Relevant bibliographies by topics / Photochemical model

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  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers
  6. Reports

Academic literature on the topic 'Photochemical model'

Author: Grafiati
Published: 4 June 2021
Last updated: 5 February 2022

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Journal articles on the topic "Photochemical model"

1

Huang, Y., D. Pagé, D. D. M. Wayner, and P. Mulder. "Radical-induced degradation of a lignin model compound. Decomposition of 1-phenyl-2-phenoxyethanol." Canadian Journal of Chemistry 73, no. 11 (1995): 2079–85. http://dx.doi.org/10.1139/v95-256.

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Reaction of 1-phenyl-2-phenoxyethanol (1) with thermally or photochemically generated tert-butoxyl radicals leads, via the intermediate ketyl radical, to the formation of the corresponding ketone, α-phenoxyacetophenone (4), as the only product at low conversion under an inert atmosphere. An approximately twofold increase in the product yield is observed when the reactions are carried out under oxygen. Under the photochemical conditions it is shown that 4 is the primary product and that acetophenone and phenol are formed as a result of secondary photolysis of 4. These data suggest that the rate constant for fragmentation of the ketyl radical derived from 1 is on the order of 10 s−1 at 298 K and contradict a report in the literature that suggests a rate constant of >106 s−1. The relevance of this study to the photodegradation of lignin and consequent photoyellowing is discussed and a revised mechanism for the photoyellowing of pulp is proposed. Keywords: ketyl radical, photochemical degradation, thermal degradation, lignin.
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Ollivier, J. L., M. Dobrijévic, and J. P. Parisot. "New photochemical model of Saturn’s atmosphere." Planetary and Space Science 48, no. 7-8 (2000): 699–716. http://dx.doi.org/10.1016/s0032-0633(00)00035-0.

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Moses, Julianne I. "SL9 impact chemistry: Long-term photochemical evolution." International Astronomical Union Colloquium 156 (May 1996): 243–68. http://dx.doi.org/10.1017/s0252921100115532.

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One-dimensional photochemical models are used to provide an assessment of the chemical composition of the Shoemaker-Levy 9 impact sites soon after the impacts, and over time, as the impact-derived molecular species evolve due to photochemical processes. Photochemical model predictions are compared with the observed temporal variation of the impact-derived molecules in order to place constraints on the initial composition at the impact sites and on the amount of aerosol debris deposited in the stratosphere. The time variation of NH3, HCN, OCS, and H2S in the photochemical models roughly parallels that of the observations. S2persists too long in the photochemical models, suggesting that some of the estimated chemical rates constants and/or initial conditions(e.g., the assumed altitude distribution or abundance of S2) are incorrect. Models predict that CS and CO persist for months or years in the jovian stratosphere. Observations indicate that the model results with regard to CS are qualitatively correct (although the measured CS abundance demonstrates the need for a larger assumed initial abundance of CS in the models), but that CO appears to be more stable in the models than is indicated by observations. The reason for this discrepancy is unknown. We use model-data comparisons to learn more about the unique photochemical processes occurring after the impacts.
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Yamartino, R. J., J. S. Scire, G. R. Carmichael, and Y. S. Chang. "The CALGRID mesoscale photochemical grid model—I. Model formulation." Atmospheric Environment. Part A. General Topics 26, no. 8 (1992): 1493–512. http://dx.doi.org/10.1016/0960-1686(92)90134-7.

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Siampiringue, Marie, Rajae Chahboune, Pascal Wong-Wah-Chung, and Mohamed Sarakha. "Carbaryl Photochemical Degradation on Soil Model Surfaces." Soil Systems 3, no. 1 (2019): 17. http://dx.doi.org/10.3390/soilsystems3010017.

