Dissertations / Theses on the topic 'Photoelectrochemical'
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Pilkington, Matthew B. G. "Photoelectrochemical E.S.R." Thesis, University of Oxford, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.253279.
Full textBuan, Marthe Emelie Melandsø. "Photoelectrochemical Hydrogen Production." Thesis, Norges teknisk-naturvitenskapelige universitet, Institutt for materialteknologi, 2012. http://urn.kb.se/resolve?urn=urn:nbn:no:ntnu:diva-19101.
Full textShan, Ying. "Colloidal photoelectrochemical systems." Thesis, Imperial College London, 1990. http://hdl.handle.net/10044/1/46546.
Full textViger, Marie-Élise. "Photoelectrochemical degradation of ciprofloxacin." Thesis, McGill University, 2010. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=92310.
Full textIn this research a photoelectrochemical reactor with a TiO2-RuO2 working electrode was built to study its possible application for the treatment of antibiotic-containing wastewaters. Ciprofloxacin was chosen as a model antibiotic.
Degradation of ciprofloxacin was carried out photocatalitically, electrochemically and photoelectrochemically. All three methods were successful in degrading the antibiotic. However, photoelectrochemical degradation was found to be significantly more efficient than the other two techniques due to a synergetic factor. For instance after one hour at a current of 0.4A for 1mM of ciprofloxacin, photoelectrochemical process degrades 56% while electrochemical and photocatalytic process only degrades 41% and 3% respectively.
Overall, it was demonstrated that photoelectrochemical degradation represents possibly a viable method for the treatment of antibiotic-containing industrial wastewaters.
Les produits pharmaceutiques sont seulement partiellement dégradés dans les centres de traitement des eaux usées. Des antibiotiques se retrouvent donc dans les ruisseaux et rivières. Leur présence cause une résistance grandissante des bactéries aux traitements antibiotiques.
Un réacteur photoélectrochimique avec une électrode RuO2-TiO2 fut construit pour déterminer s'il pouvait être utilisé pour le traitement des eaux usées contenant des antibiotiques. La ciprofloxacine fut choisie comme modèle antibiotique.
Les procédés photochimique, électrochimique et photoélectrochimique peuvent tous dégrader la ciprofloxacine. Le meilleur résultat est obtenu avec la dégradation photoélectrochimique grâce à un phénomène synergétique. Par exemple pour la dégradation d'une solution de 1mM de ciprofloxacine avec un courant de 0.4A, le procédé photoélectrochimique dégrade 56% tandis que les procédés électrochimique et photochimique dégradent respectivement 41% et 3%.
La dégradation photoélectrochimique s'avère donc prometteuse pour le traitement des eaux usées contenant des antibiotiques.
Trevellick, P. R. "Photoelectrochemical studies on semiconductors." Thesis, University of Oxford, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.371584.
Full textKoker, Lynne. "Photoelectrochemical formation of porous silicon." Thesis, University of Birmingham, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.368290.
Full textHickey, Stephen Gerard. "Photoelectrochemical studies of chalcogenide nanoparticles." Thesis, University of Bristol, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.393089.
Full textDavies, John Phillip. "Mechanistic studies of photoelectrochemical systems." Thesis, Imperial College London, 1985. http://hdl.handle.net/10044/1/37669.
Full textDukku, Bappah Mohammed. "The kinetics of photoelectrochemical systems." Thesis, Imperial College London, 1987. http://hdl.handle.net/10044/1/38293.
Full textIrvine, J. T. S. "The photoelectrochemical reduction of carbon dioxide." Thesis, University of Ulster, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.378753.
Full textHassan, Ibrahim. "Solar energy conversion by photoelectrochemical processes." Thesis, University of Bath, 2011. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.542078.
Full textBurch, Henry Arthur. "Nanostructured electrodes for photoelectrochemical water splitting." Thesis, University of Birmingham, 2016. http://etheses.bham.ac.uk//id/eprint/6903/.
Full textHöjer, Pontus. "Photoelectrochemical Water-Splitting using 3C-SiC." Thesis, Linköpings universitet, Halvledarmaterial, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-139761.
