Academic literature on the topic 'Photopolymerization'

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Journal articles on the topic "Photopolymerization"

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Peyrot, Fabienne, Sonia Lajnef, and Davy-Louis Versace. "Electron Paramagnetic Resonance Spin Trapping (EPR–ST) Technique in Photopolymerization Processes." Catalysts 12, no. 7 (2022): 772. http://dx.doi.org/10.3390/catal12070772.

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To face economic issues of the last ten years, free-radical photopolymerization (FRP) has known an impressive enlightenment. Multiple performing photoinitiating systems have been designed to perform photopolymerizations in the visible or near infrared (NIR) range. To fully understand the photochemical mechanisms involved upon light activation and characterize the nature of radicals implied in FRP, electron paramagnetic resonance coupled to the spin trapping (EPR–ST) method represents one of the most valuable techniques. In this context, the principle of EPR–ST and its uses in free-radical phot
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Jessop, Julie L. P. "A Practical Primer: Raman Spectroscopy for Monitoring of Photopolymerization Systems." Polymers 15, no. 18 (2023): 3835. http://dx.doi.org/10.3390/polym15183835.

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Photopolymerization systems provide compelling advantages for industrial applications due to their fast reaction kinetics, wide selection of monomers for physical property development, and energy-efficient initiation via illumination. These same advantages can present challenges when attempting to monitor these reactions or characterize their resulting polymers; however, Raman spectroscopy can provide the flexibility and resolution needed. In this overview, Raman spectroscopy is compared to common characterization techniques, such as photo-differential scanning calorimetry and infrared spectro
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Elian, Christine, Vlasta Brezová, Pauline Sautrot-Ba, Martin Breza, and Davy-Louis Versace. "Lawsone Derivatives as Efficient Photopolymerizable Initiators for Free-Radical, Cationic Photopolymerizations, and Thiol—Ene Reactions." Polymers 13, no. 12 (2021): 2015. http://dx.doi.org/10.3390/polym13122015.

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Two new photopolymerizable vinyl (2-(allyloxy) 1,4-naphthoquinone, HNQA) and epoxy (2-(oxiran-2yl methoxy) 1,4-naphthoquinone, HNQE) photoinitiators derived from lawsone were designed in this paper. These new photoinitiators can be used as one-component photoinitiating systems for the free-radical photopolymerization of acrylate bio-based monomer without the addition of any co-initiators. As highlighted by the electron paramagnetic resonance (EPR) spin-trapping results, the formation of carbon-centered radicals from an intermolecular H abstraction reaction was evidenced and can act as initiati
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Lin, Jui-Teng, Jacques Lalevee, and Da-Chun Cheng. "A Critical Review for Synergic Kinetics and Strategies for Enhanced Photopolymerizations for 3D-Printing and Additive Manufacturing." Polymers 13, no. 14 (2021): 2325. http://dx.doi.org/10.3390/polym13142325.

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The synergic features and enhancing strategies for various photopolymerization systems are reviewed by kinetic schemes and the associated measurements. The important topics include (i) photo crosslinking of corneas for the treatment of corneal diseases using UVA-light (365 nm) light and riboflavin as the photosensitizer; (ii) synergic effects by a dual-function enhancer in a three-initiator system; (iii) synergic effects by a three-initiator C/B/A system, with electron-transfer and oxygen-mediated energy-transfer pathways; (iv) copper-complex (G1) photoredox catalyst in G1/Iod/NVK systems for
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Zhang, Jing, Jacques Lalevée, Jiacheng Zhao, Bernadette Graff, Martina H. Stenzel, and Pu Xiao. "Dihydroxyanthraquinone derivatives: natural dyes as blue-light-sensitive versatile photoinitiators of photopolymerization." Polymer Chemistry 7, no. 47 (2016): 7316–24. http://dx.doi.org/10.1039/c6py01550f.

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Dihydroxyanthraquinone derivatives can be used as versatile blue-light-sensitive photoinitiators for cross-linked free radical photopolymerization, RAFT photopolymerization, and cationic photopolymerization.
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Lang, Margit, Stefan Hirner, Frank Wiesbrock, and Peter Fuchs. "A Review on Modeling Cure Kinetics and Mechanisms of Photopolymerization." Polymers 14, no. 10 (2022): 2074. http://dx.doi.org/10.3390/polym14102074.

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Photopolymerizations, in which the initiation of a chemical-physical reaction occurs by the exposure of photosensitive monomers to a high-intensity light source, have become a well-accepted technology for manufacturing polymers. Providing significant advantages over thermal-initiated polymerizations, including fast and controllable reaction rates, as well as spatial and temporal control over the formation of material, this technology has found a large variety of industrial applications. The reaction mechanisms and kinetics are quite complex as the system moves quickly from a liquid monomer mix
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Lin, De, Huiguang Kou, Wen-Fang Shi, Hui-Ya Yuan, and Yong-Lie Chen. "Photopolymerizaton of hyperbranched aliphatic acrylated poly(amide ester). II. Photopolymerization kinetics." Journal of Applied Polymer Science 82, no. 7 (2001): 1637–41. http://dx.doi.org/10.1002/app.2003.