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The phototransformation of carbaryl was investigated upon solar light exposure on three surfaces, silica, kaolin and sand, as soil models. By excitation with a Suntest set up at the surface of the three solid supports, the degradation of carbaryl followed first-order kinetics with a rate constant of 0.10 h−1. By using the Kubelka Munk model, the quantum yield disappearance at the surface of kaolin was evaluated to 2.4 × 10−3. Such a value is roughly one order of magnitude higher than that obtained in aqueous solutions. The results indicated that the particle size and the specific surface area of the various models have significant effects. The photo-oxidative properties as well as the byproduct elucidation by liquid chromatography combined with diode arrays (LC-DAD) and liquid chromatography coupled mass spectrometry (LC-MS) analyses allowed us to propose the degradation mechanism pathways. The main products were 1-naphtol and 2-hydroxy-1,4-naphthoquinone, which arise from a photo-oxidation process together with products from photo-Fries, photo-ejection and methyl carbamate hydrolysis. The toxicity tests clearly showed a significant decrease of the toxicity in the early stages of the irradiation. This clearly shows that the generated products are less toxic than the parent compound.
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Eichenbaum, Joseph W., Ayca Cinaroglu, Kenneth D. Eichenbaum, and Kirsten C. Sadler. "A zebrafish retinal graded photochemical stress model." Journal of Pharmacological and Toxicological Methods 59, no. 3 (2009): 121–27. http://dx.doi.org/10.1016/j.vascn.2009.02.006.

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Giorgi, F., and W. L. Chameides. "The rainout parameterization in a photochemical model." Journal of Geophysical Research: Atmospheres 90, no. D5 (1985): 7872–80. http://dx.doi.org/10.1029/jd090id05p07872.

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Nair, Hari, Mark Allen, Ariel D. Anbar, Yuk L. Yung, and R. Todd Clancy. "A Photochemical Model of the Martian Atmosphere." Icarus 111, no. 1 (1994): 124–50. http://dx.doi.org/10.1006/icar.1994.1137.

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ZACHARY, D. S., A. HAURIE, and I. SIVERGINA. "A REDUCED-ORDER PHOTOCHEMICAL AIR QUALITY MODEL." Cybernetics and Systems 35, no. 7-8 (2004): 579–93. http://dx.doi.org/10.1080/01969720490499281.

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Rasmussen, C. E., R. W. Schunk, and V. B. Wickwar. "A photochemical equilibrium model for ionospheric conductivity." Journal of Geophysical Research 93, A9 (1988): 9831. http://dx.doi.org/10.1029/ja093ia09p09831.

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Dissertations / Theses on the topic "Photochemical model"

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Plummer, David A. "On-line chemistry in a mesoscale model assessment of the Toronto emission inventory and lake-breeze effects on air quality /." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape9/PQDD_0028/NQ39304.pdf.

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Lary, David John. "Photochemical studies with a three-dimensional model of the atmosphere." Thesis, University of Cambridge, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.386150.

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Zeng, Tao. "Three-Dimensional Model Analysis of Tropospheric Photochemical Processes in the Arctic and Northern Mid_Latitudes." Diss., Georgia Institute of Technology, 2005. http://hdl.handle.net/1853/7648.

