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Dissertations / Theses on the topic 'Photocatalysis'

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1

He, Jijiang. "Preparation and photocatalysis of graphite carbon nitride based photocatalysts." Thesis, Curtin University, 2015. http://hdl.handle.net/20.500.11937/521.

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The connection between ritual and the interior is interrogated through a theoretical framework integrating Van Gennep’s Rites of Passage Theory and Turner’s Theory of Liminality. A multi-faceted methodological framework is developed from the interrogation of the disciplinary edges of multiple methodologies, addressing the experiential, cultural and subjective dimensions of ritual. This new way of exploring the interior demonstrates how knowledge can be acquired from the body’s immersion in unfolding ritual situations, revealing elements of ritual and interior in relation to one another and the
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2

Zhou, Ruixin. "SEMICONDUCTOR PHOTOCATALYSIS: MECHANISMS, PHOTOCATALYTIC PERFORMANCES AND LIFETIME OF REDOX CARRIERS." UKnowledge, 2017. http://uknowledge.uky.edu/chemistry_etds/85.

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Photocatalytic reactions mediated by semiconductors such as ZnS, TiO2, ZnO, etc. can harvest solar energy into chemical bonds, a process with important prebiotic and environmental chemistry applications. The recycling of CO2 into organic molecules (e.g., formate, methane, and methanol) facilitated by irradiated semiconductors such as colloidal ZnS nanoparticles has been demonstrated. ZnS can also drive prebiotic reactions from the reductive tricarboxylic acid (rTCA) cycle such as the reduction of fumarate to succinate. However, the mechanism of photoreduction by ZnS of the previous reaction ha
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3

Plumejeau, Sandrine. "Croissance de TiO₂ en surface de fibres de cellulose pour l'élaboration de filtres photocatalytiques." Thesis, Montpellier, 2016. http://www.theses.fr/2016MONTT230/document.

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La dépollution est aujourd’hui un enjeu majeur pour la protection de l’environnement et un développement durable. Les technologies membranaires et les procédés d’oxydation avancée jouent un rôle de plus en plus important dans le traitement de l'eau que ce soit pour la production d’eau potable que pour le traitement des eaux usées urbaines ou industrielles. La photocatalyse hétérogène est un procédé d’oxydation avancée permettant la génération des espèces très oxydantes comme les radicaux OH•, en présence d’eau et de dioxygène, lors de l’irradiation de certains solides semi-conducteurs au premi
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4

Guo, Muyao, and 郭牧遥. "Metal oxide photocatalysis." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2013. http://hub.hku.hk/bib/B50434457.

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Photocatalysis has been attracting much research interest because of its wide applications in renewable energy and environmental remediation. Among the photocatalysts, metal oxide semiconductors are the best choice due to distinctive properties, durability and cost effectiveness. However, the mechanisms of photocatalysis are still not entirely clear and the photocatalytic activity of the metal oxide materials needs to be improved. Therefore, this thesis concentrates on the study of the photocatalytic mechanism and the factors affecting the photocatalytic activity. The photocatalysis of diff
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5

Jackson, S. A. "Intermediates in photocatalysis." Thesis, University of Nottingham, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.384288.

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6

Qiao, Yu. "Preparation, Characterization, and Evaluation of Photocatalytic Properties of a Novel NaNbO3/Bi2WO6 Heterostructure Photocatalyst for Water Treatment." Thesis, Université d'Ottawa / University of Ottawa, 2018. http://hdl.handle.net/10393/38080.

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Semiconductor-based heterogeneous photocatalysis, as one of the advanced oxidation processes that makes use of semiconductors and inexhaustible solar light, has recently been extensively studied and applied to water decontamination. However, due to low light absorption efficiencies and severe electron-hole recombination, modifications on semiconductor structures are required in order to enhance their photocatalytic performance. Heterogeneous photocatalyst composites, taking advantage of the improved light absorption efficiency as well as the facilitated electron-hole separation at the interfac
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7

Yatmaz, Huseyin Cengiz. "Photocatalysis of organic effluents." Thesis, University of Newcastle Upon Tyne, 1993. http://hdl.handle.net/10443/271.

