesiak, and M. M. Tsyba. "Functionalization of Carbon and Silica Gel by Phosphoric Acid." Adsorption Science & Technology 25, no. 8 (2007): 531–42. http://dx.doi.org/10.1260/0263-6174.25.8.531.

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Functionalization of polymer-based carbon (SCS-3) and silica gel (SG60) by phosphoric acid at 800°C was investigated. It was shown that heat treatment of carbon and silica gel in the presence of phosphoric acid at 800°C provides a way of functionalizing materials with phosphorus-containing surface groups. Functionalization of the finished carbon occurs as a surface reaction while destruction of the silica gel structure was observed. Functionalization with phosphoric acid creates new acid surface groups — phosphorus-containing and oxygen-containing in the case of carbon and only phosphorus-cont

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2

Budnikova, Y. H., Y. M. Kargin, and O. G. Sinyashin. "Electrochemical Functionalization of White Phosphorus." Phosphorus, Sulfur, and Silicon and the Related Elements 144, no. 1 (1999): 565–68. http://dx.doi.org/10.1080/10426509908546307.

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3

Abellán, Gonzalo, Vicent Lloret, Udo Mundloch, et al. "Noncovalent Functionalization of Black Phosphorus." Angewandte Chemie International Edition 55, no. 47 (2016): 14557–62. http://dx.doi.org/10.1002/anie.201604784.

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4

Abellán, Gonzalo, Vicent Lloret, Udo Mundloch, et al. "Noncovalent Functionalization of Black Phosphorus." Angewandte Chemie 128, no. 47 (2016): 14777–82. http://dx.doi.org/10.1002/ange.201604784.

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5

Hindenberg, Philip, Frank Rominger, and Carlos Romero‐Nieto. "Phosphorus Post‐Functionalization of Diphosphahexaarenes." Chemistry – A European Journal 25, no. 57 (2019): 13146–51. http://dx.doi.org/10.1002/chem.201901837.

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6

Riegel, Bernhard, Arno Pfitzner, Gernot Heckmann, Ekkehard Fluck, and Herbert Binder. "Phosphorus-Boron and Phosphorus-Silicon Ring Systems Functionalization of Phosphorus Ring Systems." Phosphorus, Sulfur, and Silicon and the Related Elements 93, no. 1-4 (1994): 173–76. http://dx.doi.org/10.1080/10426509408021809.

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7

Ma, Tingting, Hao Huang, Wenfei Guo, et al. "Recent Progress in Black Phosphorus Sensors." Journal of Biomedical Nanotechnology 16, no. 7 (2020): 1045–64. http://dx.doi.org/10.1166/jbn.2020.2963.

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Black phosphorus (BP) is a new two-dimensional material with many unique properties, such as great biocompatibility, excellent surface activity, high carrier mobility, and tunable bandgap. Black phosphorus has been particularly attractive in sensor. However, black phosphorus isolated by traditional methods is easily oxidized and degraded by air, with poor stability, which limits its application as sensors. The modification and functionalization of black phosphorus enhance the stability, sensitivity, selectivity and biocompatibility of its application in sensor. This review describes recent pro

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8

Liu, Yajuan, Muqing Chen, and Shangfeng Yang. "Chemical functionalization of 2D black phosphorus." InfoMat 3, no. 3 (2021): 231–51. http://dx.doi.org/10.1002/inf2.12171.

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9

Dib, Hanna, Jérémy Rebière, Cyrille Rebout, et al. "PEG-cored phosphorus dendrimers: Synthesis and functionalization." Results in Chemistry 4 (January 2022): 100304. http://dx.doi.org/10.1016/j.rechem.2022.100304.

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10

Budnikova, Yulia H., Dmitry G. Yakhvarov, and Oleg G. Sinyashin. "Electrocatalytic eco-efficient functionalization of white phosphorus." Journal of Organometallic Chemistry 690, no. 10 (2005): 2416–25. http://dx.doi.org/10.1016/j.jorganchem.2004.11.008.

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11

Islam, Muhammad Amirul, Md Hosnay Mobarok, Regina Sinelnikov, Tapas K. Purkait, and Jonathan G. C. Veinot. "Phosphorus Pentachloride Initiated Functionalization of Silicon Nanocrystals." Langmuir 33, no. 35 (2017): 8766–73. http://dx.doi.org/10.1021/acs.langmuir.7b00518.

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12

Wild, Stefan, Xuan Thong Dinh, Harald Maid, Frank Hauke, Gonzalo Abellán, and Andreas Hirsch. "Quantifying the Covalent Functionalization of Black Phosphorus." Angewandte Chemie International Edition 59, no. 45 (2020): 20230–34. http://dx.doi.org/10.1002/anie.202008646.