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Halogen-driven ozone and nonmethane hydrocarbon losses in springtime Arctic boundary layer are investigated using a regional chemical transport model (CTM). Surface observation of O3 at Alert and Barrow and aircraft observations of O3 and hydrocarbons during the TOPSE experiment from February to May in 2000 are analyzed. We prescribe halogen radical distributions based on GOME BrO observations and calculated or observed other halogen radical to BrO ratios. GOME BrO shows an apparent anti-correlation with surface temperature over high BrO regions. At its peak, area of simulated near-surface O3 depletions (O3 LT 20ppbv) covers GT 50% of the north high latitudes. Model simulated O3 losses are in agreement with surface and aircraft O3 observations. Simulation of halogen distributions are constrained using aircraft hydrocarbon measurements. We find the currently chemical mechanism overestimate the Cl/BrO ratios. The model can reproduce the observed halogen loss of NMHCs using the empirical Cl/BrO ratios. We find that the hydrocarbon loss is not as sensitive to the prescribed boundary layer height of halogen as that of O3, therefore producing a more robust measure for evaluating satellite column measurement. Tropospheric tracer transport and chemical oxidation processes are examined on the basis of the observations at northern mid-high latitudes and over the tropical Pacific and the corresponding global 3D CTM (GEOS-CHEM) simulations. The correlation between propane and ethane/propane ratio is employed using a finite mixing model to examine the mixing in addition to the OH oxidations. At northern mid-high latitudes the model agrees with the observations before March. The model appears to overestimate the transport from lower to middle latitudes and the horizontal transport and mixing at high latitudes in May. Over the tropical Pacific the model reproduces the observed two-branch slope values reflecting an underestimate of continental convective transport at northern mid-latitudes and an overestimate of latitudinal transport into the tropics. Inverse modeling using the subsets of observed and simulated data is more reliable by reducing (systematic) biases introduced by systematic model transport model transport errors. On the basis of this subset we find the model underestimates the emissions of ethane and propane by 14 5%.
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Alfalah, Sherin [Verfasser]. "Quantum dynamics of photochemical model reactions via conical intersections / Sherin Alfalah." Berlin : Freie Universität Berlin, 2010. http://d-nb.info/1024046893/34.

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McMoneagle, Andrew. "Antioxidant behaviour in photo-oxidation studies of model lipid compounds." Thesis, University of the West of Scotland, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.311777.

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Grenfell, John Lee. "Southern hemisphere studies with a photochemical 3-dimensional model of the atmosphere." Thesis, University of Cambridge, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.388367.

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Rice, James H. "Spectroscopic studies of porphyrins in model bio-molecular environments : photophysical, photochemical and electrochemical studies." Thesis, Queen's University Belfast, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.388177.

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Dumas, Richard Allen. "An investigation of the production of nitric oxide by soft solar X-rays in the E-region of the ionosphere." Thesis, Monterey, California. Naval Postgraduate School, 1988. http://hdl.handle.net/10945/23281.

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Approved for public release; distribution is unlimited<br>The production of nitric oxide by soft solar X-rays in the E-region of the ionosphere is investigated. An empirical expression for the variation in X-ray flux as a function of F10.7 is determined. This expression is incorporated into a one-dimensional diffusive photochemical model to compute nitric oxide densities. No results of these calculation are compared with NO observation from the Solar Mesosphere Explorer satellite. Variations of X-ray flux by a factor of 30 over the solar cycle can explain the observed variation in nitric oxide densities.<br>http://archive.org/details/investigationofp00duma<br>Lieutenant, United States Navy
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Zeng, Tao. "Three-dimensional model analysis of tropospheric photochemical processes in the Arctic and northern mid-latitudes." Available online, Georgia Institute of Technology, 2005, 2005. http://etd.gatech.edu/theses/available/etd-08232005-123814/.

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Thesis (Ph. D.)--Earth and Atmospheric Sciences, Georgia Institute of Technology, 2006.<br>Wang, Yuhang, Committee Chair ; Black, Robert, Committee Member ; Curry, Judith, Committee Member ; Huey, Greg, Committee Member ; Russell, Armistead G, Committee Member. Includes bibliographical references.
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Wagstaffe, Michael. "The role of surface chemistry of a model metal oxide for photochemical and biomaterial applications." Thesis, University of Manchester, 2018. https://www.research.manchester.ac.uk/portal/en/theses/the-role-of-surface-chemistry-of-a-model-metal-oxide-for-photochemical-and-biomaterial-applications(04716afc-b352-441a-b7a4-6dded005dabc).html.