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Heterogeneous photocatalytic oxidation is a relatively new technology for the destruction of toxic organic substances in water and so far has concentrated on reaction mechanisms and kinetics, but the engineering side was hardly touched. In this study a detailed investigation for suitable reactor design has been carried out using three different reactor types. An annular photoreactor was used with two different lamps with different intensities; low pressure and medium pressure mercury lamps. Two types of Ti02 powder catalysts Degussa P-25 and Tioxide PCi were used as slurry solutions and Deguss
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8

O'Rourke, Christopher. "Photocatalysis for organic synthesis." Thesis, Queen's University Belfast, 2014. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.675420.

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A wide range of commercially available self-cleaning materials/products are now available, from architectural materials, such as; glass, paint, plastics, and concrete, to water and air purification systems. These products exploit the destructive oxidative nature of SPC to purify air and water. In contrast, this thesis introduces the less well studied use of SPC to mediate the synthesis of a range of useful organic species, and aims to develop a fast screening process for monitoring such reactions to aid future developments in SPC mediated organic synthesis. It is demonstrated that NMR is a ver
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9

Cornu, Catherine J. G. Hoffmann Michael R. "Photocatalysis under periodic illumination." Diss., Pasadena, Calif. : California Institute of Technology, 2002. http://resolver.caltech.edu/CaltechETD:etd-05082006-143046.

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10

Mercer, Sarah M. "Heterogeneous photocatalysis: Design and experimental characterization of a new photocatalytic reactor for wastewater treatment." Thesis, University of Ottawa (Canada), 2006. http://hdl.handle.net/10393/27393.

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The objective of this study is to promote photocatalytic wastewater treatment by proposing a reactor design that employs a catalyst-coated, rotating, corrugated drum to increase the surface area, induce agitation and promote reactant and photon transfer to the surface. Corrugation profiles with surface areas ranging from 405 cm2 to 3650 cm2 were considered---the addition of corrugations improved the phenol degradation rate by up to 200%. Based on an analysis of rotational speed and initial pollutant concentration, the reaction was found to be limited by the kinetics at 20 ppm and 40 ppm, but l
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11

Tran, Duc Trung. "Elaboration et mise en œuvre de membranes composites polymère-TiO2 faiblement colmatantes." Thesis, Montpellier, 2019. http://www.theses.fr/2019MONTG023.

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Cette thèse porte sur l’élaboration et l’étude des performances de membranes d’ultrafiltration PVDF-TiO2 possédant des propriétés anti-colmatantes et photo-induites. La membrane est obtenue par application de la méthode de séparation de phases induite par un non-solvant sur un collodion de polyfuorure de vinylidène au sein duquel ont été incorporées des nanoparticules de TiO2. Il est montré : i) que la presence des nanoparticules de TiO2 les propriétés membranaires, et notamment le flux de perméat, par rapport à la membrane PVDF ; ii) que l’augmentation de la température de préparation de la m
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12

Bai, Xiaofei. "Effet de taille et du dopage sur la structure, les transitions et les propriétés optiques de particules du multiferroïque BiFeO₃ pour des applications photocatalytiques." Thesis, Université Paris-Saclay (ComUE), 2016. http://www.theses.fr/2016SACLC013/document.

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Ce travail de thèse expérimentale a été consacré à la synthèse par des méthodes de chimie par voie humide de nanoparticules à base du multiferroïque BiFeO3 et à leur caractérisation, avec comme objectif finale des applications photocatalytiques. Ce matériau présente une bande interdite, avec un gap de 2.6eV, qui permet la photo-génération de porteurs de charges dans le visible faisant ainsi de BiFeO3 un système intéressant pour des processus photo-induits. Ce travail s’est en particulier focalisé à caractériser les propriétés de nanoparticules à base de BiFeO3 en vue de comprendre l’effet de s
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13

Wang, Fan. "Visible light photocatalysis with supported metal nanoparticles for organic synthesis." Thesis, Queensland University of Technology, 2017. https://eprints.qut.edu.au/103567/1/Fan_Wang_Thesis.pdf.