Full textGamstedt, Heléne. "Ionic Liquid Electrolytes for Photoelectrochemical Solar Cells." Doctoral thesis, KTH, Chemistry, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-426.
Full textPotential electrolytes for dye-sensitized photoelectrochemical solar cells have been synthesized and their applicability has been investigated. Different experimental techniques were used in order to characterize the synthesized electrolytes, such as elemental analysis, electrospray ionisation/mass spectrometry, cyclic voltammetry, dynamic viscosity measurements, as well as impedance, Raman and NMR spectroscopy. Some crystal structures were characterized by using single crystal X-ray diffraction.
In order to verify the eligibility of the ionic compounds as electrolytes for photoelectrochemical solar cells, photocurrent density/photovoltage and incident photon-to-current conversion efficiency measurements were performed, using different kinds of light sources as solar simulators. In electron kinetic studies, the electron transport times in the solar cells were investigated by using intensitymodulated photocurrent and photovoltage spectroscopy. The accumulated charge present in the semiconductor was studied in photocurrent transient measurements.
The ionic liquids were successfully used as solar cell electrolytes, especially those originating from the diethyl and dibutyl-alkylsulphonium iodides. The highest overall conversion efficiency of almost 4 % was achieved by a dye-sensitized, nanocrystalline solar cell using (Bu2MeS)I:I2 (100:1) as electrolyte (Air Mass 1.5 spectrum at 100 W m-2), quite compatible with the standard efficiencies provided by organic solvent-containing cells. Several solar cells with iodine-doped metal-iodidebased electrolytes reached stable efficiencies over 2 %. The (Bu2MeS)I:I2-containing cells showed better long-term stabilities than the organic solvent-based cells, and provided the fastest electron transports as well as the highest charge accumulation.
Several polypyridyl-ruthenium complexes were tested as solar cell sensitizers. No general improvements could be observed according to the addition of amphiphilic co-adsorbents to the dyes or nanopartices of titanium dioxide to the electrolytes. For ionic liquid-containing solar cells, a saturation phenomena in the short-circuit current densities emerged at increased light intensities, probably due to inherent material transport limitation within the systems.
Some iodoargentates and -cuprates were structurally characterized, consisting of monomeric or polymeric entities with anionic networks or layers. A system of metal iodide crownether complexes were employed and tested as electrolytes in photoelectrochemical solar cells, though with poorer results. Also, the crystal structure of a copper-iodide-(12-crown-4) complex has been characterized
Nissfolk, Jarl. "Charge Transport Processes in Mesoporous Photoelectrochemical Systems." Doctoral thesis, KTH, Organisk kemi, 2009. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-9849.
Full textQC 20100804
Gamstedt, Heléne. "Ionic liquid electrolytes for photoelectrochemical solar cells /." Stockholm, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-426.
Full textFlake, John Christopher. "Photoelectrochemical etching of silicon in nonaqeous electrolytes." Diss., Georgia Institute of Technology, 1999. http://hdl.handle.net/1853/13278.
Full textDavidson, Alison. "Photoelectrochemical cells for the treatment of wastewater." Thesis, University of Ulster, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.272204.
Full textAltalhi, Amal A. "Energy conversion and storage via photoelectrochemical methods." Thesis, University of Hull, 2013. http://hydra.hull.ac.uk/resources/hull:16512.
Full textThorne, James E. "Understanding the Limitations of Photoelectrochemical Water Splitting." Thesis, Boston College, 2018. http://hdl.handle.net/2345/bc-ir:108257.
Full textArtificial photosynthesis is achieved by placing a semiconductor in water, where photoexcited charges generate a photovoltage at the surface of the semiconductor. However, solar to fuel efficiencies of earth abundant metal oxides and metal nitrides remain limited by their low photovoltages. Many different treatments have been used to improve the photovoltages of semiconductors, such as photocharging, surface regrowths, or the addition of heterogeneous catalysts. However, in these treatments, it remains unclear whether the enhanced photovoltage arises from improved kinetics or energetics. In many of the following studies, the surface kinetics of different semiconductors are measured in order to quantify how surface kinetics are related to the photovoltage of these materials. Different spectroscopic measurements are made along with detailed analysis of the Fermi level and quasi Fermi level in order to corroborate the kinetic data with energetic data. Together, this dissertation explores a multitude of methods and procedures that demonstrate how the photovoltage of semiconductors can be understood and manipulated for photoelectrochemial artificial photosynthesis
Thesis (PhD) — Boston College, 2018
Submitted to: Boston College. Graduate School of Arts and Sciences
Discipline: Chemistry
Eklund, John C. "Electrode reaction dynamics." Thesis, University of Oxford, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.297021.
