Academic literature on the topic 'Photochemical water oxidation'

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Journal articles on the topic "Photochemical water oxidation"

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Hetterscheid, Dennis G. H., and Wilson A. Smith. "Electrochemical and photochemical water oxidation." Catalysis Today 290 (July 2017): 1. http://dx.doi.org/10.1016/j.cattod.2017.05.002.

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Yue, P. L., and O. Legrini. "Photochemical Degradation of Organics in Water." Water Quality Research Journal 27, no. 1 (February 1, 1992): 123–38. http://dx.doi.org/10.2166/wqrj.1992.007.

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Abstract Trichloroethylene, phenol, 4-cholorophenol, catechol and a pesticide were degraded by two advanced oxidation processes: photolytic oxidation with hydrogen peroxide, andphotolytic oxidation with ozone. The reactions were studied in a batch photoreactor with a low pressure mercury lamp as the radiation source. The variation of the concentration of total organic carbon with time was measured. For the organics studied, the reaction kinetics for the reduction of total organic carbon (TOC) were found to follow a power law. The exponent of the power law varies with the initial TOC concentration. Results show that TOC can be very effectively reduced provided the concentration of hydrogen peroxide used exceeds a certain threshold value. The UV/Ozone process yielded a more rapid rate of degradation and a greater degree of mineralisation.
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Sartorel, Andrea, Marcella Bonchio, Sebastiano Campagna, and Franco Scandola. "Tetrametallic molecular catalysts for photochemical water oxidation." Chem. Soc. Rev. 42, no. 6 (2013): 2262–80. http://dx.doi.org/10.1039/c2cs35287g.

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Kalisman, Philip, Yaron Kauffmann, and Lilac Amirav. "Photochemical oxidation on nanorod photocatalysts." Journal of Materials Chemistry A 3, no. 7 (2015): 3261–65. http://dx.doi.org/10.1039/c4ta06164k.

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Huang, Xiang, Juan-Pablo Aranguren, Johannes Ehrmaier, Jennifer A. Noble, Weiwei Xie, Andrzej L. Sobolewski, Claude Dedonder-Lardeux, Christophe Jouvet, and Wolfgang Domcke. "Photoinduced water oxidation in pyrimidine–water clusters: a combined experimental and theoretical study." Physical Chemistry Chemical Physics 22, no. 22 (2020): 12502–14. http://dx.doi.org/10.1039/d0cp01562h.

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Ressnig, Debora, Menny Shalom, Jörg Patscheider, René Moré, Fabio Evangelisti, Markus Antonietti, and Greta R. Patzke. "Photochemical and electrocatalytic water oxidation activity of cobalt carbodiimide." Journal of Materials Chemistry A 3, no. 9 (2015): 5072–82. http://dx.doi.org/10.1039/c5ta00369e.

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Tarasov, V. V., G. S. Barancova, N. K. Zaitsev, and Zhang Dongxiang. "Photochemical Kinetics of Organic Dye Oxidation in Water." Process Safety and Environmental Protection 81, no. 4 (July 2003): 243–49. http://dx.doi.org/10.1205/095758203322299761.

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Bofill, Roger, Jordi García-Antón, Lluís Escriche, and Xavier Sala. "Chemical, electrochemical and photochemical molecular water oxidation catalysts." Journal of Photochemistry and Photobiology B: Biology 152 (November 2015): 71–81. http://dx.doi.org/10.1016/j.jphotobiol.2014.10.022.

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Deng, Xiaohui, Hans-Josef Bongard, Candace K. Chan, and Harun Tüysüz. "Dual-Templated Cobalt Oxide for Photochemical Water Oxidation." ChemSusChem 9, no. 4 (September 25, 2015): 409–15. http://dx.doi.org/10.1002/cssc.201500872.

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Liu, Hongfei, René Moré, Henrik Grundmann, Chunhua Cui, Rolf Erni, and Greta R. Patzke. "Promoting Photochemical Water Oxidation with Metallic Band Structures." Journal of the American Chemical Society 138, no. 5 (January 28, 2016): 1527–35. http://dx.doi.org/10.1021/jacs.5b10215.

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Dissertations / Theses on the topic "Photochemical water oxidation"

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Shrestha, Sweta. "Photochemical Water Oxidation by Zeolite-supported Manganese Oxides." The Ohio State University, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=osu1408983765.