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This project was a step forward in developing new effective photocatalysts for fine organic synthesis under visible light irradiation. These kind of new photocatalysts are able to facilitate reaction rates by using visible light under moderate reaction conditions through a green, economical and environmentally friendly pathway. This thesis investigated the catalyst synthesis, characterization and the application in organic reactions with high activity and selectivity. The discovery of these new metal nanoparticle photocatalysts may inspire further studies on other efficient photocatalysts and
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14

Ran, Rong. "Preparation and Optimization of Novel Visible-Light-Active Photocatalysts for Waste-Water Treatment." Thesis, Université d'Ottawa / University of Ottawa, 2016. http://hdl.handle.net/10393/34152.

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Photocatalysis is a series of advanced light-induced redox reaction processes resulting in the degradation and mineralization of organic pollutants in the presence of oxygen and water. Due to their capability to destroy contaminants under mild conditions, photocatalytic processes have attracted considerable attention in the field of waste-water treatment. However, photocatalytic reactions using the traditional TiO2 photocatalyst suffer from low energy efficiencies under solar irradiation. This low efficiency in the utilization of solar energy lies in its incapability in absorbing visible light
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15

Yvin, Mewenn. "Synthèse de nouvelles heptazines pour la photocatalyse, à la fois en phase homogène et par l'intermédiaire de matériaux greffés." Electronic Thesis or Diss., université Paris-Saclay, 2025. http://www.theses.fr/2025UPASF010.

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Les heptazines sont constituées d'un cœur aromatique constitué d'une alternance d'atomes d'azote et de carbone. Cette structure particulièrement intéressante est utilisée de la molécule jusqu'à l'échelle du matériau dans beaucoup de domaines. De nombreuses heptazines polymériques ont été décrites dans la littérature pour des applications en photocatalyse mais très peu d'heptazines moléculaires. Ces dernières ont été étudiées en optoélectronique notamment dans des dispositifs OLEDs « Organic Light-Emitting Diode ». Au cours de cette thèse nous avons cherché à ouvrir de nouvelles voies de synthè
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16

Altomare, M. "TOWARDS THE PHOTOCATALYTIC PRODUCTION OF SOLAR FUELS - NANOSTRUCTURED TITANIUM DIOXIDE FOR PHOTOCATALYSIS & PHOTO-ELECTROCHEMISTRY." Doctoral thesis, Università degli Studi di Milano, 2014. http://hdl.handle.net/2434/229553.

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In spite of many efforts given during the last decades to find new alternative photocatalytic materials, titanium dioxide (TiO2) still represents the most widely employed semiconductor for photocatalytic applications, being photoactive, cheap, easily available, non-toxic, inert and, most of all, chemically stable. However, although exhibiting a powerful combination of extraordinary and attractive physico-chemical properties, it suffers from some issues, common to all semiconductors, related to the dynamic of the charge carriers. Precisely, trapping and recombination of valence band holes and c
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MacDonald, Grant. "Mathematical modelling of semiconductor photocatalysis." Thesis, University of Strathclyde, 2016. http://oleg.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=27029.

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Semiconductor photocatalysis can be extremely effective in the complete mineralisation of hundreds of organic materials and has been utilised in various different commercial systems, for example, self-cleaning glass, purification of water, the purification of air, sterilisation/disinfection and detecting oxygen in food packaging. The aim of this thesis is to further the understanding of semiconductor photocatalysis using mathematical models. One of the main issues considered is the applicability of assuming that reaction intermediates remain in a steady-state throughout the majority of any rea
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18

Davies, R. H. "Semiconductor photocatalysis for water purification." Thesis, Swansea University, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.636399.

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Although many aspects of the semiconductor photocatalysed mineralisation of water contaminants have been studied by researchers over the past decade, there are still certain areas which need further clarification, if the technique is to be used as an alternative to the presently available methods of water purification. It was the objective of the work in this thesis to provide further understanding of some of these remaining areas. One of the greatest inducements for the introduction of the technique of semiconductor photocatalysed pollutant mineralisation, in preference to the currently avail
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19

Coleman, Heather Margaret. "Photocatalysis of oestrogens in water." Thesis, University of Ulster, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.342532.

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Mohd, Ghazi Tinia Idaty. "Heterogeneous photocatalysis for chemicals manufacture." Thesis, University of Cambridge, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.614672.