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The functionality of devices that utilise TiO2 is heavily influenced by the interactions which occur at the surface and interface. Developing a full mechanistic understanding of these interactions is essential, and the focus of the work presented in this thesis. The interactions of phenylphosphonic acid (PPA) and [C4C1Im][BF4] with the surface of anatase(101) have been investigated using X-ray photoelectron spectroscopy (XPS) and near edge X-ray absorption fine structure (NEXAFS) spectroscopy because of their potential applications in dye-sensitised solar cells. XPS data suggests that at 0.15 monolayer (ML) coverage PPA adsorbs in a bidentate geometry following the deprotonation of both P-OH groups. At 0.85 ML coverage there is a shift to a mixed bidentate/monodentate binding mode. NEXAFS spectroscopy data shows that the phenyl ring is oriented 65 ±4 away from the surface plane and twisted 57 ±11 away from the [101] azimuth. [C4C1Im][BF4] is found to order at the surface of anatase(101) via electrostatic attraction only at low coverages, with the imidazolium ring oriented 32 ± 4 from the surface. XPS data suggests that the anion undergoes a surface induced degradation to form BF3, resulting in incorporation of F into O vacancies. The behaviour of metallic clusters supported on metal oxide supports and the nature of the crystal structure modification of TiO2 following doping with impurity ions both have important implications in catalysis. XPS and scanning tunnelling microscopy (STM) data show that the interaction of Ag with the anatase(101) surface leads to a metal-surface charge transfer, as evidenced by the reduction of Ti4+ to Ti3+, and the formation of 3D size limiting clusters. Under exposure to 3 mbar CO/H2O, partial oxidation of the Ag clusters in conjunction with the formation of a transient Ag-carbonyl species is observed. Upon returning to ultra-high vacuum these species disappear. XPS and photoelectron diffraction (PhD) have been employed and show that nitrogen doping results in an additional Ti species due to TiO2-N. XPS suggests that nitrogen exists in substitutional sites, a conclusion which is reinforced by the PhD data where the N 1s and O 1s modulation functions exhibit similarities. Theoretical modulation functions are yet to be calculated and future work will aim to provide quantitative information regarding the substitutional nature of this system. The effect of adventitious carbon on Ti implants has been modelled by studying peptide adsorption on single crystal TiO2, both as-prepared and pyrocatechol capped. XPS shows that pyrocatechol successfully prevents the adsorption of adventitious carbon species from air and leads to a greater uptake of RGD, which bonds to Ti atoms via the deprotonated carboxylate groups. An increased uptake of RGD is also observed on the SLActive surface and we conclude that the chemistry of the hydrocarbon overlayer governs the uptake of RGD, and may affect osseointegration.
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Books on the topic "Photochemical model"

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Lamb, Robert G. A regional-scale (1000 km) model of photochemical air pollution. U.S. Environmental Protection Agency, Atmospheric Sciences Research Laaboratory, 1985.

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Lamb, Robert G. A regional-scale (1000 km) model of photochemical air pollution. U.S. Environmental Protection Agency, Atmospheric Sciences Research Laaboratory, 1985.

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Lamb, Robert G. A regional-scale (1000 km) model of photochemical air pollution. U.S. Environmental Protection Agency, Atmospheric Sciences Research Laaboratory, 1985.

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Lamb, Robert G. A regional-scale (1000 km) model of photochemical air pollution. U.S. Environmental Protection Agency, Atmospheric Sciences Research Laaboratory, 1985.

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Lamb, Robert G. A regional-scale (1000 km) model of photochemical air pollution. U.S. Environmental Protection Agency, Atmospheric Sciences Research Laaboratory, 1985.

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Whitten, G. Z. Development of a chemical kinetic mechanism for the U.S. EPA regional oxidant model. U.S. Environmental Protection Agency, Atmospheric Sciences Research Laboratory, 1985.

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Haney, Jay L. Evaluation and application of the urban airshed model in the Philadelphia air quality control region. U.S. Environmental Protection Agency, Office of Air and Radiation, Office of Air Quality Planning and Standards, 1985.

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Dymek, M. K. Photochemical model of ion composition and electron density in the terrestrial ionosphere between 70 and 300 KM. I'Institut royal météorologique de Belgique, 1989.

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Perego, Silvan. Ein numerisches Modell zur Simulation des Sommersmogs. Geographisches Institut der Universität Bern, 1996.