Full textAhmed, Samina. "Electrochemical methods for the investigation of supported semiconductor photocatalysis." Thesis, University of Warwick, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.342520.
Full textCotting, Thomas Stefan. "Photoelectrochemical characterization of semiconductors for solar energy conversion /." [S.l.] : [s.n.], 1989. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=8800.
Full textArdoin, Noel A. "The effects of electrolyte chemistry in photoelectrochemical cells." Thesis, Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/11833.
Full textRandorn, Chamnan. "Synthesis and characterisation of materials for photoelectrochemical applications." Thesis, University of St Andrews, 2010. http://hdl.handle.net/10023/1716.
Full textHutton, Roger S. "Optical and photoelectrochemical studies of GaAs and GaAlAs." Thesis, University of Southampton, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.280857.
Full textEmig, Christopher Joseph. "Photoelectrochemical array platform for genomic scale DNA synthesis." Thesis, Massachusetts Institute of Technology, 2006. http://hdl.handle.net/1721.1/37200.
Full textIncludes bibliographical references (leaves 56-58).
Molecular and synthetic biologists have increasing demand for large, high-fidelity constructs of synthetic DNA. Recent developments in harvesting oligonucleotides from DNA microarrays has proven that these can be assembled into large constructs of DNA for costs significantly less than traditional methods. This thesis presents a complete platform for the photoelectrochemical cleavage of protecting groups during in situ DNA synthesis. Photoelectrochemically patterned microarrays of phosphoramidite dye were produced with spot sizes of 100 um. This technology holds the potential for lowest cost per base pair of DNA produced over alternative microarray technologies, and may prove to be useful in de novo synthesis of large DNA constructs.
by Christopher Joseph Emig.
M.Eng.
Chamier, Jessica. "Photoelectrochemical detection of inorganic mercury in aqueous solutions." Thesis, Stellenbosch : University of Stellenbosch, 2010. http://hdl.handle.net/10019.1/5213.
Full textENGLISH ABSTRACT: Due to the adverse human health effects associated with mercury (Hg) toxicity, an innovative method for inorganic mercury (Hg2+) determination in aqueous solutions was investigated. The method of Hg2+ determination involved the use of a Hg2+ selective chemosensor immobilised onto an indium tin oxide (ITO) coated electrode in a photoelectrochemical cell. Upon light activation and in the presence of Hg2+ the fluorescent chemosensor absorbed a photon, and charge separation would occur according to the nature of the semiconductive material coated onto the ITO substrate. The charge separators and semiconductors investigated were an n-type carrier TiO2, polyaniline (PANI) and copolymers of polyaniline and 2-bromoaniline (P[A-co-2- BrA]s) with different monomer ratios. The polymer and copolymer coated ITO working electrodes used in the Hg2+ sensitive photoelectrochemical cell were electrochemically evaluated. The results demonstrated that the ITO coated with PANI had superior conductive and semiconductive properties compared to ITO coated with P[A-co-2-BrA]s. The ITO glass substrates were coated with TiO2, PANI or P[A-co-2-BrA]s, followed by the fluorescent chemosensor, a rhodamine 6G derivative (RS). The electrodes were subsequently photoelectrochemically evaluated in a photoelectrochemical cell in the presence of Hg2+. The PANI-RS coated electrode behaved as a photocathode in the presence of Hg2+ under illumination. The PANI-RS photoresponse increased with increasing Hg2+ concentration in the range 10 to 150 μg L-1, with a limit of detection of 6 μg L-1. ITO coated with TiO2 (ITO/TiO2) followed by a composite of PANI and RS had a linear photoanodic response in the Hg2+ concentration range of 10 to 200 μg L-1 and a limit of detection of 5 μg L-1. ITO and ITO/TiO2 coated with the P[A-co-2-BrA]s and RS had considerably lower photoresponses towards Hg2+ in aqueous solutions compared to PANI-RS. The photoresponses decreased with increasing 2-bromoaniline content. The PANI and P[A-co-2-BrA]s coated ITO and ITO/TiO2 electrodes were then also coated with another rhodamine 6G derivative with a thiolactone moiety (RT). The PANI coated electrode yielded a photocathodic response in the Hg2+ concentration range 0.2 to 5 μg L-1. ITO coated with TiO2 had no photoresponse towards Hg2+ due to repulsive forces between TiO2 and the RT molecules. The photoresponses of the working photoelectrodes towards Hg2+ were further evaluated in a custom photoelectrochemical Hg2+ detector. The photoresponses of PANI-RS and PANI-RT gave qualitative results for the presence of Hg2+ in aqueous solutions in concentrations as low as 2 μg L-1.