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21

Crow, Matthew. "Environmental remediation and semiconductor photocatalysis." Thesis, University of Strathclyde, 2010. http://oleg.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=12837.

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22

Beheshtaein, Setareh. "Photocatalysis on a microfluidic reactor." Thesis, California State University, Long Beach, 2016. http://pqdtopen.proquest.com/#viewpdf?dispub=10108187.

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<p> The photocatalytic reaction has been integrated as a developing technology for various applications such as air and water remediation, and self-cleaning surfaces. The photocatalysis is an emerging pathway of heterogeneous photocatalysis and physical chemistry. In heterogeneous photocatalysis, semiconductor compounds, mainly TiO<sub>2</sub>, ZnO, CdS, and WO<sub>3</sub>, have been utilized especially for water treatment and contaminant degradation. Various pollutants, such as aromatic compounds, dyes and surface active agents, can be degraded with photocatalytic techniques. Ultraviolet ligh
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23

Ye, Xuejun. "Selected topics on VOC photocatalysis." online access from Digital Dissertation Consortium, 2003. http://libweb.cityu.edu.hk/cgi-bin/er/db/ddcdiss.pl?3141458.

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24

Wilson, Gregory J. "Photocatalysis with a heterosupramolecular assembly." Thesis, Queensland University of Technology, 2006. https://eprints.qut.edu.au/16290/1/Gregory_Wilson_Thesis.pdf.

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Supramolecular chemistry has asserted itself as a significant multidisciplinary field concerned with molecular effects afforded through non-covalent molecular interactions. The increased interest in the literature towards nanoscale devices, through modulation of molecular function, has seen the renaissance of supramolecular chemistry as function progresses from solution to surface. Heterosupramolecular chemistry follows the architectural principles of supramolecular chemistry and embraces both covalent and non-covalent interactions of condensed phase surfaces and molecular components. A mod
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Wilson, Gregory J. "Photocatalysis with a Heterosupramolecular Assembly." Queensland University of Technology, 2006. http://eprints.qut.edu.au/16290/.

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Supramolecular chemistry has asserted itself as a significant multidisciplinary field concerned with molecular effects afforded through non-covalent molecular interactions. The increased interest in the literature towards nanoscale devices, through modulation of molecular function, has seen the renaissance of supramolecular chemistry as function progresses from solution to surface. Heterosupramolecular chemistry follows the architectural principles of supramolecular chemistry and embraces both covalent and non-covalent interactions of condensed phase surfaces and molecular components. A mod
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Purohit, Bhagyesh. "Precursors-guided synthesis of upconverting nanomaterials for near-infrared driven photocatalysis." Electronic Thesis or Diss., Lyon, 2021. https://n2t.net/ark:/47881/m6sn08q4.

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L'utilisation de l'énergie solaire pour résoudre des problèmes environnementaux tels que la détoxification de l'eau, la purification de l'air et la production d'hydrogène a suscité un grand intérêt de la part de la communauté scientifique au cours des deux dernières décennies. La photocatalyse solaire est une piste intéressante pour cibler toutes ces questions environnementales. Actuellement, les technologies ne permettent pas encore d'utiliser efficacement une partie importante du spectre solaire, à savoir l'infrarouge, qui correspond à près de ~48 % du spectre solaire total. Cette thèse vise
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Nascimento, Ulisses Magalhães. "Preparação, caracterização e testes catalíticos de um fotocatalisador magnético (Fe3O4/TiO2) na degradação de um poluente-modelo: acid blue 9." Universidade de São Paulo, 2013. http://www.teses.usp.br/teses/disponiveis/75/75132/tde-23042013-112144/.

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A aplicação de semicondutores no tratamento de água e efluentes líquidos é uma tecnologia de remediação ambiental promissora, em especial para poluentes orgânicos. Entre os vários semicondutores que também são fotocatalisadores, o TiO2 é amplamente usado em aplicações ambientais, por ser inerte biológica e quimicamente, ter elevado potencial de oxidação, baixo custo e estabilidade frente à corrosão. Entretanto, o TiO2 também tem algumas desvantagens, tais como: ele é excitado apenas por luz UV e requer uma operação unitária adicional (por exemplo, filtração ou centrifugação) para o reuso do ca
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Huo, Zhaohui. "Polyoxometalate - porphyrin hybrids systems : application for the photocurrent generation and the photocatalysis." Thesis, Strasbourg, 2015. http://www.theses.fr/2015STRAF032/document.