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13

Hu, Zehua, Tianchao Niu, Rui Guo, et al. "Two-dimensional black phosphorus: its fabrication, functionalization and applications." Nanoscale 10, no. 46 (2018): 21575–603. http://dx.doi.org/10.1039/c8nr07395c.

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14

Kuchkaev, Aidar M., Airat M. Kuchkaev, Aleksander V. Sukhov, et al. "In-Situ Electrochemical Exfoliation and Methylation of Black Phosphorus into Functionalized Phosphorene Nanosheets." International Journal of Molecular Sciences 24, no. 4 (2023): 3095. http://dx.doi.org/10.3390/ijms24043095.

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Two-dimensional black phosphorus (BP) has attracted great attention as a perspective material for various applications. The chemical functionalization of BP is an important pathway for the preparation of materials with improved stability and enhanced intrinsic electronic properties. Currently, most of the methods for BP functionalization with organic substrates require either the use of low-stable precursors of highly reactive intermediates or the use of difficult-to-manufacture and flammable BP intercalates. Herein we report a facile route for simultaneous electrochemical exfoliation and meth

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15

Scheloske, Michael, Boris Naydenov, Carola Meyer, and Wolfgang Harneit. "Synthesis and Functionalization of Fullerenes Encapsulating Atomic Phosphorus." Israel Journal of Chemistry 46, no. 4 (2006): 407–12. http://dx.doi.org/10.1560/ijc_46_4_407.

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16

Khusainova, Narkis, Goulnara Garipova, Tat'yana Zyablikova, Rafael Cherkasov, and Arkady Pudovik. "Functionalization of Cyclic Derivatives of Two-Coordinated Phosphorus." Phosphorus, Sulfur, and Silicon and the Related Elements 177, no. 8-9 (2002): 2231. http://dx.doi.org/10.1080/10426500213366.

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17

Li, Qiang, Qionghua Zhou, Xianghong Niu, Yinghe Zhao, Qian Chen, and Jinlan Wang. "Covalent Functionalization of Black Phosphorus from First-Principles." Journal of Physical Chemistry Letters 7, no. 22 (2016): 4540–46. http://dx.doi.org/10.1021/acs.jpclett.6b02192.

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18

Palomo, José, Juan J. Ternero-Hidalgo, Juana M. Rosas, José Rodríguez-Mirasol, and Tomás Cordero. "Selective nitrogen functionalization of phosphorus-containing activated carbons." Fuel Processing Technology 156 (February 2017): 438–45. http://dx.doi.org/10.1016/j.fuproc.2016.10.006.

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19

Larré,, Christophe, Bruno Donnadieu, Anne-Marie Caminade, and Jean-Pierre Majoral. "Phosphorus-Containing Dendrimers: Chemoselective Functionalization of Internal Layers." Journal of the American Chemical Society 120, no. 16 (1998): 4029–30. http://dx.doi.org/10.1021/ja973994a.

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20

Liu, Jianming, Shanshan Zhao, Weiwei Song, et al. "Silver-Catalyzed Carbon-Phosphorus Functionalization for Polyheterocycle Formation." Advanced Synthesis & Catalysis 359, no. 4 (2017): 609–15. http://dx.doi.org/10.1002/adsc.201600850.

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21

Borger, Jaap E., Martijn S. Bakker, Andreas W. Ehlers, Martin Lutz, J. Chris Slootweg, and Koop Lammertsma. "Functionalization of P4 in the coordination sphere of coinage metal cations." Chemical Communications 52, no. 16 (2016): 3284–87. http://dx.doi.org/10.1039/c5cc10037b.

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22

Caporali, Maria, Manuel Serrano-Ruiz, Francesca Telesio, et al. "Decoration of exfoliated black phosphorus with nickel nanoparticles and its application in catalysis." Chemical Communications 53, no. 79 (2017): 10946–49. http://dx.doi.org/10.1039/c7cc05906j.

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A new surface functionalization of exfoliated black phosphorus has been carried out with Ni nanoparticles. The nanohybrid catalyzed the semihydrogenation of phenylacetylene achieving high selectivity to styrene.

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23

Lei, Wanying, Gang Liu, Jin Zhang, and Minghua Liu. "Black phosphorus nanostructures: recent advances in hybridization, doping and functionalization." Chemical Society Reviews 46, no. 12 (2017): 3492–509. http://dx.doi.org/10.1039/c7cs00021a.