AFRIKAANSE OPSOMMING: Weens die negatiewe gesondheids aspekte toegeskryf aan Hg2+ vergiftiging is ‘n nuwe innoveerende metode van Hg2+ deteksie in wateroplossings ondersoek. Die voorgestelde metode van Hg2+ deteksie behels die gebruik van ‘n Hg2+ selektiewe chemosensor geimmobiliseer op ITO elektrodes in ‘n fotoelektrochemiese sel. Met lig aktivering en in die teenwoordigheid van Hg2+, absorbeer die fluoreseerende chemosensor ‘n foton, gevolg deur lading skeiding, soos bepaal deur die aard van die halfgeleidende material wat op die ITO platjies bedek is. Die halfgeleiers wat ondersoek was, was TiO2, PANI en ko-polimere van PANI met 2-bromoanilien. Die polimeer en kopolimeer bedekte ITO werkende elektrodes wat in die Hg2+ sensitiewe fotoelektrochemiese sel gebruik is, is elektrochemies geevalueer. Daaruit is gevind dat ITO bedek met PANI superieure geleier en halfgeleier eienskappe het in vergelyking met die ITO wat bedek is met P[A-co-2-BrA] kopolimere. Die ITO glas plaatjies is bedek met TiO2, PANI en die P[A-co-2-BrA] kopolimere gevolg deur die fluoresseerende chemosensor, RS. Die elektrodes is onderskeidelik fotoelektrochemies getoets in ‘n fotoelektrochemiese sel in die teenwoordigheid van Hg2+. Die PANI-RS elektrode het soos ‘n fotokatode opgetree in die teewoordigheid van Hg2+ onder beligting. Die foto-reaksie van die PANI-RS elektrode teeonoor Hg2+ het liniêr toegeneem van 10 μg L-1 tot 150 μg.L-1 met ‘n limiet van deteksie op 6 μg L-1. ITO/TiO2 wat bedek is met ‘n samestelling van PANI en RS het ‘n fotoanodiese reaksie gehad teenoor Hg2+ in die liniêre reeks van 10 tot 200 μg L-1 met ‘n deteksie limiet van 5 μg L-1. ITO en ITO/TiO2 bedek met die P[A-co-2-BrA] kopolimere het heelwat laer fotoreaksies getoon teenoor Hg2+ in waterige oplossings Die fotoreaksie het afgeneem met toeneemende 2-bromoanilien inhoud van die kopolimeer. Die PANI en P[A-co-2-BrA] kopolimere bedekte ITO en ITO/TiO2 elektrodes is verder bedek met ‘n tweede rhodamine 6G afgeleide, RT. Die ITO/PANI bedek met RT het weer ‘n fotokatodiese reaksie gehad teenoor Hg2+ in die konsentrasie interval 0.2 tot 5 μg L-1. Die ITO/TiO2 elektrode bedek met die PANI-RT samestelling het geen fotoreaksie gehad teenoor Hg2+ weens afstotende kragte tussen die TiO2 and RT molekules. Die fotoreaksies van die verskeie werkende elektrodes teenoor Hg2+ is verder getoets in ‘n tuisgemaakte fotoelektrochemiese Hg2+ detektor. Die fotoreaksies van die PANIRS en PANI-RT samestellings op ITO het kwalitatiewe resultate gelewer vir die teenwoordigheid van Hg2+ in waterige oplossings in konsentrasies tot so laag soos 2 μg L-1.