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Des films du type polyoxométallates-porphyrines ont été synthetisés et sont basés sur des interactions du types covalentes ou électrostatiques. Les films polyoxométallates–porphyrines sont obtenus par électro-oxydation de l’octaéthylporphyrine de zinc (ZnOEP) ou la 5,15-ditolylporphyrine (H2T2P) en présence de différents types of polyoxométallates (POMs) portant deux groupes pyridyles pendants (py-POM-py) Trois type de systèmes py-POM-py ont été utilises : i) un Lindqvist polyoxovanadate fonctionalisé via deux groupes tris-alkoxo , ii) un derive organosilyl fonctionalisé du type Keggin ou Daws
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Ede, Sarah Melinda. "Infrared and photocatalytic studies of model bacterial species for water treatment." Thesis, Queensland University of Technology, 2006. https://eprints.qut.edu.au/16438/1/Sarah_Ede_Thesis.pdf.

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The use of a CO2 infrared (IR) laser and photocatalysis for water treatment microorganism disinfection purposes was investigated. During CO2 infrared (IR) laser treatment E. cloacae inactivation was comparable to inactivation via ultraviolet (UV) treatment; however no inactivation of the more resistant B. subtilis endospores occurred. Fourier Transform Infrared-Attenuated Total Reflectance (FTIR-ATR) spectroscopy of the bacterial cells displayed increased polysaccharide contents after IR treatment. FTIR and Raman spectroscopy of simple carbohydrates before and after IR laser treatment
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Ede, Sarah Melinda. "Infrared and photocatalytic studies of model bacterial species for water treatment." Queensland University of Technology, 2006. http://eprints.qut.edu.au/16438/.

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The use of a CO2 infrared (IR) laser and photocatalysis for water treatment microorganism disinfection purposes was investigated. During CO2 infrared (IR) laser treatment E. cloacae inactivation was comparable to inactivation via ultraviolet (UV) treatment; however no inactivation of the more resistant B. subtilis endospores occurred. Fourier Transform Infrared-Attenuated Total Reflectance (FTIR-ATR) spectroscopy of the bacterial cells displayed increased polysaccharide contents after IR treatment. FTIR and Raman spectroscopy of simple carbohydrates before and after IR laser treatment displaye
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Karriem, Fatiema. "Oxidative fixation of dinitrogen by photocatalysis." Thesis, University of Western Cape, 2000. http://etd.uwc.ac.za/index.php?module=etd&action=viewtitle&id=gen8Srv25Nme4_5777_1267648612.

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Cai, Yanling. "Titanium Dioxide Photocatalysis in Biomaterials Applications." Doctoral thesis, Uppsala universitet, Nanoteknologi och funktionella material, 2013. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-160634.

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Despite extensive preventative efforts, the problem of controlling infections associated with biomedical materials persists. Bacteria tend to colonize on biocompatible materials and form biofilms; thus, novel biomaterials with antibacterial properties are of great interest. In this thesis, titanium dioxide (TiO2)-associated photocatalysis under ultraviolet (UV) irradiation was investigated as a strategy for developing bioactivity and antibacterial properties on biomaterials. Although much of the work was specifically directed towards dental materials, the results presented are applicable to a
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Gomes, Ana Catarina Costa. "Photocatalysis : Carbonylation of arenas and alkanes." Thesis, University of York, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.516370.

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Lafta, Abbas Jassim Attia. "New materials for photocatalysis and photovoltaics." Thesis, University of Glasgow, 2013. http://theses.gla.ac.uk/4105/.

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Photocatalytic processes are of widespread interest. Among different types of photocatalytic material TiO2 is the generally considered amongst the best due to its favourable physical and chemical properties. In recent decades, photovoltaic devices have been widely studied to provide alternative routes to energy and reduce dependency upon fossil fuel. Solar photovoltaic are cells capable of harvesting of sunlight into electrical power. This technology is one of the most promising routes in the search for sustainable and renewable sources of energy. The study presented in this thesis relates to
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Elhage, Ayda. "Palladium-based Catalyst for Heterogeneous Photocatalysis." Thesis, Université d'Ottawa / University of Ottawa, 2019. http://hdl.handle.net/10393/39388.