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24

Julino, Markus, Uwe Bergsträßer, and Manfred Regitz. "Organophosphorus Compounds; 104. Functionalization of a Pentacyclic Phosphorus-Carbon Cage Compound at Phosphorus." Synthesis 1996, no. 01 (1996): 87–99. http://dx.doi.org/10.1055/s-1996-4161.

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25

Mitrović, Aleksandra, Gonzalo Abellán, and Andreas Hirsch. "Covalent and non-covalent chemistry of 2D black phosphorus." RSC Advances 11, no. 42 (2021): 26093–101. http://dx.doi.org/10.1039/d1ra04416h.

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This review presents novel concepts and strategies on the chemical functionalization of black phosphorus (BP), both non-covalent and covalent, emphazising the current synthetic challenges and providing fundamental insights into the chemistry of BP.

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26

Kuchkaev, Aidar M., Airat M. Kuchkaev, Aleksander V. Sukhov, et al. "Covalent Functionalization of Black Phosphorus Nanosheets with Dichlorocarbenes for Enhanced Electrocatalytic Hydrogen Evolution Reaction." Nanomaterials 13, no. 5 (2023): 826. http://dx.doi.org/10.3390/nano13050826.

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Two-dimensional black phosphorus (BP) has emerged as a perspective material for various micro- and opto-electronic, energy, catalytic, and biomedical applications. Chemical functionalization of black phosphorus nanosheets (BPNS) is an important pathway for the preparation of materials with improved ambient stability and enhanced physical properties. Currently, the covalent functionalization of BPNS with highly reactive intermediates, such as carbon-free radicals or nitrenes, has been widely implemented to modify the material’s surface. However, it should be noted that this field requires more

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27

He, Zuoliang, Rui Liu, Wanyu Shan, et al. "Stabilizing Black Phosphorus via Covalent Functionalization of Solvent Formamide." Advanced Materials Interfaces 8, no. 11 (2021): 2002247. http://dx.doi.org/10.1002/admi.202002247.

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28

He, Guozhen, Tao Dong, Zhaochu Yang, and Per Ohlckers. "Tuning 2D Black Phosphorus: Defect Tailoring and Surface Functionalization." Chemistry of Materials 31, no. 24 (2019): 9917–38. http://dx.doi.org/10.1021/acs.chemmater.9b03639.

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29

Thurakkal, Shameel, and Xiaoyan Zhang. "Covalent functionalization of two-dimensional black phosphorus nanosheets with porphyrins and their photophysical characterization." Materials Chemistry Frontiers 5, no. 6 (2021): 2824–31. http://dx.doi.org/10.1039/d0qm00997k.

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Photoactive porphyrins are covalently attached onto black phosphorus nanosheets (BPNSs) through a direct phosphorus–carbon linkage using diazonium chemistry. This hybrid material is further studied using different characterization techniques.

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30

Hissler, Muriel, Pierre-Antoine Bouit, Denis Tondelier, and Bernard Geffroy. "Organophosphorus emitters for OLEDs." EPJ Web of Conferences 266 (2022): 06006. http://dx.doi.org/10.1051/epjconf/202226606006.

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In this paper, we present the development of OLEDs using organophosphorus derivatives as emitters. In this study, we were able to show that the structural variations carried out on phospholes, phosphinines and phosphepines (functionalization of the phosphorus atom, nature of the substituents) make it possible to modulate the emission wavelengths and, thus, the emission colour of the diodes. Using this concept, we were able to develop TADF and chiral organophosphorus emitters and hybrids emitting at different wavelengths which can be used for the development of OLEDs. The diode structures used

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31

Normand, Adrien T., Constantin G. Daniliuc, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker. "Direct P-functionalization of azobenzene by a cationic phosphidozirconocene complex." Dalton Transactions 45, no. 9 (2016): 3711–14. http://dx.doi.org/10.1039/c6dt00416d.

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32

Ienco, Andrea, Gabriele Manca, Maurizio Peruzzini, and Carlo Mealli. "Modelling strategies for the covalent functionalization of 2D phosphorene." Dalton Transactions 47, no. 48 (2018): 17243–56. http://dx.doi.org/10.1039/c8dt03628d.

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This paper is a comparative outline of the potential acid–base adducts formed by an unsaturated main group or transition metal species and P atoms of phosphorene (P<sub>n</sub>), which derives from black phosphorus exfoliation.

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33

Bhattacharyya, Koyel X., Sébastien Dreyfuss, Nathalie Saffon-Merceron, and Nicolas Mézailles. "P4functionalization by hydrides: direct synthesis of P–H bonds." Chemical Communications 52, no. 29 (2016): 5179–82. http://dx.doi.org/10.1039/c6cc01683a.