Tengeler, Sven. "Cubic Silicon Carbide For Direct Photoelectrochemical Water Splitting." Thesis, TUprints, 2017. http://www.theses.fr/2017GREAI079/document.
Full textThe goal of this work was to investigate cubic silicon carbide as anode material for direct photoelectrochemical water splitting. From the performed measurements (mostly photoelectron spectroscopy, electrochemical measurements, Raman and UV-Vis spectroscopy) n-type cubic silicon carbide’s low oxygen evolution efficiency could be related to some fundamental problems.Primarily, the attainable photocurrent is limited by the flux of photo generated holes to the semiconductor surface. As cubic silicon carbide is a indirect semiconductor, the low absorption coefficient in combination with a high doping concentration and low hole diffusion length were determined as limiting factors. An additional epitaxial n- cubic silicon carbide film resulted in a significant improvement of the photocurrent.The obtainable photovoltage and recombination losses are mostly dependent on the surface properties. While a buried junction between the silicon carbide and a thin catalyst layer has proven to be promising for improving both properties, it still needs optimization, as Fermi level pinning from interface defect states drastically reduces the photovoltage
Masilela, Nkosiphile. "Photophysical and photoelectrochemical properties of water soluble metallophthalocyanines." Thesis, Rhodes University, 2010. http://hdl.handle.net/10962/d1004991.
Full textDong, Wei. "Photoelectrochemical catalysis of waste water in pharmaceutical industry." Магістерська робота, Kyiv National University of Technology and Design, 2021. https://er.knutd.edu.ua/handle/123456789/19552.
Full textYilmaz, P. "Photoelectrochemical performance of catalyst systems based on Pd deposited TiO2 and Ag incorporated BiFeO3." Thesis, Queen Mary, University of London, 2016. http://qmro.qmul.ac.uk/xmlui/handle/123456789/18403.
Full textParra, Puerto Andrés. "Towards Artificial Photosynthesis: Photoelectrochemical CO2 Reduction to Solar Fuels." Doctoral thesis, Universitat de Barcelona, 2015. http://hdl.handle.net/10803/347965.
Full textEsta tesis se ha desarrollado con el objetivo de probar el concepto de la reducción del dióxido de carbono a metano, mediante una reducción de los potenciales necesarios usando un mecanismo fotocatalítico. Parte de la energía solar es transferida a la reacción obteniendo una mejora en el balance energético total. El trabajo desarrollado se focaliza primero en el estudio de materiales nanoestructurados fotoactivos basados en dióxido de titanio obtenidos por anodización, generando nanotubos, y por síntesis hidrotermal obteniendo nanohilos sobre un sustrato conductor transparente, los cuales permiten obtener mayores superficies activas mejorando la colección de fotones, similar a las reacciones luminosas en la fotosíntesis. En segundo lugar, se ha estudiado la electroreducción del dióxido de carbono a metano usando cátodos de cobre y oxido de cobre (similar a las reacciones oscuras de la fotosíntesis). Usando el cobre como cátodo, se ha observado la obtención de metano a diferentes densidades de corriente aplicadas para poder observar la productividad respecto al potencial medido. Para el caso de los cátodos de óxido de cobre, no se ha encontrado producción de metano pero si de etileno. En estos cátodos se ha observado un efecto proveniente de la reducción de las capas de los diferentes óxidos de cobre, generados en la síntesis térmica, hacia un cobre catalíticamente activo para la reacción de reducción del dióxido de carbono. Este efecto se ha estudiado profundamente mediante un estudio de los cambios cristalográficos y superficiales a determinados tiempos. Finalmente, se ha estudiado el efecto de la humidificación del dióxido de carbono (gas) previa a la entrada a la celda electroquímica. Como parte final se ha realizado una evaluación energética de los fotoánodos generados por síntesis hidrotermal y de los cátodos basados en cobre estudiados, para poder implementar ambos en una celda fotoelectroquímica completa. En esta parte se ha estudiado los valores de los potenciales externos necesarios para que se pueda dar la reacción, asumiendo un 100% de eficiencia hacia la producción de metano para los cátodos de cobre y de etileno para los de óxido de cobre.