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Over the past decade, heterogeneous photocatalysis have gained lots of interest and attention among the organic chemistry community due to its applicability as an alternative to its homogeneous counterpart. Heterogeneous catalysis offers the advantages of easy separation and reusability of the catalyst. Several studies showed that under optimized conditions, efficient and highly selective catalytic systems could be developed using supported metal/metal oxide nanoparticles. In this dissertation, we summarize the progress in the development of supported palladium nanoparticles for different type
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Wang, Zheng. "Studies on the Photocatalytic Conversion of CO2 in and by H2O over Heterogeneous Photocatalysts." 京都大学 (Kyoto University), 2015. http://hdl.handle.net/2433/199324.

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Yamamoto, Akira. "Studies on Low-temperature De-NoX System over TiO2-based Photocatalysts." 京都大学 (Kyoto University), 2015. http://hdl.handle.net/2433/200501.

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Lam, Chun-wai Ringo, and 林俊偉. "Development of photocatalytic oxidation technology for purification ofair and water." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2007. http://hub.hku.hk/bib/B38572382.

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Hathway, Timothy Lee. "Titanium dioxide photocatalysis studies of the degradation of organic molecules and characterization of photocatalysts using mechanistic organic chemistry /." [Ames, Iowa : Iowa State University], 2009. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3369929.

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Sasser, Shawn. "The Design and Testing of a Novel Batch Photocatalytic Reactor and Photocatalyst." Scholar Commons, 2016. http://scholarcommons.usf.edu/etd/6381.

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With an ever-increasing human population, the importance in having sustainable energy resources is becoming increasingly evident, as the current energy habits have brought about massive atmospheric pollution in the form of CO2 emissions, resulting in a rise in the average global temperature. To battle the effects of climate change, many alternative energy resources have been investigated. Among these, photocatalytic conversion of CO2 to renewable hydrocarbon fuels such as methane and methanol is one of the most desirable, as it provides the opportunity to utilize the sun’s energy to convert CO
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Pang, Rui. "Development of Novel Photocatalysts and Co-catalysts for Photocatalytic Conversion of CO2 by H20." Kyoto University, 2019. http://hdl.handle.net/2433/242527.

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Xiao, Qi. "Visible light photocatalytic synthesis of fine organic chemicals with new photocatalysts." Thesis, Queensland University of Technology, 2015. https://eprints.qut.edu.au/84078/14/Qi_Xiao_Thesis.pdf.

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This project was a step forward in developing new recyclable photocatalysts for chemical reactions. These new photocatalysts can facilitate reactions by using visible light under moderate reaction conditions which is suitable for a sustainable, green and eco-friendly modern chemical industry. The outcome of the study greatly extended our understanding in metal nanoparticle photocatalysis, which reveals new photocatalytic mechanisms for the controlled transformation of chemical reactions. The prospect of sunlight irradiation driving chemical reactions may provide opportunity for the organic syn
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Shahine, Issraa. "A chemical route to design plasmonic-semiconductor nanomaterials heterojunction for photocatalysis applications." Thesis, Université de Lorraine, 2019. http://www.theses.fr/2019LORR0105/document.

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L’ingénierie de nanomatériaux hybrides semi-conducteurs/plasmoniques représente une technologie durable en raison de l’efficacité parfaite du couplage pour améliorer, rénover et enrichir les propriétés des composants intégrés. Ce couplage a pour résultat la variation des propriétés fonctionnelles du système, grâce auquel les plasmons de surface générés par les métaux peuvent améliorer la séparation des charges, l’absorption de la lumière et la luminescence du semi-conducteur. Ce phénomène permet de fortes interactions avec d'autres éléments photoniques tels que les émetteurs quantiques. Ces fo
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Grant, Neil. "Application of titania photocatalysis for organic synthesis." Thesis, University of Aberdeen, 2012. http://digitool.abdn.ac.uk:80/webclient/DeliveryManager?pid=185854.