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Functionalization of white phosphorus (P<sub>4</sub>) by hydride sources MBH<sub>4</sub>and LiBEt<sub>3</sub>H leads to the formation of HP<sub>4</sub>M and LiPH<sub>2</sub>(BEt<sub>3</sub>)<sub>2</sub>respectively.

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34

Kennedy, Noel, Ray Duffy, Luke Eaton, et al. "Phosphorus monolayer doping (MLD) of silicon on insulator (SOI) substrates." Beilstein Journal of Nanotechnology 9 (August 6, 2018): 2106–13. http://dx.doi.org/10.3762/bjnano.9.199.

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This paper details the application of phosphorus monolayer doping of silicon on insulator substrates. There have been no previous publications dedicated to the topic of MLD on SOI, which allows for the impact of reduced substrate dimensions to be probed. The doping was done through functionalization of the substrates with chemically bound allyldiphenylphosphine dopant molecules. Following functionalization, the samples were capped and annealed to enable the diffusion of dopant atoms into the substrate and their activation. Electrical and material characterisation was carried out to determine t

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35

Radinger, Hannes, Mark Hartmann, Marius Ast, et al. "Understanding efficient phosphorus-functionalization of graphite for vanadium flow batteries." Electrochimica Acta 409 (March 2022): 139971. http://dx.doi.org/10.1016/j.electacta.2022.139971.

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36

Larré,, Christophe, Daniel Bressolles, Cédric Turrin, Bruno Donnadieu, Anne-Marie Caminade, and Jean-Pierre Majoral. "Chemistry within Megamolecules: Regiospecific Functionalization after Construction of Phosphorus Dendrimers." Journal of the American Chemical Society 120, no. 50 (1998): 13070–82. http://dx.doi.org/10.1021/ja982778e.

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37

Marchand, Patrice, Laurent Griffe, Anne-Marie Caminade, Jean-Pierre Majoral, Mathias Destarac, and Frédéric Leising. "Thioacylation Reactions for the Surface Functionalization of Phosphorus-Containing Dendrimers." Organic Letters 6, no. 8 (2004): 1309–12. http://dx.doi.org/10.1021/ol049720r.

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38

Zhang, Lei, Lin-Feng Gao, Liuxiao Li, et al. "Negatively charged 2D black phosphorus for highly efficient covalent functionalization." Materials Chemistry Frontiers 2, no. 9 (2018): 1700–1706. http://dx.doi.org/10.1039/c8qm00237a.

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39

Hennersdorf, Felix, Julia Frötschel, and Jan J. Weigand. "Selective Derivatization of a Hexaphosphane from Functionalization of White Phosphorus." Journal of the American Chemical Society 139, no. 41 (2017): 14592–604. http://dx.doi.org/10.1021/jacs.7b07704.

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40

Kasaka, Tatsuji, Makoto Kyoda, Ken Taketazu, et al. "FUNCTIONALIZATION OF AMINOPHOSPHONIC CHLORIDES AND SYNTHESIS OF PHOSPHORUS HETEROCYCLIC COMPOUNDS." Phosphorus, Sulfur, and Silicon and the Related Elements 113, no. 1-4 (1996): 59–65. http://dx.doi.org/10.1080/10426509608046378.

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41

Sofer, Zdeněk, Jan Luxa, Daniel Bouša, et al. "The Covalent Functionalization of Layered Black Phosphorus by Nucleophilic Reagents." Angewandte Chemie 129, no. 33 (2017): 10023–28. http://dx.doi.org/10.1002/ange.201705722.

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42

Wild, Stefan, Michael Fickert, Aleksandra Mitrovic, et al. "Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus." Angewandte Chemie International Edition 58, no. 17 (2019): 5763–68. http://dx.doi.org/10.1002/anie.201811181.

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43

Sofer, Zdeněk, Jan Luxa, Daniel Bouša, et al. "The Covalent Functionalization of Layered Black Phosphorus by Nucleophilic Reagents." Angewandte Chemie International Edition 56, no. 33 (2017): 9891–96. http://dx.doi.org/10.1002/anie.201705722.

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44

Rottschäfer, Dennis, Sebastian Blomeyer, Beate Neumann, Hans-Georg Stammler, and Rajendra S. Ghadwal. "Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides." Chemical Science 10, no. 48 (2019): 11078–85. http://dx.doi.org/10.1039/c9sc04441h.

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A series of unique C<sub>2</sub>P<sub>3</sub>-ring compounds [(ADC<sup>Ar</sup>)P<sub>3</sub>] (4) are readily accessible in an almost quantitative yield by the direct functionalization of white phosphorus (P<sub>4</sub>) with appropriate anionic dicarbenes [Li(ADC<sup>Ar</sup>)].