Hedbor, Sigrid, and Linnéa Klar. "Plant Extract Sensitised Nanoporous TiO2 Thin Film Photoelectrochemical Cells." Thesis, Uppsala University, Department of Earth Sciences, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-88885.
Full textFör att undersöka skillnad i prestationsförmåga mellan celler sensiterade med växtextraktsbaserad färg, och celler sensiterademed ruteniumkomplex-baserad färg, samt huruvida presskraften påverkar en cells prestationsförmåga, tillverkades icke-slutna fotoelektrokemiska färg-sensiterade solceller med tunnfilmsfotoelektroder av pressad, nanoporös titandioxid.
Cellerna pressades med tre olika presskrafter och sensiterades med växtextraktsfärg från rödkål, rödbeta, viol och henna, samt en ruteniumkomplex-baserad färg som fick utgöra kontrollbetingelse. För varje cell uppmättes IPCE- och iV-värde och motsvarande fyllnadsgrad (fill factor) och dessa jämfördes.
Ingen signifikant skillnad kunde fastställas mellan celler pressade med olika presstryck. Bland cellerna sensiterade med växtextraktbaserad färg presterade rödbeta bäst. Cellen med högst effektivitet hade fyllnadsgraden 70%. Emellertid uppvisade de växtfärgade cellerna genomgående sämre effektivitet än de rutenium-sensiterade och fotoströmmarna var mycket låga. IPCE-värdena var allmännt låga: den bäst presterande cellen hade ett IPCE-värde på något över 0,06 i våglängdsintervallet 440-470 nm. En förklaring till detta är de övriga ämnen som förutom pigment återfinns i de växtbaserade färgerna. Dessa hindrar pigmentmättnad och förhindrar att växtfärgen når ruteniumfärgens intensitet. En annan anledning består i svårigheten att passa ihop energinivåerna i cellens elektrolyt-halvledarsystem med energinivåerna hos pigmentet i växtfärgen.
Non-sealed photoelectrochemical dye sensitised solar cells (DSSC) with pressed nanoporous TiO2 thin film photoelectrodes were manufactured for the purposes of finding out whether plant extractbased dye sensitised cells can perform as well as ruthenium complex-based dye sensitised cells and whether the pressing force affects the cell performance.
The cells were pressed with three different pressing forces and sensitised with plant extracts from red cabbage, beetroot, violet and henna, as well as with a ruthenium complex-based dye for comparison. The IPCE and iV values and the corresponding fill factors of the cells were evaluated and compared.
No significant difference between the cells pressed with different pressing forces could be established. Among the plant extract-based dye sensitised cells the ones sensitised with beetroot extract performed best. The cell that achieved the highest efficiency had a fill factor of 70%. Compared to the ruthenium-sensitised cells the overall performance of the plant dye sensitised cells were very poor and the produced photocurrents very low. The IPCE values were generally low: one of the best-performing cells had an IPCE value of slightly over 0.06 in the 440-470 nm wavelength ranges. One reason for this is that it is difficult to obtain a plant extract dye as intense and deep in colour as ruthenium complex-based dyes, since pigment saturation is obstructed by the presence of other chemical compounds in the plant extracts. Another is that it is a delicate and difficult matter to match the energy levels in the electrolyte-semiconductor system with the energy levels of the pigments in the plant extract dye.
Rodríguez, Rodríguez Juan Martín. "Sputter deposited titanium oxide films for photoelectrochemical water purification." Universidad Nacional de Ingeniería. Programa Cybertesis PERÚ, 2000. http://cybertesis.uni.edu.pe/uni/2000/rodriguez_rj/html/index-frames.html.