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Hayase, Shuji. "Cationic photopolymerization." Kobunshi 35, no. 2 (1986): 116–19. http://dx.doi.org/10.1295/kobunshi.35.116.

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Xu, Rui Xin, Li Jie Wang, and Ming Hui He. "Benzoylformamides as New Photocaged Bases for Free Radical Photopolymerization." Applied Mechanics and Materials 731 (January 2015): 573–77. http://dx.doi.org/10.4028/www.scientific.net/amm.731.573.

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Benzoylformamide (BFA) derivatives are proposed as new photocaged bases. Initially their abilities as photoinitiators to initiate the free radical photopolymerization of acrylic monomers have been investigated. Next, we detail regarding the model photopolymerization in the presence of BFA-dBA (N,N-Dibenzyl-2-oxo-2-phenylacetamide) as a photocaged base. In combination with a benzoyl peroxide initiator, BFA-dBA is able to initiate the amine-mediated redox photopolymerization of acrylates, and photopolymerization rate is markedly enhanced.
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Zhou, Hua, Yugang Huang, Yun Zhang, et al. "Hydrogen abstraction of carbon/phosphorus-containing radicals in photoassisted polymerization." RSC Advances 6, no. 73 (2016): 68952–59. http://dx.doi.org/10.1039/c6ra00156d.

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Dissertations / Theses on the topic "Photopolymerization"

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Gunduz, Nazan. "Synthesis and Photopolymerization of Novel Dimethacrylates." Thesis, Virginia Tech, 1998. http://hdl.handle.net/10919/37025.

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Four potential new monomers were prepared, all of which were structural analogues of BisGMA (2,2-bis(4-(2-hydroxy-3-methacryloxyprop-1-oxy) phenyl)propane). The synthesis of these tetrafunctional dimethacrylate monomers was based on structural modifications of Bis-GMA in the core and the side chain and required a two-step reaction. The first step was propoxylation or ethoxylation of the bisphenols and the second step was the methacrylation of the resulting products. The core structures are designated by Bis-A for isopropylidene and 6F for hexafluoropropyl. The side chain structures were des
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Bonneaud, Céline. "Synthesis and Photopolymerization of Novel Perfluoropolyalkylethers." Thesis, Montpellier, 2019. http://www.theses.fr/2019MONTS063.

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Depuis des années, les perfluoropolyalkyléthers (PFPAEs) ont démontré de multiples facettes. Ils sont utilisés dans de nombreux secteurs et actuellement en recherche dans de multiples secteurs de pointe comme l’imagerie médicale (IRM), les réacteurs microfluidiques, les vitrimères ou encore pour des revêtements haute-performance. Ma thèse s’inscrit dans le cadre du projet européen PhotoFluo. Ce projet est partagé entre trois équipes de recherche : Trinity Western University (Langley, Canada), Politecnico di Torino (Turin, Italie) et l’Ecole Nationale Supérieure de Chimie de Montpellier. Le but
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Slopek, Ryan Patrick. "In-situ Monitoring of Photopolymerization Using Microrheology." Thesis, Georgia Institute of Technology, 2005. http://hdl.handle.net/1853/7194.

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Photopolymerization is the basis of several multi-million dollar industries including films and coating, inks, adhesives, fiber optics, and biomaterials. The fundamentals of the photopolymerization process, however, are not well understood. As a result, spatial variations of photopolymerization impose significant limitations on applications in which a high spatial resolution is required. To address these issues, microrheology was implemented to study the spatial and temporal effects of free-radical photopolymerization. In this work a photosensitive, acrylate resin was exposed to ultravio
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Kim, Young-Min MacGregor John Frederick. "Photopolymerization of cycloaliphatic epoxide and vinyl ether /." *McMaster only, 2005.

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Elisseeff, Jennifer Hartt 1973. "Transdermal photopolymerization of hydrogels for tissue engineering." Thesis, Massachusetts Institute of Technology, 1999. http://hdl.handle.net/1721.1/84773.

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Ficek, Beth Ann Scranton Alec B. "The potential of cationic photopolymerization's long lived active centers." Iowa City : University of Iowa, 2008. http://ir.uiowa.edu/etd/280.

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Boddapati, Aparna. "Modeling cure depth during photopolymerization of multifunctional acrylates." Thesis, Georgia Institute of Technology, 2010. http://hdl.handle.net/1853/33934.