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Hansen, Malte [Verfasser], and Burkhard [Akademischer Betreuer] König. "Photochemical Water Oxidation at Dynamic Self-Assembled Interfaces / Malte Hansen ; Betreuer: Burkhard König." Regensburg : Universitätsbibliothek Regensburg, 2015. http://d-nb.info/1121302688/34.

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Eilers, Gerriet. "Molecular Approaches to Photochemical Solar Energy Conversion : Towards Synthetic Catalysts for Water Oxidation and Proton Reduction." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-7875.

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Shrestha, Sweta. "Application of Transition Metal Coordination for Energy Efficient Processes: Catalysis and Separation." The Ohio State University, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=osu1502975499629018.

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Zhao, Yanyan. "Dinuclear Heterogeneous Catalysts on Metal Oxide Supports:." Thesis, Boston College, 2020. http://hdl.handle.net/2345/bc-ir:109003.

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Thesis advisor: Dunwei Wang
Atomically dispersed catalysts refer to substrate-supported heterogeneous catalysts featuring one or a few active metal atoms that are separated from one another. They represent an important class of materials ranging from single atom catalysts (SACs) and nanoparticles (NPs). The study of SACs has brought an attention of understanding the reaction mechanism at the molecular level. SACs is a promising field, however, there are still many challenges and opportunities in developing the next generation of catalysts. Catalysts featuring two atoms with well-defined structures as active sites are poorly studied. It is expected that this class of catalysts will show uniqueness in activity, selectivity, and stability. However, the difficulty in synthesizing such structures has been a critical challenge. I tackled this challenge by using a facile photochemical method to generate active metal centers consisting of two iridium metal atoms bridged by O ligands and bound to a support by stripping the ligands of the organometallic complex. My research also unveiled the structure of this dinuclear heterogeneous catalysts (DHCs) by integrating various characterization resources. Direct evidence unambiguously supporting the dinuclear nature of catalysts anchored on metal oxides is obtained by aberration-corrected scanning transmission electron microscopy. In addition, different binding modes have been achieved on two categories of metal oxides with distinguishable surface oxygen densities and interatomic distances of binding sites. Side-on bound DHCs was demonstrated on iron oxide and ceria where both Ir atoms are affixed to the surface with similar coordination environment. The binding sites on the OH-terminated surface of Fe2O3 and CeO2 anchor the catalysts to provide outstanding stability against detachment, diffusion and aggregation. The competing end-on binding mode, where only one Ir atom is attached to the substrate and the other one is dangling was observed on WO3. Evidence supporting the binding modes was obtained by in situ diffuse reflectance infrared Fourier transform spectroscopy. In addition, the synergistic effect between two adjacent Ir atoms and the uniqueness of different coordinative oxygen atoms around Ir atoms were investigated by a series of operando spectroscopy such as X-ray absorption spectroscopy and microscopy at atomic level under the reaction condition. The resulting catalysts exhibit high activities and stabilities toward H2O photo-oxidation and preferential CO oxidation. Density functional theory calculations provide additional support for atomic structure, binding sites modes on metal oxides, as well as insights into how DHCs may be beneficial for these catalytic reactions. This research has important implications for future studies of highly effective heterogeneous catalysts for complex chemical reactions
Thesis (PhD) — Boston College, 2020
Submitted to: Boston College. Graduate School of Arts and Sciences
Discipline: Chemistry
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Lira, Daniella Cristina Barbosa de. "Estudo de degradação fotoquímica para reúso de águas de processo em complexo industrial petroquímico." Universidade de São Paulo, 2006. http://www.teses.usp.br/teses/disponiveis/3/3137/tde-19042007-143328/.