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Fuchs, Friedhelm. Modellierung der Ozon-Immissionsbelastung in Rheinland-Pfalz: Studien zur physikochemischen Entwicklung von Oxidanten in anthropogen kontaminierten Luftmassen. Geographisches Institut Johannes Gutenberg-Universität Mainz, 1994.

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Book chapters on the topic "Photochemical model"

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Manca, Vincenzo, Roberto Pagliarini, and Simone Zorzan. "Toward an MP Model of Non-Photochemical Quenching." In Membrane Computing. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-95885-7_22.

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Kawamura, Genki, and Takeaki Ozawa. "CHAPTER 8. Quantitative Control of Kinase Activity with a Mathematical Model." In Comprehensive Series in Photochemical & Photobiological Sciences. Royal Society of Chemistry, 2018. http://dx.doi.org/10.1039/9781788013284-00149.

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Vandendriessche, J., R. Goedeweeck, P. Collart, and F. C. Schryver. "Fluorescence Probing of the Local Dynamics of Polymers: A Model Approach." In Photophysical and Photochemical Tools in Polymer Science. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4726-9_10.

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Di Mauro, Ernesto, Bruno Mattia Bizzarri, and Raffaele Saladino. "CHAPTER 6. The Role of Photochemistry in the Prebiotic Model of Formamide." In Comprehensive Series in Photochemical & Photobiological Sciences. Royal Society of Chemistry, 2021. http://dx.doi.org/10.1039/9781839164354-00107.

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Lawrence, Mark G., T. Kunhikrishnan, and Rolf von Kuhlmann. "Global Photochemical Model Evaluation using GOME Tropospheric Column Data." In Sounding the Troposphere from Space. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-642-18875-6_28.

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Krüger, B. C., M. M. Hirschberg, and P. Fabian. "Photochemical Model Calculations About Environmental Effects of Hydrogen Engines." In Orbital Transport. Springer Berlin Heidelberg, 1993. http://dx.doi.org/10.1007/978-3-642-45720-3_36.

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Christensen, Jesper H., Øystein Hov, and Ruwim Berkowicz. "Modelling Photochemical Pollution by an Eulerian Long-Range Transport Model." In Air Pollution Modeling and Its Application VIII. Springer US, 1991. http://dx.doi.org/10.1007/978-1-4615-3720-5_11.

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Venkatram, Akula, Shuming Du, Ramamurthy Hariharan, William Carter, and Robert Goldstein. "The Separation of Transport and Chemistry in a Photochemical Model." In Air Pollution Modeling and Its Application XII. Springer US, 1998. http://dx.doi.org/10.1007/978-1-4757-9128-0_47.

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Lagzi, I., A. S. Tomlin, T. Turányi, L. Haszpra, M. Berzins, and R. Mészáros. "Modelling Photochemical Air Pollution in Hungary Using an Adaptive Grid Model." In Air Pollution Modelling and Simulation. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/978-3-662-04956-3_26.

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Ramamurthy, V., Richard G. Weiss, and George S. Hammond. "A Model for the Influence of Organized Media on Photochemical Reactions." In Advances in Photochemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470133491.ch2.

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Conference papers on the topic "Photochemical model"

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Myers, Anne B., David L. Phillips, Xiaopei Ci, Curtis L. Westerfield, and Jon-Marc Rodier. "Photochemical and spectroscopic studies of small model polyenes related to vision." In OE/LASE'93: Optics, Electro-Optics, & Laser Applications in Science& Engineering, edited by Laurence A. Nafie and Henry H. Mantsch. SPIE, 1993. http://dx.doi.org/10.1117/12.145245.

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Sukhova, E. M., and V. S. Sukhov. "Optical model of the distribution of non-photochemical quenching in a sheet." In IX Congress of society physiologists of plants of Russia "Plant physiology is the basis for creating plants of the future. Kazan University Press, 2019. http://dx.doi.org/10.26907/978-5-00130-204-9-2019-421.