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The addition of benzyltrimethylsilane to maleic anhydride mediated by TiO2 photocatalysis was initially investigated. The affect of changing the catalyst, the radical trap loading and the substitution of the benzyltrimethylsilane molecule was assessed. Cyclisation precursors based on benzyltrimethylsilane were prepared, but were found not to cyclise via TiO2 photocatalysis. A number of other systems were assessed for their ability to cyclise under TiO2 photocatalysis; tertiary amines, aminomethyltrimethylsilanes, phenoxymethyltrimethylsilanes and phenoxyacetic acids. Phenoxymethyltrimethylsila
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45

Sawunyama, P. "Catalysis, photocatalysis and corrosion involving metal oxides." Thesis, Swansea University, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.638775.

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In today's environmentally conscious society, greater emphasis is now on clean chemical technologies. Reactions at metal oxide-solution interfaces have received much attention in this respect. Although progress has been made in applying the associated technology to such fields as hydrometallurgy, solar energy conversion, descaling of pipework and nuclear plant decontamination, and environmental decontamination, the fundamental processes involved are not always understood. There is a need, therefore, to investigate these processes further. Chapter Three describes the oxidative dissolution kinet
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46

Belghazi, A. "Heterogeneous semiconductor UV-photocatalysis for water purification." Thesis, Swansea University, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.636072.

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As traditional disinfection techniques have proved to be inefficient in coping with toxic pollutants, there is a real need to create and develop alternatives such as Advanced Oxidation Processes (AOP's). As one of the most promising AOP's developed to date, heterogeneous semiconductor UV-photocatalysis has been shown to efficiently mineralise and inactivate a wide range of organic, inorganic and biological pollutants. This technique is based on the powerful redox properties of UV-illuminated semiconductors. The photocatalyst (semiconductor), which is insoluble in water, can be used in the form
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47

Jo, Won Jun. "Solar energy conversion via photovoltaics and photocatalysis." Thesis, Massachusetts Institute of Technology, 2017. http://hdl.handle.net/1721.1/111409.

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Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemical Engineering, 2017.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references.<br>Due to the forthcoming shortage of natural resources, the demand for more efficient and ecofriendly chemical processes for the conversion of energy and matter, especially with respect to carbon management, is growing rapidly. Therefore, a search for high-performance solar energy conversion systems to end the current carbon economy era is of paramount importance in both academic and industrial sectors. In this regard
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48

Kazantsev, Roman V. "Self-Assembled, Crystalline Organic Nanostructures for Photocatalysis." Thesis, Northwestern University, 2016. http://pqdtopen.proquest.com/#viewpdf?dispub=3741384.

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<p> The goal of this thesis was to integrate light-absorbing supramolecular materials into a photocatalytic system for solar-to-fuel conversion. Toward this end, a series of perylene-based chromophore amphiphiles was synthesized and their self-assembly properties explored. Characterization of these materials by electron microscopy and x-ray scattering techniques revealed molecular assembly into 1D ribbon nanostructures. Surprisingly, these ribbons were observed to spontaneously crystallize in solution, as observed by wide-angle and grazing incidence X-ray scattering. These crystalline nanostru
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Khan, Muhammad Abdullah. "Carbon nitride based materials for heterogeneous photocatalysis." Thesis, University of Oxford, 2016. https://ora.ox.ac.uk/objects/uuid:8498a9f5-e5c8-4eda-b62d-0cd36471759c.

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Photocatalysis on semiconductor surfaces has grown tremendously in the last four decades. One reason for this is its analogy with photosynthesis, the most important natural photochemical process. Semiconductors to some extent can mimic the key steps of this fascinating heterogeneous photocatalytic process, i.e., photochemical charge generation, charge trapping, interfacial electron exchange and subsequent reaction. Building on this premise this thesis constitutes an investigation into the photocatalytic properties and applications of semiconducting layered framework carbon nitride based materi
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Pyrgiotakis, Georgios. "Titania carbon nanotube composites for enhanced photocatalysis." [Gainesville, Fla.] : University of Florida, 2006. http://purl.fcla.edu/fcla/etd/UFE0013482.

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