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A racionalização dos recursos hídricos tem sido uma das metas das indústrias em vários setores. Tais metas exigem inovações tecnológicas tanto para novos processos produtivos quanto para novas técnicas de tratamento e reutilização de água na cadeia de produção. Os custos elevados de água industrial no Brasil, particularmente nas regiões metropolitanas, têm estimulado as indústrias nacionais a avaliar as possibilidades de reúso. O objetivo deste trabalho é a aplicação do tratamento de águas de processo contendo polipropileno utilizando radiação ultravioleta e peróxido de hidrogênio, isto é, o sistema UV/H2O2, visando adequá-las para reúso no próprio processo, reduzindo a necessidade de captação de água pré-tratada e de descarte de efluente. A primeira parte do estudo consistiu na realização de experimentos em um sistema fotoquímico de batelada, empregando quatro diferentes correntes efluentes de processo, para a avaliação da viabilidade técnico-econômica do tratamento fotoquímico, bem como para a obtenção de dados referentes à cinética das reações fotoquímicas. Com base nas informações obtidas, na segunda parte do estudo foram realizados experimentos em um sistema fotoquímico contínuo, a fim de obter dados para o aumento de escala para aplicação industrial do processo de tratamento contínuo. Os resultados experimentais indicaram a viabilidade técnica de aplicação do sistema UV/H2O2 utilizando fonte de luz artificial para todas as correntes de processo estudadas, tendo sido alcançados níveis de remoção de matéria orgânica acima de 90%. No entanto, sob o ponto de vista econômico, apenas as correntes com baixo teor de carbono orgânico total dissolvido (COT), entre 6 e 12 mgC L-1, mostraram-se adequadas ao reúso, após o tratamento.
Rationalization of water use has been one of the goals in many industrial activities, and, in particular, in the petrochemical industry. Such goals demand technological innovations in the productive processes and in techniques for treatment and reuse of water in the production chain. The high costs of industrial water, particularly in some metropolitan regions, have stimulated the industries to evaluate the possibilities of water reuse. The objective of this work is to evaluate the feasibility of the UV/H2O2 photochemical process applied to the treatment of process waste water containing polypropylene, aiming at the reuse of the waste water in the as process water in the industrial complex, thus reducing the need for tap water supply and waste water generation rate. The first part of this study consisted of laboratory-scale experiments in a batch photochemical reactor with four different waste water streams to perform the technical and economical feasibility of the photochemical treatment, as well to obtain data on the degradation rate. Based on the results of the first part, the second part of this study consisted of experiments in a continuous photochemical reactor, aimed at obtaining experimental data for reactor scale-up. Experimental results indicate that the UV/H2O2 photodegradation process is able to remove more than 90% of the organic compounds contained in the waste water. However, only waste waters containing relatively low contaminant levels (between 6 and 12 mgC L-1) can be treated at economically favourable costs.
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Gennings, Chad. "Photochemical oxidation of dissolved organic carbon in streams." 1998. http://wwwlib.umi.com/cr/yorku/fullcit?pMQ39192.

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Thesis (M. Sc.)--York University, 1998. Graduate Programme in Geography.
Typescript. Includes bibliographical references (leaves 82-88). Also available on the Internet. MODE OF ACCESS via web browser by entering the following URL: http://wwwlib.umi.com/cr/yorku/fullcit?pMQ39192.
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Wu, Bo-En, and 吳伯恩. "Photochemical Metal Organic Deposition of FeOx Catalyst on BiVO4 for Improving Solar-Driven Water Oxidation Efficiency." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/7695m9.

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碩士
國立臺灣科技大學
化學工程系
105
Serving as a photoelectrochemical water splitting material, monoclinic BiVO4 satisfies many requirements for a highly active photoanode, such as moderate band gap (2.55eV), favorable chemical and photoelectrochemical stability, low overpotential for oxygen evolution reaction. However, it suffers from a key drawback: the slow kinetics of photon-generated charge carrier reacting with water molecules. Therefore, a layer of metal oxide oxygen evolution reaction catalyst, preparing by photochemical metal-organic deposition (PMOD), was introduced on the BiVO4 photoanode surface to enhance the efficiency of photoelectrochemical water splitting reaction. In this study, amorphous iron oxide catalyst was deposited on the BiVO4 photoanode. It is found that there is an optimal thickness for the metal oxide catalyst due to the competition between the light sheltering effect of this catalyst layer and the amount for catalyst for reaction. With the introduction of this catalyst layer, the photocurrent density increases about two times, i.e. from 0.5 mA/cm2 for BiVO4 alone to 1.2 mA/cm2 for FeOx/BiVO4 at 1.3 V vs. RHE.
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Books on the topic "Photochemical water oxidation"

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Gupta, S. K. Sen. Trace organic removal by photochemical oxidation. Chalk River, Ont: Chalk River Laboratories, 1995.

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Photochemical purification of water and air. Weinheim: Wiley-VCH, 2003.