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Fanjul-Vélez, F., I. Salas-Garcĺa, L. A. Fernández-Fernández, et al. "Photochemical model of Photodynamic Therapy applied to skin diseases by a topical photosensitizer." In European Conference on Biomedical Optics. OSA, 2009. http://dx.doi.org/10.1364/ecbo.2009.7373_0s.

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Fanjul-Vélez, F., I. Salas-García, L. A. Fernández-Fernández, et al. "Photochemical model of photodynamic therapy applied to skin diseases by a topical photosensitizer." In European Conferences on Biomedical Optics, edited by Ronald Sroka and Lothar D. Lilge. SPIE, 2009. http://dx.doi.org/10.1117/12.831938.

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Lee, I.-Ju, Jia-Wen Hsu, Yung-Jen Chuang, and Ian Liau. "Confocal Imaging Guided Photochemical Thrombosis Toward the Development of a Novel Zebrafish Model of Stroke." In Asia Communications and Photonics Conference. OSA, 2016. http://dx.doi.org/10.1364/acpc.2016.as3i.3.

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Fujita, Shinichi, and Hiroyuki Tamura. "Development of a Short-term Prediction Model for Predicting Photochemical Oxidants in a Local Area." In 2006 SICE-ICASE International Joint Conference. IEEE, 2006. http://dx.doi.org/10.1109/sice.2006.315723.

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Zhang, Jie, Ranjani Sabarinathan, Tracy Bubel, David R. Williams, and Jennifer J. Hunter. "Action spectrum for photochemical retinal pigment epithelium (RPE) disruption in an in vivo monkey model." In SPIE BiOS, edited by E. Duco Jansen. SPIE, 2016. http://dx.doi.org/10.1117/12.2213615.

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Zhang, Qian, Weimin Ju, Jing M. Chen, and Fengting Yang. "Application of the photochemical reflectance index to track light use efficiency with a two-leaf model." In IGARSS 2016 - 2016 IEEE International Geoscience and Remote Sensing Symposium. IEEE, 2016. http://dx.doi.org/10.1109/igarss.2016.7730397.

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Gleeson, Michael R., Ciara E. Close, John V. Kelly, and John T. Sheridan. "Photochemical effects during holographic grating formation in photopolymer using the non-local polymerisation driven diffusion model." In SPIE Optics + Photonics, edited by Susanna Orlic and Klaus Meerholz. SPIE, 2006. http://dx.doi.org/10.1117/12.681593.

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Bolte, Michel, Roger A. Lessard, and Christine Pizzocaro. "Photochemical process in dichromated photosensitive material: dichromated (polyvinyl alcohol-polyacrylic acid)-- a model for dichromated gelatin?" In IC02, edited by Roger A. Lessard, George A. Lampropoulos, and Gregory W. Schinn. SPIE, 2003. http://dx.doi.org/10.1117/12.474364.

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Reports on the topic "Photochemical model"

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Zinn, J., C. D. Sutherland, E. E. Fenimore, and S. Ganguly. The solar flare of 18 August 1979: Incoherent scatter radar data and photochemical model comparisons. Office of Scientific and Technical Information (OSTI), 1988. http://dx.doi.org/10.2172/5061909.

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Adriaanse, P. I., J. J. T. I. Boesten, M. M. S. ter Horst, C. M. J. Jacobs, and C. van Griethuysen. Estimation of photochemical degradation rates of pesticides in outdoor cosm water : Guidance for inclusion in higher tier exposure assessments of the registration procedure in The Netherlands or at EU level, using the TOXSWA model. Wageningen Environmental Research, 2021. http://dx.doi.org/10.18174/523476.

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Hurst, J. K. [Membrane-based photochemical systems as models for photosynthetic cells]. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/6675105.

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Tamaresis, J., D. E. Kinnison, and D. J. Wuebbles. A condensed global photochemical mechanism for two-dimensional atmospheric models. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/5230906.

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Hurst, J. K. [Membrane-based photochemical systems as models for photosynthetic cells]. Progress report, February 15, 1990--August 31, 1992. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/10133636.

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