Full textSugunan, Abhilash. "Fabrication and Photoelectrochemical Applications of II-VI Semiconductor Nanomaterials." Doctoral thesis, KTH, Funktionella material, FNM, 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-95410.
Full textQC 20120525
Jami, Maryam [Verfasser]. "Nanocrystalline materials for (solar) photoelectrochemical water splitting / Maryam Jami." Hannover : Technische Informationsbibliothek (TIB), 2017. http://d-nb.info/1141305631/34.
Full textKucernak, Anthony Robert John. "Scanning laser photoelectrochemical studies of oxide films on metals." Thesis, University of Southampton, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.305577.
Full textBuchanan, J. S. "Electrochemical and photoelectrochemical studies of anodic films on lead." Thesis, University of Southampton, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.356528.
Full textCampbell, S. A. "Structural and photoelectrochemical studies of electrodeposited lead dioxide films." Thesis, University of Southampton, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.378266.
Full textMlcak, Richard. "Electrochemical and photoelectrochemical micromachining of silicon in HF electroytes." Thesis, Massachusetts Institute of Technology, 1994. http://hdl.handle.net/1721.1/37526.
Full textKatz, Jordan E. Okumura Mitchio Lewis Nathan Saul. "Metal oxide-based photoelectrochemical cells for solar energy conversion /." Diss., Pasadena, Calif. : California Institute of Technology, 2008. http://resolver.caltech.edu/CaltechETD:etd-10192007-190231.
Full textYang, Shangfeng. "Ultrathin films of metallofullerenes : preparation, characterization and photoelectrochemical applications /." View abstract or full-text, 2003. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202003%20YANG.
Full textZhang, Xuemei. "Solution-processed nanomaterials for applications in photoelectrochemical solar cells." Thesis, Imperial College London, 2015. http://hdl.handle.net/10044/1/58236.
Full textViger, Marie-Élise. "Photoelectrochemical degradation of ciprofloxacin." 2010. http://digitool.Library.McGill.CA:8881/R/?func=dbin-jump-full&object_id=92310.
Full textHwang, Jung-Min, and 黃忠民. "Photoelectrochemical etching in GaN." Thesis, 1999. http://ndltd.ncl.edu.tw/handle/75265564757670744155.
Full text國立清華大學
電機工程學系
87
Etching in GaN is an important priori for device processing due to the chemical inertness, hardness, and easily introducing damage in device process. The plasma/energetic ion etching with high reactive gas will provide a smooth etching bottom and vertical sidewall. But the ion bombardment induced damage will degrade the device performance. Another disadvantage was the different volatility of Ga and N reactant which will produce a non-stoichiometric surface. The damaged surface will limit the device application. So a mild etching process of wet etching was considered. Due to the chemical inertness of GaN, chemical wet etching can not be used for etching process, although wet etching is a low damage etching technology. From the discussion above, we want to find an etching process with high etching rate, smooth etching surface, vertical sidewall and near damage free for etching GaN. In this thesis, photoelectrochemical (PEC) etching GaN was shown to yield high etching rate comparable with dry etching and vertical sidewall. But the enhancement in etching surface roughness and etching induced damage related to yellow luminescence also appeared in this etching process. The boiled KOH solution was used to remove the PEC etching damage successfully from the PL identification. The etching surface was also smoothed by post-treatment with boiled KOH solution. Another important contribution is the rapidly identify threading dislocation density of the film by PEC etching. From selective etching of the threading dislocation and crystalline GaN, we could rapidly identify the dislocation density without using the TEM. We also use this skill to identify the dislocation related luminescence. This is the first report on the origin of this dislocation related PL peak. In this work, we have developed an etching process of PEC etching with boiled KOH solution to obtain a high etching rate, smoothing etching surface, vertical sidewall and near damage free etching. We also showed the etching mechanism and studied the etching damage. The etching process could be applied for device processing, laser cavity formation, nanostructure fabrication and surface damage removal.
Liu, Ching-Fang, and 劉靜芳. "Coupling photoelectrochemical catalysis and photoelectrochemical Fenton process for the treatment of dye industrial wastewater." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/26227799481044786150.