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Monserrat, K. J. Photochemical decomposition of H2O and NH3 using colloidal semiconductor catalysts as a method of tritium recovery from water. Mississauga: CFFTP, 1985.

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Center for Environmental Research Information (U.S.), ed. Handbook: Advanced photochemical oxidation processes. Cincinnati, Ohio: Center for Environmental Research Information, National Risk Management Research Laboratory, Office of Research and Development, U.S. Environmental Protection Agency, 1999.

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Handbook: Advanced photochemical oxidation processes. Cincinnati, Ohio: U.S. Environmental Protection Agency, Center for Environmental Research Information, National Risk Management Research Laboratory, Office of Research and Development, 1998.

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Oppenländer, Thomas. Photochemical Purification of Water and Air: Advanced Oxidation Processes (AOPs): Principles, Reaction Mechanisms, Reactor Concepts. Wiley-VCH, 2003.

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J, Jacob D., and United States. National Aeronautics and Space Administration., eds. Origin of ozone NO[subscript x] in the tropical troposphere: A photochemical analysis of aircraft observations over the South Atlantic basin. [Washington, DC: National Aeronautics and Space Administration, 1996.

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Book chapters on the topic "Photochemical water oxidation"

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Urréjola, Santiago, Claudio Cameselle, Susana Gouveia, and Mercedes Pardo. "Photochemical Oxidation of Complex Organic Contaminants in Water." In Lecture Notes in Civil Engineering, 235–42. Cham: Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-51350-4_25.

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"Use of Ultraviolet in Photochemical Synergistic Oxidation Processes in Water Sanitation." In Ultraviolet Light in Water and Wastewater Sanitation. CRC Press, 2002. http://dx.doi.org/10.1201/9781420032178.ch4.

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Lescano, M., C. Zalazar, and R. Brandi. "A combined system for arsenic removal from water by photochemical oxidation and adsorption technology." In Arsenic in the Environment - Proceedings, 664–66. CRC Press, 2014. http://dx.doi.org/10.1201/b16767-248.

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Deamer, David W. "Sources of Organic Compounds Required for Primitive Life." In Assembling Life. Oxford University Press, 2019. http://dx.doi.org/10.1093/oso/9780190646387.003.0009.

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Carbon compounds on the early Earth were not the simple mixture previously referred to as a “prebiotic soup.” Instead, there was a continuing input of organic material synthesized by geochemical and photochemical reactions in the volcanic crust and atmosphere; organic compounds were also being delivered during late accretion by the infall of interplanetary dust particles (IDPs), impacting comets, and asteroid-sized bodies. Compounds from both sources (terrestrial and not) then underwent chemical processing by volcanism, photochemistry, and mineral-driven oxidation–reduction reactions. Some of these processes were synthetic reactions that led to increasing complexity, but this was balanced by other processes such as hydrolysis and pyrolysis that degraded organic material into simpler compounds or tar-like polymers. Because the atmosphere contained no molecular oxygen, the organic compounds that formed were relatively stable as a dilute solution in the global ocean, but were also dissolved in freshwater hydrothermal pools in contact with mineral surfaces of volcanic land masses. In either case, a process was required by which the organic compounds could become sufficiently concentrated to undergo chemical reactions. Questions to be addressed: What are plausible sources of organic compounds? What is their composition and abundance? How would organic material be chemically processed on the early Earth? How can dilute organic solutes become sufficiently concentrated to undergo chemical reactions? Chapter 1 described how virtually all of the carbon now circulating in the biosphere as organic and inorganic compounds was delivered during accretion of planetesimals as the Earth formed, and it is reasonable to assume that Mars had a similar addition of carbon compounds and water after it cooled from primary accretion. On the Earth, organic substances delivered during primary accretion would have been destroyed by the heat of impacts and the moon-forming event, so the carbon compounds necessary for the origin of life were necessarily added after the Earth had cooled sufficiently for a global ocean to appear.
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Conference papers on the topic "Photochemical water oxidation"

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Torabian, A., N. Jamshidi, A. Azimi, G. N. Bidhendi, and A. Ghadimkhani. "Efficiency comparison of advanced photochemical oxidation technologies in phenol removal from aqueous solution in Iran." In WATER RESOURCES MANAGEMENT 2009. Southampton, UK: WIT Press, 2009. http://dx.doi.org/10.2495/wrm090211.

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