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The photopolymerization of multifunctional acrylates leads to the formation of a complex and insoluble network due to cross-linking. This characteristic is a useful property for stereolithography applications, where solid parts of the desired shape are cured using a pre-determined energy exposure profile. Traditionally, the required energy exposure is determined using a critical energy--depth of penetration, or Ec--Dp, model. The parameters Ec and Dp, are usually fit to experimental data at a specific resin composition and cure intensity. As a result, since the Ec--Dp model does not explicitly
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Xu, Xiaolun. "Integrated Nanoemitters on Glass-based Waveguides by Photopolymerization." Thesis, Troyes, 2020. http://www.theses.fr/2020TROY0026.

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Les nano-émetteurs et les nanosources de lumière sont des éléments essentiels pour les dispositifs photoniques. L'une des principales exigences est la capacité d'intégrer des nano-émetteurs sur des emplacements de puces optiques spécifiques. De nombreuses approches ont été explorées pour la réalisation pratique de dispositifs photoniques évolutifs. Cependant, ces méthodes présentent certaines limites, comme des opérations compliquées, des coûts de fabrication élevés et de multiples étapes de fabrication. Cette thèse vise à explorer la faisabilité de l'intégration de nanoémetteurs basés sur des
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Slopek, Ryan Patrick. "In-situ monitoring of the mechanical properties during the photopolymerization of acrylate resins using particle tracking microrheology." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2008. http://hdl.handle.net/1853/22657.

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Thesis (Ph. D.)--Chemical and Biomolecular Engineering, Georgia Institute of Technology, 2008.<br>Committee Chair: Dr. Victor Breedveld; Committee Member: Dr. Clifford Henderson; Committee Member: Dr. David Rosen; Committee Member: Dr. Peter Ludovice; Committee Member: Dr. Sai Kumar.
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Lam, Edward. "Synthesis and photochemistry of novel aromatic carbonyl photopolymerization initiators." Thesis, Manchester Metropolitan University, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.254487.

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Books on the topic "Photopolymerization"

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Scranton, Alec B., Christopher N. Bowman, and Robert W. Peiffer, eds. Photopolymerization. American Chemical Society, 1997. http://dx.doi.org/10.1021/bk-1997-0673.

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1963-, Scranton Alec B., Bowman Christopher N. 1967-, Peiffer Robert W. 1942-, American Chemical Society. Division of Polymeric Materials: Science and Engineering., and American Chemical Society Meeting, eds. Photopolymerization: Fundamentals and applications. American Chemical Society, 1997.

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Nail, Fatkullin, ed. NMR, 3D analysis, photopolymerization. Springer, 2004.

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Carr, N. A. Photopolymerization of dye-sensitized coatings by laser light. UMIST, 1991.

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1960-, Belfield Kevin, and Crivello James V. 1940-, eds. Photoinitiated polymerization. American Chemical Society, 2003.

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S, Allen Norman, ed. Photopolymerisation and photoimaging science and technology. Elsevier Applied Science, 1989.

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1947-, Fouassier Jean-Pierre, ed. Photochemistry and UV curing: New trends 2006. Research Signpost, 2006.

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Crawford, Gregory Philip. Cross-linked liquid crystalline systems: From rigid polymer networks to elastomers. Taylor & Francis, 2011.

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Kawata, Satoshi, Rainer Kimmich, Nail Fatkullin, Takayuki Ikehara, and Hiroshi Jinnai. NMR · 3D Analysis · Photopolymerization. Springer, 2004.

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NMR 3D Analysis Photopolymerization. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/b12766.

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Book chapters on the topic "Photopolymerization"

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Gooch, Jan W. "Photopolymerization." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_8687.

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Lin, Haiqing. "Photopolymerization." In Encyclopedia of Membranes. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-40872-4_1831-1.

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Mishra, Munmaya, and Biao Duan. "Photopolymerization." In The Essential Handbook of Polymer Terms and Attributes. CRC Press, 2024. http://dx.doi.org/10.1201/9781003161318-131.

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Nassar, Raja, and Weizhong Dai. "Laser Photopolymerization." In Modelling of Microfabrication Systems. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-08792-3_4.

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Gibson, Ian, David Rosen, Brent Stucker, and Mahyar Khorasani. "Vat Photopolymerization." In Additive Manufacturing Technologies. Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-56127-7_4.

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Gibson, Ian, David W. Rosen, and Brent Stucker. "Photopolymerization Processes." In Additive Manufacturing Technologies. Springer US, 2010. http://dx.doi.org/10.1007/978-1-4419-1120-9_4.

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Bongiovanni, Roberta, and Alessandra Vitale. "Vat Photopolymerization." In High Resolution Manufacturing from 2D to 3D/4D Printing. Springer International Publishing, 2022. http://dx.doi.org/10.1007/978-3-031-13779-2_2.