Full text國立交通大學
環境工程系所
104
In recent years, advanced oxidation techniques including electrochemical advanced oxidation processes (EAOP) have gained much attention. EAOP have been employed widely for the decontamination of wastewaters containing high-strength organic pollutants due to their versatility, high efficiency, and environmental compatibility. The effectiveness of EAOP such as photoelectrochemical catalysis (PEC), electro-Fenton (EF) and photoelectro-Fenton (PEF) are ascribed to the generation of hydroxyl radicals (OH•), which has a high redox potential that can react non-selectively with most organic compounds to produce CO2, water, and inorganic ions. Recently, many coupled and hybrid electrochemical processes have been proposed aiming developing more powerful processes for dyes removal. It provides more advantages than individual electrochemical processes owing to the high degradation performance on the treatment of wastewater via combined different electrochemical methods. Therefore, the purpose of this thesis was to develop the coupled PEC/PEF process by combining TiO2/Ti and stainless steel dual anode system. In the first parts of this study, the TiO2/Ti and stainless steel anodes would be integrated individually. After that, the combining both anodes with coupled PEC/PEF process for treatment of dye wastewater treatment was integrated in the second part of this study. The first part was the integration of TiO2/Ti photoanode, the TiO2/Ti photoanode was prepared by electrophoretic deposition (EPD) process. The performance of TiO2/Ti photoanode was tested by degradation of azo dye Orange G (OG) using a PEC system. Results of surface analysis and electrochemical analysis revealed that the optimal EPD condition was a deposition potential of 180 V for 1 min and annealed at 350oC. These results showed that the coupling effect of photocatalytic and electrochemical oxidation processes was evaluated in terms of the decolorization of OG. The degradation of OG increased in the following increasing order: photocatalysis (PC) < electrochemical oxidation (EO) < PEC. The degradation of OG follows the pseudo first-order kinetic in PEC process, which proposed the OH radical is the major player in the decolorization reaction. The second part was the integration of stainless steel (SS) anode and graphite cathode system with EF and PEF processes. In this system, the ferrous ions being derived from a sacrificial stainless steel anode and hydrogen peroxide being produced at a graphite cathode. Results indicated that the applied current controlled the rate of electrogeneration of ferrous ion and hydrogen peroxide. The optimal [H2O2]/[Fe2+] (molar) ratio was 3.58 at an applied current density of 45 uA/cm2 for the SS-graphite system. The OG degradation efficiency in the PEF process was greater than that of the EF process under otherwise identical conditions. At an applied current density of 45 uA/cm2, stainless steel anode achieved a decolorization of 85% after 3 h. The degradation of OG followed the pseudo first-order kinetics for both EF and PEF processes, which proposed that OH radical was a main species for the decolorization reaction. For coupling the PEC and PEF two processes, the dual anode electrochemical system by combining the TiO2/Ti and stainless steel was developed for OG treatment. From the result of kinetic aspect, the efficiency of the PEC/PEF process depended on the Fe2+ and H2O2 electrogeneration which yielded OH radical in the solution bulk, which could promote the oxidative degradation of OG and its byproducts. The degradation of OG increased in the following increasing order: photocatalysis < electrochemical oxidation < photoelectrochemical degradation < electro-Fenton < photoelectro-Fenton < coupling the photoelechemical and photoelectro-Fenton. After the 7 h reaction time, a decolorization of 99.8% and TOC removal of 70% were achieved at an applied current density of TiO2/Ti and stainless steel anodes were 75 uA/cm2 and 45 uA/cm2. The degradation of OG following the pseudo first-order kinetic for PEC/PEF process.
Chao, Wei-Chung, and 趙維中. "Flow-Enhanced Photoelectrochemical Hydrogen Production." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/wg7799.
Full textYang, Bo. "Micromachining of GaN using photoelectrochemical etching." 2005. http://etd.nd.edu/ETD-db/theses/available/etd-06292005-130851/.
Full textAzevedo, João Carlos Almeida Monteiro. "Solar Photoelectrochemical Energy Storage: Materials Devices." Doctoral thesis, 2016. https://repositorio-aberto.up.pt/handle/10216/94736.
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