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45

Turrin, Cédric-Olivier, Valérie Maraval, and Anne-Marie Caminade. "Investigation of Phosphorus Dendrons and Their Properties for the Functionalization of Materials." Journal of Composites Science 9, no. 8 (2025): 382. https://doi.org/10.3390/jcs9080382.

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Dendrons, also named dendritic wedges, are a kind of molecular tree, having a branched structure linked to a functional core. The functional core can be used in particular for the functionalization of materials. Different types of dendrons are known, synthesized either by a convergent process, from the external part to the core, or by a divergent process from the core to the external part. Polyphosphorhydrazone (PPH) dendrons are always synthesized by a divergent process, which enables a fine-tuning of both the core function and the external functions. They have been used for the functionaliza

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46

Quílez-Bermejo, Javier, Alessio Ghisolfi, Daniel Grau-Marín, Emilio San-Fabián, Emilia Morallón, and Diego Cazorla-Amorós. "Post-synthetic efficient functionalization of polyaniline with phosphorus-containing groups. Effect of phosphorus on electrochemical properties." European Polymer Journal 119 (October 2019): 272–80. http://dx.doi.org/10.1016/j.eurpolymj.2019.07.048.

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47

Favret, Jeanne M., and Sergei V. Dzyuba. "Synthetic Approaches Toward Phosphorus-Containing BODIPY and Squaraine Dyes: Enhancing Versatility of Small-Molecule Fluorophores." Molecules 30, no. 1 (2024): 116. https://doi.org/10.3390/molecules30010116.

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Phosphorus-containing fluorophores provide a versatile framework for tailoring photophysical properties, enabling the design of advanced fluorogenic materials for various applications. Boron dipyrromethene (BODIPY) and squaraine dyes are of interest due to their multifaceted modularity and synthetic accessibility. Incorporating phosphorus-based functional groups into BODIPY or squaraine scaffolds has been achieved through a plethora of synthetic methods, including post-dye assembly functionalization. These modifications often influence key spectroscopic properties and molecular functionality b

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48

Hamad, Hesham, Jesica Castelo-Quibén, Sergio Morales-Torres, Francisco Carrasco-Marín, Agustín Pérez-Cadenas, and Francisco Maldonado-Hódar. "On the Interactions and Synergism between Phases of Carbon–Phosphorus–Titanium Composites Synthetized from Cellulose for the Removal of the Orange-G Dye." Materials 11, no. 9 (2018): 1766. http://dx.doi.org/10.3390/ma11091766.

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Carbon–phosphorus–titanium composites (CPT) were synthesized by Ti-impregnation and carbonization of cellulose. Microcrystalline cellulose used as carbon precursor was initially dissolved by phosphoric acid (H3PO4) to favor the Ti-dispersion and the simultaneous functionalization of the cellulose chains with phosphorus-containing groups, namely phosphates and polyphosphates. These groups interacted with the Ti-precursor during impregnation and determined the interface transformations during carbonization as a function of the Ti-content and carbonization temperature. Amorphous composites with h

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49

Hu, Rong-Bin, Hong-Li Wang, Hong-Yu Zhang, Heng Zhang, Yan-Na Ma, and Shang-dong Yang. "P(O)R2-directed Pd-catalyzed C–H functionalization of biaryl derivatives to synthesize chiral phosphorous ligands." Beilstein Journal of Organic Chemistry 10 (September 2, 2014): 2071–76. http://dx.doi.org/10.3762/bjoc.10.215.

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Chiral phosphorus ligands have been widely used in transition metal-catalyzed asymmetric reactions. Herein, we report a new synthesis approach of chiral biaryls containing a phosphorus moiety using P(O)R2-directed Pd-catalyzed C–H activation; the functionalized products are produced with good enantioselectivity.

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50

Papis, Marta, Francesca Foschi, Sara Colombo, Egle Maria Beccalli, Camilla Loro, and Gianluigi Broggini. "Copper-Catalyzed/Hypervalent Iodine-Mediated Functionalization of Unactivated Compounds." Catalysts 13, no. 9 (2023): 1243. http://dx.doi.org/10.3390/catal13091243.

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The functionalization of unactivated substrates through the combination of copper catalysts and hypervalent iodine reagents represents a versatile tool in organic synthesis to access various classes of compounds. The hypervalent iodine derivatives can be used simply as oxidizing agents to regenerate the catalytic species or they can associate the functionalization of the starting material. In this review, special attention will be paid to methodologies which provide the introduction of nucleophiles into the reagent by use of suitable benziodoxol(on)es or iodonium salts. Many reactions concern

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