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Ware, Henry Oliver Tenadooah, Rihan Hai, and Cheng Sun. "Vat Photopolymerization." In Springer Handbook of Additive Manufacturing. Springer International Publishing, 2023. http://dx.doi.org/10.1007/978-3-031-20752-5_22.

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Kloosterboer, J. G., G. M. M. Van de Hei, and G. F. C. M. Lijten. "Photopolymerization of Diacrylates." In Integration of Fundamental Polymer Science and Technology. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4185-4_25.

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Gibson, Ian, David Rosen, and Brent Stucker. "Vat Photopolymerization Processes." In Additive Manufacturing Technologies. Springer New York, 2015. http://dx.doi.org/10.1007/978-1-4939-2113-3_4.

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Conference papers on the topic "Photopolymerization"

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Aftab, Jamshed, Izabela Naydenova, and Tatsiana Mikulchyk. "Photopolymerization shrinkage in holographic hybrid sol-gel material." In Holography: Advances and Modern Trends IX, edited by Antonio Fimia, Miroslav Hrabovský, and Izabela Naydenova. SPIE, 2025. https://doi.org/10.1117/12.3056037.

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Shishido, Atsushi. "Two-dimensionally aligned liquid-crystalline polymer coatings designed by patterned photopolymerization." In Liquid Crystals XXVIII, edited by Iam Choon Khoo. SPIE, 2024. http://dx.doi.org/10.1117/12.3027528.

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Yang, Yizhe, Bingshan Liu, Kaixiang Zhang, Xiaodong Liu, and Gong Wang. "Correction of manufacturability based on the slice for ceramic vat photopolymerization." In 3rd International Conference on Advanced Manufacturing Technology and Manufacturing Systems (ICAMTMS 2024), edited by Dailin Zhang and Ke Zhang. SPIE, 2024. http://dx.doi.org/10.1117/12.3038308.

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Yamaguchi, Katsumi, and Takeshi Nakamoto. "Microfabrication using laser-induced photopolymerization." In Laser-Assisted Microtechnology 2000, edited by Vadim P. Veiko. SPIE, 2001. http://dx.doi.org/10.1117/12.413747.

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Hesami, L., C. Yang, N. Noginova, and M. A. Noginov. "Control of Photopolymerization of BITh Thin Films with Plasmonic Metal/Dielectric Substrates." In CLEO: Applications and Technology. Optica Publishing Group, 2023. http://dx.doi.org/10.1364/cleo_at.2023.jtu2a.125.

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We studied effects of metal-dielectric substrates on photopolymerization of BITh monomer. We found that the rate of photopolymerization is getting higher if the monomer film is deposited on top of silver, gold, and lamellar structures.
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Hoyle, Charles E., Tsuyoshi Watanabe, and Joe B. Whitehead, Jr. "Photopolymerization of oriented monomeric liquid crystals." In SPIE/IS&T 1992 Symposium on Electronic Imaging: Science and Technology, edited by Paul S. Drzaic and Uzi Efron. SPIE, 1992. http://dx.doi.org/10.1117/12.60390.

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Krongayz, Vadim V., and E. R. Schmelzer. "Peculiarities of anisotropic photopolymerization in films." In San Diego, '91, San Diego, CA, edited by Roger A. Lessard. SPIE, 1991. http://dx.doi.org/10.1117/12.50685.

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Baldacchini, Tommaso, Huzhen Chen, Richard Farrer, et al. "Multiphoton photopolymerization with a Ti:sapphire oscillator." In High-Power Lasers and Applications, edited by Glenn S. Edwards, Joseph Neev, Andreas Ostendorf, and John C. Sutherland. SPIE, 2002. http://dx.doi.org/10.1117/12.461373.

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Diptanshu, Erik Young, Chao Ma, Suleiman Obeidat, Bo Pang, and Nick Kang. "Ceramic Additive Manufacturing Using VAT Photopolymerization." In ASME 2018 13th International Manufacturing Science and Engineering Conference. American Society of Mechanical Engineers, 2018. http://dx.doi.org/10.1115/msec2018-6389.

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The popularity of additive manufacturing for producing porous bio-ceramics using vat photopolymerization in the recent years has gained a lot of impetus due to its high resolution and low surface roughness. In this study, a commercial vat polymerization printer (Nobel Superfine, XYZprinting) was used to create green bodies using a ceramic suspension consisting of 10 vol.% of alumina particles in a photopolymerizable resin. Four different sizes of cubical green bodies were printed out. They were subjected to thermal processing which included de-binding to get rid of the polymer and thereafter s
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Croutxe-Barghorn, Celine, Olivier Soppera, and Daniel-Joseph Lougnot. "Microlens array fabrication through crosslinking photopolymerization." In Symposium on Micromachining and Microfabrication, edited by Sing H. Lee and J. Allen Cox. SPIE, 1999. http://dx.doi.org/10.1117/12.360531.

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